CN103450767A - Super-weather-resistant anti-fouling real stone paint - Google Patents

Super-weather-resistant anti-fouling real stone paint Download PDF

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Publication number
CN103450767A
CN103450767A CN 201310353613 CN201310353613A CN103450767A CN 103450767 A CN103450767 A CN 103450767A CN 201310353613 CN201310353613 CN 201310353613 CN 201310353613 A CN201310353613 A CN 201310353613A CN 103450767 A CN103450767 A CN 103450767A
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China
Prior art keywords
weather
resistance
paint
water
super
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Pending
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CN 201310353613
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Chinese (zh)
Inventor
董善刚
祝洒虎
王伯凤
刘永屏
李春波
张喆
殷晓燕
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Qingdao Yiqun Paint Industry Group Co Ltd
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Qingdao Yiqun Paint Industry Group Co Ltd
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Priority to CN 201310353613 priority Critical patent/CN103450767A/en
Publication of CN103450767A publication Critical patent/CN103450767A/en
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Abstract

The invention relates to super-weather-resistant anti-fouling real stone paint which comprises the following specific components in percentage by weight: 5-10% of water, 10-18% of hydroxyethyl cellulose solution, 0.1-0.2% of bactericide, 0.2-0.3% of defoaming agent, 0.1-0.2% of stain resistant assistant, 50-60% of natural quartz sand of various colors, 6-13% of bentonite, 18-25% of silicone-acrylate emulsion, 0.3-0.9% of film-forming assistant, 0.2-0.6% of thickening agent and a right amount of ammonia water. The paint has decoration effect of granite, and has the advantages of light weight, low peeling possibility, high safety and reliability, low construction difficulty and the like; the paint is super high in weather resistance, excellent in stain resistance, favorable in water resistance and alkali resistance and good in water whitening resistance and yellowing resistance; and the paint is super high in adhesive force, high in hardness and resistant to scratching and scrubbing. Besides, the paint is environment-friendly, non-toxic and pollution-free.

Description

The true mineral varnish of super weather-proof anti-soil
Technical field the present invention relates to a kind of coating, particularly a kind of protection for the skin surface and decoration, and the long-lived coating with artificial granite, marbling effect, belong to the chemistry painting industry technical field.
Background technology natural marble cost is high, and density is large, increases the weight of buildings, also has the danger come off from body of wall.Outside the building metope wall application natural real stone paint amount is larger for construction market at present, aesthetic appearance is decorated look different, but different quality problems often occur, the whiting of especially growing dim, weathering resistance and contamination resistance are poor, therefore study super true mineral varnish weather-proof, antifouling property particularly necessary.
Summary of the invention the purpose of this invention is to provide the true mineral varnish of a kind of super weather-proof anti-soil, can copy various marble grain lattice, and image is naturally true to nature, for the decorative paint of building wall.This coating had both had the decorative effect of grouan, had again more difficult drop-off of light weight, safe and reliable, the advantages such as easy construction; Have more superpower weathering resistance, contamination resistance is splendid, water-fast, alkaline resistance properties is good, water-fast white, yellowing resistance is good; Sticking power is extremely strong, and hardness is high, anti-delineation, scrubbing resistance.Environment-protecting asepsis, nuisanceless.
Concrete component and the part by weight of the true mineral varnish of super weather-proof anti-soil are: water: 5-10%; Hydroxy ethyl fiber cellulose solution: 10-18%; Sterilant: 0.1-0.2%; Defoamer: 0.2-0.3%; Stain resistant auxiliary agent: 0.1-0.2%; Natural siliceous sand of all kinds: 50-60%; Wilkinite: 6-13%; Organosilicon crylic acid latex: 18-25%; Film coalescence aid: 0.3-0.9%; Thickening material 0.2-0.6%; Proper ammonia.
The natural colorful quartz sand that the present invention uses, be that the natural crystal pulverizing forms, epigranular, be important industrial mineral raw material, quartz sand is a kind of silicate minerals of hard, wear-resisting, stable chemical performance, and its essential mineral composition is SiO2, the color of quartz sand is oyster white or colourless translucent, hardness 7, property is crisp without cleavage, conchoidal fracture, oily luster, density is 2.65, tap density (the 1-20 order is that 1.6,20-200 order is 1.5).Natural siliceous sand asepsis environment-protecting, nuisanceless, can customize colourful color according to customer demand, and the preparation of order number is various, meticulous combination can meet different decoration requirements, make well-rounded floral designs, there is superior weathering resistance simultaneously, ornamental fabulous.
Hydroxy ethyl fiber cellulose solution used in the present invention, have flow adjustment preferably, and dispersed protective colloid ability is the strongest.
Organosilicon crylic acid latex used in the present invention is base-material, and organosilicon crylic acid latex is that organosilane monomer and the acrylic monomer that will contain unsaturated link(age) add suitable auxiliary agent, by nucleocapsid, coats the emulsion that polymerization technique is polymerized.Combine organosilicon fire-resistant, weathering resistance, chemical-resistant, high tint retention, snappiness, the tack that is difficult for contaminative and acrylic resin can be hanged down in hydrophobic, surface.A kind of high weather-proof, high water-fast, resistant to pollution emulsion and coating for environment-friendly type building.Organosilicon crylic acid latex, also have water resistant Bai Xingqiang, and contamination resistance is strong, has excellent weathering resistance simultaneously, is particularly suitable for sandy paint.
Thickening material used in the present invention is alkali swelling class thickening material, has larger thixotropy.
Production technique of the present invention: first mixed at normal temperatures by above-mentioned weight ratio, add water, hydroxy ethyl fiber cellulose solution, sterilant, defoamer, stain resistant auxiliary agent under stirring at low speed, add successively natural siliceous sand of all kinds, wilkinite after stirring, after stirring at low speed 30 minutes, after adding successively again organosilicon crylic acid latex, film coalescence aid, thickening material to meet the requirements of viscosity after confirming evenly and stirring, the appropriate ammoniacal liquor conditioning agent that adds, then through check, the packing of weighing.
The objective of the invention is to utilize the height of organosilicon crylic acid latex weather-proof, high water-fast, resistant to pollution chemical-resistant, high tint retention, snappiness, the tack that is difficult for contaminative and acrylic resin can be hanged down in hydrophobic, surface, act in the true mineral varnish system of this super weather-proof anti-soil, by the quartz sand silicate minerals, implant, make the reality mineral varnish form paint vehicle hard, wear-resisting, stable chemical performance, protect the light tint retention fabulous, can for a long time effectively keep the magnificent outward appearance of coating.
In general, the good weatherability of true mineral varnish, expressive force is abundant, has been widely used in indoor and outdoor brick wall, concrete, cement wall and the various heat-insulation system performance application of building, effective, liked by the people.
Below embodiment, be one embodiment of the present of invention.
The true mineral varnish of super weather-proof anti-soil of the present invention forms (weight percent) and production technique is:
400 revolutions per seconds of agitation phases of low speed add 6% water according to order, 13.8% hydroxy ethyl fiber cellulose solution, 0.2% sterilant, 0.3% defoamer, 0.2% stain resistant auxiliary agent, after 600 turn and stir, stirring at low speed adds 25% natural siliceous sand Snow Flower White (80-120 order) successively, 5% natural siliceous sand emerald green (40-80 order), 13% natural siliceous sand nine rare red (40-80 order), 8% China Dark (20-40 order), 8% wilkinite, low speed 400 turned stirring after 30 minutes again, add successively 20% organosilicon crylic acid latex, 0.5% film coalescence aid, 600 turn lower stirring 5 minutes.After thickening material meets the requirements of viscosity and stirs, add in right amount the ammoniacal liquor conditioning agent, then through check, the packing of weighing.
Its indices of the true mineral varnish of super weather-proof anti-soil of making according to the present invention all reaches the technical requirements of rower about the sandy paint defined, and both there is the decorative effect of grouan, also can customize colourful color according to customer demand, the preparation of order number is various, meticulous combination can meet different decoration requirements, produces well-rounded picture case.The true mineral varnish of this super weather-proof anti-soil according to superpower weathering resistance, splendid contamination resistance, good water-fast, alkaline resistance properties and water-fast white, yellowing resistance is good, has formed paint vehicle hard, wear-resisting, stable chemical performance.Have lightweight, do not come off, the advantage such as safe and reliable, easy construction.There is again the light of guarantor tint retention good, can for a long time effectively keep the magnificent outward appearance of coating, ornamental fabulous.This coating environment-protecting asepsis, nuisanceless.Customer response is good.

Claims (6)

1. concrete component and the part by weight of the true mineral varnish of super weather-proof anti-soil are: water: 5-10%; Hydroxy ethyl fiber cellulose solution: 10-18%; Sterilant: 0.1-0.2%; Defoamer: 0.2-0.3%; Stain resistant auxiliary agent: 0.1-0.2%; ; Natural siliceous sand of all kinds: 50-60%; Wilkinite: 6-13%; Organosilicon crylic acid latex: 18-25%; Film coalescence aid: 0.3-0.9%; Thickening material 0.2-0.6%; Proper ammonia.
2. the true mineral varnish of super weather-proof anti-soil according to claim 1, it is characterized in that this elastic coating production stage is: first mixed at normal temperatures by above-mentioned weight ratio, add water, hydroxy ethyl fiber cellulose solution, sterilant, defoamer, stain resistant auxiliary agent under stirring at low speed, add successively natural siliceous sand of all kinds, wilkinite after stirring, after stirring at low speed 30 minutes, after adding successively again organosilicon crylic acid latex, film coalescence aid, thickening material to meet the requirements of viscosity after confirming evenly and stirring, the appropriate ammoniacal liquor conditioning agent that adds, then through check, the packing of weighing.
3. the true mineral varnish of super weather-proof anti-soil according to claim 1, is characterized in that said organosilicon crylic acid latex, is a kind of high weather-proof, high water-fast, resistant to pollution emulsion and coating for environment-friendly type building.Have water resistant Bai Xingqiang, contamination resistance is strong, has excellent weathering resistance simultaneously, is particularly suitable for sandy paint.
4. the true mineral varnish of super weather-proof anti-soil according to claim 1, is characterized in that said hydroxy ethyl fiber cellulose solution, has flow adjustment preferably, and dispersed protective colloid ability is the strongest.
5. the true mineral varnish of super weather-proof anti-soil according to claim 1, is characterized in that said natural colorful quartz sand, is that natural crystal is pulverized and to be formed, and epigranular is also a kind of silicate minerals of hard, wear-resisting, stable chemical performance.Asepsis environment-protecting, nuisanceless, pattern is rich and varied, and the preparation of order number flexibly, has superior weathering resistance, ornamental fabulous.
6. the true mineral varnish of super weather-proof anti-soil according to claim 1, is characterized in that said thickening material is alkali swelling class thickening material, has larger thixotropy.
CN 201310353613 2013-08-14 2013-08-14 Super-weather-resistant anti-fouling real stone paint Pending CN103450767A (en)

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103723951A (en) * 2013-12-27 2014-04-16 三棵树涂料股份有限公司 Environment-friendly dry powder type real stone paint and preparation method and using method thereof
CN104291738A (en) * 2014-09-26 2015-01-21 无锡七点建材有限公司 Weather-resistant fireproof waterproof really stone paint and preparation method thereof
CN104327737A (en) * 2014-11-24 2015-02-04 谢锋 Hard stone-like paint
CN104446180A (en) * 2014-11-04 2015-03-25 南京福臻再生资源科技股份有限公司 Self-cleaning type real stone lacquer and preparation method thereof
CN104694003A (en) * 2015-03-17 2015-06-10 高飞 Anti-fouling waterproof stone-like coating
CN104962140A (en) * 2015-04-23 2015-10-07 昆山联合环保涂料有限公司 Coral sand stone-like coating and preparation method thereof
CN105949911A (en) * 2016-05-11 2016-09-21 济宁赛德丽新材料有限公司 Nano self-cleaning type stone-like coating and preparation method thereof
CN106381037A (en) * 2016-08-31 2017-02-08 铃鹿复合建材(上海)有限公司 Finishing-free texture paint and preparation method thereof
CN106946504A (en) * 2017-04-22 2017-07-14 青岛金绮丽涂料股份有限公司 A kind of true mineral varnish of pottery sand and preparation method thereof
CN106957159A (en) * 2017-04-22 2017-07-18 青岛金绮丽涂料股份有限公司 Super-weather-resistanti-fouling anti-fouling real stone paint
CN106967344A (en) * 2017-04-22 2017-07-21 青岛金绮丽涂料股份有限公司 A kind of colorful true mineral varnish of enhanced water resistance
CN107857511A (en) * 2017-11-13 2018-03-30 鳄鱼制漆(上海)有限公司 A kind of weather-proof batch of scratch-type natural real stone paint of organosilicon and preparation method thereof
CN109321072A (en) * 2018-10-18 2019-02-12 扬州中涂科技集团有限公司 A kind of aqueous liquid two-component granite and marble paint of baked wheaten cake face type
CN110183924A (en) * 2019-07-13 2019-08-30 安徽星光标识***有限公司 Imitation marble paint and preparation method thereof
CN111620602A (en) * 2020-05-30 2020-09-04 湖北美利佳涂料有限公司 Real stone paint coating and preparation method thereof
CN112680040A (en) * 2020-12-07 2021-04-20 北京三棵树新材料科技有限公司 Ceramic real stone paint environment-friendly coating

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103723951A (en) * 2013-12-27 2014-04-16 三棵树涂料股份有限公司 Environment-friendly dry powder type real stone paint and preparation method and using method thereof
CN103723951B (en) * 2013-12-27 2016-01-27 三棵树涂料股份有限公司 Environment-friendlydry dry powder type real stone paint and preparation method thereof and using method
CN104291738A (en) * 2014-09-26 2015-01-21 无锡七点建材有限公司 Weather-resistant fireproof waterproof really stone paint and preparation method thereof
CN104446180A (en) * 2014-11-04 2015-03-25 南京福臻再生资源科技股份有限公司 Self-cleaning type real stone lacquer and preparation method thereof
CN104327737A (en) * 2014-11-24 2015-02-04 谢锋 Hard stone-like paint
CN104694003A (en) * 2015-03-17 2015-06-10 高飞 Anti-fouling waterproof stone-like coating
CN104962140A (en) * 2015-04-23 2015-10-07 昆山联合环保涂料有限公司 Coral sand stone-like coating and preparation method thereof
CN105949911A (en) * 2016-05-11 2016-09-21 济宁赛德丽新材料有限公司 Nano self-cleaning type stone-like coating and preparation method thereof
CN106381037A (en) * 2016-08-31 2017-02-08 铃鹿复合建材(上海)有限公司 Finishing-free texture paint and preparation method thereof
CN106946504A (en) * 2017-04-22 2017-07-14 青岛金绮丽涂料股份有限公司 A kind of true mineral varnish of pottery sand and preparation method thereof
CN106957159A (en) * 2017-04-22 2017-07-18 青岛金绮丽涂料股份有限公司 Super-weather-resistanti-fouling anti-fouling real stone paint
CN106967344A (en) * 2017-04-22 2017-07-21 青岛金绮丽涂料股份有限公司 A kind of colorful true mineral varnish of enhanced water resistance
CN107857511A (en) * 2017-11-13 2018-03-30 鳄鱼制漆(上海)有限公司 A kind of weather-proof batch of scratch-type natural real stone paint of organosilicon and preparation method thereof
CN109321072A (en) * 2018-10-18 2019-02-12 扬州中涂科技集团有限公司 A kind of aqueous liquid two-component granite and marble paint of baked wheaten cake face type
CN110183924A (en) * 2019-07-13 2019-08-30 安徽星光标识***有限公司 Imitation marble paint and preparation method thereof
CN111620602A (en) * 2020-05-30 2020-09-04 湖北美利佳涂料有限公司 Real stone paint coating and preparation method thereof
CN112680040A (en) * 2020-12-07 2021-04-20 北京三棵树新材料科技有限公司 Ceramic real stone paint environment-friendly coating

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Application publication date: 20131218

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