CN104910709A - Antistatic water-based oil polish and preparation method thereof - Google Patents
Antistatic water-based oil polish and preparation method thereof Download PDFInfo
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- CN104910709A CN104910709A CN201510329982.3A CN201510329982A CN104910709A CN 104910709 A CN104910709 A CN 104910709A CN 201510329982 A CN201510329982 A CN 201510329982A CN 104910709 A CN104910709 A CN 104910709A
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Abstract
The invention discloses an antistatic water-based oil polish. The invention is characterized in that the oil polish is prepared from the following raw materials in parts by weight: 60-80 parts of modified styrene-acrylic emulsion, 1-2 parts of hydroxypropylguar gum, 0.3-0.5 part of polyglycol oleate, 0.3-0.5 part of castor oil polyethenoxy ether, 3-5 parts of polyethylene wax emulsion, 1-2 parts of peanut protein, 0.1-0.2 part of amine lauramidopropyloxide, 0.1-0.2 part of sodium benzoate and 10-15 parts of water. The water-based oil polish has the advantages of favorable hardness, favorable wear resistance, favorable impact resistance, water resistance, excellent corrosion resistance, favorable antistatic performance, higher service performance and higher operational safety.
Description
Technical field
The present invention relates to printing processing technology, be specifically related to a kind of anti-electrostatic water lustering oil and preparation method thereof.
Background technology
In recent years, along with the progress of economy and living standards of the people improve constantly, the specification of quality of printed matter and the environmental requirement of Printing industry are improved constantly.On only Printing industry apply one of maximum technique, be an indispensable part in Printing industry, it is imperative to develop it and improve.Oil polish is a kind of colourless, transparent or semitransparent ink, upper smooth time by being covered with one deck oil polish at printed matter surface, form transparent optical bright layers in conjunction with subsequent technique at printed matter surface, to reach the effect of decoration and protection printed matter.Solvent evaporates not only contaminate environment in traditional solvent-borne type oil polish glazing operation; also certain infringement is produced to HUMAN HEALTH; be difficult to reach the standard-required of the health of increasingly stringent, environmental protection, labour protection; therefore environment-friendly aqueous oil polish is more and more paid attention to, and has good development prospect and market potential.The existing problem of water lustering oil mainly comprises price and the over-all properties of product, and the greatest problem that wherein product performance exist improves the weathering resistance of product, as wear resistance, water tolerance etc.
Summary of the invention
The object of this invention is to provide a kind of anti-electrostatic water lustering oil, mechanical property is high, and antistatic performance is good.
The present invention is achieved by the following technical solutions:
A kind of anti-electrostatic water lustering oil, it is obtained by the raw material of following weight parts:
Modifying cinepazid emulsion 60-80, hydroxypropylguar gum 1-2, Polyethylene Glycol Oleate 0.3-0.5, castor oil polyoxyethylene ether 0.3-0.5, polythene wax emulsion 3-5, Semen arachidis hypogaeae protein 1-2, dodecanamide propyl amine oxide 0.1-0.2, Sodium Benzoate 0.1-0.2, water 10-15;
Wherein modifying cinepazid emulsion is made up of the raw material of following weight part:
Vinylbenzene 40-50, butyl acrylate 40-50, vinylformic acid 3-4, methyl methacrylate 10-15, sodium lauryl sulphate 3-4, emulsifier op-10 1-1.5, titanate coupling agent TMC-311W 1-2, sodium bicarbonate 4-6, initiator A PS 3-4, water 80-100;
Wherein the preparation method of modifying cinepazid emulsion is:
By sodium lauryl sulphate and emulsifier op-10 soluble in water, obtain pre-reaction liquid; The pre-reaction liquid getting 3/5-4/5 weight part adds vinylbenzene, butyl acrylate, vinylformic acid and methyl methacrylate high-speed stirring 20-30min, obtains reaction solution A; The pre-reaction liquid of surplus is mixed with sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W and 60-70 DEG C stir 10-15min, obtain reaction solution B; Reaction solution B is slowly added dropwise to reaction solution A under 70-80 DEG C of condition, insulation reaction 2-4h, after cooling by pH regulator to 7-8, after filtration and get final product.
A preparation method for anti-electrostatic water lustering oil, comprises the following steps:
(1) raw material is taken by weight, first hydroxypropylguar gum and Sodium Benzoate are added to the water heated and stirred until dissolve completely, add Semen arachidis hypogaeae protein 600-800r/min after cooling and stir 2-4h, filter and in filtrate, add Polyethylene Glycol Oleate, castor oil polyoxyethylene ether and dodecanamide propyl amine oxide 1200-1500r/min and stir 15-30min, finally add polythene wax emulsion to mix, obtain aqueous promoter;
(2) aqueous promoter obtained in (1) and modifying cinepazid emulsion are jointly added in reactor, high-speed stirring 0.5-1h, filtration, packing, obtain anti-electrostatic water lustering oil.
Advantage of the present invention is:
1. by titanate coupling agent modified benzene emulsion, improve the defect of water lustering oil mechanical property and weathering resistance, add the film-forming properties that Semen arachidis hypogaeae protein improves oil polish simultaneously, oil polish film is made both to have had good hardness, wear resistance, shock-resistance, water tolerance, corrosion resistance nature are superior, and have good tensile property and glossiness, make product have good antistatic performance simultaneously, improve the use properties of product, improve the security of operation;
2. production and use procedure safety non-toxic do harm to pollution-free, environmental protection.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of anti-electrostatic water lustering oil, is prepared from by the component raw material of following weight (kg):
Modifying cinepazid emulsion 70, hydroxypropylguar gum 1.5, Polyethylene Glycol Oleate 0.4, castor oil polyoxyethylene ether 0.4, polythene wax emulsion 4, Semen arachidis hypogaeae protein 1.5, dodecanamide propyl amine oxide 0.15, Sodium Benzoate 0.15, water 12;
Wherein modifying cinepazid emulsion is made up of the component raw material of following weight (kg):
Vinylbenzene 45, butyl acrylate 45, vinylformic acid 3, methyl methacrylate 12, sodium lauryl sulphate 4, emulsifier op-10 1.5, titanate coupling agent TMC-311W 1.5, sodium bicarbonate 5, initiator A PS 4, water 95;
Wherein the preparation method of modifying cinepazid emulsion is:
By sodium lauryl sulphate and emulsifier op-10 soluble in water, obtain pre-reaction liquid; The pre-reaction liquid getting 3/5 weight part adds vinylbenzene, butyl acrylate, vinylformic acid and methyl methacrylate high-speed stirring 30min, obtains reaction solution A; The pre-reaction liquid of surplus is mixed with sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W and 70 DEG C stir 10min, obtain reaction solution B; Reaction solution B is slowly added dropwise to reaction solution A under 80 DEG C of conditions, insulation reaction 2h, after cooling by pH regulator to 7-8, after filtration and get final product.
The preparation method of anti-electrostatic water lustering oil comprises the following steps:
(1) raw material is taken by weight, first hydroxypropylguar gum and Sodium Benzoate are added to the water heated and stirred until dissolve completely, add Semen arachidis hypogaeae protein 800r/min after cooling and stir 2h, filter and in filtrate, add Polyethylene Glycol Oleate, castor oil polyoxyethylene ether and dodecanamide propyl amine oxide 1500r/min and stir 15min, finally add polythene wax emulsion to mix, obtain aqueous promoter;
(2) aqueous promoter obtained in (1) and modifying cinepazid emulsion are jointly added in reactor, high-speed stirring 0.5h, filtration, packing, obtain anti-electrostatic water lustering oil.
Through inspection, above-mentioned obtained product performance are as follows:
Glossiness: 83;
Wear resistance: 1200 times;
Water-intake rate: 10.7%;
Stability in storage: 6 months constant.
Claims (2)
1. an anti-electrostatic water lustering oil, is characterized in that, it is obtained by the raw material of following weight parts:
Modifying cinepazid emulsion 60-80, hydroxypropylguar gum 1-2, Polyethylene Glycol Oleate 0.3-0.5, castor oil polyoxyethylene ether 0.3-0.5, polythene wax emulsion 3-5, Semen arachidis hypogaeae protein 1-2, dodecanamide propyl amine oxide 0.1-0.2, Sodium Benzoate 0.1-0.2, water 10-15;
Described modifying cinepazid emulsion is made up of the raw material of following weight part:
Vinylbenzene 40-50, butyl acrylate 40-50, vinylformic acid 3-4, methyl methacrylate 10-15, sodium lauryl sulphate 3-4, emulsifier op-10 1-1.5, titanate coupling agent TMC-311W 1-2, sodium bicarbonate 4-6, initiator A PS 3-4, water 80-100;
The preparation method of described modifying cinepazid emulsion is:
By sodium lauryl sulphate and emulsifier op-10 soluble in water, obtain pre-reaction liquid; The pre-reaction liquid getting 3/5-4/5 weight part adds vinylbenzene, butyl acrylate, vinylformic acid and methyl methacrylate high-speed stirring 20-30min, obtains reaction solution A; The pre-reaction liquid of surplus is mixed with sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W and 60-70 DEG C stir 10-15min, obtain reaction solution B; Reaction solution B is slowly added dropwise to reaction solution A under 70-80 DEG C of condition, insulation reaction 2-4h, after cooling by pH regulator to 7-8, after filtration and get final product.
2. the preparation method of a kind of anti-electrostatic water lustering oil according to claim 1, is characterized in that, comprise the following steps:
(1) raw material is taken by weight, first hydroxypropylguar gum and Sodium Benzoate are added to the water heated and stirred until dissolve completely, add Semen arachidis hypogaeae protein 600-800r/min after cooling and stir 2-4h, filter and in filtrate, add Polyethylene Glycol Oleate, castor oil polyoxyethylene ether and dodecanamide propyl amine oxide 1200-1500r/min and stir 15-30min, finally add polythene wax emulsion to mix, obtain aqueous promoter;
(2) aqueous promoter obtained in (1) and modifying cinepazid emulsion are jointly added in reactor, high-speed stirring 0.5-1h, filtration, packing, obtain anti-electrostatic water lustering oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510329982.3A CN104910709A (en) | 2015-06-16 | 2015-06-16 | Antistatic water-based oil polish and preparation method thereof |
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| CN201510329982.3A CN104910709A (en) | 2015-06-16 | 2015-06-16 | Antistatic water-based oil polish and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240833A (en) * | 2019-04-24 | 2019-09-17 | 杭州天龙油墨有限公司 | A kind of waterproof water lustering oil and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632022A (en) * | 2004-11-24 | 2005-06-29 | 广州电器科学研究院 | Aqueous buffing oil with shell/core structure |
-
2015
- 2015-06-16 CN CN201510329982.3A patent/CN104910709A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1632022A (en) * | 2004-11-24 | 2005-06-29 | 广州电器科学研究院 | Aqueous buffing oil with shell/core structure |
Non-Patent Citations (4)
| Title |
|---|
| 季根忠: "《应用化学实验教程》", 31 May 2015 * |
| 徐宝财等: "《洗涤剂配方设计6步》", 30 April 2010 * |
| 林宣益: "《涂料助剂》", 31 July 2006 * |
| 郑奕雄等: "《南方花生产业技术学》", 31 October 2009 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110240833A (en) * | 2019-04-24 | 2019-09-17 | 杭州天龙油墨有限公司 | A kind of waterproof water lustering oil and preparation method thereof |
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Application publication date: 20150916 |