CN110240833A - A kind of waterproof water lustering oil and preparation method thereof - Google Patents
A kind of waterproof water lustering oil and preparation method thereof Download PDFInfo
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- CN110240833A CN110240833A CN201910334717.2A CN201910334717A CN110240833A CN 110240833 A CN110240833 A CN 110240833A CN 201910334717 A CN201910334717 A CN 201910334717A CN 110240833 A CN110240833 A CN 110240833A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a kind of waterproof water lustering oils and preparation method thereof, it is formulated by the raw material of following parts by weight meter: being formulated by the raw material of following parts by weight meter: modifying cinepazid emulsion: 60-80 parts, ptfe emulsion: 8-12 parts, triethanolamine: 2-4 parts, sodium lauroyl sarcosine: 0.5-1 parts, Tripolyglycerol monostearates: 0.05-0.1 parts, sodium benzoate: 0.1-0.2 parts, peanut protein: 1-2 parts, linseed oil: 2-4 parts, dimethyl-silicon: 0.3-0.5 parts, water: 10-15 parts.Water lustering oil of the invention has good hardness, wearability, impact resistance, while film has excellent water resistance and corrosion resistance, and resist blocking and that, non-skid property are good.
Description
Technical field
The present invention relates to printing processing technique fields, and in particular to a kind of waterproof water lustering oil and preparation method thereof.
Background technique
In recent years, as economic progress and living standards of the people are continuously improved, quality requirement and printing to printed matter
The environmental requirement of industry is continuously improved.Glazing is printing industry using one of maximum technique, is indispensable in printing industry
A part, it is imperative to be developed and improved to it.Oil polish is a kind of colourless, transparent or semitransparent ink, glazing
When by being covered with one layer of oil polish in printed matter surface, transparent bright layer is formed in printed matter surface in conjunction with subsequent technique, to reach
To the effect for decorating and protecting printed matter.Environment is not only polluted in solvent volatilization in traditional solvent type oil polish glazing operation,
Also certain damage is generated to human health, it is difficult to reach increasingly strict health, the standard requirements of environmental protection, labour protection, because
This environment-friendly aqueous oil polish is more and more paid attention to, and has good development prospect and market potential.On aqueous
The existing problem of gloss oil mainly includes the price and comprehensive performance of product, and wherein greatest problem existing for properties of product is to improve to produce
The weatherability of product, such as wearability, water resistance.
Summary of the invention
It is an object of the invention to overcome the shortcomings of the prior art, and provide a kind of waterproof water lustering oil and its system
Preparation Method.
The object of the present invention is achieved by the following technical solutions: this waterproof water lustering oil, by following weight
The raw material of part meter is formulated: modifying cinepazid emulsion: 60-80 parts, ptfe emulsion: and 8-12 parts, triethanolamine: 2-4 parts,
Sodium lauroyl sarcosine: 0.5-1 parts, Tripolyglycerol monostearates: 0.05-0.1 parts, sodium benzoate: 0.1-0.2 parts, peanut
Albumen: 1-2 parts, linseed oil: 2-4 parts, dimethyl-silicon: 0.3-0.5 parts, water: 10-15 parts.
The modifying cinepazid emulsion is made from the following raw materials in parts by weight: styrene: 40-50 parts, butyl acrylate: 40-
50 parts, acrylic acid: 3-4 parts, methyl methacrylate: 10-15 parts, lauryl sodium sulfate: 3-4 parts, emulsifier op-10: 1-
1.5 parts, TMC-311W:1-2 parts of titanate coupling agent, sodium bicarbonate: 4-6 parts, PS:3-4 parts of initiator A, water: 80-100 parts.
This waterproof water lustering oil preparation process of the present invention, preparation process are as follows:
Step 1: weighing raw material by weight, and heating stirring in reaction kettle first is added until having dissolved in sodium benzoate and water
Entirely, peanut protein is added after cooling and being stirred with dispersion machine makes it be uniformly dispersed, rotating speed of agitator 600-800r/min,
Persistently being dispersed with stirring the time is 2-4h, filtrate is obtained by filtration, then by Tripolyglycerol monostearates, linseed oil and dimethyl
Silicone oil is uniformly mixed, and is added jointly in reaction kettle with filtrate and in 60-70 DEG C, rotating speed of agitator 1500-1800r/min, stirring
10-15min adds sodium lauroyl sarcosine, triethanolamine and ptfe emulsion with rotating speed of agitator 1200-1500r/
Min stirs 15-30min, obtains aqueous promoter;
Step 2: lauryl sodium sulfate and emulsifier op-10 is soluble in water, obtain pre-reaction liquid;Take 3/5-4/5 weight
Styrene, butyl acrylate, acrylic acid and methyl methacrylate high-speed stirred 20-30min is added in the pre-reaction liquid of part, obtains instead
Answer liquid A;Then the pre-reaction liquid of surplus and sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W are mixed and is incorporated in
60-70 DEG C of stirring 10-15min, obtains reaction solution B;Reaction solution B is slowly added dropwise into reaction solution A under the conditions of 70-80 DEG C again, is protected
Temperature reaction 2-4h, is adjusted to 7-8 for pH after cooling, up to modifying cinepazid emulsion after filtering;
Step 3: modifying cinepazid emulsion obtained in aqueous promoter obtained in step 1 and step 2 is added instead jointly
It answers in kettle, high-speed stirred 0.5-1h, filtering dispenses to get waterproof water lustering oil.
The invention has the benefit that improving the defect of water lustering oil mechanical performance and weatherability, peanut egg is added
The white film forming for improving oil polish, making oil polish film both has good hardness, wearability, impact resistance, water resistance, resistance to
Corrosive nature is superior, and has good tensile property and glossiness, moreover it is possible to film be made to have excellent water resistance and corrosion-resistant
Property, resist blocking and that, non-skid property are good;Furthermore safe and non-toxic pollution-free, environmentally protective in the production and use process.
Specific embodiment
Below in conjunction with embodiment, the present invention will be described in detail:
Embodiment: a kind of waterproof water lustering oil is formulated by the raw material of following parts by weight meter: modifying cinepazid emulsion:
70 parts, ptfe emulsion: 10 parts, triethanolamine: 3 parts, sodium lauroyl sarcosine: 0.8 part, trimerization glycerol monostearate
Ester: 0.08 part, sodium benzoate: 0.15 part, peanut protein: 1.5 parts, linseed oil: 3 parts, dimethyl-silicon: 0.4 part, water: 12 parts;
Wherein modifying cinepazid emulsion is made from the following raw materials in parts by weight: styrene: 45 parts, butyl acrylate: and 45 parts, acrylic acid: 3
Part, methyl methacrylate: 12 parts, lauryl sodium sulfate: 4 parts, emulsifier op-10: 1.5 parts, titanate coupling agent TMC-
311W:1-2 parts, sodium bicarbonate: 5 parts, PS:4 parts of initiator A, water: 95 parts.
Preparation method:
Step 1: weighing raw material by weight, and heating stirring in reaction kettle first is added until having dissolved in sodium benzoate and water
Entirely, peanut protein is added after cooling and being stirred with dispersion machine makes it be uniformly dispersed, rotating speed of agitator 800r/min, continues
Being dispersed with stirring the time is 2h, and filtrate is obtained by filtration, then mixes Tripolyglycerol monostearates, linseed oil and dimethicone
It closes uniformly, be added jointly with filtrate in reaction kettle and add the moon in 70 DEG C, rotating speed of agitator 1500r/min, stirring 10min
Osmanthus acylsarcosine sodium, triethanolamine and ptfe emulsion stir 15min with rotating speed of agitator 1500r/min, obtain aqueous help
Agent;
Step 2: lauryl sodium sulfate and emulsifier op-10 is soluble in water, obtain pre-reaction liquid;Take 3/5 parts by weight
Styrene, butyl acrylate, acrylic acid and methyl methacrylate high-speed stirred 30min is added in pre-reaction liquid, obtains reaction solution A;
Then the pre-reaction liquid of surplus and sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W are mixed and is incorporated in 70 DEG C of stirrings
10min obtains reaction solution B;Reaction solution B is slowly added dropwise under the conditions of 80 DEG C again into reaction solution A, insulation reaction 2h, it will after cooling
PH is adjusted to 7-8, up to modifying cinepazid emulsion after filtering;
Step 3: modifying cinepazid emulsion obtained in aqueous promoter obtained in step 1 and step 2 is added instead jointly
It answers in kettle, high-speed stirred 0.5h, filtering dispenses to get waterproof water lustering oil.
Through examining, properties of product obtained above are as follows:
Glossiness: 85;
Wearability: 1400 times;
Water absorption rate: 7.8%;
Storage stability: 6 months constant.
Above embodiments are used for illustrative purposes only, rather than limitation of the present invention, other any without departing from this hair
Modification, equivalent variations, modification, substitution, the combination made under bright spiritual essence and principle still fall within protection model of the invention
Within enclosing.
It is understood that it will be understood by those skilled in the art that being subject to technical solution of the present invention and inventive concept
It all should fall within the scope of protection of the appended claims of the present invention with replacement or change.
Claims (3)
1. a kind of waterproof water lustering oil, it is characterised in that: be formulated by the raw material of following parts by weight meter: modifying cinepazid cream
Liquid: 60-80 parts, ptfe emulsion: 8-12 parts, triethanolamine: 2-4 parts, sodium lauroyl sarcosine: 0.5-1 parts, trimerization is sweet
Oily monostearate: 0.05-0.1 parts, sodium benzoate: 0.1-0.2 parts, peanut protein: 1-2 parts, linseed oil: 2-4 parts, diformazan
Base silicon: 0.3-0.5 parts, water: 10-15 parts.
2. waterproof water lustering oil according to claim 1, it is characterised in that: the modifying cinepazid emulsion is by following weight
The raw material of part meter is made: styrene: 40-50 parts, butyl acrylate: and 40-50 parts, acrylic acid: 3-4 parts, methyl methacrylate:
10-15 parts, lauryl sodium sulfate: 3-4 parts, emulsifier op-10: 1-1.5 parts, TMC-311W:1-2 parts of titanate coupling agent,
Sodium bicarbonate: 4-6 parts, PS:3-4 parts of initiator A, water: 80-100 parts.
3. a kind of method for preparing waterproof water lustering oil as described in claim 1, is characterized in that, preparation process is as follows:
Step 1: weighing raw material by weight, and it is cold up to dissolving completely that heating stirring in reaction kettle first is added in sodium benzoate and water
But peanut protein is added afterwards and being stirred with dispersion machine makes it be uniformly dispersed, rotating speed of agitator 600-800r/min, continues
Being dispersed with stirring the time is 2-4h, filtrate is obtained by filtration, then by Tripolyglycerol monostearates, linseed oil and dimethicone
It is uniformly mixed, is added jointly with filtrate in reaction kettle and in 60-70 DEG C, rotating speed of agitator 1500-1800r/min, stirring 10-
15min adds sodium lauroyl sarcosine, triethanolamine and ptfe emulsion with rotating speed of agitator 1200-1500r/min
15-30min is stirred, aqueous promoter is obtained;
Step 2: lauryl sodium sulfate and emulsifier op-10 is soluble in water, obtain pre-reaction liquid;Take 3/5-4/5 parts by weight
Styrene, butyl acrylate, acrylic acid and methyl methacrylate high-speed stirred 20-30min is added in pre-reaction liquid, obtains reaction solution
A;Then the pre-reaction liquid of surplus and sodium bicarbonate, initiator A PS, titanate coupling agent TMC-311W are mixed and is incorporated in 60-70
DEG C stirring 10-15min, obtain reaction solution B;Reaction solution B is slowly added dropwise into reaction solution A, insulation reaction under the conditions of 70-80 DEG C again
PH is adjusted to 7-8 after cooling by 2-4h, up to modifying cinepazid emulsion after filtering;
Step 3: reaction kettle is added in modifying cinepazid emulsion obtained in aqueous promoter obtained in step 1 and step 2 jointly
In, high-speed stirred 0.5-1h, filtering dispenses to get waterproof water lustering oil.
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CN201910334717.2A CN110240833A (en) | 2019-04-24 | 2019-04-24 | A kind of waterproof water lustering oil and preparation method thereof |
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CN201910334717.2A CN110240833A (en) | 2019-04-24 | 2019-04-24 | A kind of waterproof water lustering oil and preparation method thereof |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104910709A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | Antistatic water-based oil polish and preparation method thereof |
CN104910707A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | Waterproof water-based varnish and preparation method thereof |
CN104910712A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | High-gloss water-based gloss oil and preparation method thereof |
CN104910705A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | High-wear-resistance water-based oil polish and preparation method thereof |
-
2019
- 2019-04-24 CN CN201910334717.2A patent/CN110240833A/en not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104910709A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | Antistatic water-based oil polish and preparation method thereof |
CN104910707A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | Waterproof water-based varnish and preparation method thereof |
CN104910712A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | High-gloss water-based gloss oil and preparation method thereof |
CN104910705A (en) * | 2015-06-16 | 2015-09-16 | 合肥启华环保科技有限公司 | High-wear-resistance water-based oil polish and preparation method thereof |
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Application publication date: 20190917 |