CN104871254A - 形成太阳能电池电极用的组成物及使用其所制的电极 - Google Patents
形成太阳能电池电极用的组成物及使用其所制的电极 Download PDFInfo
- Publication number
- CN104871254A CN104871254A CN201380068324.2A CN201380068324A CN104871254A CN 104871254 A CN104871254 A CN 104871254A CN 201380068324 A CN201380068324 A CN 201380068324A CN 104871254 A CN104871254 A CN 104871254A
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- Prior art keywords
- oxide
- electrode
- constituent
- solar battery
- silver
- Prior art date
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- 239000000203 mixture Substances 0.000 title abstract description 7
- 229910052709 silver Inorganic materials 0.000 claims abstract description 59
- 239000004332 silver Substances 0.000 claims abstract description 59
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000000470 constituent Substances 0.000 claims description 54
- 229910044991 metal oxide Inorganic materials 0.000 claims description 14
- 150000004706 metal oxides Chemical class 0.000 claims description 14
- -1 silver halide Chemical class 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
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- 239000000460 chlorine Substances 0.000 claims description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
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- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 3
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- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 3
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/062—Glass compositions containing silica with less than 40% silica by weight
- C03C3/07—Glass compositions containing silica with less than 40% silica by weight containing lead
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/122—Silica-free oxide glass compositions containing oxides of As, Sb, Bi, Mo, W, V, Te as glass formers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/16—Silica-free oxide glass compositions containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/16—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions with vehicle or suspending agents, e.g. slip
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/14—Conductive material dispersed in non-conductive inorganic material
- H01B1/16—Conductive material dispersed in non-conductive inorganic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/80—Constructional details
- H10K10/82—Electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
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- Materials Engineering (AREA)
- Organic Chemistry (AREA)
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- Condensed Matter Physics & Semiconductors (AREA)
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- Sustainable Development (AREA)
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- Spectroscopy & Molecular Physics (AREA)
- Photovoltaic Devices (AREA)
- Conductive Materials (AREA)
Abstract
Description
AgI | PbO | Bi2O3 | TeO2 | P2O5 | Li2CO3 | SiO2 | ZnO | WO3 | MgO | CeO2 | SrCO3 | MoO3 | TIO2 | SnO | In2O3 | |
实施例1 | 2 | - | 39 | 50 | - | 2 | 7 | - | - | - | - | - | - | - | - | - |
实施例2 | 5 | - | 40 | 50 | - | 2 | 3 | - | - | - | - | - | - | - | - | - |
实施例3 | 10 | - | 35 | 50 | - | 2 | 3 | - | - | - | - | - | - | - | - | - |
实施例4 | 20 | - | 30 | 40 | - | 2 | 8 | - | - | - | - | - | - | - | - | - |
实施例5 | 40 | - | - | 50 | - | 2 | 8 | - | - | - | - | - | - | - | - | - |
实施例6 | 2 | 40 | - | 50 | - | 2 | 6 | - | - | - | - | - | - | - | - | - |
实施例7 | 5 | 40 | - | 50 | - | 2 | 3 | - | - | - | - | - | - | - | - | - |
实施例8 | 10 | 35 | - | 50 | - | 2 | 3 | - | - | - | - | - | - | - | - | - |
实施例9 | 20 | 30 | - | 40 | - | 2 | 8 | - | - | - | - | - | - | - | - | - |
实施例10 | 30 | 25 | - | 35 | - | 2 | 8 | - | - | - | - | - | - | - | - | - |
实施例11 | 2 | 38 | - | 50 | 2 | 2 | - | 6 | - | - | - | - | - | - | - | - |
实施例12 | 5 | 27 | - | 50 | 7 | 2 | - | 9 | - | - | - | - | - | - | - | - |
实施例13 | 10 | 29 | - | 50 | 5 | 2 | - | 4 | - | - | - | - | - | - | - | - |
实施例14 | 20 | 29 | - | 40 | 3 | 2 | - | 6 | - | - | - | - | - | - | - | - |
实施例15 | 30 | 25 | - | 43 | 2 | - | - | - | - | - | - | - | - | - | - | |
实施例16 | 2 | - | 39 | 50 | - | 2 | 5 | 2 | - | - | - | - | - | - | - | - |
实施例17 | 5 | - | 40 | 50 | - | 2 | 2 | - | 1 | - | - | - | - | - | - | - |
AgI | PbO | Bi2O3 | TeO2 | P2O5 | Li2CO3 | SiO2 | ZnO | WO3 | MgO | CeO2 | SrCO3 | MoO3 | TiO2 | SnO | In2O3 | |
实施例18 | 10 | - | 35 | 50 | - | 2 | 2 | - | - | 1 | - | - | - | - | - | - |
实施例19 | 20 | - | 30 | 40 | - | 2 | 5 | - | - | - | - | - | 3 | - | - | - |
实施例20 | 30 | - | 25 | 35 | - | 2 | 5 | - | - | - | - | - | - | - | 3 | - |
实施例21 | 2 | 39 | 20 | 32 | - | 2 | 5 | - | - | - | - | - | - | - | - | - |
实施例22 | 5 | 40 | 40 | 11 | - | 2 | 2 | - | - | - | - | - | - | - | - | - |
实施例23 | 10 | 35 | 35 | 16 | - | 2 | 2 | - | - | - | - | - | - | - | - | - |
实施例24 | 20 | 30 | 30 | 13 | - | 2 | 5 | - | - | - | - | - | - | - | - | - |
实施例25 | 30 | 25 | 25 | 13 | - | 2 | 5 | - | - | - | - | - | - | - | - | - |
实施例26 | 2 | 40 | 20 | 21 | - | 5 | - | 12 | - | - | - | - | - | - | - | - |
实施例27 | 5 | 40 | 40 | 8 | - | 2 | - | 5 | - | - | - | - | - | - | - | - |
实施例28 | 10 | 35 | 35 | 9 | - | 2 | - | 9 | - | - | - | - | - | - | - | - |
实施例29 | 20 | 30 | 30 | 10 | - | 5 | - | 5 | - | - | - | - | - | - | - | - |
实施例30 | 30 | 25 | 25 | 6 | - | 3 | - | 11 | - | - | - | - | - | - | - | - |
实施例31 | 18 | - | 30 | 40 | - | 2 | 8 | - | - | - | - | - | - | - | - | 2 |
实施例32 | 18 | - | 30 | 40 | - | 2 | 8 | - | - | - | - | - | - | 2 | - | - |
比较例1 | - | - | 40 | 50 | - | 2 | 7 | 1 | - | - | - | - | - | - | - | - |
比较例2 | - | 25 | - | 60 | - | 2 | 8 | 5 | - | - | - | - | - | - | - | - |
元素银含量(摩尔%) | 元素银的含量(摩尔%) | ||
实施例1 | 1.09 | 实施例26 | 0.82 |
实施例2 | 2.88 | 实施例27 | 2.74 |
实施例3 | 5.12 | 实施例28 | 5.52 |
实施例4 | 10.44 | 实施例29 | 11.19 |
实施例5 | 19.16 | 实施例30 | 16.95 |
比较例1 | 0 | 比较例2 | 0 |
Claims (9)
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KR1020130152676A KR101802546B1 (ko) | 2012-12-29 | 2013-12-09 | 태양전지 전극 형성용 조성물 및 이로부터 제조된 전극 |
KR10-2013-0152676 | 2013-12-09 | ||
PCT/KR2013/011534 WO2014104623A1 (ko) | 2012-12-29 | 2013-12-12 | 태양전지 전극 형성용 조성물 및 이로부터 제조된 전극 |
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CN111354803A (zh) * | 2018-12-21 | 2020-06-30 | 三星Sdi株式会社 | 用于形成太阳能电池电极的方法及太阳能电池 |
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KR101991976B1 (ko) * | 2014-10-08 | 2019-06-24 | 삼성에스디아이 주식회사 | 태양전지 전극 형성용 조성물 및 이로부터 제조된 전극 |
JP6236557B1 (ja) | 2016-03-18 | 2017-11-22 | Dowaエレクトロニクス株式会社 | 銀テルル被覆ガラス粉およびその製造方法、ならびに導電性ペーストおよびその製造方法 |
US20170291846A1 (en) * | 2016-04-07 | 2017-10-12 | Heraeus Precious Metals North America Conshohocken Llc | Halogenide containing glasses in metallization pastes for silicon solar cells |
JP6246877B1 (ja) | 2016-09-08 | 2017-12-13 | Dowaエレクトロニクス株式会社 | 導電性ペーストおよびその製造方法、ならびに太陽電池の製造方法 |
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