CN104522050B - A kind of compound disinfectant and processing technology of Nano Silver and polyhexamethylene guanide - Google Patents
A kind of compound disinfectant and processing technology of Nano Silver and polyhexamethylene guanide Download PDFInfo
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- CN104522050B CN104522050B CN201510006862.XA CN201510006862A CN104522050B CN 104522050 B CN104522050 B CN 104522050B CN 201510006862 A CN201510006862 A CN 201510006862A CN 104522050 B CN104522050 B CN 104522050B
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- nano silver
- polyhexamethylene guanide
- ammonium
- polyhexamethylene
- compound disinfectant
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Abstract
The present invention relates to a kind of Nano Silver and the compound disinfectant and processing technology of polyhexamethylene guanide, the compound disinfectant is by Nano Silver, polyhexamethylene guanide, dispersant, stabilizer, complexing agent and water composition, the compound disinfectant is the aqueous solution, the mass ratio of Nano Silver and polyhexamethylene guanide is (1: 100) (1: 10000), Nano Silver and polyhexamethylene guanide gross mass account for the 1%~50% of total solution quality, dispersant accounts for the 0.1%~10% of total solution quality, stabilizer accounts for the 0.1%~10% of total solution quality, complexing agent accounts for the 1%~30% of total solution quality, its surplus of solution is water.Sterilization of high efficiency, cost are low.
Description
Technical field
The present invention relates to material chemistry technical field, and in particular to a kind of composite bactericidal of Nano Silver and polyhexamethylene guanide
Agent.
Background technology
Bactericide has organic bactericide and inorganic fungicide, and organic bactericide dosage is small, sterilization of high efficiency, but makes for a long time
With making mushroom be also easy to produce the resistance to the action of a drug, the usage amount of bactericide needs lasting increase, finally acted on less and less.Another weakness is
Organic bactericide easily fails, and the drug effect phase is short.Inorganic fungicide dosage is big, and germicidal efficiency is low, and toxicity is big.But inorganic sterilization
Often duration of efficacy is grown for agent, does not develop immunity to drugs, present polyhexamethylene guanide is very effective environment-friendly type organic bactericide
Agent, its toxicity is very low, human body is not damaged, but it there is also be also easy to produce the resistance to the action of a drug and duration of efficacy is short asks
Topic.Silver is close human metalloproteinase, silver salt bactericide because sterilizing rate is high, lasting medicine and it is welcome, but silver salt, which is oxidized form, to kill
Microbial inoculum, improper use easily produce injury to human body.
The content of the invention
The main object of the present invention is to provide a kind of compound disinfectant and processing technology of Nano Silver and polyhexamethylene guanide,
Sterilization of high efficiency, cost are low.
The technical solution adopted for the present invention to solve the technical problems is：
A kind of compound disinfectant of Nano Silver and polyhexamethylene guanide, the compound disinfectant is by Nano Silver, polyhexamethylene
Guanidine, dispersant, stabilizer, complexing agent and water composition, the compound disinfectant is the matter of the aqueous solution, Nano Silver and polyhexamethylene guanide
It is (1: 100)-(1: 10000) to measure ratio, and Nano Silver and polyhexamethylene guanide gross mass account for the 1%~50% of total solution quality, point
Powder accounts for the 0.1%~10% of total solution quality, and stabilizer accounts for the 0.1%~10% of total solution quality, and complexing agent accounts for total solution
The 1%~30% of quality, its surplus of solution are water.
Preferably, the particle size range of Nano Silver is 1 nanometer -100 nanometers；Polyhexamethylene guanide is：Polyhexamethylene hydrochloric acid
One or any several combinations according to arbitrary proportion in guanidine, polyhexamethylene phosphoguanidine or polyhexamethylene sulfuric acid guanidine.
Preferably, dispersant includes cationic surfactant and neutral surface active agent, and cationic surfactant is：
Eight alkyl bromination ammoniums, eight alkyl ammomium chlorides, ten alkyl bromination ammoniums, ten alkyl ammomium chlorides, dodecyl bromination ammonium, dodecyl chloride
Change ammonium, Tetra-n-decylammonium bromide, tetradecyl ammonium chloride, cetyl ammonium bromide, cetyl chloride ammonium, octadecyl bromination
Ammonium, octadecyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, dodecyl benzyl dimethyl ammonium chloride, myristyl
Dimethylbenzyl ammonium bromide, myristyl benzyl dimethyl ammonium chloride, cetyl dimethyl benzyl ammonium bromide, cetyl two
Methyl-benzyl ammonium chloride, octadecyl dimethyl benzyl ammonium bromide or one kind in stearyl dimethyl benzyl ammonium chloride or
Any several combinations according to arbitrary proportion；Neutral surface active agent includes：Triethanolamine, diethanol amine, monoethanolamine, poly- second
The more ammonium salts of alkene, polyoxyethylated alkyl alcohol, polyethenoxy alkylphenols, polyoxyethylated alkyl alcohol sulfuric ester sodium salt, OP (alkane
Base phenol polyethenoxy ether), one or any several combinations according to arbitrary proportion in tween or this Pan.
Preferably, stabilizer includes：Sodium Polyacrylate, dodecyl benzyl dimethyl ammonium chloride, acetamide or acyl in oneself
One or any several combinations according to arbitrary proportion in amine.
Preferably, complexing agent is amino acid, and it includes：Glycine, glutamic acid, lysine, serine, threonine, first sulphur
Propylhomoserin, phenylalanine, alanine, leucine, valine, isoleucine, proline, tryptophan, cysteine, aspartic acid,
One or any several combinations according to arbitrary proportion in arginine or histidine.
The present invention also provides a kind of compound disinfectant processing technology of Nano Silver and polyhexamethylene guanide, at room temperature, takes
The various raw materials of proportioning in above-mentioned technical proposal, polyhexamethylene guanide is dissolved in the water, and then adds dispersant, stably
Agent, complexing agent, stirring, Nano Silver is added after dissolving, is sufficiently stirred, is completely dispersed Nano Silver, filtered, obtain Nano Silver
With the composite bactericidal agent solution of polyhexamethylene guanide.
Implement technical scheme, have the advantages that：Nano Silver and polyhexamethylene provided by the invention
The compound disinfectant of guanidine, it is compound by Nano Silver and polyhexamethylene guanide, both germicidal efficiencies are enhanced significantly, and are reduced
Cost, is easy to popularize.Nano Silver and polyhexamethylene guanide compound disinfectant can use in medicine, daily life, also may be used
To treat domestic birds and animals disease of skin.
The skin disease external application liquid medicine such as tinea pedis, eczema is pharmaceutically may be used as, the medicament for the eyes for the treatment of keratitis, sty can be made
Water, it is also used as women's private parts washing liquid medicine.Skin disease caused by the fungal infections such as tinea pedis, eczema, belong to refractory illness, it is existing
There are aureomycin, chloramphenicol, Natamycin, TOB, fluoquinolone in conventional medicament for the eyes, drug effect is low, and the resistance to the action of a drug is strong, and drug effect is lasting
Time is short.Women's private parts washing medicine has clean your the moon, the clean, potassium permanganate of woman's inflammation etc., same problem be present.The fungies such as tinea pedis, eczema
Skin disease medication caused by infection has pungent compound thunder lock, the tincture of iodine, onychomycosis tincture, calamine, boric acid, triamcinolone, nitric acid Micon
Azoles, neomycinsulphate, compound Triamcinolone Acetonide, Da Kening, benzoic acid etc., these organic synthesis medicines are short not due to duration of efficacy
Easily thoroughly eradicate fungi.Polyhexamethylene guanide is polycation macromolecular electrolyte, and it can be adsorbed in skin surface with large area
Live germ cell membrane surface, and Nano Silver complexing more enhances its bactericidal effect thereon, and Nano Silver duration of efficacy length can
Thoroughly to eradicate fungi, Nano Silver and polyhexamethylene guanide compound disinfectant are efficient, lasting, safe bactericide.
Thimerosal, desinfactant detergent, dishwashing liquid, fruit detergent with sterilizing are may be used as in daily life, in daily life,
Swimming sterilizing agent.Although there is various bactericide, majority is oxidative bactericide, e.g., liquid chlorine, potassium permanganate, hydrogen peroxide,
Ozone, chloramines, chlorine dioxide, Peracetic acid, 84 thimerosals, formalin, lysol.During these conventional bactericide sterilizations pair
Environment has an impact, and has residual hazard after sterilization, is hazardous to the human body.When Nano Silver and polyhexamethylene guanide compound disinfectant use very
Gently, without residual hazard, duration of efficacy length, is more satisfactory bactericide.
The frequent skin infection disease of domestic birds and animals to poultry house, it is necessary to often carry out disinfection.Common drug has bromogeramine (season
Ammonium salt compounds), lysol (methylphenol), domiphen (Domiphen bromide), Peracetic acid, sodium dichloro cyanurate.These medicines
Product are all small molecules, and duration of efficacy is short, and drug effect is low, have pollution to environment, there is residual hazard.Nano Silver and polyhexamethylene guanide are answered
Close when bactericide uses as mild as a dove, without residual hazard, poultry do not injured, duration of efficacy length, environment is not polluted,
There is no residual hazard, be more satisfactory bactericide.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below and embodiment, the present invention is entered
Row is further described.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit
The fixed present invention.
A kind of compound disinfectant of Nano Silver and polyhexamethylene guanide, the compound disinfectant is by Nano Silver, polyhexamethylene
Guanidine, dispersant, stabilizer, complexing agent and water composition, the compound disinfectant is the matter of the aqueous solution, Nano Silver and polyhexamethylene guanide
It is (1: 100)-(1: 10000) to measure ratio, and Nano Silver and polyhexamethylene guanide gross mass account for the 1%~50% of total solution quality, point
Powder accounts for the 0.1%~10% of total solution quality, and stabilizer accounts for the 0.1%~10% of total solution quality, and complexing agent accounts for total solution
The 1%~30% of quality, its surplus of solution are water.
Preferably, the particle size range of Nano Silver is 1 nanometer -100 nanometers；Polyhexamethylene guanide is：Polyhexamethylene hydrochloric acid
One or any several combinations according to arbitrary proportion in guanidine, polyhexamethylene phosphoguanidine or polyhexamethylene sulfuric acid guanidine.
Preferably, dispersant includes cationic surfactant and neutral surface active agent, and cationic surfactant is：
Eight alkyl bromination ammoniums, eight alkyl ammomium chlorides, ten alkyl bromination ammoniums, ten alkyl ammomium chlorides, dodecyl bromination ammonium, dodecyl chloride
Change ammonium, Tetra-n-decylammonium bromide, tetradecyl ammonium chloride, cetyl ammonium bromide, cetyl chloride ammonium, octadecyl bromination
Ammonium, octadecyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, dodecyl benzyl dimethyl ammonium chloride, myristyl
Dimethylbenzyl ammonium bromide, myristyl benzyl dimethyl ammonium chloride, cetyl dimethyl benzyl ammonium bromide, cetyl two
Methyl-benzyl ammonium chloride, octadecyl dimethyl benzyl ammonium bromide or one kind in stearyl dimethyl benzyl ammonium chloride or
Any several combinations according to arbitrary proportion；Neutral surface active agent includes：Triethanolamine, diethanol amine, monoethanolamine, poly- second
The more ammonium salts of alkene, polyoxyethylated alkyl alcohol, polyethenoxy alkylphenols, polyoxyethylated alkyl alcohol sulfuric ester sodium salt, OP, tell
One or any several combinations according to arbitrary proportion in warm or this Pan.
Preferably, stabilizer includes：Sodium Polyacrylate, dodecyl benzyl dimethyl ammonium chloride, acetamide or acyl in oneself
One or any several combinations according to arbitrary proportion in amine.
Preferably, complexing agent is amino acid, and it includes：Glycine, glutamic acid, lysine, serine, threonine, first sulphur
Propylhomoserin, phenylalanine, alanine, leucine, valine, isoleucine, proline, tryptophan, cysteine, aspartic acid,
One or any several combinations according to arbitrary proportion in arginine or histidine.
The present invention also provides a kind of compound disinfectant processing technology of Nano Silver and polyhexamethylene guanide, at room temperature, takes
The various raw materials of proportioning in above-mentioned technical proposal, polyhexamethylene guanide is dissolved in the water, and then adds dispersant, stably
Agent, complexing agent, stirring, Nano Silver is added after dissolving, is sufficiently stirred, is completely dispersed Nano Silver, filtered, obtain Nano Silver
With the composite bactericidal agent solution of polyhexamethylene guanide.
Embodiment 1：
0.5 gram of Nano Silver, 10 grams of polyhexamethylene guanides, 1 gram of DTAB, 5 grams of acetamides, 10 grams it is sweet
Propylhomoserin, remaining be pharmaceutical grade purified water.Polyhexamethylene guanide is dissolved in water at room temperature, then adds trimethyl
Ammonium bromide, glycine and acetamide, are stirred evenly, and are eventually adding Nano Silver, are sufficiently stirred mixing, filtering.
Embodiment 2：
0.01 gram of Nano Silver, 20 grams of polyhexamethylene guanides, 2 grams of cetyl trimethylammonium bromides, 2 grams of Sodium Polyacrylates,
15 grams of glutamic acid, remaining be pharmaceutical grade purified water.Polyhexamethylene guanide is dissolved in water at room temperature, then adds cetyl
Trimethylammonium bromide, glutamic acid and Sodium Polyacrylate, are stirred evenly, and are eventually adding Nano Silver, are sufficiently stirred mixing, filtering.
Embodiment 3：
0.15 gram of Nano Silver, 18 grams of polyhexamethylene guanides, 3 grams of Tween 80s, 1 restrain oneself lactams, 20 grams of alanine, remaining be
Pharmaceutical grade purified water.Polyhexamethylene guanide is dissolved in water at room temperature, then adds Tween 80, alanine and caprolactam,
Stir evenly, be eventually adding Nano Silver, be sufficiently stirred mixing, filtering.
Embodiment 4：
0.0016 gram of Nano Silver, 21 grams of polyhexamethylene guanides, 2 grams of OP-10,5 grams of Sodium Polyacrylates, 16 grams of leucines, its
Remaining is pharmaceutical grade purified water.Polyhexamethylene guanide is dissolved in water at room temperature, then add Sodium Polyacrylate, leucine and
OP-10, stir evenly, be eventually adding Nano Silver, be sufficiently stirred mixing, filtering.
Embodiment 5：
0.8 gram of Nano Silver, 16 grams of polyhexamethylene guanides, 2 grams of this Pan 80,4 grams of dodecyl benzyl dimethyl ammonium chlorides, 18
Gram serine, remaining be pharmaceutical grade purified water.Polyhexamethylene guanide is dissolved in water at room temperature, then adds this Pan 80, silk
Propylhomoserin and dodecyl benzyl dimethyl ammonium chloride, are stirred evenly, and are eventually adding Nano Silver, are sufficiently stirred mixing, filtering.
Embodiment 6：
0.4 gram of Nano Silver, 23 grams of polyhexamethylene guanides, 2 grams of triethanolamines, 1 gram of acetamide, 20 grams of methionines, remaining
For pharmaceutical grade purified water.Polyhexamethylene guanide is dissolved in water at room temperature, then adds acetamide, methionine and three ethanol
Amine, stir evenly, be eventually adding Nano Silver, be sufficiently stirred mixing, filtering.
Presently preferred embodiments of the present invention is above are only above, is not intended to limit the invention, all essences in the present invention
All any modification, equivalent and improvement made within refreshing and principle etc., should be included in the scope of the protection.
Claims (6)
1. the compound disinfectant of a kind of Nano Silver and polyhexamethylene guanide, it is characterised in that the compound disinfectant is by Nano Silver, poly-
Hexa-methylene guanidine, dispersant, stabilizer, complexing agent and water composition, the compound disinfectant is the aqueous solution, Nano Silver and poly- six methylene
The mass ratio of base guanidine is (1: 100)-(1: 10000), Nano Silver and polyhexamethylene guanide gross mass account for total solution quality 1%~
50%, dispersant accounts for the 0.1%~10% of total solution quality, and stabilizer accounts for the 0.1%~10% of total solution quality, and complexing agent accounts for
The 1%~30% of total solution quality, its surplus of solution are water.
2. the compound disinfectant of Nano Silver as claimed in claim 1 and polyhexamethylene guanide, it is characterised in that
The particle size range of Nano Silver is 1 nanometer -100 nanometers；Polyhexamethylene guanide is：Polyhexamethylene guanidine hydrochloride, poly- six methylene
One or any several combinations according to arbitrary proportion in base phosphoguanidine or polyhexamethylene sulfuric acid guanidine.
3. the compound disinfectant of Nano Silver as claimed in claim 1 and polyhexamethylene guanide, it is characterised in that dispersant includes sun
Ionic surface active agent and neutral surface active agent, cationic surfactant are：Eight alkyl bromination ammoniums, eight alkyl ammomium chlorides,
Ten alkyl bromination ammoniums, ten alkyl ammomium chlorides, dodecyl bromination ammonium, lauryl ammonium chloride, Tetra-n-decylammonium bromide, the tetradecane
Ammonium chloride, cetyl ammonium bromide, cetyl chloride ammonium, octadecyl bromination ammonium, octadecyl ammonium chloride, dodecyl
Dimethylbenzyl ammonium bromide, dodecyl benzyl dimethyl ammonium chloride, tetradecyl dimethyl benzyl ammonium, myristyl two
Methyl-benzyl ammonium chloride, cetyl dimethyl benzyl ammonium bromide, cetalkonium chloride, hexadecyldimethylamine
One or any several combinations according to arbitrary proportion in base Benzylphosphonium Bromide ammonium or stearyl dimethyl benzyl ammonium chloride；
Neutral surface active agent includes：The more ammonium salts of triethanolamine, diethanol amine, monoethanolamine, polyethylene, polyoxyethylated alkyl alcohol,
It is one or any several in polyethenoxy alkylphenols, polyoxyethylated alkyl alcohol sulfuric ester sodium salt, OP, tween or this Pan
Plant the combination according to arbitrary proportion.
4. the compound disinfectant of Nano Silver as claimed in claim 1 and polyhexamethylene guanide, it is characterised in that stabilizer includes：
In Sodium Polyacrylate, dodecyl benzyl dimethyl ammonium chloride, acetamide or caprolactam it is one or any it is several according to
The combination of arbitrary proportion.
5. the compound disinfectant of Nano Silver as claimed in claim 1 and polyhexamethylene guanide, it is characterised in that complexing agent is amino
Acid, it includes：Glycine, glutamic acid, lysine, serine, threonine, methionine, phenylalanine, alanine, leucine,
One kind in valine, isoleucine, proline, tryptophan, cysteine, aspartic acid, arginine or histidine is appointed
Anticipate several combinations according to arbitrary proportion.
A kind of 6. compound disinfectant processing technology of Nano Silver and polyhexamethylene guanide, it is characterised in that at room temperature, weighting profit
It is required that the various raw materials of the proportioning in 1, polyhexamethylene guanide is dissolved in the water, dispersant, stabilizer, complexing are then added
Agent, stirring, Nano Silver is added after dissolving, is sufficiently stirred, is completely dispersed Nano Silver, filtered, obtain Nano Silver and poly- six
The composite bactericidal agent solution of methylene guanidine.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1729787A (en) * | 2005-08-08 | 2006-02-08 | 深圳清华大学研究院 | Liquid nanometer simple substance silver antibacterial agent and preparation method thereof |
| WO2006026026A2 (en) * | 2004-07-30 | 2006-03-09 | Acrymed, Inc. | Antimicrobial silver compositions |
| CN101341883A (en) * | 2008-08-13 | 2009-01-14 | 司徒健强 | Nano-silver antiseptic solution |
| CN102057961A (en) * | 2010-11-15 | 2011-05-18 | 赵正坤 | Air purifying composition and preparation method and use thereof |
| CN103817348A (en) * | 2014-03-21 | 2014-05-28 | 德华兔宝宝装饰新材股份有限公司 | Nano-silver aqueous solution and application method for applying nano-silver aqueous solution to technical wood |
-
2015
- 2015-01-07 CN CN201510006862.XA patent/CN104522050B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006026026A2 (en) * | 2004-07-30 | 2006-03-09 | Acrymed, Inc. | Antimicrobial silver compositions |
| CN1729787A (en) * | 2005-08-08 | 2006-02-08 | 深圳清华大学研究院 | Liquid nanometer simple substance silver antibacterial agent and preparation method thereof |
| CN101341883A (en) * | 2008-08-13 | 2009-01-14 | 司徒健强 | Nano-silver antiseptic solution |
| CN102057961A (en) * | 2010-11-15 | 2011-05-18 | 赵正坤 | Air purifying composition and preparation method and use thereof |
| CN103817348A (en) * | 2014-03-21 | 2014-05-28 | 德华兔宝宝装饰新材股份有限公司 | Nano-silver aqueous solution and application method for applying nano-silver aqueous solution to technical wood |
Non-Patent Citations (1)
| Title |
|---|
| 新型果蔬类消毒洗涤剂的研究和应用;沈开成 等;《日用化学品科学》;20071031;第30卷(第10期);第23-26页 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108605986A (en) * | 2018-05-25 | 2018-10-02 | 苏州佑君环境科技有限公司 | A kind of oil field composite bactericide and preparation method thereof |
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