CN104496180B - A kind of citrite pearl embryo and preparation method thereof - Google Patents
A kind of citrite pearl embryo and preparation method thereof Download PDFInfo
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- CN104496180B CN104496180B CN201510003788.6A CN201510003788A CN104496180B CN 104496180 B CN104496180 B CN 104496180B CN 201510003788 A CN201510003788 A CN 201510003788A CN 104496180 B CN104496180 B CN 104496180B
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Abstract
The invention discloses a kind of citrite pearl embryo and preparation method thereof, this citrite pearl embryo is made up of following weight composition: quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part.Citrite pearl embryo of the present invention does not adopt the compound of a large amount of ceriums when preparing, fix the painted of methyl seleninic acid in secondary integer; Do not adopt leaded raw material, have glossiness good, bright-colored, neat, no color differnece, without decorative pattern, output is high, unleaded pollution-free, the advantage that productivity effect is good.
Description
Technical field
The present invention relates to a kind of citrite pearl embryo and preparation method thereof.
Background technology
Citrite pearl embryo is used to the work in-process preparing citrite product, existing citrite pearl embryo technique adopts crucible manufacture, there is aberration, color is uneven, have decorative pattern, unstable product quality, production efficiency is low, be not suitable for continuous production in enormous quantities, and cause environmental pollution by coal burning.And the rare-earth oxidation erbium of the consumption costliness had in existing technical recipe, but some selenium powders are painted unstable, the lead compound containing contaminate environment had.
Summary of the invention
It is good that technical problem to be solved by this invention is to provide a kind of color reproduction, and solid colour no color differnece, without decorative pattern, constant product quality, production efficiency is high, and can be applicable to the production operation of continuous tank furnace, production cost is low, free of contamination citrite pearl embryo.
For solving the problem, the present invention is achieved through the following technical solutions: a kind of citrite pearl embryo, and this citrite pearl embryo is made up of following weight composition: quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part.
Another technical problem to be solved by this invention is to provide a kind of preparation method of citrite pearl embryo,
The present invention is achieved through the following technical solutions: the preparation process of described citrite pearl embryo is as follows:
1) extract quartz sand 95-165 part, zinc oxide 10-18 part, soda ash 28-52 part, salt of wormwood 15-31 part, boric acid 6-16 part, calcium carbonate 3-5 part, aluminium hydroxide 0.8-3.2 part, salt 1-2 part, antimonous oxide 2-5 part, saltpetre 0.1-2 part, Sodium Selenite 0.01-0.18 part, Iron sulfuret 0.001-0.003 part and Neodymium trioxide 0.1-0.9 part by weight ratio to mix;
2) the citrite pearl embryo raw material mixed is carried out granulation by tablets press;
3) granular citrite pearl embryo raw material will be made put into glass quartz tank furnace and found, and when founding, keep weak oxide atmosphere and liquid level of solution to stablize;
4) crystal solution is molded into citrite pearl embryo after the homogenizing cooling of material road;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, citrite pearl embryo without decorative pattern.
Further, described in the preparation process 3 of citrite pearl embryo, when founding, temperature controls at 1320 DEG C-1380 DEG C.
Further, described in the preparation process 4 of citrite pearl embryo, cooling temperature controls at 800 DEG C-1000 DEG C.
The beneficial effect of citrite pearl embryo of the present invention is: the compound not adopting a large amount of ceriums time prepared by described citrite pearl embryo, fixes the painted of methyl seleninic acid in secondary integer; Do not adopt leaded raw material, have glossiness good, bright-colored, neat, no color differnece, without decorative pattern, output is high, unleaded pollution-free, the advantage that productivity effect is good.
Embodiment
Following examples for illustration of the present invention, but are not used for limiting the scope of the invention.
Embodiment 1
A kind of citrite pearl embryo of the present invention, this citrite pearl embryo is made up of following weight composition: quartz sand 150 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 15 parts, 3.8 parts, calcium carbonate, 1.2 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.2 parts, 0.5 part, saltpetre, Sodium Selenite 0.015 part, Iron sulfuret 0.0011 part and Neodymium trioxide 0.16 part.
The preparation process of described citrite pearl embryo is as follows:
1) extract quartz sand 150 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 15 parts, 3.8 parts, calcium carbonate, 1.2 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.2 parts, 0.5 part, saltpetre, Sodium Selenite 0.015 part, Iron sulfuret 0.0011 part and Neodymium trioxide 0.16 part by weight ratio to mix;
2) the citrite pearl embryo raw material mixed is carried out granulation by tablets press;
3) will make granular citrite pearl embryo raw material to put into glass quartz tank furnace and found, keep weak oxide atmosphere and liquid level of solution to stablize when founding, glass melting temperature controls at 1320 DEG C-1380 DEG C;
4) crystal solution is molded into citrite pearl embryo after the homogenizing cooling of material road, cooling temperature controls at 800 DEG C-1000 DEG C;
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, citrite pearl embryo without decorative pattern.
Embodiment 2
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 165 parts, 18 parts, zinc oxide, soda ash 52 parts, 31 parts, salt of wormwood, boric acid 16 parts, 5 parts, calcium carbonate, 3.2 parts, aluminium hydroxide, salt 2 parts, antimonous oxide 5 parts, 2 parts, saltpetre, Sodium Selenite 0.18 part, Iron sulfuret 0.003 part and Neodymium trioxide 0.9 part.
Embodiment 3
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 95 parts, 10 parts, zinc oxide, soda ash 28 parts, 15 parts, salt of wormwood, boric acid 6 parts, 3 parts, calcium carbonate, 0.8 part, aluminium hydroxide, salt 1 part, antimonous oxide 2 parts, 0.1 part, saltpetre, Sodium Selenite 0.01 part, Iron sulfuret 0.001 part and Neodymium trioxide 0.1 part.
Embodiment 4
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 155 parts, 17 parts, zinc oxide, soda ash 49 parts, 29 parts, salt of wormwood, boric acid 15 parts, 4.7 parts, calcium carbonate, 3 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 4.4 parts, 1.8 parts, saltpetre, Sodium Selenite 0.16 part, Iron sulfuret 0.0025 part and Neodymium trioxide 0.7 part.
Embodiment 5
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 100 parts, 11 parts, zinc oxide, soda ash 30 parts, 17 parts, salt of wormwood, boric acid 8 parts, 3.3 parts, calcium carbonate, 1 part, aluminium hydroxide, salt 1.2 parts, antimonous oxide 2.4 parts, 0.4 part, saltpetre, Sodium Selenite 0.03 part, Iron sulfuret 0.0013 part and Neodymium trioxide 0.3 part.
Embodiment 6
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 130 parts, 14 parts, zinc oxide, soda ash 41 parts, 22 parts, salt of wormwood, boric acid 12 parts, 4.1 parts, calcium carbonate, 1.6 parts, aluminium hydroxide, salt 1.6 parts, antimonous oxide 3.7 parts, 1.1 parts, saltpetre, Sodium Selenite 0.09 part, Iron sulfuret 0.0021 part and Neodymium trioxide 0.5 part.
Embodiment 7
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 125 parts, 13 parts, zinc oxide, soda ash 36 parts, 24 parts, salt of wormwood, boric acid 12 parts, 3.9 parts, calcium carbonate, 2.2 parts, aluminium hydroxide, salt 1 part, antimonous oxide 5 parts, 1.1 parts, saltpetre, Sodium Selenite 0.11 part, Iron sulfuret 0.0022 part and Neodymium trioxide 0.7 part.
Embodiment 8
Its difference from Example 1 is, this citrite pearl embryo is made up of following weight composition: quartz sand 115 parts, 14 parts, zinc oxide, soda ash 42 parts, 19 parts, salt of wormwood, boric acid 9 parts, 4.4 parts, calcium carbonate, 2.8 parts, aluminium hydroxide, salt 1.7 parts, antimonous oxide 3.6 parts, 1.4 parts, saltpetre, Sodium Selenite 0.14 part, Iron sulfuret 0.0014 part and Neodymium trioxide 0.2 part.
The present invention is not limited to above-mentioned preferred forms, anyone other any or akin products identical with the present invention drawn under enlightenment of the present invention, all drops within protection scope of the present invention.
Claims (1)
1. a citrite pearl embryo, is characterized in that: be made up of following weight composition: quartz sand 150 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 15 parts, 3.8 parts, calcium carbonate, 1.2 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.2 parts, 0.5 part, saltpetre, Sodium Selenite 0.015 part, Iron sulfuret 0.0011 part and Neodymium trioxide 0.16 part; The preparation process of described citrite pearl embryo is as follows: 1) extract quartz sand 150 parts, 13 parts, zinc oxide, soda ash 30 parts, 18 parts, salt of wormwood, boric acid 15 parts, 3.8 parts, calcium carbonate, 1.2 parts, aluminium hydroxide, salt 1.8 parts, antimonous oxide 2.2 parts, 0.5 part, saltpetre, Sodium Selenite 0.015 part, Iron sulfuret 0.0011 part and Neodymium trioxide 0.16 part by weight ratio and mix; 2) the citrite pearl embryo raw material mixed is carried out granulation by tablets press; 3) will make granular citrite pearl embryo raw material to put into glass quartz tank furnace and found, keep weak oxide atmosphere and liquid level of solution to stablize when founding, glass melting temperature controls at 1320 DEG C-1380 DEG C; 4) crystal solution is molded into citrite pearl embryo after the homogenizing cooling of material road, cooling temperature controls at 800 DEG C-1000 DEG C; 5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, shaping pearl embryo is allowed at the uniform velocity to enter stainless steel pipes, pipe temperature controls at 800 DEG C-900 DEG C, rotating speed 180 revolutions per seconds, in pipeline 5 minutes, pipeline was out just through integer, solid colour, no color differnece, citrite pearl embryo without decorative pattern.
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CN102503126A (en) * | 2011-10-08 | 2012-06-20 | 浙江伟兴水晶有限公司 | Preparation method for smoky yellow crystal bead blanks |
CN103508671A (en) * | 2012-06-26 | 2014-01-15 | 广东华兴玻璃有限公司 | Brown glass and preparation method thereof |
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