CN104312343A - Elastic water-proof coating used for automobiles - Google Patents

Elastic water-proof coating used for automobiles Download PDF

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Publication number
CN104312343A
CN104312343A CN201410502425.2A CN201410502425A CN104312343A CN 104312343 A CN104312343 A CN 104312343A CN 201410502425 A CN201410502425 A CN 201410502425A CN 104312343 A CN104312343 A CN 104312343A
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China
Prior art keywords
parts
stirring
minute
raw material
rev
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Pending
Application number
CN201410502425.2A
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Chinese (zh)
Inventor
徐泽军
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Ruizhan Tongling Technologies Co Ltd
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Ruizhan Tongling Technologies Co Ltd
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Priority to CN201410502425.2A priority Critical patent/CN104312343A/en
Publication of CN104312343A publication Critical patent/CN104312343A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

Elastic water-proof coating used for automobiles is disclosed. The coating comprises following raw materials by weight: 70-80 parts of silicone acrylic emulsion, 10-20 parts of XL-800 elastic pure acrylic emulsion, 3-4 parts of glycerol ester of rosin, 0.1-0.2 part of potassium peroxodisulfate, 1-2 parts of fenugreek gum, 2-4 parts of ethylparaben, 0.7-2 parts of alkenyl succinic anhydride, 1-2 parts of sodium pyrophosphate, 1-2 parts of polyvinylpyrrolidone, 1-2 parts of ammonium alcohol ether sulphate, 10-14 parts of titanium dioxide, 2-3 parts of zinc stearate, 1-2 parts of polyethylene glycol adipate, 0.7-1 part of 8-hydroxyquinoline, 18-25 parts of deionized water and 5-8 parts of an adhesion auxiliary agent. The water-proof coating can be subjected to direct construction on base surfaces of a plurality of materials which are wet or dry, and has advantages of good extensibility, high surface strength, high coefficient of elongation, good adhesiveness, good freezing resistance, high weather fastness, good quality feeling and wide application.

Description

A kind of automobile elastic water proofing paint
?
Technical field
The present invention relates generally to a kind of coating, particularly relates to a kind of automobile elastic water proofing paint.
Background technology
So-called coating refers to that coating body surface can form film under certain conditions and play protection, the class I liquid I of decoration or other specific functions (insulation, antirust, mildew-resistant, heat-resisting etc.) or solid material.Be main raw material mainly with vegetables oil greatly because of early stage coating, therefore also known as painting.Present synthetic resins is most of or all instead of vegetables oil, therefore is called coating.Application of paints is all respects in life, and coating not only requires that cohesiveness is strong, good weatherability, and resistance is high, also wants nontoxic pollution-free, therefore improves constantly the overall quality of coating for improving people's living standard, and accelerating urban development has very great meaning.
Summary of the invention
The object of the invention is just to provide a kind of automobile elastic water proofing paint.
The present invention is achieved by the following technical solutions:
A kind of automobile elastic water proofing paint, it is made up of the raw material of following weight parts:
Organosilicon crylic acid latex 70-80, XL-800 elasticity pure-acrylic emulsion 10-20, ester gum 3-4, Potassium Persulphate 0.1-0.2, fenugreek gum 1-2, ethyl p-hydroxybenzoate 2-4, alkenyl succinic anhydride 0.7-2, trisodium phosphate 1-2, polyvinylpyrrolidone 1-2, ethoxylated alkylphenol ammonium sulfate 1-2, titanium dioxide 10-14, Zinic stearas 2-3, poly-adipate glycol 1-2, oxine 0.7-1, deionized water 18-25, adhesive aid 5-8;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-46, lauryl glucosyl 1-2, methyl methacrylate 2-4, vulcabond 1-2, allyl polyglycol 3-4, potassium zirconium carbonate 1-2, nano-carbon powder 2-3, tetrafluoroethylene wax 2-3, nano titanium oxide 0.1-1, deionized water 6-8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 60-70 DEG C, be uniformly mixed 10-16 minute, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200-300 rev/min of dispersed with stirring 10-12 minute;
Lauryl glucosyl is joined in deionized water, after stirring, add vulcabond, methyl methacrylate, 60-80 rev/min of dispersed with stirring 3-5 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1000 rev/min of dispersed with stirring 2-4 minute, obtains described adhesive aid.
A preparation method for automobile elastic water proofing paint, is characterized in that comprising the following steps:
Joined by ester gum in XL-800 elasticity pure-acrylic emulsion, be heated to 50-60 DEG C, add titanium dioxide, Zinic stearas, 200-300 rev/min is stirred 5-10 minute;
Join in deionized water by ethoxylated alkylphenol ammonium sulfate, add ethyl p-hydroxybenzoate, trisodium phosphate, polyvinylpyrrolidone after stirring, 200-300 rev/min is stirred a point 7-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 600-800 rev/min of dispersed with stirring 20-30 minute, obtains described automobile elastic water proofing paint.
Advantage of the present invention is:
Waterproof paint of the present invention directly can be constructed on moist or dry multiple material basal plane, and good-extensibility, surface strength are high, unit elongation is high, and cohesiveness is good, and frost resistance is good, and weathering resistance is strong, and texture is good, is widely used.
Embodiment
Embodiment 1
A kind of automobile elastic water proofing paint, it is made up of the raw material of following weight parts (kilogram):
Organosilicon crylic acid latex 80, XL-800 elasticity pure-acrylic emulsion 20, ester gum 3, Potassium Persulphate 0.2, fenugreek gum 2, ethyl p-hydroxybenzoate 2, alkenyl succinic anhydride 0.7, trisodium phosphate 2, polyvinylpyrrolidone 1-2, ethoxylated alkylphenol ammonium sulfate 2, titanium dioxide 14, Zinic stearas 3, poly-adipate glycol 2, oxine 0.7, deionized water 25, adhesive aid 5;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 46, lauryl glucosyl 2, methyl methacrylate 4, vulcabond 1, allyl polyglycol 3, potassium zirconium carbonate 1, nano-carbon powder 2, tetrafluoroethylene wax 3, nano titanium oxide 0.1, deionized water 8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 70 DEG C, be uniformly mixed 16 minutes, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 300 revs/min of dispersed with stirring 12 minutes;
Lauryl glucosyl is joined in deionized water, after stirring, add vulcabond, methyl methacrylate, 80 revs/min of dispersed with stirring 5 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 1000 revs/min of dispersed with stirring 4 minutes, obtain described adhesive aid.
A preparation method for automobile elastic water proofing paint, is characterized in that comprising the following steps:
Joined by ester gum in XL-800 elasticity pure-acrylic emulsion, be heated to 60 DEG C, add titanium dioxide, Zinic stearas, 300 revs/min are stirred 10 minutes;
Join in deionized water by ethoxylated alkylphenol ammonium sulfate, add ethyl p-hydroxybenzoate, trisodium phosphate, polyvinylpyrrolidone after stirring, 300 revs/min of stirrings divide 10 minutes;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800 revs/min of dispersed with stirring 30 minutes, obtain described automobile elastic water proofing paint.
Performance test:
Unit elongation: >=300%;
Watertightness: 0.3MPa (one hour waterproof).

Claims (2)

1. an automobile elastic water proofing paint, is characterized in that what it was made up of the raw material of following weight parts:
Organosilicon crylic acid latex 70-80, XL-800 elasticity pure-acrylic emulsion 10-20, ester gum 3-4, Potassium Persulphate 0.1-0.2, fenugreek gum 1-2, ethyl p-hydroxybenzoate 2-4, alkenyl succinic anhydride 0.7-2, trisodium phosphate 1-2, polyvinylpyrrolidone 1-2, ethoxylated alkylphenol ammonium sulfate 1-2, titanium dioxide 10-14, Zinic stearas 2-3, poly-adipate glycol 1-2, oxine 0.7-1, deionized water 18-25, adhesive aid 5-8;
Described adhesive aid is made up of the raw material of following weight parts:
Eva emulsion 40-46, lauryl glucosyl 1-2, methyl methacrylate 2-4, vulcabond 1-2, allyl polyglycol 3-4, potassium zirconium carbonate 1-2, nano-carbon powder 2-3, tetrafluoroethylene wax 2-3, nano titanium oxide 0.1-1, deionized water 6-8;
By potassium zirconium carbonate, nano-carbon powder mixing, add tetrafluoroethylene wax after stirring, at 60-70 DEG C, be uniformly mixed 10-16 minute, add allyl polyglycol, be stirred to normal temperature, join in Eva emulsion, 200-300 rev/min of dispersed with stirring 10-12 minute;
Lauryl glucosyl is joined in deionized water, after stirring, add vulcabond, methyl methacrylate, 60-80 rev/min of dispersed with stirring 3-5 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 800-1000 rev/min of dispersed with stirring 2-4 minute, obtains described adhesive aid.
2. a preparation method for automobile elastic water proofing paint as claimed in claim 1, is characterized in that comprising the following steps:
Joined by ester gum in XL-800 elasticity pure-acrylic emulsion, be heated to 50-60 DEG C, add titanium dioxide, Zinic stearas, 200-300 rev/min is stirred 5-10 minute;
Join in deionized water by ethoxylated alkylphenol ammonium sulfate, add ethyl p-hydroxybenzoate, trisodium phosphate, polyvinylpyrrolidone after stirring, 200-300 rev/min is stirred a point 7-10 minute;
Mixed with each raw material of residue by each raw material after above-mentioned process, 600-800 rev/min of dispersed with stirring 20-30 minute, obtains described automobile elastic water proofing paint.
CN201410502425.2A 2014-09-26 2014-09-26 Elastic water-proof coating used for automobiles Pending CN104312343A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410502425.2A CN104312343A (en) 2014-09-26 2014-09-26 Elastic water-proof coating used for automobiles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410502425.2A CN104312343A (en) 2014-09-26 2014-09-26 Elastic water-proof coating used for automobiles

Publications (1)

Publication Number Publication Date
CN104312343A true CN104312343A (en) 2015-01-28

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240139A (en) * 2008-01-17 2008-08-13 黄敏文 Water-based paint and its preparation technique
CN103614011A (en) * 2013-10-28 2014-03-05 蚌埠市高华电子有限公司 Waterproof paint containing oyster shell powder
CN103614025A (en) * 2013-10-28 2014-03-05 蚌埠市高华电子有限公司 Environmentally-friendly highly-elastic waterproof coating
CN103614036A (en) * 2013-10-28 2014-03-05 蚌埠市高华电子有限公司 Polymer emulsion waterproof paint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101240139A (en) * 2008-01-17 2008-08-13 黄敏文 Water-based paint and its preparation technique
CN103614011A (en) * 2013-10-28 2014-03-05 蚌埠市高华电子有限公司 Waterproof paint containing oyster shell powder
CN103614025A (en) * 2013-10-28 2014-03-05 蚌埠市高华电子有限公司 Environmentally-friendly highly-elastic waterproof coating
CN103614036A (en) * 2013-10-28 2014-03-05 蚌埠市高华电子有限公司 Polymer emulsion waterproof paint

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Application publication date: 20150128