CN104258790A - Thermosensitive organic compound heating smelting device - Google Patents
Thermosensitive organic compound heating smelting device Download PDFInfo
- Publication number
- CN104258790A CN104258790A CN201410462842.9A CN201410462842A CN104258790A CN 104258790 A CN104258790 A CN 104258790A CN 201410462842 A CN201410462842 A CN 201410462842A CN 104258790 A CN104258790 A CN 104258790A
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- Prior art keywords
- heat
- heat fused
- material stock
- furnace
- organic compound
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000002894 organic compounds Chemical class 0.000 title claims abstract description 27
- 238000010438 heat treatment Methods 0.000 title abstract description 15
- 238000003723 Smelting Methods 0.000 title abstract 10
- 239000000463 material Substances 0.000 claims abstract description 81
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- 238000005485 electric heating Methods 0.000 claims description 14
- 229910001220 stainless steel Inorganic materials 0.000 claims description 8
- 239000010935 stainless steel Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 4
- 239000011343 solid material Substances 0.000 abstract description 14
- 239000007788 liquid Substances 0.000 abstract description 7
- 239000007787 solid Substances 0.000 abstract description 5
- 238000004321 preservation Methods 0.000 abstract 7
- 241001062472 Stokellia anisodon Species 0.000 abstract 1
- 238000013021 overheating Methods 0.000 abstract 1
- 230000035945 sensitivity Effects 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 37
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 7
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 230000003628 erosive effect Effects 0.000 description 4
- 239000012530 fluid Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- WTPYFJNYAMXZJG-UHFFFAOYSA-N 2-[4-(2-hydroxyethoxy)phenoxy]ethanol Chemical compound OCCOC1=CC=C(OCCO)C=C1 WTPYFJNYAMXZJG-UHFFFAOYSA-N 0.000 description 3
- IBOFVQJTBBUKMU-UHFFFAOYSA-N 4,4'-methylene-bis-(2-chloroaniline) Chemical compound C1=C(Cl)C(N)=CC=C1CC1=CC=C(N)C(Cl)=C1 IBOFVQJTBBUKMU-UHFFFAOYSA-N 0.000 description 3
- 241001112258 Moca Species 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000011344 liquid material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000003913 materials processing Methods 0.000 description 2
- 230000029052 metamorphosis Effects 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 1
- -1 aromatic series alcohols Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 150000004053 quinones Chemical class 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008542 thermal sensitivity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/005—Fusing
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Resistance Heating (AREA)
Abstract
The invention discloses a thermosensitive organic compound heating smelting device which comprises an electric control box, a heating smelting furnace and a heat preservation furnace, wherein the heating smelting furnace is communicated with the heat preservation furnace and is arranged above the heat preservation furnace; a material outlet is formed in the bottom of the heat preservation furnace; a top cover is arranged on the top of the heating smelting furnace; a heating smelting furnace heating device is arranged in the heating smelting furnace; a heat preservation device is arranged on the heat preservation furnace; a material storage card for containing materials is mounted at the bottom in the heating smelting furnace; a slit for enabling the smelted materials to flow into the heat preservation furnace is formed in the material storage card; a material storage card heating device matched with the material storage card is mounted in the heating smelting furnace. The heating smelting device can store solid materials and absorb heat to smelt the materials, has a function of separating solid and liquid immediately after the materials are heated to be smelted, and has the characteristics of control sensitivity, convenience in use and the like, can precisely heat the materials, does not cause partial overheating, saves energy and the like.
Description
Technical field
The present invention relates to a kind of heater, particularly relate to a kind of heat-sensitive organic compound heat fused device.
Background technology
Heat fused solid material is the manufacturing procedure often run at industrial department, and usual technology is that the stockpile of a batch is put and heated in the heater, allows the fusing of material nature, becomes liquid.There is two problems in this heat fused mode, one is that the heat transfer type of solid material only carries out in thermo-conducting manner, and heat transfer is very slow, need using higher than the many Δ t of material fusing point as motive force, improve burn-off rate; Two is that too high Δ t is easy to cause temperature after the material melting of heating wall to be much higher than its melting temperature, and this phenomenon is called hot-spot.Not enough in order to overcome these, some loads onto stirring in the heater, when solid material starts fusing gradually, slowly opens stirring, and the transmission of strengthening heat, makes melt speed be promoted.But this mode of adding stirring effectively can not avoid the generation of hot-spot phenomenon, because solid material is be difficult to start stir when there is not local melting, some material had both been exactly local melting, at this moment lump on the contrary very serious, stirring cannot be started, and the material near heating wall is overheated still can hardly be avoided.The problem of organic materials hot-spot is easily caused in order to overcome this heat fused mode, technology is had to take to use the way of solvent, namely first material is dissolved in suitable solvent completely and becomes homogeneous liquid, then heat while stirring, when temperature reaches the fusing point of material, adopt the mode of decompression to be steamed by solvent, at the bottom of still, obtain liquid organic materials.Well imagine, just to melting materials capable, suitable solvent be selected, dissolve, then again solvent be steamed under vacuum, this is how time-consuming, take a lot of work, meaningless consumption of natural resource.
Organic compound is heated the erosion of oxygen, easily decompose, variable color, the physical and chemical changes such as aging, especially to the compound of some thermal sensitivity, such as organic amine, phenols, aromatic series alcohols, quinones, isocyanates etc. are all the more so.But these compounds are again the auxiliary material often will used in materials processing industry, such as at polyurethane and epoxy resin manufacture field, usually use solid aromatic race diamines and glycol (is called curing agent in epoxy resin field as vulcanizing agent, vulcanizing agent is called as) in polyurethane elastomeric materials field, in order to carry out chain extension-crosslinking curing reaction to base resin, thus reach the object of toughen and intensify.Before mixing with base resin, by the vulcanizing agent of this solid or curing agent heat fused, fully must can mix with base resin after there is mobility, then enter next step manufacturing procedure.These solid curing agents of heat fused often run into above-mentioned hot-spot, cause curing agent variable color serious, do not reach instructions for use and the phenomenon of scrapping occurs.And in order to accelerate burn-off rate in heat fused process, it is higher that heating-up temperature is generally all arranged, after hot-spot, not only material deterioration, and produce a large amount of smog, contaminated environment, against clean requirement of carrying out production strictly in line with rules and regulations.
Summary of the invention
The object of the present invention is to provide a kind of heat-sensitive organic compound heat fused device, it has the feature of exact heat, compact conformation, easy to use, environmental protection and economize energy, to solve the problems referred to above existed in heat-sensitive organic compound heating process in prior art.
For reaching this object, the present invention by the following technical solutions:
A kind of heat-sensitive organic compound heat fused device, it comprises electric cabinet, heat fused stove and holding furnace, wherein, described heat fused stove is communicated with holding furnace and is arranged at the top of described holding furnace, the bottom of described holding furnace is provided with discharging opening, the top of described heat fused stove arranges top cover, and be provided with heat fused stove heater in described heat fused stove, described holding furnace is provided with attemperator, the material stock card for holding material is installed in bottom in described heat fused stove, described material stock card has the gap for making the material after fusing flow into holding furnace, coordinate material stock card that material stock card heater is installed in heat fused stove, described heat fused stove heater, attemperator and material stock card heater are electrically connected with electric cabinet.
Especially, described heat fused stove heater, attemperator and material stock card heater all adopt electric heating tube and conduction oil to heat, the body of heater of described heat fused stove is outside equipped with chuck, in described upper chuck, electric heating tube and conduction oil are set, the body of heater of described holding furnace is outside equipped with lower chuck, conduction oil is provided with in described lower chuck, electric heating tube and conduction oil is provided with in described material stock card, and described upper and lower chuck and material stock card are provided with into and out of hydraulic fluid port, describedly connect Heat-transfer Oil Pump into and out of hydraulic fluid port by pipeline.
Especially, described material stock card is the shell and tube shape having certain interval, it is made up of some spaced material stock pipes, conduction oil is connected with in described material stock pipe, described electric heating tube is arranged in material stock pipe, and on card, absorb the heat radiation of tube wall and material stock card before solid material does not melt, temperature raises gradually, the material of contact material stock card is once fusing very soon can along the moist closet of the inflow bottom, gap of material stock pipe, and the gap size between material stock pipe can design along with different material.
Especially, the spacing in described material stock pipe between adjacent two is 0.4 ~ 5 ㎜.
Especially, described material stock pipe is made up of stainless steel tube or concentric loop pipe.
Especially, the spacing between described some material stock pipes adopts adjustable structure, according to the different physical property of melting materials capable to be heated, artificially can regulate the distance between tubulation, the efficiency of heat fused is optimized further.
Especially, described Heat-transfer Oil Pump is connected with heat-conducting oil furnace, is heated conduction oil by heat-conducting oil furnace and electric heating tube, to be applicable to the heat fused to heat organic compound responsive especially.
Especially, in described holding furnace, be provided with the nitrogen tube for sending into nitrogen in stove, with heat fused not only temperature-sensitive but also use during the material that oxygen is also responsive especially.
Especially, described electric cabinet, heat fused stove, holding furnace and heat-conducting oil furnace are integrated is arranged on a mobile handcart.
Above-mentioned heat-sensitive organic compound heat fused device material is first on material stock card in solid form, at this moment it is subject to the heat source of bottom and surrounding, temperature moves closer to its fusing point, the Temperature Distribution of solid material is gesture low on lower height, bottoms material reaches fusing point and continues to absorb heat and becomes drop, this drop accumulates liquid stream very soon, along the moist closet of the inflow bottom, gap of material stock card.The solid material of fusing and unfused solid material are separated in time, make unfused solid material continue to accept heat generation metamorphosis, what melted enters moist closet, is incubated near its fusing point, is no longer subject to the erosion of higher temperature.
Beneficial effect of the present invention is, compared with prior art described heat-sensitive organic compound heat fused device can be widely used in the industries such as chemical industry, light textile, materials processing to the heat fused of heat-sensitive organic compound and insulation.Have the following advantages:
1) exact heat is realized to material, the solid material of fusing and unfused solid material are separated in time, make unfused solid material continue to accept heat generation metamorphosis, what melted enters in holding furnace, be incubated near its fusing point, be no longer subject to the erosion of higher temperature; Thus avoid the generation of hot-spot phenomenon;
2) heat-sensitive organic compound can be made by heat fused process, exempt from overheated erosion, avoid degrading, the generation of variable color and aging phenomenon;
3) can organifying compound in heat fused process, exempt from hot-spot, effectively can avoid producing a large amount of smog, be conducive to protection of the environment;
4) can effectively melting materials capable and unfused solid material be separated in time, can economize energy while avoiding hot-spot;
5) by whole heat fused device control of dust on a mobile handcart, compact conformation, convenient operation.
Accompanying drawing explanation
Fig. 1 is the side view of the heat-sensitive organic compound heat fused device that the specific embodiment of the invention 1 provides;
Fig. 2 is the top view of the heat-sensitive organic compound heat fused device that the specific embodiment of the invention 1 provides;
Fig. 3 is the heat fused stove of heat-sensitive organic compound heat fused device that provides of the specific embodiment of the invention 1 and the schematic diagram of moist closet.
In figure:
1, electric cabinet; 2, heat fused stove; 3, holding furnace; 4, Heat-transfer Oil Pump; 5, heat-conducting oil furnace; 6, mobile handcart; 7, discharging opening; 8, top cover; 9, upper chuck; 10, conduction oil; 11, lower chuck; 12, stainless steel tube; 13, nitrogen tube; 14, aviation plug; 15, flange; 16, case.
Detailed description of the invention
Technical scheme of the present invention is further illustrated by detailed description of the invention below in conjunction with accompanying drawing.
Refer to shown in Fig. 1 to Fig. 3, in the present embodiment, a kind of heat-sensitive organic compound heat fused device comprises electric cabinet 1, heat fused stove 2, holding furnace 3, Heat-transfer Oil Pump 4 and heat-conducting oil furnace 5, described electric cabinet 1, heat fused stove 2, holding furnace 3, Heat-transfer Oil Pump 4 and heat-conducting oil furnace 5 are concentrated and are assemblied on mobile handcart 6, described heat fused stove 2 is communicated with holding furnace 3 and is arranged at the top of described holding furnace 3, the bottom of described holding furnace 3 is provided with discharging opening 7, the top of described heat fused stove 2 arranges top cover 8, the body of heater of described heat fused stove 2 adopts circular stainless steel cask, and it is outside equipped with chuck 9, electric heating tube and conduction oil 10 are set in described upper chuck 9, the body of heater of described holding furnace 3 adopts circular stainless steel cask, and it is outside equipped with lower chuck 11, the conduction oil 10 of circulation is provided with in described lower chuck 11, its insulation heat is provided by conduction oil, bottom in described heat fused stove 2 is provided with the material stock card for holding material, described material stock card is made up of the stainless steel tube 12 of many φ 10 side by side, in-built electric heater and conduction oil, spacing between tube and tube is 3mm.And described upper chuck 9, lower chuck 11 and stainless steel tube 12 are provided with into and out of hydraulic fluid port, described into and out of hydraulic fluid port by pipeline connect Heat-transfer Oil Pump 4, described Heat-transfer Oil Pump 4 is connected with heat-conducting oil furnace 5, is heated conduction oil by heat-conducting oil furnace 5 and electric heating tube.
The nitrogen tube 13 for sending into nitrogen in stove is provided with, with heat fused not only temperature-sensitive but also use during the material that oxygen is also responsive especially in described holding furnace 3.
Described electric cabinet comprises various setting, control and warning device.Moist closet and heat fused room are designed to one-piece type, and heat fused stove 2 is connected by flange 15 between the two with holding furnace 3.Liquid material after fusing can enter into moist closet in time.Realized by aviation plug 14 with the connection of control system.
The upper chuck 9 of above-mentioned heat fused stove 2 is outside equipped with case 16.
Adopt the equipment heat fused graininess MOCA (3,3 '-two chloro-4,4 '-diaminourea-diphenyl methane) (particle diameter about 5mm) of the material stock card of above-mentioned specification, obtain ideal effect.Concrete operations: 50 kg particles MOCA are put into heat fused room, arrange material stock card and heat fused room chuck oil temperature is 130 DEG C, electric heating conduction oil furnace oil temperature 110 DEG C, and open oil pump, carry out soak cycles.About 10 points just have liquid to flow into moist closet, and burn-off rate is more and more faster subsequently, at this moment suitably can turn down the preset temperature of heat fused room and material stock card conduction oil.45 minutes complete used times of whole fusing, on-the-spot non smoke loss, the liquid material of melting is limpid bright, and color and luster does not have significant change.The fusing point of MOCA is 103 DEG C.
Employing specification is the stainless steel tube of many φ 8 side by side, and the spacing between tube and tube is the equipment heat fused powdery HQEE (quinhydrones-bis-(beta-hydroxyethyl) ether) of the material stock card of 1mm, obtains ideal effect.Concrete operations: 50 kilograms of powdered crystalline HQEE are put into heat fused room, arrange material stock card and heat fused room chuck oil temperature is 135 DEG C, electric heating conduction oil furnace oil temperature 115 DEG C, and open oil pump, carry out soak cycles.About 10 points just have liquid to flow into moist closet, and burn-off rate is more and more faster subsequently, at this moment suitably can turn down the preset temperature of heat fused room and material stock card conduction oil.40 minutes complete used times of whole fusing, on-the-spot non smoke loss, the liquid material of melting is limpid bright, and color and luster still keeps water colour not have significant change.The fusing point of HQEE is 106 DEG C.
Certain above-mentioned heat-sensitive organic compound heat fused device also can save heat-conducting oil furnace 5, with in heat fused room chuck and material stock card by warmed-up conduction oil, the material melted in moist closet is incubated, heat is fully used, has more power conservation feature.
Above embodiment has just set forth general principle of the present invention and characteristic; the present invention does not limit by above-mentioned example; without departing from the spirit and scope of the present invention, the present invention also has various change and change, and these changes and change all fall in the claimed scope of the invention.Application claims protection domain is defined by appending claims and equivalent thereof.
Claims (9)
1. a heat-sensitive organic compound heat fused device, it comprises electric cabinet, heat fused stove and holding furnace, it is characterized in that, described heat fused stove is communicated with holding furnace and is arranged at the top of described holding furnace, the bottom of described holding furnace is provided with discharging opening, the top of described heat fused stove arranges top cover, and be provided with heat fused stove heater in described heat fused stove, described holding furnace is provided with attemperator, the material stock card for holding material is installed in bottom in described heat fused stove, described material stock card has the gap for making the material after fusing flow into holding furnace, coordinate material stock card that material stock card heater is installed in heat fused stove, described heat fused stove heater, attemperator and material stock card heater are electrically connected with electric cabinet.
2. heat-sensitive organic compound heat fused device according to claim 1, it is characterized in that, described heat fused stove heater, attemperator and material stock card heater all adopt electric heating tube and conduction oil to heat, the body of heater of described heat fused stove is outside equipped with chuck, in described upper chuck, electric heating tube and conduction oil are set, the body of heater of described holding furnace is outside equipped with lower chuck, conduction oil is provided with in described lower chuck, electric heating tube and conduction oil is provided with in described material stock card, and described on, lower chuck and material stock card are provided with into, oil-out, described enter, oil-out connects Heat-transfer Oil Pump by pipeline.
3. heat-sensitive organic compound heat fused device according to claim 2, it is characterized in that, described material stock card is the shell and tube shape having certain interval, it is made up of some spaced material stock pipes, be connected with conduction oil in described material stock pipe, described electric heating tube is arranged in material stock pipe.
4. heat-sensitive organic compound heat fused device according to claim 3, is characterized in that, the spacing in described material stock pipe between adjacent two is 0.4 ~ 5 ㎜.
5. the heat-sensitive organic compound heat fused device according to claim 3 or 4, is characterized in that, described material stock pipe is made up of stainless steel tube or concentric loop pipe.
6. the heat-sensitive organic compound heat fused device according to claim 3 or 4, is characterized in that, the spacing between described some material stock pipes adopts adjustable structure.
7. heat-sensitive organic compound heat fused device according to claim 2, it is characterized in that, described Heat-transfer Oil Pump is connected with heat-conducting oil furnace, is heated conduction oil by heat-conducting oil furnace and electric heating tube.
8. heat-sensitive organic compound heat fused device according to claim 1, is characterized in that, is provided with the nitrogen tube for sending into nitrogen in stove in described holding furnace.
9. heat-sensitive organic compound heat fused device according to claim 7, is characterized in that, described electric cabinet, heat fused stove, holding furnace, Heat-transfer Oil Pump and heat-conducting oil furnace are integrated to be arranged on a mobile handcart.
Priority Applications (1)
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CN201410462842.9A CN104258790B (en) | 2014-09-11 | 2014-09-11 | A kind of heat-sensitive organic compound heating melting appartus |
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CN201410462842.9A CN104258790B (en) | 2014-09-11 | 2014-09-11 | A kind of heat-sensitive organic compound heating melting appartus |
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CN104258790A true CN104258790A (en) | 2015-01-07 |
CN104258790B CN104258790B (en) | 2016-08-17 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106390865A (en) * | 2016-10-09 | 2017-02-15 | 深圳市爱能森科技有限公司 | Movable continuous salt dissolving system and salt dissolving method thereof |
CN107063962A (en) * | 2016-12-16 | 2017-08-18 | 河海大学 | Rock couples infiltration experiment device and method |
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JP3873229B2 (en) * | 2001-10-23 | 2007-01-24 | 関西電力株式会社 | Thermal storage device |
CN200975781Y (en) * | 2006-07-27 | 2007-11-14 | 陈定兴 | Indirect heating second tube pass heat exchange type energy accumulation heating apparatus |
CN100541043C (en) * | 2007-10-19 | 2009-09-16 | 朴荣山 | Full-automatic thermal storage electric boiler |
CN204107480U (en) * | 2014-09-11 | 2015-01-21 | 无锡市巍栋生化设备制造有限公司 | A kind of heat-sensitive organic compound heat fused device |
-
2014
- 2014-09-11 CN CN201410462842.9A patent/CN104258790B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3873229B2 (en) * | 2001-10-23 | 2007-01-24 | 関西電力株式会社 | Thermal storage device |
CN200975781Y (en) * | 2006-07-27 | 2007-11-14 | 陈定兴 | Indirect heating second tube pass heat exchange type energy accumulation heating apparatus |
CN100541043C (en) * | 2007-10-19 | 2009-09-16 | 朴荣山 | Full-automatic thermal storage electric boiler |
CN204107480U (en) * | 2014-09-11 | 2015-01-21 | 无锡市巍栋生化设备制造有限公司 | A kind of heat-sensitive organic compound heat fused device |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106390865A (en) * | 2016-10-09 | 2017-02-15 | 深圳市爱能森科技有限公司 | Movable continuous salt dissolving system and salt dissolving method thereof |
CN107063962A (en) * | 2016-12-16 | 2017-08-18 | 河海大学 | Rock couples infiltration experiment device and method |
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