CN103896660A - Humic acid type fluid compound fertilizer composition utilizing wastes from sugar mills, alcohol plants, gourmet powder factories and yeast plants - Google Patents
Humic acid type fluid compound fertilizer composition utilizing wastes from sugar mills, alcohol plants, gourmet powder factories and yeast plants Download PDFInfo
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- CN103896660A CN103896660A CN201410030990.3A CN201410030990A CN103896660A CN 103896660 A CN103896660 A CN 103896660A CN 201410030990 A CN201410030990 A CN 201410030990A CN 103896660 A CN103896660 A CN 103896660A
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- filter mud
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 102
- 239000012530 fluid Substances 0.000 title claims abstract description 31
- 239000000843 powder Substances 0.000 title claims abstract description 21
- 239000004021 humic acid Substances 0.000 title claims abstract description 20
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 240000004808 Saccharomyces cerevisiae Species 0.000 title claims abstract description 10
- 239000000203 mixture Substances 0.000 title claims description 7
- 150000001875 compounds Chemical class 0.000 title abstract description 5
- 239000002699 waste material Substances 0.000 title abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 claims abstract description 104
- 238000000855 fermentation Methods 0.000 claims abstract description 72
- 230000004151 fermentation Effects 0.000 claims abstract description 72
- 240000008067 Cucumis sativus Species 0.000 claims abstract description 45
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims abstract description 44
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 claims abstract description 25
- 229930002875 chlorophyll Natural products 0.000 claims abstract description 23
- 235000019804 chlorophyll Nutrition 0.000 claims abstract description 23
- WOSNCVAPUOFXEH-UHFFFAOYSA-N thifluzamide Chemical compound S1C(C)=NC(C(F)(F)F)=C1C(=O)NC1=C(Br)C=C(OC(F)(F)F)C=C1Br WOSNCVAPUOFXEH-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 59
- 238000003756 stirring Methods 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 239000000126 substance Substances 0.000 claims description 40
- 239000011573 trace mineral Substances 0.000 claims description 32
- 235000013619 trace mineral Nutrition 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 30
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 26
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 22
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 22
- 238000010792 warming Methods 0.000 claims description 20
- 241000228245 Aspergillus niger Species 0.000 claims description 18
- 241000194107 Bacillus megaterium Species 0.000 claims description 18
- 229930006000 Sucrose Natural products 0.000 claims description 18
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 18
- 229960004793 sucrose Drugs 0.000 claims description 18
- -1 alkyl glycoside Chemical class 0.000 claims description 15
- 230000000149 penetrating effect Effects 0.000 claims description 13
- 238000009736 wetting Methods 0.000 claims description 13
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 12
- 229910019142 PO4 Inorganic materials 0.000 claims description 12
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 12
- 241000589614 Pseudomonas stutzeri Species 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- 239000011591 potassium Substances 0.000 claims description 12
- 229910052700 potassium Inorganic materials 0.000 claims description 12
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 11
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 11
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 11
- 235000010333 potassium nitrate Nutrition 0.000 claims description 11
- 239000004323 potassium nitrate Substances 0.000 claims description 11
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 11
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 11
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 11
- 229960001763 zinc sulfate Drugs 0.000 claims description 11
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- 239000007921 spray Substances 0.000 claims description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 9
- 235000001014 amino acid Nutrition 0.000 claims description 8
- 150000001413 amino acids Chemical class 0.000 claims description 8
- 229930182470 glycoside Natural products 0.000 claims description 7
- 240000006439 Aspergillus oryzae Species 0.000 claims description 6
- 235000002247 Aspergillus oryzae Nutrition 0.000 claims description 6
- 241000589941 Azospirillum Species 0.000 claims description 6
- 241000193755 Bacillus cereus Species 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 241000219112 Cucumis Species 0.000 claims description 5
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 5
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 5
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 claims description 5
- 239000011609 ammonium molybdate Substances 0.000 claims description 5
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 5
- 229940010552 ammonium molybdate Drugs 0.000 claims description 5
- 230000012010 growth Effects 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 5
- 239000011592 zinc chloride Substances 0.000 claims description 5
- 235000005074 zinc chloride Nutrition 0.000 claims description 5
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 4
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 abstract description 6
- 239000010802 sludge Substances 0.000 abstract description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 abstract 2
- 235000011941 Tilia x europaea Nutrition 0.000 abstract 2
- 239000004571 lime Substances 0.000 abstract 2
- 235000009849 Cucumis sativus Nutrition 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 239000003899 bactericide agent Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 32
- 238000004519 manufacturing process Methods 0.000 description 13
- 241000894006 Bacteria Species 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 10
- 230000008569 process Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 240000000111 Saccharum officinarum Species 0.000 description 3
- 235000007201 Saccharum officinarum Nutrition 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000002338 glycosides Chemical class 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UHFFFAOYSA-N Rohrzucker Natural products OCC1OC(CO)(OC2OC(CO)C(O)C(O)C2O)C(O)C1O CZMRCDWAGMRECN-UHFFFAOYSA-N 0.000 description 2
- 229930002868 chlorophyll a Natural products 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 230000037039 plant physiology Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- FRXSZNDVFUDTIR-UHFFFAOYSA-N 6-methoxy-1,2,3,4-tetrahydroquinoline Chemical compound N1CCCC2=CC(OC)=CC=C21 FRXSZNDVFUDTIR-UHFFFAOYSA-N 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000019750 Crude protein Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- RDXARWSSOJYNLI-UHFFFAOYSA-N [P].[K] Chemical compound [P].[K] RDXARWSSOJYNLI-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229930002869 chlorophyll b Natural products 0.000 description 1
- NSMUHPMZFPKNMZ-VBYMZDBQSA-M chlorophyll b Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C=O)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 NSMUHPMZFPKNMZ-VBYMZDBQSA-M 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 235000019784 crude fat Nutrition 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000012262 fermentative production Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 230000034659 glycolysis Effects 0.000 description 1
- 239000003864 humus Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000009923 sugaring Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to a humic acid type fluid compound fertilizer utilizing wastes from sugar mills, alcohol plants, gourmet powder factories and yeast plants and containing lime sludge and secondary and minor elements, which contains a lime sludge fermentation liquid, a secondary element fertilizer, a minor element fertilizer and the like. Preferably, the compound fertilizer also contains appropriate bactericide such as thifluzamide. The compound fertilizer can effectively increase the chlorophyll content of cucumber leaves, and can also increase the yield of cucumbers.
Description
Technical field
The present invention relates to fertilizer field, be specifically related to a kind of humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element that utilizes sugar refinery, grain distillery, Gourmet Powder Factory, yeast factory waste.
Background technology
Filter mud is in cane sugar manufacture process, the residue after sugarcane juice filters by clarification, by pressure filter or vacuum suction filter.In industry sugaring process, (sulfurous method or carbonatation process etc.) there will be a large amount of mud waste things, in these filter muds, comprise a large amount of beneficial elements such as the abundant organic matter such as sucrose, crude fat, thick dimension fibre, crude protein and nitrogen, phosphorus, potassium, calcium, sulphur, magnesium, zinc, sodium, manganese, be applicable to being very much developed as fertilizer.
At present conventional way is that filter mud is piled up and allowed its spontaneous fermentation, or carries out solid fermentation after filter mud is mixed with organism of fermentation.For example, CN102746038A discloses a kind of humus organic material material with cane sugar filter mud fermentation, comprises following raw materials according component: filter mud, sugarcane marrow, peanut press pulp, system chaff, Mai Pi and bacterium powder, obtain through fermentation preparation.CN102924133A discloses a kind of method of utilizing filter mud of sugar refinery fermentative production microbiobacterial agent, getting the fresh filter mud of sugar refinery milling shop, humic acids weathered coal, dry straw ash mixes, make its water content be controlled at 50% left and right, in above-mentioned 1 ton of mixture, add the prosperous EM third generation of soil fertility microbiobacterial agent (living bacteria count >=10,000,000,000/milliliter) to stir, ferment.CN101618982 discloses a kind of method of utilizing microorganism to make cane sugar filter mud fermentation and adding proper N phosphorus potassium production efficient composite biological fertilizer, while preparing composite biological fertilizer, the thalline of composite biological fertilizer is inserted take cane sugar filter mud and pile rotten glycolysis in main organism.Mono-kind of CN1055351 makes the method for fertilizer with filtrated sludge of cane sugar refinery, in the wet filter mud of wherein processing to undried, directly add one or more amendments that can change wet filter mud physical behavior, and control PH, through being uniformly mixed reaction, process or process without stacking through stacking, make and be powdery or granular organic-inorganic mixed fertilizer.CN103288522 discloses a kind of sugarcane organic-inorganic compound fertilizer special that utilizes filter mud of sugar refinery to produce, and it comprises urea, calcium superphosphate or fused(calcium magnesium)phosphate, Repone K, dry filter mud; Wherein filter mud adopts accumulation natural fermentating method to become thoroughly decomposed.
But, because fresh filter mud water content is larger, conventionally reach 60-70%, need dry just and can pulverize, ferment through super-dry or naturally, wherein in drying process, power consumption is larger, and naturally dry and need larger place, and consuming time; Most important, solid fermentation is not easy filter mud to mix with organism of fermentation, once mix inhomogeneously, can cause the incomplete phenomenon of fermenting, and then affect fertilizer efficiency.
The present inventor, through groping for a long time, testing, attempts filter mud to carry out liquid state fermentation, and fermented liquid is used for to agriculture production.Surprised discovery in experimentation, is equipped with other nutritive elements by filter mud liquid state fermentation liquid, and such as macroelement, moderate-element and trace element etc. can significantly increase the chlorophyll content of crop leaf, can make crop yield simultaneously.And when above-mentioned fermented liquid is mixed with suitable sterilant, above-mentioned effect is more obvious.Just because of above-mentioned discovery, contriver has completed the present invention.
Summary of the invention
An object of the present invention is to provide a kind of humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element.The present invention adopts following technical scheme.
One embodiment of the present invention relate to a kind of humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element, and it comprises following component and weight part thereof:
Filter mud fermentation liquid: 50-100 part
Moderate-element fertilizer: 1-5 part
Trace element fertilizer: 1-5 part
Wherein said filter mud is from sugar refinery, grain distillery, Gourmet Powder Factory or yeast factory, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 50-80 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 100～200: 300～800: 0.5～5;
3) fermented liquid temperature is maintained to 50-80 ℃, fermentation 5-10 days, regularly stirs fermented liquid during this time;
4) afterwards, fermented liquid normal temperature is left standstill to 5-10 hour, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/4 to 1/8 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 6-8, obtain filter mud fermentation liquid;
Preferably, described Chemical Mixed Fertilizer comprises following component and weight part thereof:
Filter mud fermentation liquid: 50-100 part, preferably 60-80 part, more preferably 70 parts;
Macroelement fertilizer: 10-20 part, preferably 12-16 part, more preferably 15 parts;
Moderate-element fertilizer: 2-8 part, preferably 4-6 part, more preferably 5 parts;
Trace element fertilizer: 1-5 part, preferably 2-4 part, more preferably 3 parts;
Aminoacids complex: 1-5 part, preferably 2-5 part, more preferably 4 parts;
Wetting and penetrating agent: 2-6 part, preferably 3-5 part, more preferably 4 parts;
Wherein,
Described filter mud is from sugar refinery, grain distillery, Gourmet Powder Factory or yeast factory, and preferred described filter mud is from sugar refinery or grain distillery, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 50-80 ℃, preferably 60-75 ℃, more preferably 70 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 100～200: 300～800: 0.5～5, preferably 130～160: 400～600: 2～4, and more preferably 150: 500: 3;
3) fermented liquid temperature is maintained to 50-80 ℃, preferably 60-80 ℃, more preferably 70 ℃, fermentation 5-10 days, preferably 6-9 days, more preferably 8 days, regularly stir during this time fermented liquid, preferably within every 0.5 day, stir once;
4) afterwards, fermented liquid normal temperature is left standstill to 5-10 hour, preferably 6-8 hour, more preferably 8 hours, collect fermented liq, abandon bottom settlings thing;
5) by the fermented liq obtaining at 60-80 ℃, preferably concentrated at 70 ℃, be concentrated into and collect 1/4 to 1/8 of fermented liq initial weight, preferably 1/5 to 1/7, more preferably 1/6, stop concentrating, concentrated solution is down to normal temperature, and regulate described concentrated solution pH value to 6-8, preferably pH value to 7, obtains filter mud fermentation liquid;
Described fermenting agent is selected from aspergillus oryzae, aspergillus niger, bacillus cereus, bacillus megaterium, one or more in candiyeast, nitrogen-fixing rhizobia, azospirillum thermally; Preferably, described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1～2: 1～3: 1～2; Preferred, described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1: 2: 1;
Described macroelement fertilizer is selected from one or more in urea, ammonium nitrate, potassium primary phosphate, calcium superphosphate, Repone K, saltpetre; Preferably, described macroelement fertilizer is ammonium nitrate, potassium primary phosphate and saltpetre, and its weight ratio is 1～2: 1～2: 1～2; Preferred, described macroelement fertilizer is ammonium nitrate, potassium primary phosphate and saltpetre, and its weight ratio is 1: 1: 1;
Described moderate-element fertilizer is selected from one or more in calcium sulfate, magnesium sulfate, magnesium chloride; Preferably, described moderate-element fertilizer is calcium sulfate and magnesium sulfate, and its weight ratio is 1: 1～3; Preferred, described moderate-element fertilizer is calcium sulfate and magnesium sulfate, and its weight ratio is 1: 2;
Described trace element fertilizer is selected from one or more in zinc sulfate, manganous sulfate, zinc chloride, copper sulfate, ammonium molybdate, Sodium orthomolybdate; Preferably, described trace element fertilizer is zinc sulfate, manganous sulfate and Sodium orthomolybdate, and its weight ratio is 1～3: 1～3: 1～3; Preferred, described trace element fertilizer is zinc sulfate, manganous sulfate and Sodium orthomolybdate, and its weight ratio is 2: 1: 1;
Described wetting and penetrating agent is selected from such as C of penetrant t, alkyl glycoside
8-C
10alkyl glycoside, C
12-C
14one or more in alkyl glycoside, trisiloxanes Soxylat A 25-7, oleoyl N-methyltaurine sodium; Preferably, described wetting and penetrating agent is penetrant t, trisiloxanes Soxylat A 25-7 and oleoyl N-methyltaurine sodium, and its weight ratio is 1～2: 1～2: 1～2; Preferred, described wetting and penetrating agent is penetrant t, trisiloxanes Soxylat A 25-7 and oleoyl N-methyltaurine sodium, and its weight ratio is 1: 1: 2;
Filter mud fermentation liquid of the present invention obtains at specifically fermentation condition bottom fermentation, the surprised discovery of contriver is in the time being applied to cucumber by the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element of the present invention, with respect to not using cucumber, can obviously increase the chlorophyll content of cucumber leaves, for example increase by 3%, preferably increase by 6%; In addition, with respect to not using cucumber, can increase cucumber yield, for example, increase production 5%, preferably increase production 10%.
The using method of Chemical Mixed Fertilizer of the present invention for example can be used in the vegetative period of cucumber, and vegetative period of for example cucumber, preferably initial bloom stage is watered spray application to tying the melon after date phase, is watered extension rate and is 2-10 doubly.Whole growth season can spray one or many, and preferably 1-3 time, more preferably 2-3 time.
Preferably, in the present invention, described Chemical Mixed Fertilizer further comprises the thifluzamide of 0.05-0.5 weight part, adds thifluzamide can further increase the chlorophyll content of cucumber leaves and increase cucumber yield.For example:
Another embodiment of the invention relates to a kind of humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element, and it comprises following component and weight part thereof:
Wherein,
Described filter mud is from sugar refinery, grain distillery, Gourmet Powder Factory or yeast factory, and preferred described filter mud is from sugar refinery or grain distillery, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 50-80 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 100～200: 300～800: 0.5～5;
3) fermented liquid temperature is maintained to 50-80 ℃, fermentation 5-10 days, regularly stirs fermented liquid during this time;
4) afterwards, fermented liquid normal temperature is left standstill to 5-10 hour, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/4 to 1/8 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 6-8, obtain filter mud fermentation liquid;
Described fermenting agent is selected from aspergillus oryzae, aspergillus niger, bacillus cereus, bacillus megaterium, one or more in candiyeast, nitrogen-fixing rhizobia, azospirillum thermally;
Described macroelement fertilizer is selected from one or more in urea, ammonium nitrate, potassium primary phosphate, calcium superphosphate, Repone K, saltpetre;
Described moderate-element fertilizer is selected from one or more in calcium sulfate, magnesium sulfate, magnesium chloride;
Described trace element fertilizer is selected from one or more in zinc sulfate, manganous sulfate, zinc chloride, copper sulfate, ammonium molybdate, Sodium orthomolybdate;
Described wetting and penetrating agent is selected from one or more in penetrant t, alkyl glycoside, trisiloxanes Soxylat A 25-7, oleoyl N-methyltaurine sodium.
Preferably, the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element of the present invention, it comprises following component and weight part thereof:
Wherein,
Described filter mud is from cane sugar factory, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 60-75 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 130～160: 400～600: 2～4;
3) fermented liquid temperature is maintained to 60-80 ℃, fermentation 6-9 days, regularly stirs fermented liquid during this time;
4) afterwards, fermented liquid normal temperature is left standstill to 6-8 hour, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/5 to 1/7 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid;
Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1～2: 1～3: 1～2;
Described macroelement fertilizer is ammonium nitrate, potassium primary phosphate and saltpetre, and its weight ratio is 1～2: 1～2: 1～2;
Described moderate-element fertilizer is calcium sulfate and magnesium sulfate, and its weight ratio is 1: 1～3;
Described trace element fertilizer is zinc sulfate, manganous sulfate and Sodium orthomolybdate, and its weight ratio is 1～3: 1～3: 1～3;
Described wetting and penetrating agent is penetrant t, trisiloxanes Soxylat A 25-7 and oleoyl N-methyltaurine sodium, and its weight ratio is 1～2: 1～2: 1～2.
Preferred, the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element of the present invention, wherein said Chemical Mixed Fertilizer comprises following component and weight part thereof:
Wherein,
Described filter mud is from cane sugar factory, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 70 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 150: 500: 3;
3) fermented liquid temperature is maintained to 70 ℃, ferment 8 days, within every 0.5 day, stir once;
4) afterwards, fermented liquid normal temperature is left standstill to 8 hours, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 70 ℃, be concentrated into and collect 1/6 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid;
Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1: 2: 1;
Described macroelement fertilizer is ammonium nitrate, potassium primary phosphate and saltpetre, and its weight ratio is 1: 1: 1;
Described moderate-element fertilizer is calcium sulfate and magnesium sulfate, and its weight ratio is 1: 2;
Described trace element fertilizer is zinc sulfate, manganous sulfate and Sodium orthomolybdate, and its weight ratio is 2: 1: 1;
Described wetting and penetrating agent is penetrant t, trisiloxanes Soxylat A 25-7 and oleoyl N-methyltaurine sodium, and its weight ratio is 1: 1: 2.
In the time that the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element that contains thifluzamide of the present invention is applied to cucumber, surprised discovery, with respect to the cucumber of not using, can obviously increase the chlorophyll content of cucumber leaves, for example increase by 5%, preferably increase by 8%; In addition, with respect to not using cucumber, can increase cucumber yield, for example, increase production 8%, preferably increase production 15%.
The using method of Chemical Mixed Fertilizer of the present invention for example can be used in the vegetative period of cucumber, and vegetative period of for example cucumber, preferably initial bloom stage is watered spray application to tying the melon after date phase, is watered extension rate and is 2-10 doubly.Whole growth season can spray one or many, and preferably 1-3 time, more preferably 2-3 time.
Another aspect of the present invention relates to the preparation method of the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element of the present invention, and its concrete steps are:
1) prepare filter mud fermentation liquid: a. and add water in fermentor tank, then fermentor tank is warming up to 50-80 ℃; B. then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 100～200: 300～800: 0.5～5; C. fermented liquid temperature is maintained to 50-80 ℃, fermentation 5-10 days, regularly stirs fermented liquid during this time; D. after, fermented liquid normal temperature is left standstill to 5-10 hour, collect fermented liq, abandon bottom settlings thing; E. the fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/4 to 1/8 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 6-8, obtain filter mud fermentation liquid.Wherein, described filter mud is from sugar refinery, grain distillery, Gourmet Powder Factory or yeast factory, preferably from sugar refinery or grain distillery; Described fermenting agent is aspergillus oryzae, aspergillus niger, bacillus cereus, bacillus megaterium, one or more in candiyeast, nitrogen-fixing rhizobia, azospirillum thermally;
2) successively macroelement fertilizer, moderate-element fertilizer, trace element fertilizer, aminoacids complex, wetting and penetrating agent and the thifluzamide of formula ratio are added in the filter mud fermentation liquid of formula ratio;
3) by step 2) filter mud fermentation liquid under 100-1000rpm, stir 30min, mix, obtain fluid Chemical Mixed Fertilizer of the present invention.
Preferably, described filter mud is from cane sugar factory, and the preparation method of described filter mud fermentation liquid is:
A. in fermentor tank, add water, then fermentor tank is warming up to 60-75 ℃;
B. then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 130～160: 400～600: 2～4;
C. fermented liquid temperature is maintained to 60-80 ℃, fermentation 6-9 days, regularly stirs fermented liquid during this time;
D. after, fermented liquid normal temperature is left standstill to 6-8 hour, collect fermented liq, abandon bottom settlings thing;
E. the fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/5 to 1/7 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid;
Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1～2: 1～3: 1～2.
Preferred, described filter mud is from cane sugar factory, and the preparation method of described filter mud fermentation liquid is:
A. in fermentor tank, add water, then fermentor tank is warming up to 70 ℃;
B. then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 150: 500: 3;
C. fermented liquid temperature is maintained to 70 ℃, ferment 8 days, within every 0.5 day, stir once;
D. after, fermented liquid normal temperature is left standstill to 8 hours, collect fermented liq, abandon bottom settlings thing;
E. the fermented liq obtaining is concentrated at 70 ℃, be concentrated into and collect 1/6 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid;
Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1: 2: 1.
Another aspect of the present invention relates to the purposes of described fluid Chemical Mixed Fertilizer for increasing cucumber leaves chlorophyll content and/or increase cucumber yield.In the time that the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element of the present invention is applied to cucumber, with respect to not using cucumber, can obviously increase the chlorophyll content of cucumber leaves, for example increase by 3%, preferably increase by 6%; In addition, with respect to not using cucumber, can increase cucumber yield, for example, increase production 5%, preferably increase production 10%.Preferably, when additionally adding after thifluzamide, with respect to not using cucumber, can obviously increase the chlorophyll content of cucumber leaves, for example, increase by 5%, preferably increase by 8%; In addition, with respect to not using cucumber, can increase cucumber yield, for example, increase production 8%, preferably increase production 15%.
The using method of Chemical Mixed Fertilizer of the present invention for example can be used in the vegetative period of cucumber, and vegetative period of for example cucumber, preferably initial bloom stage is watered spray application to tying the melon after date phase, is watered extension rate and is 2-10 doubly.Whole growth season can spray one or many, and preferably 1-3 time, more preferably 2-3 time.
In the present invention, method described in " plant physiology experiment instructs (second edition) " that chlorophyll content is published according to Chen Jianxun chief editor, press of South China Science & Engineering University is measured, and the wavelength of mensuration is respectively 663nm (chlorophyll a) and 645nm (chlorophyll b).
The present invention's various materials used are commercially available or hold facile.For example, the present invention's filter mud used for example, from sugar refinery, grain distillery, Gourmet Powder Factory or yeast factory, cane sugar factory; The present invention's macroelement fertilizer, moderate-element fertilizer and trace element fertilizer used is commercially available; The present invention fermenting agent for example aspergillus oryzae, aspergillus niger, bacillus cereus, bacillus megaterium used, thermally candiyeast, nitrogen-fixing rhizobia, azospirillum are to be all easy on market, for example, purchased from the western beneficial micro-yield increasing fungus biotechnological formulation of Cangzhou City fortune factory, Jiangsu Lv Ke Bioisystech Co., Ltd, red autumnal leaves bio tech ltd of hazard prevention etc., described microbial inoculum can be bacterium powder or bacterium liquid, for example hundred million/g of 50-150 of viable bacteria content in bacterium powder, for example hundred million/ml of 50-150 of viable bacteria content in bacterium liquid; Described wetting and penetrating agent is commercially available, for example can be purchased from BASF, Rhodia, Mai Tu new high-tech material company limited etc.; Described aminoacids complex is commercially available, for example, reach chemical fertilizer company limited etc. purchased from Zhengzhou He Kang chemical fertilizer company limited, Shandong rich peasant; Described thifluzamide is the former medicine of thifluzamide or its preparation, and as 25% thifluzamide wettable powder pulvis, 50% thifluzamide suspension agent etc., described preparation is commercially available.
Beneficial effect of the present invention is:
1, filter mud is carried out to liquid fermenting at specified conditions, make fermentation more complete, benefit materials utilization is more abundant, and described fermented liquid can increase chlorophyll content of plant, and makes crop yield;
2, find to add such as thifluzamide of suitable sterilant in above-mentioned fluid Chemical Mixed Fertilizer, can further increase chlorophyll content of plant, further improve crop yield simultaneously;
3, compound of the present invention the necessary multiple nutrients material of plant-growth, can reduce fertilizer application frequency, guarantee the nutrition that sufficient plant-growth is required simultaneously.
Embodiment
For a better understanding of the present invention, further explain in the mode of embodiment below, but the present invention is not restricted to this.
Embodiment 1
Take the fresh filter mud of 300kg cane sugar factory, 6kg zymophyte powder (the wherein each 2kg of aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and viable bacteria content be greater than 10,000,000,000/g) for subsequent use.
Clean fermentor tank, and add 1000kg water in fermentor tank, then fermentor tank is warming up to 70 ℃; Afterwards, in fermentor tank, add successively load weighted fresh filter mud and zymophyte powder, and stir; Then filter mud is fermented, wherein fermented liquid temperature maintains 70 ℃, and continuing fermentation 8 days stirs once for every 0.5 day.
After having fermented, fermented liquid normal temperature is left standstill to 8 hours, collect fermented liq, abandon bottom settlings thing; And the fermented liq obtaining is concentrated at 70 ℃, be concentrated into 150kg left and right, now stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid, about 150kg.
Take above-mentioned filter mud fermentation liquid 70kg, then add wherein while stirring ammonium nitrate 5kg, potassium primary phosphate 5kg, saltpetre 5kg, calcium sulfate 1.67kg, magnesium sulfate 3.33kg, zinc sulfate 1.5kg, manganous sulfate 0.75kg, Sodium orthomolybdate 0.75kg, aminoacids complex 4kg, penetrant t 1kg, trisiloxanes Soxylat A 25-7 1kg, oleoyl N-methyltaurine sodium 2kg.Then described fermented liquid is continued under 150rpm to stir 30min, it is mixed, obtain fluid Chemical Mixed Fertilizer of the present invention.
Embodiment 2
Take the fresh filter mud of 200kg beet-sugar factory, 4kg zymophyte powder (the wherein each 2kg of candiyeast and nitrogen-fixing rhizobia thermally, and viable bacteria content be greater than 10,000,000,000/g) for subsequent use.
Clean fermentor tank, and add 700kg water in fermentor tank, then fermentor tank is warming up to 60 ℃; Afterwards, in fermentor tank, add successively load weighted fresh filter mud and zymophyte powder, and stir; Then filter mud is fermented, wherein fermented liquid temperature is warming up to 75 ℃, and continuing fermentation 10 days stirs once for every 0.5 day.
After having fermented, fermented liquid normal temperature is left standstill to 10 hours, collect fermented liq, abandon bottom settlings thing; And the fermented liq obtaining is concentrated at 80 ℃, be concentrated into 120kg left and right, now stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid, about 120kg.
Take above-mentioned filter mud fermentation liquid 100kg, then add wherein while stirring urea 6kg, phosphorus Repone K 10kg, calcium sulfate 4kg, magnesium chloride 4kg, zinc chloride 2kg, ammonium molybdate 2kg, aminoacids complex 5kg, penetrant t 2kg, C
8-C
10alkyl glycoside 4kg.Then described fermented liquid is continued under 150rpm to stir 30min, it is mixed, obtain fluid Chemical Mixed Fertilizer of the present invention.
Embodiment 3
Take the fresh filter mud of 300kg cane sugar factory, 6kg zymophyte powder (the wherein each 2kg of aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and viable bacteria content be greater than 10,000,000,000/g) for subsequent use.
Clean fermentor tank, and add 1000kg water in fermentor tank, then fermentor tank is warming up to 70 ℃; Afterwards, in fermentor tank, add successively load weighted fresh filter mud and zymophyte powder, and stir; Then filter mud is fermented, wherein fermented liquid temperature maintains 70 ℃, and continuing fermentation 8 days stirs once for every 0.5 day.
After having fermented, fermented liquid normal temperature is left standstill to 8 hours, collect fermented liq, abandon bottom settlings thing; And the fermented liq obtaining is concentrated at 70 ℃, be concentrated into and collect 1/6 of fermented liq initial weight, about 150kg, now stops concentrating, and concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtains filter mud fermentation liquid, about 150kg.
Take above-mentioned filter mud fermentation liquid 70kg, then add wherein while stirring ammonium nitrate 5kg, potassium primary phosphate 5kg, saltpetre 5kg, calcium sulfate 1.67kg, magnesium sulfate 3.33kg, zinc sulfate 1.5kg, manganous sulfate 0.75kg, Sodium orthomolybdate 0.75kg, aminoacids complex 4kg, penetrant t 1kg, trisiloxanes Soxylat A 25-7 1kg, oleoyl N-methyltaurine sodium 2kg and 25% thifluzamide wettable powder 320g (amounting to thifluzamide activeconstituents 80g).Then described fermented liquid is continued under 150rpm to stir 30min, it is mixed, obtain fluid Chemical Mixed Fertilizer of the present invention.
Embodiment 4
Take the fresh filter mud of 200kg beet-sugar factory, 4kg zymophyte powder (the wherein each 2kg of candiyeast and nitrogen-fixing rhizobia thermally, and viable bacteria content be greater than 10,000,000,000/g) for subsequent use.
Clean fermentor tank, and add 700kg water in fermentor tank, then fermentor tank is warming up to 60 ℃; Afterwards, in fermentor tank, add successively load weighted fresh filter mud and zymophyte powder, and stir; Then filter mud is fermented, wherein fermented liquid temperature is warming up to 75 ℃, and continuing fermentation 10 days stirs once for every 0.5 day.
After having fermented, fermented liquid normal temperature is left standstill to 10 hours, collect fermented liq, abandon bottom settlings thing; And the fermented liq obtaining is concentrated at 80 ℃, be concentrated into 120kg left and right, now stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid, about 120kg.
Take above-mentioned filter mud fermentation liquid 100kg, then add wherein while stirring urea 6kg, phosphorus Repone K 10kg, calcium sulfate 4kg, magnesium chloride 4kg, zinc chloride 2kg, ammonium molybdate 2kg, aminoacids complex 5kg, penetrant t 2kg, C
8-C
10alkyl glycoside 4kg and 50% thifluzamide suspension agent 240g (amounting to thifluzamide activeconstituents 120g).Then described fermented liquid is continued under 150rpm to stir 30min, it is mixed, obtain fluid Chemical Mixed Fertilizer of the present invention.
Comparative example 1
Take 500kg water, then add wherein the fresh filter mud 200kg of cane sugar factory, stir 30min, leave standstill 8 hours afterwards, disgorging, supernatant liquor is concentrated at 80 ℃, obtain the about 110kg of concentrated solution, concentrated solution is down to normal temperature, and regulate described concentrated solution pH value to 7.Then add wherein 20kg ammonium nitrate, 7kg magnesium nitrate.After having fed in raw material, under 150rpm, continue to stir 30min, it is mixed, obtain comparative fluid fertilizer, wherein filter mud is not carried out to fermentative processing.
Test example 1 cucumber yield comparison
Choose smooth open country, be divided into 1-6 totally 6 communities, water respectively, spread fertilizer over the fields base manure, turn over, plant afterwards cucumber (kind: Shandong cucumber No. 8) plantation.For each community, after initial bloom stage, 10 days and knot melon Sheng Qiduige community spray respectively the product of the present invention of table 1 correspondence and comparative example product and clear water contrast respectively, spray altogether twice in cucumber whole growth season, in wherein spraying at every turn, the consumption of product of the present invention and comparative example product is amounted to a mu consumption and is 20kg, and extension rate is 4 times.After results, the each community of statistics cucumber yield, contrasts.
The comparison of the each processing of table 1 cucumber yield
| Cell number | Process | Extension rate | Amount to per mu yield (kg) |
| 1 | Embodiment 1 product | 4 | 6200 |
| 2 | Embodiment 2 products | 4 | 6110 |
| 3 | Embodiment 3 products | 4 | 6220 |
| 4 | Embodiment 4 products | 4 | 6150 |
| 5 | Comparative example 1 product | 4 | 5850 |
| 6 | Clear water contrast | - | 5500 |
Above-mentioned data are not difficult to find out, product of the present invention is obvious with respect to the effect of increasing production of comparative example product and clear water contrast, for example, while using embodiment of the present invention 1-4 product, per mu yield is respectively 6200kg, 6110kg, 6220kg, 6150kg, and per mu yield is only 5850 while using comparative example 1 product, the per mu yield of clear water contrast is 5500kg.Further, it can also be seen that from above-mentioned data, when product of the present invention further comprises sterilant for example when thifluzamide, also can increase to a certain extent cucumber yield, for example, while using embodiment 3 product, with respect to embodiment 1 product volume increase 20kg, while using embodiment 4 product, increase production 40kg with respect to embodiment 2 products.That is to say, can further increase cucumber yield when adding after thifluzamide.
Test example 2 measuring chlorophyll contents
For respectively processing in test example 1, when spraying for the second time described fluid fertilizer after 10 days, apply multi-point sampling method and gather respectively 5 leaves of each community cucumber leaves, mainly gather plant middle and upper part healthy leaves.Method described in " plant physiology experiment instructs (second edition) " of then publishing according to Chen Jianxun chief editor, press of South China Science & Engineering University is measured, measure respectively the content of chlorophyll a, b at 663nm and 645nm, and then the total content of calculating blade Determination of Chlorophyll, its result is as shown in table 2 below.
The comparison of the each processing of table 2 chlorophyll content
| Cell number | Process | Chlorophyll content (mg/g FW) |
| 1 | Embodiment 1 product | 2.35 |
| 2 | Embodiment 2 products | 2.32 |
| 3 | Embodiment 3 products | 2.57 |
| 4 | Embodiment 4 products | 2.52 |
| 5 | Comparative example 1 product | 2.05 |
| 6 | Clear water contrast | 1.94 |
Above-mentioned data are not difficult to find out, use after product of the present invention, with respect to comparative example product and clear water contrast, the chlorophyll content of cucumber leaves obviously increases, for example, while using embodiment of the present invention 1-4 product, chlorophyll content is respectively 2.35,2.32,2.57 and 2.52mg/g, and chlorophyll content is only 2.05mg/g while using comparative example 1 product, only a little more than clear water contrast 1.94mg/g.Further, in the time that product of the present invention further comprises sterilant thifluzamide, can further increase chlorophyll content in leaf blades, for example, while using embodiment 3 product, the chlorophyll content of blade is 2.57mg/g, is significantly higher than the 2.35mg/g of embodiment 1 product; While using embodiment 4 product, the chlorophyll content of blade is 2.52mg/g, is significantly higher than the 2.32mg/g of embodiment 2 products.That is to say, add the chlorophyll content that can further increase cucumber leaves after thifluzamide.
Above-mentioned example is only to further explanation of the present invention, is not limitation of the invention, by the scheme that such scheme is simply adjusted and then obtained, same within the application's protection domain.
Claims (10)
1. a humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element, it comprises following component and weight part thereof:
Filter mud fermentation liquid: 50-100 part
Moderate-element fertilizer: 1-5 part
Trace element fertilizer: 1-5 part
Wherein said filter mud is from sugar refinery, grain distillery, Gourmet Powder Factory or yeast factory.
2. the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element according to claim 1, is characterized in that, described Chemical Mixed Fertilizer comprises following component and weight part thereof:
Wherein,
Described filter mud is from sugar refinery or grain distillery, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 50-80 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 100～200: 300～800: 0.5～5;
3) fermented liquid temperature is maintained to 50-80 ℃, fermentation 5-10 days, regularly stirs fermented liquid during this time;
4) afterwards, fermented liquid normal temperature is left standstill to 5-10 hour, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/4 to 1/8 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 6-8, obtain filter mud fermentation liquid;
Described fermenting agent is selected from aspergillus oryzae, aspergillus niger, bacillus cereus, bacillus megaterium, one or more in candiyeast, nitrogen-fixing rhizobia, azospirillum thermally;
Described macroelement fertilizer is selected from one or more in urea, ammonium nitrate, potassium primary phosphate, calcium superphosphate, Repone K, saltpetre;
Described moderate-element fertilizer is selected from one or more in calcium sulfate, magnesium sulfate, magnesium chloride;
Described trace element fertilizer is selected from one or more in zinc sulfate, manganous sulfate, zinc chloride, copper sulfate, ammonium molybdate, Sodium orthomolybdate;
Described wetting and penetrating agent is selected from one or more in penetrant t, alkyl glycoside, trisiloxanes Soxylat A 25-7, oleoyl N-methyltaurine sodium.
3. the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element according to claim 2, is characterized in that, described Chemical Mixed Fertilizer further comprises the thifluzamide of 0.05-0.5 weight part.
4. according to the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element described in claim 2 or 3, it is characterized in that, described Chemical Mixed Fertilizer comprises following component and weight part thereof:
Wherein,
Described filter mud is from cane sugar factory, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 60-75 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 130～160: 400～600: 2～4;
3) fermented liquid temperature is maintained to 60-80 ℃, fermentation 6-9 days, regularly stirs fermented liquid during this time;
4) afterwards, fermented liquid normal temperature is left standstill to 6-8 hour, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/5 to 1/7 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid;
Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1～2: 1～3: 1～2;
Described macroelement fertilizer is ammonium nitrate, potassium primary phosphate and saltpetre, and its weight ratio is 1～2: 1～2: 1～2;
Described moderate-element fertilizer is calcium sulfate and magnesium sulfate, and its weight ratio is 1: 1～3;
Described trace element fertilizer is zinc sulfate, manganous sulfate and Sodium orthomolybdate, and its weight ratio is 1～3: 1～3: 1～3;
Described wetting and penetrating agent is penetrant t, trisiloxanes Soxylat A 25-7 and oleoyl N-methyltaurine sodium, and its weight ratio is 1～2: 1～2: 1～2.
5. the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element according to claim 4, is characterized in that, described Chemical Mixed Fertilizer comprises following component and weight part thereof:
Wherein,
Described filter mud is from cane sugar factory, and described filter mud fermentation liquid obtains by the following method:
1) in fermentor tank, add water, then fermentor tank is warming up to 70 ℃;
2) then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 150: 500: 3;
3) fermented liquid temperature is maintained to 70 ℃, ferment 8 days, within every 0.5 day, stir once;
4) afterwards, fermented liquid normal temperature is left standstill to 8 hours, collect fermented liq, abandon bottom settlings thing;
5) fermented liq obtaining is concentrated at 70 ℃, be concentrated into and collect 1/6 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid;
Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1: 2: 1;
Described macroelement fertilizer is ammonium nitrate, potassium primary phosphate and saltpetre, and its weight ratio is 1: 1: 1;
Described moderate-element fertilizer is calcium sulfate and magnesium sulfate, and its weight ratio is 1: 2;
Described trace element fertilizer is zinc sulfate, manganous sulfate and Sodium orthomolybdate, and its weight ratio is 2: 1: 1;
Described wetting and penetrating agent is penetrant t, trisiloxanes Soxylat A 25-7 and oleoyl N-methyltaurine sodium, and its weight ratio is 1: 1: 2.
6. the preparation method of the humic acid type fluid Chemical Mixed Fertilizer that comprises filter mud and middle trace element described in claim 1-5, is characterized in that:
1) prepare filter mud fermentation liquid: a. and add water in fermentor tank, then fermentor tank is warming up to 50-80 ℃; B. then, then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 100～200: 300～800: 0.5～5; C. fermented liquid temperature is maintained to 50-80 ℃, fermentation 5-10 days, regularly stirs fermented liquid during this time; D. after, fermented liquid normal temperature is left standstill to 5-10 hour, collect fermented liq, abandon bottom settlings thing; E. the fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/4 to 1/8 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 6-8, obtain filter mud fermentation liquid; Wherein, described fermenting agent is aspergillus oryzae, aspergillus niger, bacillus cereus, bacillus megaterium, one or more in candiyeast, nitrogen-fixing rhizobia, azospirillum thermally;
2) successively macroelement fertilizer, moderate-element fertilizer, trace element fertilizer, aminoacids complex, wetting and penetrating agent and the thifluzamide of formula ratio are added in the filter mud fermentation liquid of formula ratio;
3) by step 2) filter mud fermentation liquid under 100-1000rpm, stir 30min, mix, obtain fluid Chemical Mixed Fertilizer of the present invention.
7. method according to claim 6, is characterized in that, described filter mud is from cane sugar factory, and the preparation method of described filter mud fermentation liquid is: a. adds water in fermentor tank, then fermentor tank is warming up to 60-75 ℃; B. then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 130～160: 400～600: 2～4; C. fermented liquid temperature is maintained to 60-80 ℃, fermentation 6-9 days, regularly stirs fermented liquid during this time; D. after, fermented liquid normal temperature is left standstill to 6-8 hour, collect fermented liq, abandon bottom settlings thing; E. the fermented liq obtaining is concentrated at 60-80 ℃, be concentrated into and collect 1/5 to 1/7 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid; Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1～2: 1～3: 1～2.
8. according to the method described in claim 6 or 7, it is characterized in that, described filter mud is from cane sugar factory, and the preparation method of described filter mud fermentation liquid is: a. adds water in fermentor tank, then fermentor tank is warming up to 70 ℃; B. then, in fermentor tank, add successively fresh filter mud and fermenting agent, and stir; Wherein the weight ratio control of filter mud, water and fermenting agent is 150: 500: 3; C. fermented liquid temperature is maintained to 70 ℃, ferment 8 days, within every 0.5 day, stir once; D. after, fermented liquid normal temperature is left standstill to 8 hours, collect fermented liq, abandon bottom settlings thing; E. the fermented liq obtaining is concentrated at 70 ℃, be concentrated into and collect 1/6 of fermented liq initial weight, stop concentrating, concentrated solution is down to normal temperature, and regulates described concentrated solution pH value to 7, obtain filter mud fermentation liquid; Described fermenting agent is aspergillus niger, bacillus megaterium and nitrogen-fixing rhizobia, and its weight ratio is 1: 2: 1.
9. the fluid Chemical Mixed Fertilizer preparing according to the method described in fluid Chemical Mixed Fertilizer or claim 6-8 described in claim 1-5 is for increasing the purposes of cucumber leaves chlorophyll content and/or increase cucumber yield.
10. purposes according to claim 9, is characterized in that, the using method of described Chemical Mixed Fertilizer is used for being watered spraying, and extension rate is 2-10 times; Be the vegetative period of cucumber the period of using, and preferably initial bloom stage sprays to tying the melon after date phase; It is one or many that whole growth season sprays number of times, preferably 1-3 time, and more preferably 2-3 time.
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