CN103773170B - A kind of frie retardant coating adding biotite powder - Google Patents

A kind of frie retardant coating adding biotite powder Download PDF

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CN103773170B
CN103773170B CN201410057041.4A CN201410057041A CN103773170B CN 103773170 B CN103773170 B CN 103773170B CN 201410057041 A CN201410057041 A CN 201410057041A CN 103773170 B CN103773170 B CN 103773170B
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parts
powder
biotite
retardant coating
frie retardant
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CN103773170A (en
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何益庆
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Anhui Willy Paint Science And Technology Ltd
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Tongling Xiangyun Fire Fighting Technology Co Ltd
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Abstract

The invention discloses a kind of frie retardant coating adding biotite powder, be made up of the raw material of following weight part: biotite powder 10-15 part, mullite powder 5-8 part, nano imvite 8-10 part, dimethyl phosphate 3-5 part, acrylic resin 10-15 part, aminoresin 15-30 part, chlorinated rubber 2-4 part, urea phosphate 2-3 part, silane coupling agent 1-3 part, sorbyl alcohol 5-6 part, aluminum oxide 7-9 part, borax 3-5 part, vermiculite 8-10 part, semi-hydrated gypsum 3-4 part, Graphite Powder 99 3-5 part, titanium dioxide 2-3 part, organic-silicon-modified benzene emulsion 8-13 part, ether of cellulose 5-6 part, glass powder 2-3 part, isobutylene-isoprene latex 6-8 part, Sodium Silicofluoride 2-3 part, wood fibre 3-5 part.Frie retardant coating of the present invention has that heat insulation fire retardant is good, bonding force is good, water tolerance, resistance to acids and bases, salt tolerant corrodibility are good, difficult drop-off, shelf-stable, the advantages such as asepsis environment-protecting.

Description

A kind of frie retardant coating adding biotite powder
Technical field
The present invention relates to fire-fighting quipment technical field, particularly relate to a kind of frie retardant coating adding biotite powder.
Background technology
At present, frie retardant coating is more and more extensive in petrochemical complex, electric power, industry and the sector application such as covil construction, machinery.Frie retardant coating is for flammable substrates surface, can reduces by the rapid spread of the combustibility of painting material surface, retardance fire, in order to improve by a kind of speciality coating being coated with material fire endurance.But there is coating face sticking power in existing frie retardant coating, moistureproofness, water tolerance, frost resistance, flame retardant resistance are difficult to the problem taken into account.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide that a kind of fire insulation performance is good, bonding force is good,
The frie retardant coating of the interpolation biotite powder of water-tolerant, resistance to acids and bases, erosion resistance, difficult drop-off, and the impact of cold cycle can be stood, shelf-stable, asepsis environment-protecting.
The present invention adopts following technical scheme to achieve these goals:
A kind of frie retardant coating adding biotite powder, be made up of the raw material of following weight part: biotite powder 10-15 part, mullite powder 5-8 part, nano imvite 8-10 part, dimethyl phosphate 3-5 part, acrylic resin 10-15 part, aminoresin 15-30 part, chlorinated rubber 2-4 part, urea phosphate 2-3 part, silane coupling agent 1-3 part, sorbyl alcohol 5-6 part, aluminum oxide 7-9 part, borax 3-5 part, vermiculite 8-10 part, semi-hydrated gypsum 3-4 part, Graphite Powder 99 3-5 part, titanium dioxide 2-3 part, organic-silicon-modified benzene emulsion 8-13 part, ether of cellulose 5-6 part, glass powder 2-3 part, isobutylene-isoprene latex 6-8 part, Sodium Silicofluoride 2-3 part, wood fibre 3-5 part.
Preferably, add the frie retardant coating of biotite powder, be made up of the raw material of following weight part: 13 parts, biotite powder, mullite powder 8 parts, nano imvite 10 parts, dimethyl phosphate 5 parts, acrylic resin 13 parts, 20 parts, aminoresin, chlorinated rubber 3 parts, urea phosphate 2 parts, silane coupling agent 2 parts, sorbyl alcohol 5 parts, 8 parts, aluminum oxide, borax 3 parts, vermiculite 10 parts, semi-hydrated gypsum 3 parts, Graphite Powder 99 4 parts, titanium dioxide 2 parts, organic-silicon-modified benzene emulsion 10 parts, ether of cellulose 6 parts, 2 parts, glass powder, isobutylene-isoprene latex 6 parts, Sodium Silicofluoride 2 parts, wood fibre 3 parts.
The preparation method of the frie retardant coating of described interpolation biotite powder, comprises following preparation process:
(1) by above-mentioned weight ratio, dimethyl phosphate, acrylic resin, aminoresin, chlorinated rubber, silane coupling agent, sorbyl alcohol, organic-silicon-modified benzene emulsion, ether of cellulose, isobutylene-isoprene latex, Sodium Silicofluoride are stirred 10-15min under 1000-1300 rev/min, mix;
(2) in the batch mixing of step (1), add biotite powder successively by above-mentioned weight ratio again, mullite powder, nano imvite, urea phosphate, aluminum oxide, borax, vermiculite, semi-hydrated gypsum, Graphite Powder 99, titanium dioxide stir 30-35min under 2000-2500 rev/min, mix rear development fineness to 50-60um;
(3) add glass powder, wood fibre successively in the batch mixing of the most backward step (2), under 600-800 rev/min, stir 30-35min, after dispersion stirs evenly and get final product.
Compared with the prior art, beneficial effect of the present invention is as follows:
By adding, biotite powder, mullite powder, nano imvite etc. are fire-resistant in the present invention, resistance to acids and bases composition is in frie retardant coating, adjustment formula, solves that existing frie retardant coating exists sticking power, moistureproofness, water tolerance, frost resistance, flame retardant resistance is difficult to the problem taken into account.Frie retardant coating of the present invention has that heat insulation fire retardant is good, bonding force is good, water tolerance, resistance to acids and bases, salt tolerant corrodibility are good, difficult drop-off, shelf-stable, the advantages such as asepsis environment-protecting.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
Add a frie retardant coating for biotite powder, be made up of the raw material of following weight part: 13 parts, biotite powder, mullite powder 8 parts, nano imvite 10 parts, dimethyl phosphate 5 parts, acrylic resin 13 parts, 20 parts, aminoresin, chlorinated rubber 3 parts, urea phosphate 2 parts, silane coupling agent 2 parts, sorbyl alcohol 5 parts, 8 parts, aluminum oxide, borax 3 parts, vermiculite 10 parts, semi-hydrated gypsum 3 parts, Graphite Powder 99 4 parts, titanium dioxide 2 parts, organic-silicon-modified benzene emulsion 10 parts, ether of cellulose 6 parts, 2 parts, glass powder, isobutylene-isoprene latex 6 parts, Sodium Silicofluoride 2 parts, wood fibre 3 parts.
The preparation method of the frie retardant coating of described interpolation biotite powder, comprises following preparation process:
(1) by above-mentioned weight ratio, dimethyl phosphate, acrylic resin, aminoresin, chlorinated rubber, silane coupling agent, sorbyl alcohol, organic-silicon-modified benzene emulsion, ether of cellulose, isobutylene-isoprene latex, Sodium Silicofluoride are stirred 15min under 1200 revs/min, mix;
(2) in the batch mixing of step (1), add biotite powder successively by above-mentioned weight ratio again, mullite powder, nano imvite, urea phosphate, aluminum oxide, borax, vermiculite, semi-hydrated gypsum, Graphite Powder 99, titanium dioxide stir 30min under 2500 revs/min, mix rear development fineness to 60um;
(3) add glass powder, wood fibre successively in the batch mixing of the most backward step (2), under 700 revs/min, stir 30min, after dispersion stirs evenly and get final product.
Embodiment 2:
Add a frie retardant coating for biotite powder, be made up of the raw material of following weight part: 10 parts, biotite powder, mullite powder 5 parts, nano imvite 8 parts, dimethyl phosphate 3 parts, acrylic resin 10 parts, 15 parts, aminoresin, chlorinated rubber 2 parts, urea phosphate 2 parts, silane coupling agent 2 parts, sorbyl alcohol 5 parts, 7 parts, aluminum oxide, borax 3 parts, vermiculite 8 parts, semi-hydrated gypsum 3 parts, Graphite Powder 99 3 parts, titanium dioxide 2 parts, organic-silicon-modified benzene emulsion 8 parts, ether of cellulose 5 parts, 2 parts, glass powder, isobutylene-isoprene latex 6 parts, Sodium Silicofluoride 2 parts, wood fibre-5 parts.
The preparation method of the frie retardant coating of described interpolation biotite powder, comprises following preparation process:
(1) by above-mentioned weight ratio, dimethyl phosphate, acrylic resin, aminoresin, chlorinated rubber, silane coupling agent, sorbyl alcohol, organic-silicon-modified benzene emulsion, ether of cellulose, isobutylene-isoprene latex, Sodium Silicofluoride are stirred 15min under 1000 revs/min, mix;
(2) in the batch mixing of step (1), add biotite powder successively by above-mentioned weight ratio again, mullite powder, nano imvite, urea phosphate, aluminum oxide, borax, vermiculite, semi-hydrated gypsum, Graphite Powder 99, titanium dioxide stir 35min under 2000 revs/min, mix rear development fineness to 50um;
(3) add glass powder, wood fibre successively in the batch mixing of the most backward step (2), under 600 revs/min, stir 35min, after dispersion stirs evenly and get final product.
Embodiment 3:
Add a frie retardant coating for biotite powder, be made up of the raw material of following weight part: 15 parts, biotite powder, mullite powder 8 parts, nano imvite 10 parts, dimethyl phosphate 5 parts, acrylic resin 15 parts, 30 parts, aminoresin, chlorinated rubber 4 parts, urea phosphate 3 parts, silane coupling agent 3 parts, sorbyl alcohol 6 parts, 9 parts, aluminum oxide, borax 5 parts, vermiculite 10 parts, semi-hydrated gypsum 4 parts, Graphite Powder 99 5 parts, titanium dioxide 3 parts, organic-silicon-modified benzene emulsion 13 parts, ether of cellulose 6 parts, 3 parts, glass powder, isobutylene-isoprene latex 8 parts, Sodium Silicofluoride 3 parts, wood fibre 5 parts.
The preparation method of the frie retardant coating of described interpolation biotite powder, comprises following preparation process:
(1) by above-mentioned weight ratio, dimethyl phosphate, acrylic resin, aminoresin, chlorinated rubber, silane coupling agent, sorbyl alcohol, organic-silicon-modified benzene emulsion, ether of cellulose, isobutylene-isoprene latex, Sodium Silicofluoride are stirred 10min under 1300 revs/min, mix;
(2) in the batch mixing of step (1), add biotite powder successively by above-mentioned weight ratio again, mullite powder, nano imvite, urea phosphate, aluminum oxide, borax, vermiculite, semi-hydrated gypsum, Graphite Powder 99, titanium dioxide stir 30min under 2500 revs/min, mix rear development fineness to 60um;
(3) add glass powder, wood fibre successively in the batch mixing of the most backward step (2), under 800 revs/min, stir 35min, after dispersion stirs evenly and get final product.
The performance test results of the frie retardant coating of the present embodiment 1 is as shown in the table:
Reference standard Technical indicator Embodiment 1 result
Condition in container GB/T6753.3-86 Without caking, viscous fluid Without caking, viscous fluid
Surface drying time GB/T1728-89 ≤ 3 hours 0.5 hour
Water tolerance GB/T1733-93 24 hours, peel off without wrinkling, nothing 160 hours, peel off without wrinkling, nothing
Oil-proofness GA181-985.7 Soak 7 days, peel off without wrinkling, nothing Soak 50 days, peel off without wrinkling, nothing
Cold-hot circulates GA191-985.10 15 circulations, peel off without wrinkling, nothing 45 circulations, peel off without wrinkling, nothing
Sticking power GB/T1720-89 ≤ 3 grades 1 grade
Shock-resistance GB/T1732-93 ≧20kg/cm 80 kg/cm
Snappiness GB/T1731-93 ≦3mm 1mm
The resistance to combustion time GB12441-2005 ≧15min 48min
From the above results, frie retardant coating high comprehensive performance of the present invention.

Claims (3)

1. one kind is added the frie retardant coating of biotite powder, it is characterized in that: be made up of the raw material of following weight part: biotite powder 10-15 part, mullite powder 5-8 part, nano imvite 8-10 part, dimethyl phosphate 3-5 part, acrylic resin 10-15 part, aminoresin 15-30 part, chlorinated rubber 2-4 part, urea phosphate 2-3 part, silane coupling agent 1-3 part, sorbyl alcohol 5-6 part, aluminum oxide 7-9 part, borax 3-5 part, vermiculite 8-10 part, semi-hydrated gypsum 3-4 part, Graphite Powder 99 3-5 part, titanium dioxide 2-3 part, organic-silicon-modified benzene emulsion 8-13 part, ether of cellulose 5-6 part, glass powder 2-3 part, isobutylene-isoprene latex 6-8 part, Sodium Silicofluoride 2-3 part, wood fibre 3-5 part.
2. the frie retardant coating of interpolation biotite powder according to claim 1, it is characterized in that: be made up of the raw material of following weight part: 13 parts, biotite powder, mullite powder 8 parts, nano imvite 10 parts, dimethyl phosphate 5 parts, acrylic resin 13 parts, 20 parts, aminoresin, chlorinated rubber 3 parts, urea phosphate 2 parts, silane coupling agent 2 parts, sorbyl alcohol 5 parts, 8 parts, aluminum oxide, borax 3 parts, vermiculite 10 parts, semi-hydrated gypsum 3 parts, Graphite Powder 99 4 parts, titanium dioxide 2 parts, organic-silicon-modified benzene emulsion 10 parts, ether of cellulose 6 parts, 2 parts, glass powder, isobutylene-isoprene latex 6 parts, Sodium Silicofluoride 2 parts, wood fibre 3 parts.
3. the preparation method adding the frie retardant coating of biotite powder as claimed in claim 1, is characterized in that: comprise following preparation process:
(1) by above-mentioned weight ratio, dimethyl phosphate, acrylic resin, aminoresin, chlorinated rubber, silane coupling agent, sorbyl alcohol, organic-silicon-modified benzene emulsion, ether of cellulose, isobutylene-isoprene latex, Sodium Silicofluoride are stirred 10-15min under 1000-1300 rev/min, mix;
(2) in the batch mixing of step (1), add biotite powder successively by above-mentioned weight ratio again, mullite powder, nano imvite, urea phosphate, aluminum oxide, borax, vermiculite, semi-hydrated gypsum, Graphite Powder 99, titanium dioxide stir 30-35min under 2000-2500 rev/min, mix rear development fineness to 50-60 μm;
(3) add glass powder, wood fibre successively in the batch mixing of the most backward step (2), under 600-800 rev/min, stir 30-35min, after dispersion stirs evenly and get final product.
CN201410057041.4A 2014-02-20 2014-02-20 A kind of frie retardant coating adding biotite powder Active CN103773170B (en)

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CN106046962B (en) * 2016-05-31 2018-03-30 安徽开林新材料股份有限公司 A kind of steel surface coating
CN106187019A (en) * 2016-06-30 2016-12-07 北京华企光科贸有限公司 A kind of wall rustproof lacquer and processing technique thereof
CN106593005B (en) * 2016-12-26 2019-02-15 怀宁县三禾保洁服务有限公司 A kind of lintel renovation technology
CN107474681A (en) * 2017-07-14 2017-12-15 太仓市老船长船舶服务有限公司 A kind of ship bottom anticorrosion paint
CN108795221A (en) * 2018-07-03 2018-11-13 贵州大学 A kind of technique of ardealite and coal ash for manufacturing fireproof coating coproduction acid

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58210970A (en) * 1982-06-01 1983-12-08 Central Glass Co Ltd Coating composition
CN1076947A (en) * 1992-04-01 1993-10-06 薛志纯 Frie retardant coating
CN1544552A (en) * 2003-11-28 2004-11-10 厦门大学 Tunnel fireproof paint based on nano-surface-treatment technology and method for making same
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN103540243A (en) * 2013-10-16 2014-01-29 苏州瑞邦塑胶有限公司 Nano flame-retardant coating

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58210970A (en) * 1982-06-01 1983-12-08 Central Glass Co Ltd Coating composition
CN1076947A (en) * 1992-04-01 1993-10-06 薛志纯 Frie retardant coating
CN1544552A (en) * 2003-11-28 2004-11-10 厦门大学 Tunnel fireproof paint based on nano-surface-treatment technology and method for making same
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN103540243A (en) * 2013-10-16 2014-01-29 苏州瑞邦塑胶有限公司 Nano flame-retardant coating

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Inventor after: Ni Shujun

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Address after: Baishuiyang town Huang Tanyang coastal village of Taizhou City, Zhejiang province 317032 City No. 155

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Patentee before: Tongling Xiangyun Fire-fighting Technology Co., Ltd.

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Effective date of registration: 20191127

Address after: 234000 in Yongqiao Economic Development Zone, Suzhou City, Anhui Province (north side of Longhua Mining Machinery Co., Ltd., west side of National Road 206)

Patentee after: ANHUI WILLY PAINT SCIENCE AND TECHNOLOGY LTD.

Address before: Baishuiyang town Huang Tanyang coastal village of Taizhou City, Zhejiang province 317032 City No. 155

Patentee before: Ni Shujun

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