CN104403451A - Environment-friendly fireproof floor paint and preparation method thereof - Google Patents

Environment-friendly fireproof floor paint and preparation method thereof Download PDF

Info

Publication number
CN104403451A
CN104403451A CN201410624453.1A CN201410624453A CN104403451A CN 104403451 A CN104403451 A CN 104403451A CN 201410624453 A CN201410624453 A CN 201410624453A CN 104403451 A CN104403451 A CN 104403451A
Authority
CN
China
Prior art keywords
environment
floor paint
friendly fireproof
wetting agent
fireproof floor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410624453.1A
Other languages
Chinese (zh)
Other versions
CN104403451B (en
Inventor
王志杰
许吉果
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ZHEJIANG DAYOU WOOD INDUSTRY Co Ltd
Original Assignee
ZHEJIANG DAYOU WOOD INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ZHEJIANG DAYOU WOOD INDUSTRY Co Ltd filed Critical ZHEJIANG DAYOU WOOD INDUSTRY Co Ltd
Priority to CN201410624453.1A priority Critical patent/CN104403451B/en
Publication of CN104403451A publication Critical patent/CN104403451A/en
Application granted granted Critical
Publication of CN104403451B publication Critical patent/CN104403451B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an environment-friendly fireproof floor paint, which comprises the following main components: acrylic acid emulsion, a wetting agent, a surfactant, a filling material, vermiculite powder, deionized water, nano-level silicon dioxide powder, superfine dolomite, alumina fine powder, and color paste. Through the components mentioned above and combination with a specific ratio, the floor paint has a better fireproof performance and is more environment-friendly, compared to the conventional floor paints in the market. At the same time, the preparation process is controlled so as to ensure the application performance of the paint.

Description

A kind of environment-friendly fireproof Floor paint and preparation method thereof
Technical field
The present invention relates to a kind of manufacture method of coating, belong to building material field, particularly relate to a kind of environment-friendly fireproof Floor paint and preparation method thereof.
Background technology
In repairs profession, the fire prevention of timber floor is the content that human consumer is concerned about always.Frie retardant coating in the market is generally divided into expanded polystyrene veneer and non-expansion type two class, Non-expansive fireproof paint is that the mode by adding fire retardant reaches fp effect, it is very thick that the flameproof effect wanting to have reached must be coated with, and add a large amount of containing fire retardants such as halogen, nitrogen, phosphorus, produce a large amount of toxic gases; Expanding fire-proof paint is exactly that film expanded by heating forms cellular carburization zone, flame heat regulating is isolated and reduces or slow down the transmission to ground, when high temperature, coating decomposites not so gas simultaneously, isolated also diluent air, the series of physical that occurs when preventing fires of coating and chemical reaction absorb a large amount of heats thus play fire-retardant and delay flame spread, spread in addition, for people provide the time of fire extinguishing, but expanding fire-proof paint, mainly based on the solvent based coating of high VOC, cannot meet the demand of the low VOC in market.
Summary of the invention
Based on the technical problem that background technology exists, the present invention proposes a kind of environment-friendly fireproof Floor paint, additionally provide the preparation method of this coating simultaneously.
Technical scheme of the present invention is as follows:
A kind of environment-friendly fireproof Floor paint, comprises the component of following weight percent,
The ACRYLIC EMULSION of described ACRYLIC EMULSION to be solid content be 55-60%, the solid content as used is on the low side, suitably can regulate the content of deionized water.
Described wetting agent is the wetting agent A337 of Kening Co., Ltd, adds this wetting agent and effectively can strengthen fluency in coating use procedure.
Described tensio-active agent is Sodium dodecylbenzene sulfonate, and what add tensio-active agent act as the solubility property strengthening ACRYLIC EMULSION.
Described filler is one or more the mixing in titanium dioxide, light calcium carbonate, china clay, silica powder.
Vermiculite power is clay mineral like a kind of smectites, for the silicate of laminate structure, vermiculite through its volume of high-temperature roasting can undergoes rapid expansion 6-20 doubly, the effect adding vermiculite power is in order under the high temperature that is heated, vermiculite power expands, isolation heat slows down the transmission to ground, simultaneously for the reaction of super fine bitter spar and alumina powder provides room and time.
The effect adding nanometer grade silica powder body is when envrionment temperature raises rapidly, is attached on the vermiculite power of expansion, and of short duration auxiliary vermiculite power resists high temperature.
Super fine bitter spar and alumina powder can react very soon under high temperature action, can generate on high temperature resistant species distribution vermiculite upon inflation, can play good flameproof effect.
The fire prevention principle of environment-friendly fireproof Floor paint of the present invention is as follows: when being subject to the temperatures involved of flame on floor, vermiculite power meeting undergoes rapid expansion, form sealing coat, thus slow down the impact of flame heat regulating on floor, nanometer grade silica powder has good dispersity simultaneously, the advantage that resistance to elevated temperatures is good, high temperature attack can be resisted, but because nanometer grade silica powder price is higher, in order to reduce costs, the present invention only adds a small amount of nanometer grade silica powder, of short durationly resist high temperature, add super fine bitter spar and alumina powder simultaneously, under the high temperature conditions, super fine bitter spar and alumina powder can generate the high temperature resistant material based on magnesia-alumina spinel structure by fast response very much, thus reach long-time fp effect.
Following table lists the impact of the weight percent comparison coating flameproof effect added of nanometer grade silica powder, super fine bitter spar and alumina powder.
1 2 3 4 5 6 7 8 9 10 11 12 13
A 5 3 3 3 1 1 1 0.5 0.5 0.5 0.1 0.1 0.1
B 0 0 2 5 0 2 5 0 2 5 0 2 5
C 0 0 5 8 0 5 8 0 5 8 0 5 8
Result Nothing Slightly Nothing Nothing Seriously Slightly Nothing Seriously Slightly Nothing Seriously Seriously Slightly
A: nanometer grade silica powder; B: super fine bitter spar (325 order) C: alumina powder (700 order), the unit of A, B, C is g.
Other materials in coating and content are respectively:
Described detection method is: by above-mentioned coating uniform application in timber floor, carries out fire resistance test, when build is 0.5mm, and alcohol baking 30min, the base material carbonization result (nothing: base material Non-carbonized of gained; Slight: the slight carbonization of base material; Serious: the serious carbonization of base material).
Obtained by above table, in the present invention, the add-on be applicable to of nanometer grade silica powder, super fine bitter spar and alumina powder is
Nanometer grade silica powder 0.5-1%
Super fine bitter spar (325 order) 2-5%
Alumina powder (700 order) 5-8%.
A preparation method for environment-friendly fireproof Floor paint, comprises the following steps:
Add deionized water, wetting agent, filler, nanometer grade silica powder, super fine bitter spar, alumina powder in a reservoir, high-speed stirring (1000-1500 rev/min) evenly after, enter sand mill and be ground to fineness and be less than 50 microns;
After adding tensio-active agent middling speed (600-800 rev/min) stirring 2-3min, then add ACRYLIC EMULSION, stir 4-6min.
Finally add vermiculite, stirring at low speed (100-300 rev/min) evenly rear filtration gets product.
Finished product the tap water of additional 10-20% can be diluted to suitable viscosity in use.
Preferably, if used under 0-10 DEG C of environment, glycerol can also be added in use.
Beneficial effect of the present invention is: by the combination of each component and the specific proportioning of each component, compare the existing product on market, have fire performance and environmental-protecting performance better, simultaneously by the control to dope preparing process, ensure that the use properties of coating.
Embodiment
Embodiment 1:
A kind of environment-friendly fireproof Floor paint, comprising: by weight percentage,
Described ACRYLIC EMULSION to be solid content be 55% ACRYLIC EMULSION.
Described wetting agent is the wetting agent A337 of Kening Co., Ltd.
Described tensio-active agent is Sodium dodecylbenzene sulfonate.
Described filler is titanium dioxide.
Painting color in this embodiment is white, and filler titanium dioxide has played the effect of mill base, therefore does not add other mill base.
A preparation method for environment-friendly fireproof Floor paint, comprises the following steps:
Add deionized water, wetting agent, titanium dioxide, nanometer grade silica powder, super fine bitter spar, alumina powder in a reservoir, high-speed stirring (1500 revs/min) evenly after, enter sand mill and be ground to fineness and be less than 50 microns;
After adding tensio-active agent middling speed (800 revs/min) stirring 3min, then add ACRYLIC EMULSION, stir 5min.
Finally add vermiculite, stirring at low speed (100 revs/min) evenly rear filtration gets product.
Finished product in use can additional 10% tap water be diluted to suitable viscosity.
Embodiment 2:
A kind of environment-friendly fireproof Floor paint, comprising: by weight percentage,
Described ACRYLIC EMULSION to be solid content be 60% ACRYLIC EMULSION.
Described wetting agent is the wetting agent A337 of Kening Co., Ltd.
Described tensio-active agent is Sodium dodecylbenzene sulfonate.
Described filler is the mixture of light calcium carbonate and silica powder, and its blending ratio is 1:1.
Described mill base is ultramarine.
A preparation method for environment-friendly fireproof Floor paint, comprises the following steps:
Add deionized water, wetting agent, filler, nanometer grade silica powder, super fine bitter spar, alumina powder in a reservoir, high-speed stirring (1000 revs/min) evenly after, enter sand mill and be ground to fineness and be less than 50 microns;
After adding tensio-active agent middling speed (600 revs/min) stirring 2min, then add ACRYLIC EMULSION, stir 6min.
Regulate PH to 8-9, add ultramarine, continue to stir 3min.
Finally add vermiculite, stirring at low speed (300 revs/min) evenly rear filtration gets product.
Finished product in use can additional 15% tap water be diluted to suitable viscosity.
Embodiment 3:
A kind of environment-friendly fireproof Floor paint, comprising: by weight percentage,
Described ACRYLIC EMULSION to be solid content be 56.5% ACRYLIC EMULSION.
Described wetting agent is the wetting agent A337 of Kening Co., Ltd.
Described tensio-active agent is Sodium dodecylbenzene sulfonate.
Described filler is the mixture of china clay, light calcium carbonate and silica powder, and its blending ratio is 1:3:3.
Described mill base is carbon black.
A preparation method for environment-friendly fireproof Floor paint, comprises the following steps:
Add deionized water, wetting agent, filler, nanometer grade silica powder, super fine bitter spar, alumina powder, carbon black in a reservoir, high-speed stirring (1200 revs/min) evenly after, enter sand mill and be ground to fineness and be less than 50 microns;
After adding tensio-active agent middling speed (650 revs/min) stirring 2.5min, then add ACRYLIC EMULSION, stir 4min.
Finally add vermiculite, stirring at low speed (200 revs/min) evenly rear filtration gets product.
Finished product is when using for 5 DEG C, and the tap water of additional 20% and the glycerol dilution of coating quality 5% are stirred to suitable viscosity.
The environment-friendly fireproof Floor paint prepared embodiment 1-3 below carries out every objectionable impurities test.
In addition the sample of embodiment 1-3 is through tuerculoderma, does not find anaphylaxis, through respiratory tract test for sample is to respiratory tract nonirritant.
By the coating uniform application of embodiment 1-3 in timber floor, carry out fire resistance test, when build is 0.5mm, detected result is as follows:
Test item Embodiment 1 Embodiment 2 Embodiment 3
Alcohol baking 30min Base material Non-carbonized Base material Non-carbonized Base material Non-carbonized
Alcohol baking 45min Base material Non-carbonized The slight carbonization of base material Base material Non-carbonized
Alcohol baking 60min Base material Non-carbonized The slight carbonization of base material The slight carbonization of base material
This detects data only for above-mentioned detection sample.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (9)

1. an environment-friendly fireproof Floor paint, is characterized in that, comprises the component of following weight percent:
ACRYLIC EMULSION 30-50%
Wetting agent 0.2-0.5%
Tensio-active agent 1.5-4%
Filler 15-25%
Vermiculite power (80-120 order) 0.5-2%
Deionized water 30-40%
Nanometer grade silica powder 0.5-1%
Super fine bitter spar (325 order) 0.2-0.5%
Alumina powder (700 order) 0.5-0.8%
Mill base 0-2%.
2. environment-friendly fireproof Floor paint as claimed in claim 1, is characterized in that, the ACRYLIC EMULSION of described ACRYLIC EMULSION to be solid content be 55-60%, the solid content as used is on the low side, suitably can regulate the content of deionized water in formula.
3. environment-friendly fireproof Floor paint as claimed in claim 1, it is characterized in that, described wetting agent is the wetting agent A337 of Kening Co., Ltd.
4. environment-friendly fireproof Floor paint as claimed in claim 1, it is characterized in that, described tensio-active agent is Sodium dodecylbenzene sulfonate.
5. environment-friendly fireproof Floor paint as claimed in claim 1, it is characterized in that, described filler is one or more the mixing in titanium dioxide, light calcium carbonate, china clay, silica powder.
6. a preparation method for environment-friendly fireproof Floor paint, is characterized in that, its preparation method comprises the following steps:
Add deionized water, wetting agent, filler, nanometer grade silica powder, super fine bitter spar, alumina powder in a reservoir, high-speed stirring (1000-1500 rev/min) evenly after, enter sand mill and be ground to fineness and be less than 50 microns;
After adding tensio-active agent middling speed (600-800 rev/min) stirring 2-3min, then add ACRYLIC EMULSION, stir 4-6min;
Finally add vermiculite power, stirring at low speed (100-300 rev/min) evenly rear filtration gets product.
7. the preparation method of environment-friendly fireproof Floor paint as claimed in claim 6, is characterized in that, the tap water of described coating additional 10-20% is in use diluted to suitable viscosity.
8. the preparation method of environment-friendly fireproof Floor paint as claimed in claims 6 or 7, is characterized in that, when described coating uses under 0-10 DEG C of environment, separately add appropriate glycerol.
9. the preparation method of environment-friendly fireproof Floor paint as claimed in claim 6, is characterized in that, its preparation method comprises the following steps:
Add deionized water, wetting agent, filler, nanometer grade silica powder, super fine bitter spar, alumina powder in a reservoir, high-speed stirring (1000 revs/min) evenly after, enter sand mill and be ground to fineness and be less than 50 microns;
After adding tensio-active agent middling speed (600 revs/min) stirring 2-3min, then add ACRYLIC EMULSION, stir 4-6min;
Finally add vermiculite power, stirring at low speed (300 revs/min) evenly rear filtration gets product;
Described environment-friendly fireproof Floor paint comprises the component of following weight percent:
ACRYLIC EMULSION (solid content 55%) 30%
Wetting agent 0.2%
Sodium dodecylbenzene sulfonate 2%
Titanium dioxide 25%
Vermiculite power (80-120 order) 2%
Deionized water 39%
Nanometer grade silica powder 0.5%
Super fine bitter spar (325 order) 0.5%
Alumina powder (700 order) 0.8%
Described wetting agent is the wetting agent A337 of Kening Co., Ltd.
CN201410624453.1A 2014-11-07 2014-11-07 A kind of environment-friendly fireproof floor paint and preparation method thereof Active CN104403451B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410624453.1A CN104403451B (en) 2014-11-07 2014-11-07 A kind of environment-friendly fireproof floor paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410624453.1A CN104403451B (en) 2014-11-07 2014-11-07 A kind of environment-friendly fireproof floor paint and preparation method thereof

Publications (2)

Publication Number Publication Date
CN104403451A true CN104403451A (en) 2015-03-11
CN104403451B CN104403451B (en) 2016-07-06

Family

ID=52641125

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410624453.1A Active CN104403451B (en) 2014-11-07 2014-11-07 A kind of environment-friendly fireproof floor paint and preparation method thereof

Country Status (1)

Country Link
CN (1) CN104403451B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106930505A (en) * 2017-03-06 2017-07-07 张家港市星泰防火保温材料有限公司 A kind of fireproof floorboard and its manufacture method
CN108546473A (en) * 2018-05-29 2018-09-18 芜湖市元奎新材料科技有限公司 Floor fireproof coating
CN108753081A (en) * 2018-05-29 2018-11-06 芜湖市元奎新材料科技有限公司 Floor anti-flaming dope
CN112282261A (en) * 2020-10-29 2021-01-29 安徽扬子地板股份有限公司 Spliced fireproof wallboard and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19922247A1 (en) * 1998-05-15 1999-12-02 Samson Perlite Co Fireproofing and soundproofing coating composition, especially for use in steel buildings
CN1817976A (en) * 2005-02-08 2006-08-16 庆东塞拉泰克有限公司 Coating composition for fire retardant and sound absorption
CN102659436A (en) * 2012-05-28 2012-09-12 武汉科技大学 Calcic spinel refractory material and preparation method thereof
CN104017445A (en) * 2014-06-06 2014-09-03 湖州百胜涂料有限公司 Water-based coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19922247A1 (en) * 1998-05-15 1999-12-02 Samson Perlite Co Fireproofing and soundproofing coating composition, especially for use in steel buildings
CN1817976A (en) * 2005-02-08 2006-08-16 庆东塞拉泰克有限公司 Coating composition for fire retardant and sound absorption
CN102659436A (en) * 2012-05-28 2012-09-12 武汉科技大学 Calcic spinel refractory material and preparation method thereof
CN104017445A (en) * 2014-06-06 2014-09-03 湖州百胜涂料有限公司 Water-based coating

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
欧立绵: "蛭石膨胀防火材料", 《四川建材学院《国外建材译丛》》 *
赵瑞编译: "用氧化铝和白云石反应烧结制备尖晶石_铝酸钙耐火材料", 《耐火材料》 *
马雅琳等: "阻燃剂及其阻燃机理的研究现状", 《材料导报》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106930505A (en) * 2017-03-06 2017-07-07 张家港市星泰防火保温材料有限公司 A kind of fireproof floorboard and its manufacture method
CN108546473A (en) * 2018-05-29 2018-09-18 芜湖市元奎新材料科技有限公司 Floor fireproof coating
CN108753081A (en) * 2018-05-29 2018-11-06 芜湖市元奎新材料科技有限公司 Floor anti-flaming dope
CN112282261A (en) * 2020-10-29 2021-01-29 安徽扬子地板股份有限公司 Spliced fireproof wallboard and preparation method thereof

Also Published As

Publication number Publication date
CN104403451B (en) 2016-07-06

Similar Documents

Publication Publication Date Title
CN104403451B (en) A kind of environment-friendly fireproof floor paint and preparation method thereof
CN102241931B (en) Environment-friendly type flame-retarding and smoke-suppressing paint and preparation method thereof
WO2015096562A1 (en) Aqueous expandable nano fireproof coating for cables and preparation method therefor
CN104774509A (en) Fireproof paint
US20150251036A1 (en) Metallic Oxysalt Fire Extinguishing Composition
CN109439083A (en) A kind of ultrathin expansion type steel structure aqueous fire-proof coating and preparation method thereof
CN109627867B (en) Graphene modified fireproof coating and preparation method thereof
CN108753081A (en) Floor anti-flaming dope
CN109929345A (en) A kind of expanding fire-proof paint and preparation method thereof
CN106497339A (en) A kind of power equipment environment-friendly fireproof material and preparation method thereof
CN108192450A (en) A kind of preparation method of architectural fireproof paint
CN107641221A (en) A kind of hydroxide-modified expansible graphite fire retardant and preparation method thereof
CN105153564B (en) A kind of Graphene molybdenum oxide nano fire-retarding composite material
CN102533009B (en) Monocomponent aqueous environmentally-friendly fireproof paint for plastic as well as preparation and use methods thereof
CN106833185A (en) A kind of preparation method of extinguishing waterborn coating
CN102719154A (en) Flame-retardant heat-insulating coating and preparation method thereof
CN103897458B (en) A kind of environmental protection flame retardant paint
CN109593414B (en) Expandable foamed single-component polymer emulsion fireproof and waterproof coating and preparation method thereof
CN105220846B (en) A kind of coating process of building fireproof coating
CN107033734B (en) One kind can ceramic epoxy resin fireproof coating
CN108913040A (en) A kind of modified inorganic fireproof gum and preparation method thereof
CN104650676A (en) High-efficient aqueous expansion fireproof coating and preparation method thereof
CN110938341A (en) Preparation method of veneer heat-insulation fireproof coating
CN106479297A (en) A kind of aeroge Water-borne inflation type refractory coating and preparation method thereof
CN109401406A (en) A kind of water paint intumescent smoke inhibition fire retardant and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant