CN103755486A - Compound traditional Chinese medicine liquid foliar fertilizer and production method thereof - Google Patents
Compound traditional Chinese medicine liquid foliar fertilizer and production method thereof Download PDFInfo
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Abstract
The invention relates to a compound traditional Chinese medicine liquid foliar fertilizer and a production method thereof. The production method of the compound traditional Chinese medicine liquid foliar fertilizer comprises the steps of: mixing three or more out of the following traditional herbal medicines: pinellia ternata, herba seu radix cirsii japonici, moon valley green, rumex patientia l., datura, fructus meliae toosendan, annual artemisia, bidens tripartita l, drug sweetflag rhizome, spanish needles herb, Chinese ixeris herb, herba taraxaci, virgate wormwood, chinese stellera root, euphorbia fischeriana, artemisia scoparia and season radix euphorbiae lantu with three or more of the following acidic solvents: tri-n-butyl borate, selenious acid, sodium selenite, methyl salicylate, sterile crystal sulfanilamide, niflumic acid, ethyl acetate, sulindac, monopotassium phosphate, ammonium sulfate, mefenamic acid and zinc sulfate into mixed a 100 DEG C hot water solution, and carrying out soaking, grinding and pulping, filtering and clarifying to obtain the compound traditional Chinese medicine liquid foliar fertilizer. The compound traditional Chinese medicine liquid foliar fertilizer is a botanical pesticide, and has toxic effect of organic insecticide and bactericide and compound liquid preparation of acidic nutrient element fertilizer.
Description
Technical field
The invention belongs to technical field of fertilizers, relate to a kind of herbal mixture liquid foliage fertilizer and manufacture craft of preventing and treating plant pest tool nutrition.
Background technology
For many years, raising along with farm output, the application quantity of chemical fertilizer, agricultural chemicals strengthens, and its residual quantity on farm crop is also strengthening, and causing environmental pollution and people and animals potential hazard acute or chronic poisoning is the difficult problem that in agriculture production, urgent need will solve or will solve for a long time.In recent years, along with continuing to optimize of the structure of agricultural production, green agricultural product area constantly increases, agriculture production technology improves constantly, agricultural product quality standard constantly promotes, greatly develop the target that green safety agricultural-food are our national agriculture productions, reduce the consumption of chemical fertilizer and chemical pesticide, the height poison of restriction chemical fertilizer and chemical pesticide, the kind of high residue and using method and use range are applied in the standardized production of development green agricultural product, and opening up environment-friendly and green agrochemical fertilizer product is related industries technician's main task.In agriculture production at present, generally apply the effect that foliar nutrient only has its supplementary plant nutrition; even also just join and use with sterilant or sterilant compound; and chemical composition residual quantity is high has a potential threat to people and animals are healthy; the Remixed agent of some medicine fertilizer simultaneously, production process equipment is loaded down with trivial details, and the equipment that has both needed to produce fertilizer is as tablets press dryer etc.; also to produce the equipment of liquid Chinese medicine; this will consume mass energy, and its facility investment is also large, is that medium-sized and small enterprises can not bear.
In addition, how reaching the unification of Chinese medicine fertilizer is also the difficult problem that professional person will solve and pay close attention to always.Herbal medicine is the rarity of China's traditional Chinese medical science, its natural resources is extensive, utilize herbal control plant pest to develop simultaneously with the fertilizer application of supplementary plant nutrition simultaneously, can reach and gather materials on the spot, ecological safety, the object of environmental protection is the important content of current national development environment friendly agricultural, green fertilizer.Utilization has extensively, easily getting of local resources and preventing disease pest control strengthens the hypertoxicity of the effective herbal medicine of plant immunization and in high-temperature hot water acidic solution, easily extract the active high characteristic of virulence, with the acidotrophy preparation of industry, medicine, widespread use in agricultural as solvent agent make herbal mixture liquid foliage fertilizer, thereby there is raw material and easily obtain, utilize waste material weeds poisonous in productive life, the best Chinese herbal medicine formula of research trial, to belong to botanical pesticide fertilizer, refuse reclamation, production technique easy, and fertilizer drug effect is high, the innovation of environmental protection.
Summary of the invention
The object of the invention is for developing agricultural green agricultural product, open up botanical pesticide fertilizer, enforcement environment protective plant protecting, environment friendly agricultural fertilizer provide a kind of efficient ecological safety and environmental protection that has, and production technique is simple, does not need Chinese medicine fertilizer new variety and the making method of complex apparatus.The object of this invention is to provide a kind of herbal mixture liquid foliage fertilizer and manufacture craft of preventing and treating plant pest tool nutrition.
For achieving the above object, the technical solution used in the present invention is:
A herbal mixture liquid foliage fertilizer, is characterized in that comprising that following raw material is made:
Herbal medicine: the tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., in euphorbia fischeriana, Artemisia scoparia, month root of langdu more than three kinds or three kinds; Described herbal medicine is the tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., three kinds or three kinds of above dry root medicine materical crude slice or dry herbs in euphorbia fischeriana, Artemisia scoparia, month root of langdu; Weight proportion between herbal raw material is 1:0.8～1.2;
Acidotrophy fertilizer as solvent agent: comprise boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, three kinds or three kinds of above saturated hot-water solution in ammonium sulfate, zinc sulfate; Utilize boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, the potassium primary phosphate of acidotrophy fertilizer, the mixed solution of the saturated hot-water solution of ammonium sulfate, zinc sulfate, as solvent agent, grinds the technique acquisition Chinese medicine of soya-bean milk and the fertile slurries body of herbal mixture of fertilizer by tradition;
The described acidic fertilizier as solvent agent is boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, the concentration of three kinds or three kinds above saturated hot-water mixed solutions in ammonium sulfate, zinc sulfate is 70%～80%, and the weight ratio of herbal medicine and solvent agent fertilizer is 1:2～11.
Herbal mixture liquid foliage fertilizer according to described, is characterized in that: described composition of raw materials is calculated by weight to:
Herbal medicine gross weight 50 ㎏, fill a prescription as dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 10 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 10 ㎏ of taraxacum; Herba daturae 10 ㎏;
Solvent agent gross weight 100 ㎏, formula is 100 ℃ of hot water 60 ㎏; Sterilization crystallizing sulfanilamide 0.1 ㎏; Niflumic acid 0.05 ㎏; Potassium primary phosphate 35 ㎏; Selenous acid 0.1 ㎏; Zinc sulfate 4.75 ㎏;
Composition of raw materials product herbal medicine is 1:8 with the gross weight ratio of solvent agent; Herbal medicine amounts to 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 10 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 10 ㎏ of taraxacum; Herba daturae 10 ㎏, than 100 ℃ of hot water mixing solutions 400 ㎏ of solvent agent; The formulation by weight ratio of mediator is 100 ℃ of hot water 239 ㎏; Sterilization crystallizing sulfanilamide 0.4 ㎏; Niflumic acid 0.2 ㎏; Potassium primary phosphate 140 ㎏; Selenous acid 0.4 ㎏; Zinc sulfate 20 ㎏; First soak solvent agent 100 ㎏ for herbal medicine, for the first time solvent agent 200 ㎏ for defibrination; 100 ㎏ of defibrination use solvent agent for the second time.
Herbal mixture liquid foliage fertilizer according to described, is characterized in that: described raw material herbal medicine and solvent agent prescription are counted by product weight:
Herbal medicine is 1:9 with the gross weight ratio of solvent agent; Herbal medicine amounts to 50 ㎏, wherein: dry herb 10 ㎏ of Herba Artemisiae annuae, dry herb 12 ㎏ of wolf tail grass, dry root medicine materical crude slice 8 ㎏ of the root of langdu, dry herb 10 ㎏ of taraxacum, dry herb 10 ㎏ of thorn apple; Than solvent agent hot water mixing solutions 450 ㎏, its solvent agent weight ratio formula: be 100 ℃ of hot water 270 ㎏; Boric acid tri butyl ester 0.45 ㎏; Sulindac 0.225 ㎏; Potassium primary phosphate 157.5 ㎏; Sodium Selenite 0.45 ㎏; Zinc sulfate 21.375 ㎏; Soak with solvent agent 150 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time.
Herbal mixture liquid foliage fertilizer according to described, is characterized in that: described raw material herbal medicine is 1:10 with solvent agent prescription by gross weight ratio; Herbal medicine amounts to 50 ㎏; Dry herb 9 ㎏ of calamus, dry herb 8 ㎏ of Herba Ixeritis chinensis, dry herb 11 ㎏ of Herba Artemisiae Scopariae, dry herb 11 ㎏ of setose thistle, dry herb 11 ㎏ of Herba Artemisiae annuae in formula; Than solvent agent hot water mixing solutions 500 ㎏, solvent agent weight ratio is 100 ℃ of hot water 300 ㎏; Methyl salicylate 0.5 ㎏; Niflumic acid 0.25 ㎏; Potassium primary phosphate 175 ㎏; Sodium Selenite 0.5 ㎏; Zinc sulfate 22.75 ㎏; Soak with solvent agent 200 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time.
Herbal mixture liquid foliage fertilizer according to described, is characterized in that: raw material herbal medicine is 1:11 with solvent agent prescription product gross weight ratio; Herbal medicine amounts to 50 ㎏, and formula is dry herb 10 ㎏ of crowndaisy chrysanthemum, dry herb 11 ㎏ of Artemisia scoparia, Szechwan Chinaberry Fruit dry fruit 10 ㎏, dry root medicine materical crude slice 10 ㎏ of the root of langdu, dry herb 9 ㎏ of wolf tail grass; Than solvent agent hot water mixing solutions 550 ㎏, solvent agent formulation by weight is 100 ℃ of hot water 330 ㎏; Methyl salicylate 0.55 ㎏; Ethyl acetate 0.275 ㎏; Potassium primary phosphate 192.5 ㎏; Boric acid tri butyl ester 0.55 ㎏; Zinc sulfate 26.125 ㎏; Soak with solvent agent 200 ㎏; 300 ㎏ of defibrination use solvent agent for the first time; 50 ㎏ of defibrination use solvent agent for the second time.
Herbal mixture liquid foliage fertilizer according to described, is characterized in that: described raw material herbal medicine is 1:10 with solvent agent prescription by gross weight ratio; Wherein: dry herb 12 ㎏ of Herba Potentillae Chinensis, dry herb 8 ㎏ of Herba Ixeritis chinensis, dry herb 11 ㎏ of Herba Artemisiae Scopariae, dry herb 10 ㎏ of setose thistle, dry herb 9 ㎏ of Herba Artemisiae annuae; Than solvent agent hot water mixing solutions 500 ㎏; Soak with solvent agent 200 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time; Solvent agent formulation by weight is 100 ℃ of hot water 300 ㎏; Methyl salicylate 0.5 ㎏; Niflumic acid 0.25 ㎏; Potassium primary phosphate 175 ㎏; Sodium Selenite 1.5 ㎏; Zinc sulfate 22.75 ㎏.
Herbal mixture liquid foliage fertilizer according to described, is characterized in that: described raw material herbal medicine is 1:10 with solvent agent prescription by product gross weight ratio; The dry herb of Herba Potentillae Chinensis, the dry herb of Herba Ixeritis chinensis, the dry herb of Herba Artemisiae Scopariae, the dry herb of setose thistle, each 10 ㎏ of the dry herb of Herba Artemisiae annuae, amount to 50 ㎏ than solvent agent hot water mixing solutions 500 ㎏; Solvent agent formulation by weight is 100 ℃ of hot water 300 ㎏; Methyl salicylate 1.5 ㎏; Niflumic acid 0.25 ㎏; Potassium primary phosphate 155 ㎏; Sodium Selenite 0.5 ㎏; Zinc sulfate 42.75 ㎏; Soak with solvent agent 200 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time.
Make a method for described herbal mixture liquid foliage fertilizer, it is characterized in that comprising the following steps:
(1) soak: by the herbal medicine tuber of pinellia, Herba Potentillae Chinensis, setose thistle, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., euphorbia fischeriana, Artemisia scoparia, three kinds or three kinds of above dry root medicine materical crude slice or dry herbs in month root of langdu, use boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, ammonium sulfate, the mixing solutions that the concentration of the hot water saturated solution of three kinds, zinc sulfate or three kinds of above solvent agent is 70%～80% soak 24 hours standby, the weight ratio of the dry root medicine materical crude slice of compound Chinese herb and nutritious fertilizer is 1:2～2.5,
(2) grind slurrying totally 2 times: according to the formula herbal medicine soaking, than solvent agent, equal the ratio defibrination of 1:4～6, with mill beans slag-removing device, grind slurrying, with the formula herbal medicine soaking, than solvent agent, equal 1:4 for the first time and grind the dregs of a decoction that squeeze out, according to the dregs of a decoction, than solvent agent, equaling 1:2～3 again mixes thoroughly, continue to squeeze once slurry, defibrination particle diameter is 1～100 micron;
(3) filter.By grinding the compound Chinese herb fertilizer liquid slurry squeezing, first with non-woven fabrics, make filter cloth 100～200 order pressing plate coarse filtration; And then use liquid medicine filter circular impact screen, screening is the most carefully to 0.028mm, filters I to 5 micron, fills the screen cloth of 1～5 layer of different meshes, the material of 2～6 grades carried out to sorting or filtration simultaneously.Filtering accuracy: 5～100 microns; Making the compound medicines solution body that contains herbal medicine and fertilizer is herbal mixture fertilizer liquid.
(4) centrifugal clarification: adopt high speed tubular-bowl centrifuge to carry out centrifugal clarification, extract some albumen, pectin, polysaccharide, saponin and some insoluble fluid impurities and fine particle etc. in medical fertilizer liquid body, whizzer separating factor 15000, separated smallest particles is 0.5 micron, and collecting clarified liq is medical fertilizer liquid body finished product.
Making method according to described herbal mixture liquid foliage fertilizer, is characterized in that: proportioning raw materials is calculated as by product weight:
Herbal raw material gross weight 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 11 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 11 ㎏ of taraxacum; Herba daturae 8 ㎏;
Solvent agent gross weight 100 ㎏: solvent agent is 100 ℃ of hot water 60 ㎏; Sterilization crystallizing sulfanilamide 0.1 ㎏; Niflumic acid 0.05 ㎏; Potassium primary phosphate 35 ㎏; Selenous acid 0.1 ㎏; Zinc sulfate 4.75 ㎏;
Herbal raw material is 1:8 with the gross weight ratio of solvent agent;
Herbal raw material gross weight 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 11 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 11 ㎏ of taraxacum; Herba daturae 8 ㎏; Than 100 ℃ of hydrothermal solution mixed solution 400 ㎏ of solvent agent, the formulation by weight ratio of solvent agent is 100 ℃ of hot water 239 ㎏, sterilization crystallizing sulfanilamide 0.4 ㎏, niflumic acid 0.2 ㎏, potassium primary phosphate 130 ㎏, selenous acid 0.4 ㎏, zinc sulfate 30 ㎏; First soak herbal medicine use solvent agent 100 ㎏, for the first time solvent agent 200 ㎏, 100 ㎏ of defibrination use solvent agent for the second time for defibrination;
Concrete technology making step is as follows:
(1) soak; Herbal medicine and solvent agent weight ratio: herbal medicine gross weight 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 11 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 11 ㎏ of taraxacum; Herba daturae 8 ㎏; Than solvent agent hot water mixing solutions consumption 100 ㎏, soak 24 hours;
(2) grind liquid slurry secondary altogether: herbal medicine and solvent agent weight ratio: the impregnated formula herbal medicine of the use solvent agent tuber of pinellia, the root of langdu, Rumex patientia Linn., taraxacum, Herba daturae totally 150 ㎏ than solvent agent formulation by weight than 200 ㎏, again grind liquid slurry and with the coarse filtration dregs of a decoction that grind for the first time slurries, add again hot water mixing solutions 100 ㎏ of above solvent agent, grind secondary slurries, the slurrying liquid mixing of twice obtains raw product herbal medicine fertilizer liquid slurry;
(3) filter: comprise two step process: the one, coarse filtration mistake, filters with plate-and-frame filter press grinding the liquid slurry squeezing, and lint-free non-woven fabrics is made filter cloth 100～200 order pressing plate coarse filtration, and the material of some macrobeads, thickness is removed; The 2nd, adopt circular impact screen, screening the most carefully to 500 order or 0.028mm, filter I to 5 micron, fill the screen cloth of 1～5 layer of different meshes, the material of 2～6 grades is carried out to sorting or filtration simultaneously.Filtering accuracy: 5～100 microns;
(4) clarification: filtrate later adopts high speed tubular-bowl centrifuge centrifugal after filtration, rotating speed 16000r/h, diameter 105mm, power 3kw, the centrifugal relative density of medicine liquid 1.07 going out, makes the fertile clarified liq head product of herbal medicine.
Tool of the present invention has the following advantages:
1, the present invention is a kind of botanical pesticide fertilizer, has the toxic effect composition of organic pesticide-germicide and the composite fluid preparation of acidotrophy unit fertilizer.Its technique is the principle that the pesticide-germicide effective constituent of utilizing herbal medicine easily minute parses in hot acidic solution, then through the hot acid aqueous solution soaking of solvent agent, mill, filter, the liquid preparation that separated, clarification is produced.The present invention utilize contained sterilization in the dry heel piece of poisonous Chinese herbal medicine formula or herb control the toxic effect composition of worm and acid solvent agent prescription mixed hot water solution through soaking, mill, filtration, separating clarifying produce liquid Chinese medicine foliar nutrient product.It has changed the multifunctionality that the single trophicity of conventional foliage fertilizer is disease-resistant sterilization and disinsection, and having solved existing foliage fertilizer product technology only has the trophic function of fertilizer without the shortcoming of desinsection disease cure function, has realized the environmental protection object of botanical pesticide fertilizer.The present invention makes " fertilizer " combine with " herbal medicine "; Crop alimentary combines with the ecological, environmental protective of preventing disease pest control, increases the security of plant and farm environment, make fertilising with prevention and elimination of disease and pests in one, save man-hour, save labour, reaching the cure the disease multiple-effect function of disease-resistant resistance to sick desinsection of fertilising.Increase security and the feature of environmental protection that agrochemical fertilizer is used simultaneously, improved long-lasting and the high efficiency of fertilizer and agricultural chemicals.This product herbal medicine material is the injurious weed on deserted mountain, can turn waste into wealth.
The simple four step programs that only need of this products production manufacture craft, equipment is simple, improved effect and the energy saving of productive labor, improved the security of plant, thoroughly removed the residual hazard of agrochemical fertilizer, realize innovation and the creation of botanical pesticide fertilizer, for development environment friendly agricultural fertilizer, create product innovation, for producing green agricultural product, provide technical support, for agricultural produce, the good creation good basis of agricultural product quality.
2, the physicochemical property of this Chinese medicinal liquor fertilizer are acid.Be the physico-chemical property of utilizing the virulence composition of its Chinese medicine easily to dissolve in hot water acidic solution, its toxic effect composition is extracted, be dispersed in the Chinese medicine fertilizer of the liquid form of making in the medium of suitable acid compound water.Medium and the acute toxicity with Chinese medicine antibacterial desinsection, nutritive ingredient that its plant needs high effective constituent > 70% such as () phosphorus, potassium, zinc, stable chemical nature, odorless, tasteless, without residual hazard, soluble in water, do not lump.
3, the medicine in liquid Chinese medicine fertilizer is dispersed in medium with molecularity or graininess, thereby forms the liquid medicine fertilizer of homogeneous phase.Herbal medicine toxic effect particle in liquid medicine fertilizer disperse evenly, liquid phase stability is good and toxic side effect is little.The dispersity of medicine is large, absorbs soon, with corresponding solid dosage phase specific energy, brings into play more rapidly drug effect, improves the bioavailability of medicine;
4, production technique is simple, does not need complex apparatus, and processing charges is only 1/10th of general liquid fertilizer and Chinese medicine preparation, can greatly reduce production costs, and can also save a large amount of fuel energies.
5, there is the effect of plant sterilization being controlled to worm and supplementary plant nutrition.Utilization has and supplements the nutrients and the effect of control plant pest on plant leaf surface, can fill with root for foliar spray, soil foliage top dressing or the seed soaking of plant, and the rushing of day-light greenhouse fruits and vegetables executed with drip irrigation etc.
6, belong to the free from chloride Chinese medicine fertilizer of ecological organic safety, use range is extensive.
This product expression goes out significant effect of increasing production and improves crop quality, the various resistances of enhancing crop, for farm crop base fertilizer and middle and later periods foliage application, be applicable to the various crops such as various grain, cash crop and melon and fruit, vegetables, for some fear-chlorion crops, it shows better effect.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described:
A kind of herbal mixture liquid foliage fertilizer of the present invention, its composition comprises:
Herbal medicine: the tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., in euphorbia fischeriana, Artemisia scoparia, month root of langdu more than three kinds or three kinds; Acidotrophy fertilizer comprises boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, three kinds or three kinds of above saturated hot-water solution in ammonium sulfate, zinc sulfate.Its special feature is: the boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, the potassium primary phosphate that utilize acidotrophy fertilizer, the mixed solution of the saturated hot-water solution of ammonium sulfate, zinc sulfate, as solvent agent, grinds the technique acquisition Chinese medicine of soya-bean milk and the fertile slurries body of herbal mixture of fertilizer by tradition.
Described in above-mentioned herbal mixture liquid foliage fertilizer, herbal medicine is the tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., three kinds or three kinds of above dry root medicine materical crude slice or dry herbs in euphorbia fischeriana, Artemisia scoparia, month root of langdu; Weight proportion between herbal raw material is 1:0.8～1.2;
Acidic fertilizier as solvent agent is boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, the concentration of three kinds or three kinds above saturated hot-water mixed solutions in ammonium sulfate, zinc sulfate is 70%～80%, and the weight ratio of herbal medicine and solvent agent fertilizer is 1:2～11.
Making method of the present invention is as follows:
A kind of making method of herbal mixture liquid foliage fertilizer, it is characterized in that: its formula forms and comprises the herbal medicine tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., euphorbia fischeriana, Artemisia scoparia, in month root of langdu more than three kinds or three kinds, respectively with 100 ℃ of hot water dissolving's boric acid tri butyl esters, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, ammonium sulfate, the concentration of three kinds or the three kinds above saturated mixed solutions of hot water in zinc sulfate is 70%～80%, as the solvent agent of extracting Chinese medicine toxic effect composition, the weight ratio of herbal medicine and solvent agent fertilizer is 1:2～11.
The manufacturing process steps of its production method is:
1, the raw material of herbal medicine and fertilizer is prepared.
Press quality standard and the agricultural commodity fertilizer standard of the dry root medicine materical crude slice of herbal medicine of < < Chinese Pharmacopoeia > >, get ready and prepare enough the qualified herbal medicine tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., euphorbia fischeriana, Artemisia scoparia, month root of langdu etc.; Acid solvent agent nutritious fertilizer is boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, ammonium sulfate, zinc sulfate etc.
2, soak.By the herbal medicine tuber of pinellia, Herba Potentillae Chinensis, setose thistle, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., euphorbia fischeriana, Artemisia scoparia, three kinds or three kinds of above dry root medicine materical crude slice or dry herbs in month root of langdu, use boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, ammonium sulfate, the mixing solutions that the concentration of the hot water saturated solution of three kinds, zinc sulfate or three kinds of above solvent agent is 70%～80% soak 24 hours standby.During immersion, by the weight ratio of the dry root medicine materical crude slice of compound Chinese herb and nutritious fertilizer, be 1:2～2.5.
3, grind filter pulp.According to the formula herbal medicine soaking, than the mixed hot water solvent agent of 70%～80% concentration, equal the ratio defibrination of 1:4～6, with mill beans slag-removing device, grind slurrying, grind for the first time the dregs of a decoction that squeeze out, according to the dregs of a decoction, than the mixed hot water solvent agent of 70%～80% concentration, equaling 1:2～3 again mixes thoroughly, continue to squeeze once slurry, defibrination particle diameter is 1～100 micron.
4, filter.By grinding the compound Chinese herb fertilizer slurries that squeeze, first with non-woven fabrics, make filter cloth 100-200 order pressing plate coarse filtration; And then with liquid medicine filter, " capable DL " serial circular impact screen, screening is the most carefully to 0.028mm, filters I to 5 micron, fills the screen cloth of 1～5 layer of different meshes (fineness), the material of 2～6 grades carried out to sorting or filtration simultaneously.Filtering accuracy: 5～100 microns.Making the compound medicines solution body that contains herbal medicine and fertilizer is herbal mixture fertilizer liquid.
5, centrifugal clarification.Adopt GQ105R type high speed tubular-bowl centrifuge to carry out centrifugal clarification, extract some albumen, pectin, polysaccharide, saponin and some insoluble fluid impurities and fine particle etc. in medical fertilizer liquid body, whizzer separating factor 15000, separated smallest particles is 0.5 micron, and collecting clarified liq is the elementary finished product of herbal mixture solution body.
6, the elementary finished product of herbal mixture solution body, packs large tank into and enters head product storehouse.
7, finished product and quality examination.
Adopting the herbal medicine of this manufacture craft production and the compound liquid of fertilizer is just finished product of herbal mixture fertilizer, detects pH value and the density of this Chinese medicine fertilizer compound fluid with acidometer (PHS-2 type), it is acid that this liquid is, it is 4.6～5.6 that pH value is 5.04, pH value scope, and density is 1.07, utilize gas chromatography determination, its compound fluid also contains the tuber of pinellia, Herba Potentillae Chinensis, setose thistle, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, the flavonoid that the herbal medicine such as the root of langdu have, coumarins, diterpenes, triterpenes, organic and the Inorganic chemical composition of the antibacterial insecticidal actions such as lignanoids and cinnamic acid alcohol glycoside, determining general flavone content is 1.77%, total acidic component content is 1.57%, polysaccharide content is 25.6%, contents of monosaccharides is 1.35%, (comprise glucose, fructose and sucrose and polysaccharide) and contain much starch and fiber, measure in this herbal mixture solution body and also contain KH
2pO
4(in acid anhydride base) 27%～40% or ZnSO
2the content of 9 kinds of metallic elements such as 0.5%, Ca, Mg, Pb, Cu, Zn, Cd, Fe, Mn totally 5%.
8, liquid perfusion and packing.Adopt high-precision liquid pouring package machine to carry out finished product production.The whole processes such as this machinery bag, filling, involution, printing lot number, cut-out, counting complete automatically, and microprocessor is controlled, and accurate positioning is reliable, and liquid product is taked the plastic bottle packing of compound film bag packing or 20～50 milliliters.
Below this Chinese medicinal liquor fertilizer and making method are elaborated:
Principle of work of the present invention is: adopt acid solvent pickling process to extract the toxic effect composition in herbal medicine.Utilize acidic fertilizier as the solvent agent of extracting the poisonous activeconstituents of herbal medicine, according to the dissolving properties of toxic effect composition in the acid solvent of high temperature in herbal medicine, select the large characteristic of poisonous activeconstituents solubleness, and effective constituent is dissolved out in the tissue of medicinal material.When diffusion, osmosis that high-temperature acidic solvent is added in the dry root medicine materical crude slice of herbal medicine (herb) due to solvent, dissolve effective constituent, make high temperature volatile and be dissolved in component separating acid or organic acid combination out.Chemical transformation in chemical composition not.The contained moisture of liquid Chinese medicine fertilizer is also separated or dissolves the solvent of the poisonous activeconstituents of herbal medicine simultaneously.
Fabrication processing:
Select materials and adopt the herbal medicine tuber of pinellia, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., three kinds or three kinds of above dry root medicine materical crude slice or dry herb in euphorbia fischeriana, Artemisia scoparia, setose thistle, month root of langdu etc., acid solvent agent is boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, ammonium sulfate, more than three kinds or the three kinds saturated mixing solutions concentration of hot water of zinc sulfate are 70%～80%, soak formula herbal medicine 24 hours → grind slurrying continuous quadratic → filtrations (2～100 microns) → separating clarifying (0.5-10 micron) → head product quality is carried out to efficiency light spectrometer and the perfusion of chemical physical property detections → liquid and finished product packing → product warehousing → market development sale
Below in conjunction with example, technological process is described in detail.
embodiment 1
Raw material herbal medicine and solvent agent prescription are calculated as by product weight:
Herbal medicine gross weight 50 ㎏, fill a prescription as the dry root medicine materical crude slice of the dry root medicine materical crude slice of the tuber of pinellia 10 ㎏+root of langdu dry root medicine materical crude slice 10 ㎏+Rumex patientia Linn. dry root medicine materical crude slice 10 ㎏+taraxacum 10 ㎏+Herba daturae 10 ㎏;
Solvent agent gross weight 100 ㎏, formula is 100 ℃ of hot water 60 ㎏+sterilization crystallizing sulfanilamide 0.1 ㎏+niflumic acid 0.05 ㎏+potassium primary phosphate 35 ㎏+selenous acid 0.1 ㎏+zinc sulfate 4.75 ㎏.
Herbal medicine is 1:8 with the gross weight ratio of solvent agent;
Herbal medicine amounts to 50 ㎏ (the wherein dry root medicine materical crude slice of the dry root medicine materical crude slice of the tuber of pinellia 10 ㎏+root of langdu dry root medicine materical crude slice 10 ㎏+Rumex patientia Linn. dry root medicine materical crude slice 10 ㎏+taraxacum 10 ㎏+Herba daturae 10 ㎏) than 100 ℃ of hydrothermal solution mixed solution 400 ㎏ of solvent agent (the formulation by weight ratio of solvent agent is 100 ℃ of hot water 239 ㎏+sterilization crystallizing sulfanilamide 0.4 ㎏+niflumic acid 0.2 ㎏+potassium primary phosphate 140 ㎏+selenous acid 0.4 ㎏+zinc sulfate 20 ㎏), first soaks herbal medicine use solvent agent 100 ㎏+defibrination use solvent agent for the first time 200 ㎏+defibrination use solvent agent for the second time 100 ㎏);
Concrete technology making step is as follows:
(1) soak.Herbal medicine and solvent agent weight ratio: Chinese herbal medicine formula is that the dry root medicine materical crude slice+Herba daturae of the dry root medicine materical crude slice+taraxacum of the dry root medicine materical crude slice+Rumex patientia Linn. of the dry root medicine materical crude slice+root of langdu of the tuber of pinellia (each 10 ㎏) amounts to 50 ㎏ than solvent agent hot water mixing solutions consumption 100 ㎏, and solvent agent formulation by weight ratio is that 100 ℃ of hot water 60 ㎏+sterilization crystallizing sulfanilamide 0.1 ㎏+niflumic acid 0.05 ㎏+potassium primary phosphate 35 ㎏+selenous acid 0.1 ㎏+zinc sulfate, 4.75 ㎏ soak 24 hours.
(2) defibrination, comprises twice.Herbal medicine and solvent agent weight ratio: use the impregnated formula herbal medicine of the solvent agent tuber of pinellia+root of langdu+Rumex patientia Linn.+taraxacum+Herba daturae totally 150 ㎏ ratio formula solvent agent weight 200 ㎏, be 100 ℃ of hot water 120 ㎏+sterilization crystallizing sulfanilamide 0.2 ㎏+niflumic acid 0.1 ㎏+potassium primary phosphate 70 ㎏+selenous acid 0.2 ㎏+zinc sulfate 9.5 ㎏ and grind liquid slurry processed.Secondary slurrying is the filter dregs of a decoction that grind for the first time slurries to be added again to hot water mixing solutions 100 ㎏ (instant mediator formulation by weight is 100 ℃ of hot water 60 ㎏+sterilization crystallizing sulfanilamide 0.1 ㎏+niflumic acid 0.05 ㎏+potassium primary phosphate 35 ㎏+selenous acid 0.1 ㎏+zinc sulfate 4.75 ㎏) of above solvent agent, grind secondary slurries, the slurrying liquid mixing of twice obtains raw product herbal medicine fertilizer slurries.
(3) filter.Comprise two step process
The one, coarse filtration mistake, filters with plate-and-frame filter press grinding the liquid slurry squeezing, and lint-free non-woven fabrics is made filter cloth 100～200 order pressing plate coarse filtration, and the material of some macrobeads, thickness is removed; The 2nd, adopt " capable DL " serial circular impact screen, screening the most carefully to 500 order or 0.028mm, filter I to 5 micron, fill the screen cloth of 1～5 layer of different meshes (fineness), the material of 2～6 grades is carried out to sorting or filtration simultaneously.Filtering accuracy: 5～100 microns.
(4) clarification.Later filtrate adopts GQ105R type high speed tubular-bowl centrifuge centrifugal (rotating speed 16000r/h, diameter 105mm, power 3kw) after filtration, and the centrifugal relative density of medicine liquid 1.07 going out, makes the fertile clarified liq head product of herbal medicine.
The technical parameter of said herbal medicine liquid foliage fertilizer:
1, appearance color: brown light yellow transparent liquid
2, relative density: the density 1.07kg/L(liter of liquid).
3, pH value: PH4.6～5.04; Meet 3.5～8 of GB.
4, solubleness: in solution, insolubles content 0.1%; 5% of symbol GB.
5, stability: herbal mixture solution body, under simulation commercially available back condition, is put in room temperature, after the primary stability carrying out 24 hours, 48 hours, 72 hours is examined; Proceed to examine once for 1,2,3 month, then every half a year once again; In 37～40 ℃ and relative humidity 75%, preserve, monthly examination once, continuous three months) stability assessment result, this compound Chinese herb solution body preparation good stability, stablizes and within 3 months, occurs minute quantity precipitation, but after shaking, resolution of precipitate, does not affect drug effect quality, does not belong to rotten.
6, assay: utilize high performance liquid chromatography and chemical property determination, this Chinese medicine fertilizer contains main chemical compositions flavonoid, coumarins, lignanoids, diterpenes, sterol and the amino acid etc. in root of Stellera chamaejasme, total flavonoid component content 1.77%, total acidic component content 1.57%, furoeoumarin lactone content 0.5%; Also contain the K in potassium dihydrogen phosphate
2o content is more than or equal to 27%, P
2o
5be more than or equal to 40%; Hydrocarbon polymer is more than or equal to 15.5%, in, trace element 9.5% and organic and inorganic chemical composition 4.16%.
embodiment 2
Raw material herbal medicine and solvent agent prescription are counted by product weight: herbal medicine is 1:9 with solvent agent gross weight ratio; Formula herbal medicine gross weight 50 ㎏ (wherein, dry herb 10 ㎏ of the dry herb 10 ㎏+thorn apple of the dry herb 12 ㎏+root of langdu of the dry herb 10 ㎏+wolf tail grass of Herba Artemisiae annuae dry root medicine materical crude slice 8 ㎏+taraxacum) than solvent agent hot water mixing solutions 450 ㎏ (solvent agent weight ratio formula is 100 ℃ of hot water 270 ㎏+boric acid tri butyl ester 0.45 ㎏+sulindac 0.225 ㎏+potassium primary phosphate 157.5 ㎏+Sodium Selenite 0.45 ㎏+zinc sulfate 21.375 ㎏), soak solvent agent 100 ㎏ for defibrination with solvent agent 200 ㎏ for defibrination of solvent agent 150 ㎏+for the first time+for the second time); Other operating process are with embodiment 1.
embodiment 3
Raw material herbal medicine and solvent agent prescription are counted by product weight: herbal medicine is 1:10 with solvent agent gross weight ratio; Herbal medicine gross weight 50 ㎏ (wherein, dry herb 11 ㎏ of crowndaisy chrysanthemum, dry herb 10 ㎏ of+Artemisia scoparia, + Szechwan Chinaberry Fruit (dry fruit) 8 ㎏, the dry root medicine materical crude slice 10 ㎏ of+root of langdu, dry herb 11 ㎏ of+Herba Artemisiae annuae), than solvent agent hot water mixing solutions 500 ㎏ (solvent agent prescription weight ratio is 100 ℃ of hot water 300 ㎏+methyl salicylate 0.5 ㎏+niflumic acid 0.25 ㎏+potassium primary phosphate 175 ㎏+Sodium Selenite 0.5 ㎏+zinc sulfate 22.75 ㎏); Soak solvent agent 100 ㎏ for defibrination with solvent agent 200 ㎏ for defibrination of solvent agent 200 ㎏+for the first time+for the second time); Other operations are with embodiment 1.
embodiment 4
Raw material herbal medicine and solvent agent prescription are counted by product weight: herbal medicine is 1:11 with solvent agent gross weight ratio; Herbal medicine amounts to 50 ㎏ (formula is dry herb 9 ㎏ of the dry root medicine materical crude slice of the crowndaisy chrysanthemum dry herb 11 ㎏+Szechwan Chinaberry Fruit of dry herb 10 ㎏+Artemisia scoparia (dry fruit) 10 ㎏+root of langdu 10 ㎏+wolf tail grass) than solvent agent hot water mixing solutions 550 ㎏ (solvent agent formulation by weight is 100 ℃ of hot water 330 ㎏+methyl salicylate 0.55 ㎏+ethyl acetate 0.275 ㎏+potassium primary phosphate 192.5 ㎏+boric acid tri butyl ester 0.55 ㎏+zinc sulfate 26.125 ㎏), soaks solvent agent 50 ㎏ for defibrination with solvent agent 300 ㎏ for defibrination of solvent agent 200 ㎏+for the first time+for the second time); Other operations are with embodiment 1.
embodiment 5
Raw material herbal medicine and solvent agent prescription are counted by product weight: herbal medicine is 1:10 with solvent agent gross weight ratio: herbal medicine amounts to 50 ㎏ (dry herb 11 ㎏ of the dry herb 11 ㎏+Herba Artemisiae annuae of the dry herb 11 ㎏+setose thistle of the dry herb 8 ㎏+Herba Artemisiae Scopariae of the dry herb 9 ㎏+Herba Ixeritis chinensis of calamus in formula) than solvent agent hot water mixing solutions 500 ㎏; (comprise and soak solvent agent 100 ㎏ for defibrination with solvent agent 200 ㎏ for defibrination of solvent agent 200 ㎏+for the first time+for the second time); Solvent agent formulation by weight is 100 ℃ of hot water 300 ㎏+methyl salicylate 0.5 ㎏+niflumic acid 0.25 ㎏+potassium primary phosphate 175 ㎏+Sodium Selenite 0.5 ㎏+zinc sulfate 22.75 ㎏, and other operate with embodiment 1.
embodiment 6
Raw material herbal medicine and solvent agent prescription are counted 1:10 by product weight, herbal medicine and solvent agent gross weight amount to 50 ㎏ (wherein, dry herb 9 ㎏ of the dry herb 10 ㎏+Herba Artemisiae annuae of the dry herb 11 ㎏+setose thistle of the dry herb 8 ㎏+Herba Artemisiae Scopariae of the dry herb 12 ㎏+Herba Ixeritis chinensis of Herba Potentillae Chinensis), than solvent agent hot water mixing solutions 500 ㎏ (solvent agent formulation by weight is 100 ℃ of hot water 300 ㎏+methyl salicylate 0.5 ㎏+niflumic acid 0.25 ㎏+potassium primary phosphate 175 ㎏+Sodium Selenite 1.5 ㎏+zinc sulfate 22.75 ㎏), soak solvent agent 100 ㎏ for defibrination with solvent agent 200 ㎏ for defibrination of solvent agent 200 ㎏+for the first time+for the second time), other operations are with embodiment 1.
The solubleness of three kinds of above mixed solutions of three kinds of the solvent agent such as the ethyl acetate+boric acid tri butyl ester+niflumic acid in the present invention or potassium primary phosphate+Sodium Selenite+sulindac+boron nitride+wintergreen oil+selenous acid+sterilization crystallizing sulfanilamide+fenamic acid+vialidon+ammonium sulfate+zinc sulfate is 70%～80%, the aqueous solubilities of dissolved mediator is low, adding the easy volatilization under more than 60 ℃ high-temperature conditions of medium-height grass the effective elements of the medicine dilutes and decomposes out, therefore, soak and minute secondary pulping process in be all with the dissolved in boiled water solvent agent of the 100 ℃ slurrying of milling simultaneously.
Drug effect, the fertilizer efficiency field test of compound Chinese herb foliage fertilizer control plant pest
On crop yield impact and preventing disease pest control effect summary sheet
In this table, experimental plot area is 10 mu, and two are repeated three processing, and processing 1 is 500 times of No. 1, herbal medicine foliage fertilizer (product of example 2) dilutions, and in disease insect pest early period of origination, foliar spray, sprayed for the second time every one week again, connected and sprayed 2 times; Process 2 and to process 3 be No. 2, compound Chinese herb foliage fertilizer (products of example 3), dilute 800 times, dilute 500 times with disease insect pest early period of origination foliar spray, every one week, spray again for the second time, even spray 2 times; From the comparative test result of different treatment, can find out, fertilizer efficiency is basically identical on the impact of output, but drug effect significant difference, the holding effect of diluting 500 times is the longest 61 days, substantially the prevention and elimination of disease and pests of need not going and buy Chinese medicine before vegetable sprout term, due to high temperature summer and autumn, the time of controlling disease is longer, resisted seedling stage hot and humid root disease and be easier to the critical porion occurring, for vegetables are kept a full stand of seedings and the disease-resistant resistance to disease of the middle and late growth stage lays good basis strong sprout.
Compound Chinese herb foliar nutrient using method:
Seed soaking: 500 times of immersion kinds of this product dilution, pull out after drying and can sow.
Base manure: mix fine earth or farm manure for 3～5 kilograms every mu and mix and use.
Fill with root: dilute 500～1000 times and evenly water in crop root to crop growth period, rushing of booth fruits and vegetables executed and drip irrigation.
Compound Chinese herb foliar nutrient leaf surface spraying test effect is recorded table:
Claims (9)
1. a herbal mixture liquid foliage fertilizer, is characterized in that comprising that following raw material is made:
Herbal medicine: the tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., in euphorbia fischeriana, Artemisia scoparia, month root of langdu more than three kinds or three kinds; Described herbal medicine is the tuber of pinellia, setose thistle, Herba Potentillae Chinensis, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., three kinds or three kinds of above dry root medicine materical crude slice or dry herbs in euphorbia fischeriana, Artemisia scoparia, month root of langdu; Weight proportion between herbal raw material is 1:0.8～1.2;
Acidotrophy fertilizer as solvent agent: comprise boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, three kinds or three kinds of above saturated hot-water solution in ammonium sulfate, zinc sulfate; Utilize boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, the potassium primary phosphate of acidotrophy fertilizer, the mixed solution of the saturated hot-water solution of ammonium sulfate, zinc sulfate, as solvent agent, grinds the technique acquisition Chinese medicine of soya-bean milk and the fertile slurries body of herbal mixture of fertilizer by tradition;
The described acidic fertilizier as solvent agent is boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, the concentration of three kinds or three kinds above saturated hot-water mixed solutions in ammonium sulfate, zinc sulfate is 70%～80%, and the weight ratio of herbal medicine and solvent agent fertilizer is 1:2～11.
2. herbal mixture liquid foliage fertilizer according to claim 1, is characterized in that: described composition of raw materials is calculated by weight to:
Herbal medicine gross weight 50 ㎏, fill a prescription as dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 10 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 10 ㎏ of taraxacum; Herba daturae 10 ㎏;
Solvent agent gross weight 100 ㎏, formula is 100 ℃ of hot water 60 ㎏; Sterilization crystallizing sulfanilamide 0.1 ㎏; Niflumic acid 0.05 ㎏; Potassium primary phosphate 35 ㎏; Selenous acid 0.1 ㎏; Zinc sulfate 4.75 ㎏;
Composition of raw materials product herbal medicine is 1:8 with the gross weight ratio of solvent agent; Herbal medicine amounts to 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 10 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 10 ㎏ of taraxacum; Herba daturae 10 ㎏, than 100 ℃ of hot water mixing solutions 400 ㎏ of solvent agent; The formulation by weight ratio of mediator is 100 ℃ of hot water 239 ㎏; Sterilization crystallizing sulfanilamide 0.4 ㎏; Niflumic acid 0.2 ㎏; Potassium primary phosphate 140 ㎏; Selenous acid 0.4 ㎏; Zinc sulfate 20 ㎏; First soak solvent agent 100 ㎏ for herbal medicine, for the first time solvent agent 200 ㎏ for defibrination; 100 ㎏ of defibrination use solvent agent for the second time.
3. herbal mixture liquid foliage fertilizer according to claim 1, is characterized in that: described raw material herbal medicine and solvent agent prescription are counted by product weight:
Herbal medicine is 1:9 with the gross weight ratio of solvent agent; Herbal medicine amounts to 50 ㎏, wherein: dry herb 10 ㎏ of Herba Artemisiae annuae, dry herb 12 ㎏ of wolf tail grass, dry root medicine materical crude slice 8 ㎏ of the root of langdu, dry herb 10 ㎏ of taraxacum, dry herb 10 ㎏ of thorn apple; Than solvent agent hot water mixing solutions 450 ㎏, its solvent agent weight ratio formula: be 100 ℃ of hot water 270 ㎏; Boric acid tri butyl ester 0.45 ㎏; Sulindac 0.225 ㎏; Potassium primary phosphate 157.5 ㎏; Sodium Selenite 0.45 ㎏; Zinc sulfate 21.375 ㎏; Soak with solvent agent 150 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time.
4. herbal mixture liquid foliage fertilizer according to claim 1, is characterized in that: described raw material herbal medicine is 1:10 with solvent agent prescription by gross weight ratio; Herbal medicine amounts to 50 ㎏; Dry herb 9 ㎏ of calamus, dry herb 8 ㎏ of Herba Ixeritis chinensis, dry herb 11 ㎏ of Herba Artemisiae Scopariae, dry herb 11 ㎏ of setose thistle, dry herb 11 ㎏ of Herba Artemisiae annuae in formula; Than solvent agent hot water mixing solutions 500 ㎏, solvent agent weight ratio is 100 ℃ of hot water 300 ㎏; Methyl salicylate 0.5 ㎏; Niflumic acid 0.25 ㎏; Potassium primary phosphate 175 ㎏; Sodium Selenite 0.5 ㎏; Zinc sulfate 22.75 ㎏; Soak with solvent agent 200 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time.
5. herbal mixture liquid foliage fertilizer according to claim 1, is characterized in that: raw material herbal medicine is 1:11 with solvent agent prescription product gross weight ratio; Herbal medicine amounts to 50 ㎏, and formula is dry herb 10 ㎏ of crowndaisy chrysanthemum, dry herb 11 ㎏ of Artemisia scoparia, Szechwan Chinaberry Fruit dry fruit 10 ㎏, dry root medicine materical crude slice 10 ㎏ of the root of langdu, dry herb 9 ㎏ of wolf tail grass; Than solvent agent hot water mixing solutions 550 ㎏, solvent agent formulation by weight is 100 ℃ of hot water 330 ㎏; Methyl salicylate 0.55 ㎏; Ethyl acetate 0.275 ㎏; Potassium primary phosphate 192.5 ㎏; Boric acid tri butyl ester 0.55 ㎏; Zinc sulfate 26.125 ㎏; Soak with solvent agent 200 ㎏; 300 ㎏ of defibrination use solvent agent for the first time; 50 ㎏ of defibrination use solvent agent for the second time.
6. herbal mixture liquid foliage fertilizer according to claim 1, is characterized in that: described raw material herbal medicine is 1:10 with solvent agent prescription by gross weight ratio; Wherein: dry herb 12 ㎏ of Herba Potentillae Chinensis, dry herb 8 ㎏ of Herba Ixeritis chinensis, dry herb 11 ㎏ of Herba Artemisiae Scopariae, dry herb 10 ㎏ of setose thistle, dry herb 9 ㎏ of Herba Artemisiae annuae; Than solvent agent hot water mixing solutions 500 ㎏; Soak with solvent agent 200 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time; Solvent agent formulation by weight is 100 ℃ of hot water 300 ㎏; Methyl salicylate 0.5 ㎏; Niflumic acid 0.25 ㎏; Potassium primary phosphate 175 ㎏; Sodium Selenite 1.5 ㎏; Zinc sulfate 22.75 ㎏.
7. herbal mixture liquid foliage fertilizer according to claim 1, is characterized in that: described raw material herbal medicine is 1:10 with solvent agent prescription by product gross weight ratio; The dry herb of Herba Potentillae Chinensis, the dry herb of Herba Ixeritis chinensis, the dry herb of Herba Artemisiae Scopariae, the dry herb of setose thistle, each 10 ㎏ of the dry herb of Herba Artemisiae annuae, amount to 50 ㎏ than solvent agent hot water mixing solutions 500 ㎏; Solvent agent formulation by weight is 100 ℃ of hot water 300 ㎏; Methyl salicylate 1.5 ㎏; Niflumic acid 0.25 ㎏; Potassium primary phosphate 155 ㎏; Sodium Selenite 0.5 ㎏; Zinc sulfate 42.75 ㎏; Soak with solvent agent 200 ㎏; 200 ㎏ of defibrination use solvent agent for the first time; 100 ㎏ of defibrination use solvent agent for the second time.
8. a method of making herbal mixture liquid foliage fertilizer described in claim 1,2,3,4,5,6 or 7, is characterized in that comprising the following steps:
(1) soak: by the herbal medicine tuber of pinellia, Herba Potentillae Chinensis, setose thistle, Rumex patientia Linn., thorn apple, Szechwan Chinaberry Fruit, Herba Artemisiae annuae, wolf tail grass, Chang Pu, Herba Bidentis Bipinnatae, Herba Ixeritis chinensis, taraxacum, Herba Artemisiae Scopariae, Stellera chamaejasme L., euphorbia fischeriana, Artemisia scoparia, three kinds or three kinds of above dry root medicine materical crude slice or dry herbs in month root of langdu, use boric acid tri butyl ester, selenous acid, Sodium Selenite, wintergreen oil, sterilization crystallizing sulfanilamide, niflumic acid, ethyl acetate, sulindac, potassium primary phosphate, ammonium sulfate, the mixing solutions that the concentration of the hot water saturated solution of three kinds, zinc sulfate or three kinds of above solvent agent is 70%～80% soak 24 hours standby, the weight ratio of the dry root medicine materical crude slice of compound Chinese herb and nutritious fertilizer is 1:2～2.5,
(2) grind slurrying totally 2 times: according to the formula herbal medicine soaking, than solvent agent, equal the ratio defibrination of 1:4～6, with mill beans slag-removing device, grind slurrying, with the formula herbal medicine soaking, than solvent agent, equal 1:4 for the first time and grind the dregs of a decoction that squeeze out, according to the dregs of a decoction, than solvent agent, equaling 1:2～3 again mixes thoroughly, continue to squeeze once slurry, defibrination particle diameter is 1～100 micron;
(3) filter.By grinding the compound Chinese herb fertilizer liquid slurry squeezing, first with non-woven fabrics, make filter cloth 100～200 order pressing plate coarse filtration; And then use liquid medicine filter circular impact screen, screening is the most carefully to 0.028mm, filters I to 5 micron, fills the screen cloth of 1～5 layer of different meshes, the material of 2～6 grades carried out to sorting or filtration simultaneously.Filtering accuracy: 5～100 microns; Making the compound medicines solution body that contains herbal medicine and fertilizer is herbal mixture fertilizer liquid.
(4) centrifugal clarification: adopt high speed tubular-bowl centrifuge to carry out centrifugal clarification, extract some albumen, pectin, polysaccharide, saponin and some insoluble fluid impurities and fine particle etc. in medical fertilizer liquid body, whizzer separating factor 15000, separated smallest particles is 0.5 micron, and collecting clarified liq is medical fertilizer liquid body finished product.
9. the making method of herbal mixture liquid foliage fertilizer according to claim 8, is characterized in that: proportioning raw materials is calculated as by product weight:
Herbal raw material gross weight 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 11 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 11 ㎏ of taraxacum; Herba daturae 8 ㎏;
Solvent agent gross weight 100 ㎏: solvent agent is 100 ℃ of hot water 60 ㎏; Sterilization crystallizing sulfanilamide 0.1 ㎏; Niflumic acid 0.05 ㎏; Potassium primary phosphate 35 ㎏; Selenous acid 0.1 ㎏; Zinc sulfate 4.75 ㎏;
Herbal raw material is 1:8 with the gross weight ratio of solvent agent;
Herbal raw material gross weight 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 11 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 11 ㎏ of taraxacum; Herba daturae 8 ㎏; Than 100 ℃ of hydrothermal solution mixed solution 400 ㎏ of solvent agent, the formulation by weight ratio of solvent agent is 100 ℃ of hot water 239 ㎏, sterilization crystallizing sulfanilamide 0.4 ㎏, niflumic acid 0.2 ㎏, potassium primary phosphate 130 ㎏, selenous acid 0.4 ㎏, zinc sulfate 30 ㎏; First soak herbal medicine use solvent agent 100 ㎏, for the first time solvent agent 200 ㎏, 100 ㎏ of defibrination use solvent agent for the second time for defibrination;
Concrete technology making step is as follows:
(1) soak; Herbal medicine and solvent agent weight ratio: herbal medicine gross weight 50 ㎏, wherein: dry root medicine materical crude slice 10 ㎏ of the tuber of pinellia; Dry root medicine materical crude slice 10 ㎏ of the root of langdu; Dry root medicine materical crude slice 11 ㎏ of Rumex patientia Linn.; Dry root medicine materical crude slice 11 ㎏ of taraxacum; Herba daturae 8 ㎏; Than solvent agent hot water mixing solutions consumption 100 ㎏, soak 24 hours;
(2) grind liquid slurry secondary altogether: herbal medicine and solvent agent weight ratio: the impregnated formula herbal medicine of the use solvent agent tuber of pinellia, the root of langdu, Rumex patientia Linn., taraxacum, Herba daturae totally 150 ㎏ than solvent agent formulation by weight than 200 ㎏, again grind liquid slurry and with the coarse filtration dregs of a decoction that grind for the first time slurries, add again hot water mixing solutions 100 ㎏ of above solvent agent, grind secondary slurries, the slurrying liquid mixing of twice obtains raw product herbal medicine fertilizer liquid slurry;
(3) filter: comprise two step process: the one, coarse filtration mistake, filters with plate-and-frame filter press grinding the liquid slurry squeezing, and lint-free non-woven fabrics is made filter cloth 100～200 order pressing plate coarse filtration, and the material of some macrobeads, thickness is removed; The 2nd, adopt circular impact screen, screening the most carefully to 500 order or 0.028mm, filter I to 5 micron, fill the screen cloth of 1～5 layer of different meshes, the material of 2～6 grades is carried out to sorting or filtration simultaneously.Filtering accuracy: 5～100 microns;
(4) clarification: filtrate later adopts high speed tubular-bowl centrifuge centrifugal after filtration, rotating speed 16000r/h, diameter 105mm, power 3kw, the centrifugal relative density of medicine liquid 1.07 going out, makes the fertile clarified liq head product of herbal medicine.
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