CN1275588A - Plastics for preventing cable from being eaten by ant and mouse - Google Patents
Plastics for preventing cable from being eaten by ant and mouse Download PDFInfo
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- CN1275588A CN1275588A CN 99113759 CN99113759A CN1275588A CN 1275588 A CN1275588 A CN 1275588A CN 99113759 CN99113759 CN 99113759 CN 99113759 A CN99113759 A CN 99113759A CN 1275588 A CN1275588 A CN 1275588A
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Abstract
The presentinvention relates to a kind of plastics for making electric cable for preventing ant and rat from biting injury, and is characterized by that it uses polyvinyl chloride or polyethylene resin as main body and matches it with ant and rat expelling agent and heat-resisting, antioxidative and photoageing stabilizer, and adopts a specific production process to produce said invented polyvinyl chloride or polyethylene functional material for preventing ant and rat from biting injury, through the secondary working process by cable manufacturer, said functional material can be made into ant-resisting rat-proofing cable with excellent performance.
Description
The present invention relates to a kind of polymer-function material, specifically is a kind of cable prevented from being eaten by ant and mouse plastics.
As everyone knows, muroid animal length has upper and lower two sharp front teeth, has the habit of constantly grinding one's teeth in sleep and disorderly stinging object, when using plastics such as polyvinyl chloride or polyethylene as the lining of electric wire, cable during with sheath or insulating material, in laying environment, can be subjected to the food organism injury of home mouse or field rodent, usually cause that power outage, telecommunication interrupt, the distribution of computer is taken place by mouse food evil back that action stops and phenomenon such as mishandle happens occasionally.Cause harm such as fire owing to electric wire, cable are produced short circuit accident by mouse food evil, the social activity and the development of the national economy etc. are had a strong impact on.Termite has the food of stinging habit in the process of looking for food, polyvinyl chloride or polyethylene are because poor to the corrosion stability of termite, very easily suffer the infringement of termite moth erosion, electric wire, cable sheath or insulating material can " little cave " occur and cause electric wire, cable fault after being snapped food destruction, when these electric wires of being encroached on, cable makes moist or during entry, cause leak electricity short-circuit, even cause accidents such as blast.In the cable fault accident,, the ratio that termite damage causes accounts for 60-70% because adding up according to investigations.Therefore, the problem of preventing and treating of mouse, termite food evil has caused the great attention of countries in the world research department.For this reason, research and develop a kind of cable prevented from being eaten by ant and mouse with plastics to guarantee safety, have significant significance.
In prior art, the poisoning agent of the Niran of the biological injury of the ant and mouse proofing in cable sheath material agent high density commonly used, aldrin, Dieldrin-attapulgite mixture and so on.But there is the hazardness of contaminate environment in this type of medicine, and is bigger to the human influence, and belongs to carcinogenic substance, therefore, stops using both at home and abroad.
The cable prevented from being eaten by ant and mouse plastics that the purpose of this invention is to provide a kind of novelty, electric wire with add in the plastic material " in, low toxicity, efficient, the transformation period is permanent " repellent, to overcome the defective that exists in the prior art, can reach the purpose of cable prevented from being eaten by ant and mouse again.
The present invention is based on polyvinyl chloride or polyethylene, the anti-ant of adopting, protection against rodents food evil repellent are 2-isopropyl phenyl-N-methyl carbamate, the alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2 of selecting high-efficiency low-toxicity for use, 2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound, diphenylol propane or vanillyl pelargonamide; Softening agent can be selected dioctyl phthalate, phthalic acid two isodecyl esters, phthalic acid di-isooctyl, phthalic acid ester in two ninth of the ten Heavenly Stems, hot 13 esters of phthalic acid, adipic acid dioctyl ester, dioctyl sebacate, trimethyl phosphite 99, phenyl alkylsulfonate, clorafin or epoxy soybean for use; Stablizer can be selected tribasic property Tai-Ace S 150, dibasicity aluminum phosphite, dibasicity phthalic acid aluminium, dibasicity aluminum stearate, aluminum foil stearate, pure aluminium silicate, calcium stearate, barium stearate, epoxide or sequestrant for use; Oxidation inhibitor can adopt antioxidant 1010, oxidation inhibitor 3.00, anti-oxidant DLTP or antioxidant CA; Properties-correcting agent can be selected properties-correcting agent EVA or modifier CPE for use; Photomask agent can be selected high-carbon black pigment or medium abrasion resistant carbon black for use; Described polyvinyl resin can be selected LDPE, HEPE, MDPE or LLDPE and blend thereof for use.
Above-mentioned purpose of the present invention realizes in the following manner: a kind of cable prevented from being eaten by ant and mouse plastics, comprise polyvinyl chloride (PVC) RESINS 100 (weight part), 2-isopropyl phenyl-N-methyl carbamate 0-2.0 (weight part), alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 0-0.2 (weight part), vanillyl pelargonamide 1-5.0 (weight part), diphenylol propane 0.1-0.5 (weight part), stablizer 5-9.0 (weight part), softening agent 45-70.0 (weight part), lime carbonate 0-30.0 (weight part) and tinting material are an amount of.
It is characterized in that polyvinyl resin 100 (weight part) 2-isopropyl phenyl-N-methyl carbamate 0-2.0 (weight part), alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 0-2.0 (weight part), vanillyl pelargonamide 1-5.0 (weight part), oxidation inhibitor 0.05-3.0 (weight part), properties-correcting agent 0-15.0 (weight part), photomask agent 1-5.0 (weight part) and lime carbonate 0-30.0 (weight part).
Above-mentioned component of the present invention becomes preventing from being eaten by ant and mouse electric wire product through electric wire, cable factory's secondary processing again through the kneading of plastics kneader, tablets press granulation, and it has excellent preventing from being eaten by ant and mouse performance, and its property is as follows:
1. termite-proof is knocked down the time (kt50 value)≤250 minutes.
2. mouse food evil test (degree evaluation bites): reach " one " level level.
Evaluation criteria (with the blank sample contrast):
One: do not have and hinder or the area that bites＜0.5/10
Ten: the area that bites＜1/10
++: the area that bites＜5/10
+++: area＞5/10 of biting
++ ++: the area that bites＜8/10
++ +++: the area that bites＜9.5/10
The present invention is described in further detail below with reference to specific embodiment, so that advantage of the present invention is more obvious.
Embodiment 1:
Following component is mediated through the plastics kneader, after the tablets press granulation, become the electric wire product of preventing from being eaten by ant and mouse again through wire ﹠ cable factory's secondary processing, described plastics are composed as follows:
Composition consumption (weight part)
Polyvinyl chloride (PVC) RESINS 100
2-isopropyl phenyl-N-methyl carbamate 2.0
Alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2,2-
Dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 2.0
Vanillyl pelargonamide 2.0
Diphenylol propane 0.1
Stablizer 5.0
Softening agent 45.0
Lime carbonate 15.0
Tinting material is an amount of
Described stablizer is selected from tribasic lead sulfate, dibasic Lead Phosphite, dibasicity phthalic acid lead, dibasic lead stearate, lead stearate, lead silicate, calcium stearate, barium stearate, epoxy compounds and/or sequestrant class stablizer.
Described softening agent is selected from dioctyl phthalate, phthalic acid two isodecyl esters, phthalic acid di-isooctyl, phthalic acid ester in two ninth of the ten Heavenly Stems, hot 13 esters of phthalic acid, adipic acid dioctyl ester, dioctyl sebacate, Tritolyl Phosphate, clorafin, epoxy soybean and mixture thereof.
Embodiment 2:
Repeat the process of embodiment 1, described plastic formula is composed as follows:
Composition consumption (weight part)
Polyvinyl chloride (PVC) RESINS 100
-cyano group-3-phenoxy benzyl-dextrorotation cis-2,2-
Dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 2.0
Vanillyl pelargonamide 3.0
Diphenylol propane 0.3
Stablizer 9.0
Softening agent 70.0
Lime carbonate 30.0
Tinting material is an amount of
Embodiment 3:
Repeat the process of embodiment 1, described plastic formula is composed as follows:
Composition consumption (weight part)
Polyvinyl chloride (PVC) RESINS 100
-cyano group-3-phenoxy benzyl-dextrorotation cis-2,2-
Dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 1.5
Vanillyl pelargonamide 5.0
Diphenylol propane 0.5
Stablizer 7.0
Softening agent 60.0
Lime carbonate 30.0
Tinting material is an amount of
Embodiment 4:
Following component is mediated through the plastics kneader, after the tablets press granulation, become the ground electric wire product of preventing from being eaten by ant and mouse again through wire ﹠ cable factory's secondary processing, described plastics are composed as follows:
Composition consumption (weight part)
Polyvinyl resin 100
2-sec.-propyl-N-methyl carbamate 1.0
-cyano group-3-phenoxy benzyl-dextrorotation cis-2,2-
Dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 1.0
Vanillyl pelargonamide 2.5
Oxidation inhibitor 0.05
Properties-correcting agent 10
Photomask agent 5
Lime carbonate 15
Described properties-correcting agent is selected from properties-correcting agent EVA, CPE.Described oxidation inhibitor is selected from antioxidant 1010, antioxidant 300, anti-oxidant DLTP and/or antioxidant CA.Described polyvinyl resin can be selected LDPE, HDPE, MDPE and LLDPE and blend thereof for use.
Embodiment 5:
Repeat the process of embodiment 4, described plastic formula is composed as follows:
Composition consumption (weight part) polyvinyl resin 100 alpha-cyanos-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 1.5 vanillyl pelargonamides 4.0 oxidation inhibitor 2.0 properties-correcting agent 8.0 photomask agent 3.0 lime carbonate 20.0 embodiment 6: repeat the process of embodiment 4, described plastic formula is composed as follows:
Composition consumption (weight portion) polyvinyl resin 1002-isopropyl-N-methyl carbamate 2.0 vanillyl pelargonamides 5.0 antioxidant 3.0 modifier 15.0 photomask agent 1.0 calcium carbonate 10.0 embodiment 7: repeat the process of embodiment 4, described plastic formula is composed as follows:
Composition consumption (weight part) polyvinyl resin 100 alpha-cyanos-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound 2.0 vanillyl pelargonamides 1.0 oxidation inhibitor 1.5 properties-correcting agent 10.0 photomask agent 1.0 lime carbonate 30.0 embodiment 8: repeat the process of embodiment 4, described plastic formula is composed as follows:
Composition consumption (weight portion) polyvinyl resin 1002-isopropyl-N-methyl carbamate 1.5 vanillyl pelargonamides 3.0 antioxidant 1.5 modifier 0 photomask agent 4.0
The foregoing description only for illustrative purposes, protection scope of the present invention will embody in claims.
Claims (6)
1. cable prevented from being eaten by ant and mouse plastics, it is characterized in that in the polyvinyl chloride (PVC) RESINS of per hundred parts of weight, also comprise (in parts by weight) 0-2.0 part 2-isopropyl phenyl-N-methyl carbamate and/or alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound, 1-5.0 part vanillyl pelargonamide, 0.1-0.5 part diphenylol propane, 0.1-0.5 part stablizer, 45-70.0 part softening agent, 0-30.0 part lime carbonate and an amount of tinting material.
2. cable prevented from being eaten by ant and mouse plastics according to claim 1 is characterized in that comprising 1-2.0 part 2-isopropyl phenyl-N-methyl carbamate, 1-4 part vanillyl pelargonamide and 0.2-0.5 part diphenylol propane in the polyvinyl chloride (PVC) RESINS of per hundred parts of weight.
3. cable prevented from being eaten by ant and mouse plastics according to claim 1, the polyvinyl chloride (PVC) RESINS that it is characterized in that per hundred parts of weight comprises 1-2.0 part alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound, 1-4 part vanillyl pelargonamide and 0.2-0.4 part diphenylol propane.
4. cable prevented from being eaten by ant and mouse plastics, it is characterized in that in the polyvinyl resin of per hundred parts of weight, also comprise (in parts by weight) 0-2.0 part 2-isopropyl phenyl-N-methyl carbamate, 0-2.0 part alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2,2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound, 1-5.0 part vanillylnonanamide, 0.05-3.0 part oxidation inhibitor, 0-15.0 part properties-correcting agent, 1-5.0 part photomask agent and 0-30.0 part lime carbonate.
5. cable prevented from being eaten by ant and mouse plastics according to claim 4 is characterized in that comprising that 1-2.0 part 2-isopropyl phenyl-N-methyl carbamate, 1-4 divide the vanillyl pelargonamide in the polyvinyl resin of per hundred parts of weight.
6. cable prevented from being eaten by ant and mouse plastics according to claim 4, it is characterized in that comprising 1-2.0 part alpha-cyano-3-phenoxy benzyl-dextrorotation cis-2 in the polyvinyl resin of per hundred parts of weight, 2-dimethyl-3-(2 ', 2 '-dibromo vinyl) cyclopropanecarboxylcompound and 1-4 part vanillyl pelargonamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991137590A CN1141332C (en) | 1999-06-01 | 1999-06-01 | Plastics for preventing cable from being eaten by ant and mouse |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB991137590A CN1141332C (en) | 1999-06-01 | 1999-06-01 | Plastics for preventing cable from being eaten by ant and mouse |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1275588A true CN1275588A (en) | 2000-12-06 |
| CN1141332C CN1141332C (en) | 2004-03-10 |
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ID=5276913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB991137590A Expired - Fee Related CN1141332C (en) | 1999-06-01 | 1999-06-01 | Plastics for preventing cable from being eaten by ant and mouse |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1141332C (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503574B (en) * | 2009-03-04 | 2011-06-29 | 佛山市顺德区阿波罗环保器材有限公司 | Anti-mouse sleeve and method for manufacturing the same |
| CN103059445A (en) * | 2011-10-20 | 2013-04-24 | 常熟市筑紫机械有限公司 | Flame-retardant polyvinyl chloride wire and cable material capable of preventing termites |
| CN103065715A (en) * | 2013-01-18 | 2013-04-24 | 森赫电梯股份有限公司 | Anti-microbico elevator cable with automatic detection function |
| CN101587759B (en) * | 2009-06-29 | 2013-08-28 | 深圳市联嘉祥科技股份有限公司 | Environmental cable for preventing white ant |
| CN103694668A (en) * | 2013-12-15 | 2014-04-02 | 上海悦萌环保科技有限公司 | PPO/PPS (Polyphenylene Oxide/Polyphenylene Sulfide) environmental-friendly plastics capable of resisting mice and ants |
| CN104987663A (en) * | 2015-06-26 | 2015-10-21 | 佛山市粤佳信电线电缆有限公司 | Anti-mouse agent formula for cable insulation layers |
| WO2015184936A1 (en) * | 2014-06-06 | 2015-12-10 | 桐庐雷泰生物科技有限公司 | Rodent-proof low smoke zero halogen material |
| WO2015184937A1 (en) * | 2014-06-06 | 2015-12-10 | 桐庐雷泰生物科技有限公司 | Rodent-proof pe material |
| CN109181052A (en) * | 2018-07-18 | 2019-01-11 | 山东华能线缆有限公司 | A kind of slow-release termite-resistant rodent-resistant cable jacket material |
-
1999
- 1999-06-01 CN CNB991137590A patent/CN1141332C/en not_active Expired - Fee Related
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101503574B (en) * | 2009-03-04 | 2011-06-29 | 佛山市顺德区阿波罗环保器材有限公司 | Anti-mouse sleeve and method for manufacturing the same |
| CN101587759B (en) * | 2009-06-29 | 2013-08-28 | 深圳市联嘉祥科技股份有限公司 | Environmental cable for preventing white ant |
| CN103059445A (en) * | 2011-10-20 | 2013-04-24 | 常熟市筑紫机械有限公司 | Flame-retardant polyvinyl chloride wire and cable material capable of preventing termites |
| CN103065715A (en) * | 2013-01-18 | 2013-04-24 | 森赫电梯股份有限公司 | Anti-microbico elevator cable with automatic detection function |
| CN103065715B (en) * | 2013-01-18 | 2016-04-13 | 森赫电梯股份有限公司 | A kind of antibacterial elevator cable with automatically detecting |
| CN103694668A (en) * | 2013-12-15 | 2014-04-02 | 上海悦萌环保科技有限公司 | PPO/PPS (Polyphenylene Oxide/Polyphenylene Sulfide) environmental-friendly plastics capable of resisting mice and ants |
| CN103694668B (en) * | 2013-12-15 | 2016-08-17 | 上海悦萌环保科技有限公司 | Rat-and-ant proof PPO/PPS environmentally-friendly plastic |
| WO2015184936A1 (en) * | 2014-06-06 | 2015-12-10 | 桐庐雷泰生物科技有限公司 | Rodent-proof low smoke zero halogen material |
| WO2015184937A1 (en) * | 2014-06-06 | 2015-12-10 | 桐庐雷泰生物科技有限公司 | Rodent-proof pe material |
| CN104987663A (en) * | 2015-06-26 | 2015-10-21 | 佛山市粤佳信电线电缆有限公司 | Anti-mouse agent formula for cable insulation layers |
| CN109181052A (en) * | 2018-07-18 | 2019-01-11 | 山东华能线缆有限公司 | A kind of slow-release termite-resistant rodent-resistant cable jacket material |
| CN109181052B (en) * | 2018-07-18 | 2021-03-23 | 山东华能线缆有限公司 | Slow-release type rat-proof and termite-proof cable sheath material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1141332C (en) | 2004-03-10 |
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Granted publication date: 20040310 Termination date: 20110601 |