CN103553805A - Method for producing organic fertilizer by using erythromycin waste residue and tetracycline urea double salt mother liquor - Google Patents
Method for producing organic fertilizer by using erythromycin waste residue and tetracycline urea double salt mother liquor Download PDFInfo
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- CN103553805A CN103553805A CN201310532484.XA CN201310532484A CN103553805A CN 103553805 A CN103553805 A CN 103553805A CN 201310532484 A CN201310532484 A CN 201310532484A CN 103553805 A CN103553805 A CN 103553805A
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- mother liquor
- double salt
- salt mother
- tsiklomitsin
- erythromycin
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Abstract
The invention relates to a method for producing an organic fertilizer by using erythromycin waste residue and tetracycline urea double salt mother liquor. The method is characterized by comprising the following steps: evenly mixing erythromycin waste residue hydrolysate obtained by heating and hydrolyzing under an acid condition with dialysate of the tetracycline urea double salt mother liquor separated by an organic membrane in a manner of nanofiltration separation at a volume ratio of (2-3):1; then adding 5-10% of ammonium humate and 10-15% of bentonite based on total volume; evenly stirring, detecting that the total nutrient (N+P2O5+K2O) is greater than or equal to 2.0%, the organic matter is greater than or equal to 20% and the dry matter is greater than or equal to 35%; spraying and pelletilizing when the PH is 5.5-8.5, drying until the moisture is smaller than or equal to 20%, and sieving, so as to obtain the product, namely the organic fertilizer. By adopting the method, the organic fertilizer is prepared from the hydrolyzed erythromycin waste residue hydrolysate obtained by hydrolytic degradation and the dialysate of the tetracycline urea double salt mother liquor separated by the organic membrane by nanofiltration separation in a mixing manner, so that the problem of environmental pollution of antibiotic residues is ended; reutilization of resources is taken in; new economic benefits are brought about for enterprises; furthermore, the method is sufficient in raw materials, and low in manufacturing cost.
Description
Technical field
The present invention relates to biological and medical technical field, particularly relate to a kind of method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor.
Background technology
For many years, China's agricultural is due to life-time service chemical fertilizer, and fertilizer is not enough, causes Soil structure to destroy, all kinds of nutritive props imbalances, and ecotope is also subject to certain pollution.And Organic farming is that manure use material replaces chemical fertilizer in agriculture production, carry out arable land rotation system simultaneously, just can preserve the ecological environment, improve Soil structure, increase soil fertility, improve quality of agricultural product.Therefore, Development of Organic Agriculture is the emerging agricultural of producing green agricultural product.
In production of antibiotics technical field, the harmless treatment of waste residue is a difficult problem for puzzlement enterprise always.For example, erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor, except containing mycelium and a small amount of microbiotic, also contain the trace elements such as abundant organic matter, nitrogen, phosphorus in them.If processed not in time, can cause Secondary Fermentation, cause environmental pollution even more serious, and process iff work is general, can cause again the organic and micro-loss in vain such as nitrogen, phosphorus in a large number in bacterium slag, cause the wasting of resources.Therefore how to deal carefully with antibiotic bacterium dregs, it is turned waste into wealth is to guarantee the normal production problem in urgent need to solve of enterprise.
Summary of the invention
The object of the present invention is to provide a kind of method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor, the method has realized the recycling of resource when solving environmental pollution.
The technical solution used in the present invention is:
A kind of method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor, it is characterized in that: by the erythromycin bacterium slag hydrolyzed solution of heating hydrolysis gained under acidic conditions with through the dialyzate of the tsiklomitsin urea double salt mother liquor of organic membrane nanofiltration separation gained, according to the volume ratio of 2～3:1, mix, then add 5～10% ammonium humate of cumulative volume, 10～15% wilkinite, stir, detect total nutrient (N+P
2o
5+ K
2o)>=2.0%, organic>=20%, dry-matter>=35%, PH5.5～8.5 o'clock spray granulating, dries to moisture≤20%, and screening obtains finished product fertilizer.
Described acidic conditions refers to pH value <4.0.
Described acidic conditions adopts and adds 2～5% nitric acid to wash film water realization.
Described heating hydrolysis refers to heated and boiled 1～2 hour.
The molecular weight 100～600 of described organic membrane.
The present invention has following technical characterstic:
1, adopt the method degraded erythromycin bacterium slag of heating hydrolysis under acidic conditions, thereby greatly reduce erythromycin residual (being less than 10mg/Kg) in film slurry, and effective constituent is retained.
2, the direct method with organic membrane nanofiltration separation filters out most of residual tsiklomitsin in tsiklomitsin urea double salt mother liquor, and large amount of organic is enriched in dialyzate.
3, add the improvement that ammonium humate is conducive to organic fertilizer product outward appearance and quality, wilkinite can increase dry-matter ratio, is conducive to the operation of spray granulating, reduces production costs simultaneously.
The present invention becomes fertilizer by the above-mentioned tsiklomitsin urea double salt mother liquor dialyzate mixing manufacture by hydrolytic deterioration gained erythromycin bacterium slag hydrolyzed solution and gained after organic membrane nanofiltration separation, both final result the problem of environmental pollution of microbiotic waste residue, the recycling ，Wei enterprise that has realized again resource brings new economic interests.And starting material of the present invention are sufficient, low cost of manufacture.
Embodiment
In following embodiment, erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor are according to the residue after routine techniques fermentative production erythromycin and tsiklomitsin or raffinate.
Embodiment 1
Get 10L erythromycin bacterium slag, detect the residual 274mg/ml of erythromycin, PH6.5.Add and wash nitric acid aqueous solution after film and regulate pH value 3.3, heated and boiled 1h.Survey the residual 5.6mg/Kg of erythromycin, organic 14.11%.Add 5L to adopt the dialyzate (organic 3.76% of the tsiklomitsin urea double salt mother liquor after the organic membrane separation of molecular weight 100～600, dry-matter 33.86%, total nitrogen 16.83%, PH6.09) after stirring, then adds respectively ammonium humate 0.8Kg, wilkinite 1.5Kg to mix.Qualified rear spray granulating, dries to moisture≤20%, screening, finished product packing after testing.
Embodiment 2
Get 10L erythromycin bacterium slag, the residual 281mg/ml of erythromycin, PH6.62.Add and wash nitric acid aqueous solution after film and regulate pH value 2.8, heated and boiled 2h.Survey the residual 4.7mg/Kg of erythromycin, organic 15.02%.Add 5L to adopt the dialyzate (organic 3.76% of the tsiklomitsin urea double salt mother liquor after the organic membrane separation of molecular weight 100～600, dry-matter 33.86%, total nitrogen 16.83%, PH6.09) after stirring, then adds respectively ammonium humate 1.2Kg, wilkinite 1.8Kg to mix.Qualified rear spray granulating, dries to moisture≤20%, screening, finished product packing after testing.
Embodiment 3
Get 15L erythromycin bacterium slag, the residual 260mg/ml of erythromycin, PH6.48.Add and wash nitric acid aqueous solution after film and regulate pH value 3.5, heated and boiled 1h.Survey the residual 4.4mg/Kg of erythromycin, organic 10.74%.Add 5L to adopt the dialyzate (organic 3.76% of the tsiklomitsin urea double salt mother liquor after the organic membrane separation of molecular weight 100～600, dry-matter 33.86%, total nitrogen 16.83%, PH6.09) after stirring, then adds respectively ammonium humate 2.0Kg, wilkinite 3Kg to mix.Qualified rear spray granulating, dries to moisture≤20%, screening, finished product packing after testing.
Embodiment 4
Get 10T erythromycin bacterium slag, the residual 306mg/ml of erythromycin, PH6.60.Add and wash nitric acid aqueous solution after film and regulate pH value 3.0, heated and boiled 2h.Survey the residual 5.2mg/Kg of erythromycin, organic 8.32%.Add 5T to adopt the dialyzate (organic 4.05% of the tsiklomitsin urea double salt mother liquor after the organic membrane separation of molecular weight 100～600, dry-matter 31.53%, total nitrogen 17.12%, PH6.17) after stirring, then adds respectively ammonium humate 1T, wilkinite 1.5T to mix.Qualified rear spray granulating, dries to moisture≤20%, screening, finished product packing after testing.
Embodiment 5
Get 15T erythromycin bacterium slag, the residual 290mg/ml of erythromycin, PH6.57.Add and wash nitric acid aqueous solution after film and regulate pH value 2.5, heated and boiled 2h.Survey the residual 3.9mg/Kg of erythromycin, organic 11.64%.Add 5L to adopt the dialyzate (organic 4.38% of the tsiklomitsin urea double salt mother liquor after the organic membrane separation of molecular weight 100～600, dry-matter 32.41%, total nitrogen 17.85%, PH6.02) after stirring, then adds respectively ammonium humate 2T, wilkinite 2.5T to mix.Qualified rear spray granulating, dries to moisture≤20%, screening, finished product packing after testing.
Claims (5)
1. a method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor, it is characterized in that: by the erythromycin bacterium slag hydrolyzed solution of heating hydrolysis gained under acidic conditions with through the dialyzate of the tsiklomitsin urea double salt mother liquor of organic membrane nanofiltration separation gained, according to the volume ratio of 2～3:1, mix, then add 5～10% ammonium humate of cumulative volume, 10～15% wilkinite, stir, detect total nutrient (N+P
2o
5+ K
2o)>=2.0%, organic>=20%, dry-matter>=35%, PH5.5～8.5 o'clock spray granulating, dries to moisture≤20%, and screening obtains finished product fertilizer.
2. according to method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor claimed in claim 1, it is characterized in that described acidic conditions refers to pH value <4.0.
3. according to the method for producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor described in claim 1 or 2, it is characterized in that described acidic conditions employing adds 2～5% nitric acid to wash film water and realizes.
4. according to method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor claimed in claim 1, it is characterized in that described heating hydrolysis refers to heated and boiled 1～2 hour.
5. according to method of producing fertilizer with erythromycin bacterium slag and tsiklomitsin urea double salt mother liquor claimed in claim 1, it is characterized in that the molecular weight 100～600 of described organic membrane.
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| CN201310532484.XA CN103553805B (en) | 2013-10-31 | 2013-10-31 | Method for producing organic fertilizer by using erythromycin waste residue and tetracycline urea double salt mother liquor |
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| CN103553805A true CN103553805A (en) | 2014-02-05 |
| CN103553805B CN103553805B (en) | 2015-06-17 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104355759A (en) * | 2014-11-20 | 2015-02-18 | 福建省奥格生物工程有限公司 | Garden flower/tree matrix fertilizer produced from antibiotic bacterium slag and preparation method thereof |
| CN104387183A (en) * | 2014-11-14 | 2015-03-04 | 砀山县沃福农业发展有限公司 | Biological organic fertilizer containing rice hull and duck manure and preparation method thereof |
| CN105016790A (en) * | 2015-07-10 | 2015-11-04 | 伊犁川宁生物技术有限公司 | Processing method of erythrocin bacterium residues |
| CN105924271A (en) * | 2016-04-22 | 2016-09-07 | 潘峰 | Biological organic fertilizer produced by using erythromycin bacterium residues and preparation method of biological organic fertilizer |
| CN106925596A (en) * | 2015-12-30 | 2017-07-07 | 中粮营养健康研究院有限公司 | A kind of handling process of antibiotic bacterium dregs |
| CN106925597A (en) * | 2015-12-30 | 2017-07-07 | 中粮营养健康研究院有限公司 | A kind of handling process of antibiotic bacterium dregs |
| CN106925595A (en) * | 2015-12-30 | 2017-07-07 | 中粮营养健康研究院有限公司 | A kind of handling process of antibiotic bacterium dregs |
| CN107522525A (en) * | 2017-09-21 | 2017-12-29 | 哈尔滨工业大学 | A kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs |
| CN108383671A (en) * | 2018-06-14 | 2018-08-10 | 山西绿福园农业开发有限责任公司 | A kind of organic fertilizer and production technology |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5472946A (en) * | 1988-04-08 | 1995-12-05 | Peck; James V. | Transdermal penetration enhancers |
| CN101126064A (en) * | 2007-07-18 | 2008-02-20 | 武汉烁森生态科技有限公司 | Biological modified method for erythromycin bacterium slag and reuse thereof |
| CN101148372A (en) * | 2007-09-07 | 2008-03-26 | 吕宏轩 | Method for producing liquid fertilizer by using pharmaceutical factory waste liquid |
| CN101407473A (en) * | 2008-11-28 | 2009-04-15 | 宁夏启元药业有限公司 | Method for recycling abricycline from abricycline crystal mother liquor |
| CN103214281A (en) * | 2013-05-06 | 2013-07-24 | 四川千业环保产业发展有限公司 | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer |
-
2013
- 2013-10-31 CN CN201310532484.XA patent/CN103553805B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5472946A (en) * | 1988-04-08 | 1995-12-05 | Peck; James V. | Transdermal penetration enhancers |
| CN101126064A (en) * | 2007-07-18 | 2008-02-20 | 武汉烁森生态科技有限公司 | Biological modified method for erythromycin bacterium slag and reuse thereof |
| CN101148372A (en) * | 2007-09-07 | 2008-03-26 | 吕宏轩 | Method for producing liquid fertilizer by using pharmaceutical factory waste liquid |
| CN101407473A (en) * | 2008-11-28 | 2009-04-15 | 宁夏启元药业有限公司 | Method for recycling abricycline from abricycline crystal mother liquor |
| CN103214281A (en) * | 2013-05-06 | 2013-07-24 | 四川千业环保产业发展有限公司 | Method for performing chemical innocent treatment on erythromycin waste residues and using erythromycin waste residues for producing organic fertilizer |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387183A (en) * | 2014-11-14 | 2015-03-04 | 砀山县沃福农业发展有限公司 | Biological organic fertilizer containing rice hull and duck manure and preparation method thereof |
| CN104355759A (en) * | 2014-11-20 | 2015-02-18 | 福建省奥格生物工程有限公司 | Garden flower/tree matrix fertilizer produced from antibiotic bacterium slag and preparation method thereof |
| CN105016790A (en) * | 2015-07-10 | 2015-11-04 | 伊犁川宁生物技术有限公司 | Processing method of erythrocin bacterium residues |
| CN106925596A (en) * | 2015-12-30 | 2017-07-07 | 中粮营养健康研究院有限公司 | A kind of handling process of antibiotic bacterium dregs |
| CN106925597A (en) * | 2015-12-30 | 2017-07-07 | 中粮营养健康研究院有限公司 | A kind of handling process of antibiotic bacterium dregs |
| CN106925595A (en) * | 2015-12-30 | 2017-07-07 | 中粮营养健康研究院有限公司 | A kind of handling process of antibiotic bacterium dregs |
| CN106925596B (en) * | 2015-12-30 | 2020-04-17 | 中粮营养健康研究院有限公司 | Treatment process of antibiotic fungi residues |
| CN106925595B (en) * | 2015-12-30 | 2020-04-17 | 中粮营养健康研究院有限公司 | Treatment process of antibiotic fungi residues |
| CN106925597B (en) * | 2015-12-30 | 2020-04-17 | 中粮营养健康研究院有限公司 | Treatment process of antibiotic fungi residues |
| CN105924271A (en) * | 2016-04-22 | 2016-09-07 | 潘峰 | Biological organic fertilizer produced by using erythromycin bacterium residues and preparation method of biological organic fertilizer |
| CN107522525A (en) * | 2017-09-21 | 2017-12-29 | 哈尔滨工业大学 | A kind of method for producing organic fertilizer using ozone processing antibiotic bacterium dregs |
| CN108383671A (en) * | 2018-06-14 | 2018-08-10 | 山西绿福园农业开发有限责任公司 | A kind of organic fertilizer and production technology |
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| CN103553805B (en) | 2015-06-17 |
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