CN103468419B - Solid laundry magic square of a kind of natural environmental-protective and preparation method thereof - Google Patents
Solid laundry magic square of a kind of natural environmental-protective and preparation method thereof Download PDFInfo
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- CN103468419B CN103468419B CN201310459446.6A CN201310459446A CN103468419B CN 103468419 B CN103468419 B CN 103468419B CN 201310459446 A CN201310459446 A CN 201310459446A CN 103468419 B CN103468419 B CN 103468419B
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Abstract
The invention provides a kind of natural environmental-protective solid laundry magic square, it forms by Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, Peppermint essential oil and deionized water are composite, by suitable selection and the particular combination of component, this laundry magic square is had concurrently, and component is simple effectively, Production Flow Chart is short, washing effect is excellent and use portable multiple excellent properties, and environmentally friendly, superpower soil removability and the ability of sterilization and disinfection make it have industrial prospect and marketable value widely.
Description
Technical field
The present invention relates to a kind of daily life solid laundry magic square, relate more specifically to a kind of containing natural component, the solid laundry magic square not adding any chemical additive and preparation method thereof, belong to Betengent product field.
Background technology
Seed of Chinese Soapberry has another name called wood and suffers from son, yellow order etc., containing a large amount of saponin constituent in its pericarp, shell, except there is good whipability and removing except the performance of spot, also report in some documents sapindust saponin also have antibacterial, brighten, nti-freckle, anti-acne, prevent dermopathic medicinal efficacy, can as the main component of natural active matter in various skin care product.
Up to the present, there is the many relevant reports relating to Wu Huan Zi detergen or sanitising agent in prior art, such as:
CN101177655A application discloses a kind of natural surface-active dinnerware washing agent, it is by Seed of Chinese Soapberry actives extracting solution, alkyl polyglycoside (APG), ammonium lauryl sulfate, alkylpolyoxyethylene ammonium sulfate, EDTA, sodium-chlor, Sargassum polysaccharides and form with excess water, has the advantage that preparation method is simple, material source extensive and be easy to degraded.
CN101659909A application discloses a kind of natural washing particle, and it is mixed by powder component A and liquid material B component.Wherein component A comprises calcium carbonate 2.1-33.5%, natural zeolite powder 1.2-25.9%, spaonin powder 1.9-48.9%, tea saponin 2.5-37.8%, Seed of Chinese Soapberry fruit peel powder 0.2-15.5%; B component comprises epoxy resin binder 2.6-37.5%, epoxy curing agent 2.6-37.5%.This detergent compositions achieve washing effect good, can repeatedly recycle, the excellent effect such as safety non-toxic.
CN101880608A application discloses a kind of natural solid cleaning agent, it is made up of the component of kaolin 6-50%, zeolite powder 4-36%, calcite in powder 7-45%, pumice sand 3-40%, Feldspar Powder 4-55%, diatomite 2-17%, polynite powder 3-22%, talcum powder 4-40%, saponin 1-15%, white carbon black 3-18%, water 0-40%, and wherein saponin is Chinese honey locust saponin or sapindust saponin.It is clean that this sanitising agent can realize metal, pottery, plank, glass etc., and produce simple, easy to use, can effectively remove various spot.
CN102021086A application discloses a kind of natural plant cleanser essence, it is made up of soapberry extract 2-20%, propylene glycol 5-10%, ethanol 0-10%, Zulkovsky starch 0.5-2%, Xylo-Mucine 0.5-1.5%, potassium sorbate 0.2-0.3% and sodium-chlor, citric acid, excess water, reaches and effectively can remove again the multi-efficiency of garden stuff pesticide residue and heavy metal contamination by wipe oil.
CN101177655A application discloses a kind of Soapberry liquid laundry detergent, it comprises Seed of Chinese Soapberry extracting solution 60-70%, APG0810 alkyl glycoside 10-20%, Oleum Cocois 5-10%, citric acid 0.04-0.08%, Herba Lysimachiae foenumgraeci quintessence oil 0.06-1%, the various ingredients such as deionized water 10-48%, show pungency low, there is the active and anti-microbial activity of natural environmental-protective Phytoremediation, to human body and the beneficial functional such as environmentally friendly.
CN102517177A application discloses a kind of biological environmental production multifunction special effect washing liquid, it forms by the various ingredients of alkyl glycoside 30-50 part, Oleum Cocois 15-20 part, Sumizyme MP 5-10 part, Seed of Chinese Soapberry soap breast 5-15 part, matrine 1-5 part, natural soap powder 5-10 part, Oleum Cocois LAO 5-10 part, disodium ethylene diamine tetraacetate 0.1-0.5 part, auxiliary agent 5-10 part, sanitas 0.1-0.5 part, essence 0.5-1 part, appropriate citric acid is composite, has the effect that environmentally friendly, comprehensive scourability is outstanding, can remove multiple stain simultaneously.
There is the large drawback of various, the composite difficulty of complicated components in above-mentioned washing composition of the prior art or sanitising agent, cause that production cost is high, technical process is long, other washing powder, washing liquid or washing soap adopting chemical composition to be prepared from then has certain hazardness to human body skin and easily causes environmental pollution.
For problems of the prior art, the present invention is intended to develop a kind of natural environmental-protective solid laundry magic square, by suitable selection and the particular combination of component, this laundry magic square is had concurrently, and component is simple effectively, Production Flow Chart is short, washing effect is excellent and use portable multiple excellent properties, the ability of superpower soil removability, adsorptive power, sterilization and disinfection and the ability of mosquito repellent, make it have industrial prospect and marketable value widely.
Summary of the invention
Based on above-mentioned many defects that prior art exists, the present inventor, through a large amount of further investigations, after having paid sufficient creative work, have developed a kind of natural environmental-protective solid laundry magic square, thus has solved the above-mentioned many defects pointed out.
Specifically, the present invention relates generally to two aspects.
First aspect, the present invention relates to a kind of natural environmental-protective solid laundry magic square, it is made up of Seed of Chinese Soapberry extracting solution, detergent builder, thickening material, Peppermint essential oil and deionized water.
In solid laundry magic square of the present invention, with 100 parts by weight, the weight content of its concrete component is as follows:
In solid laundry magic square of the present invention, the parts by weight of Seed of Chinese Soapberry extracting solution are 30-70 part, and this scope includes any sub-range scope wherein, as being 32-58 part, 35-55 part, 38-52 part, 40-50 part.
In solid laundry magic square of the present invention, washing auxiliary detergent is one or more in cellulase, proteolytic enzyme, lipase, Sumizyme MP, and its parts by weight are 2-5 part, as being 2 parts, 3 parts, 4 parts or 5 parts.
In solid laundry magic square of the present invention, thickening material is starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide element derivative, sodium alginate, one or more in gum arabic, its parts by weight are 5-10 part, as being 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts.
In solid laundry magic square of the present invention, washing auxiliary detergent is preferably Sumizyme MP.
In solid laundry magic square of the present invention, the activity of preferred Sumizyme MP is 10-30U/mg, such as, be 10U/mg, 15U/mg or 20U/mg.
In solid laundry magic square of the present invention, thickening material is preferably sodium alginate.
In solid laundry magic square of the present invention, the parts by weight of Peppermint essential oil are 1-3 part, as being 1 part, 1.5 parts, 2 parts, 2.5 parts or 3 parts.
In described solid laundry magic square of the present invention, Seed of Chinese Soapberry extracting solution adopts any one method preparation in following A-D:
Preparation method A: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, taking and be a certain amount ofly placed in Erlenmeyer flask, add the water that volume/mass ratio (ml/g) is 14-18 times amount, adopt ultrasonic extraction to extract 45-65min under room temperature, ultrasonic power is 100W, in leaching process, water temperature rising 12-16 DEG C, ultrasonic wave continues to extract 45-65min, finally, and suction filtration removing filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains Seed of Chinese Soapberry extracting solution.
Preparation method B: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, take and be a certain amount ofly placed in Erlenmeyer flask, add the water that volume/mass ratio (ml/g) is 8-12 times amount, when 55-65 DEG C, 5-7h is extracted by wet distillation, continuous extraction 3 times, finally, suction filtration removing filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains Seed of Chinese Soapberry extracting solution.
Preparation method C: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, take and be a certain amount ofly placed in Erlenmeyer flask, add the dehydrated alcohol that volume/mass ratio (ml/g) is 8-12 times amount, when 60-70 DEG C, 4-6h is extracted by wet distillation, continuous extraction 3 times, last suction filtration removing filter residue, rotary evaporation removing ethanol, be concentrated into 3/4 of original solution volume, obtain Seed of Chinese Soapberry extracting solution.
Preparation method D: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, adopt soxhlet extraction, take and be a certain amount ofly placed in apparatus,Soxhlet's, add the normal hexane that volume/mass ratio (ml/g) is 18-22 times amount, colourless to flow liquid in 80-100 DEG C of refluxing extraction 6-10h, rotary evaporation reclaims normal hexane again, adds anhydrous slufuric acid magnesium dust in liquid, concussion, drying obtains Seed of Chinese Soapberry extracting solution after filtering.
Second aspect, the present invention relates to the preparation method of above-mentioned natural environmental-protective solid laundry magic square, specific as follows: by Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, Peppermint essential oil and deionized water, by above-mentioned weight ratio, stirring and dissolving at 30-60 DEG C of temperature, make dense thick liquid, be then placed in mould cooling and make it sizing, obtain laundry magic square.
In the preparation method of the described natural environmental-protective solid laundry magic square of invention, described stirring and dissolving temperature is preferably 45 DEG C.
Embodiment
Below by specific embodiment, the present invention is described in detail; but the purposes of these exemplary embodiments and object are only used for exemplifying the present invention; not any type of any restriction is formed to real protection scope of the present invention, more non-protection scope of the present invention is confined to this.
Preparation example 1: the preparation of Seed of Chinese Soapberry extracting solution
Get Seed of Chinese Soapberry fruit to dry, peel off and pulverize, taking 15g and be placed in Erlenmeyer flask, add water 250mL, adopt ultrasonic extraction to extract 50min under room temperature, ultrasonic power is 100W, in leaching process, water temperature rises 14 DEG C, ultrasonic wave continues to extract 50min, finally, and suction filtration removing filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains the concentrated solution that Seed of Chinese Soapberry extracts.
Preparation example 2: the preparation of Seed of Chinese Soapberry extracting solution
Get Seed of Chinese Soapberry fruit to dry, peel off and pulverize, taking 15g and be placed in Erlenmeyer flask, add water 150mL, when 60 DEG C, extract 6h by wet distillation, extract 3 times continuously, finally, suction filtration removing filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains Seed of Chinese Soapberry extracting solution.
Preparation example 3: the preparation of Seed of Chinese Soapberry extracting solution
Get Seed of Chinese Soapberry fruit to dry, peel off and pulverize, taking 15g and be placed in Erlenmeyer flask, adding dehydrated alcohol 150mL, when 65 DEG C, extract 5h by wet distillation, extract 3 times continuously, finally, suction filtration removing filter residue, rotary evaporation removing ethanol, is concentrated into 3/4 of original solution volume, obtains Seed of Chinese Soapberry extracting solution.
Preparation example 4: the preparation of Seed of Chinese Soapberry extracting solution
Get Seed of Chinese Soapberry fruit to dry, peel off and pulverize, adopt soxhlet extraction, take 15g and be placed in apparatus,Soxhlet's, add normal hexane 300mL, at 90 DEG C, refluxing extraction 8h is colourless to flow liquid, rotary evaporation reclaims normal hexane again, adds anhydrous slufuric acid magnesium dust in liquid, concussion, drying obtains Seed of Chinese Soapberry extracting solution after filtering after drying.
Embodiment 1
It is 100 parts by total weight parts, by the Seed of Chinese Soapberry extracting solution of 30 weight part preparation examples 1,3 parts by weight of activated be the Sumizyme MP of 10U/mg, 5 weight part sodium alginates, the Peppermint essential oil of 2 weight parts and balance deionized water, mix, stir until become sticky mass at 30 DEG C, be placed in the plastic pattern of multiple 2cm × 2cm × 2cm and extrude, by the time take out after sizing is dry, obtain natural environmental-protective laundry magic square, called after MF-1.
Embodiment 2
It is 100 parts by total weight parts, by the Seed of Chinese Soapberry extracting solution of 40 weight part preparation examples 2,4 parts by weight of activated be the Sumizyme MP of 15U/mg, 7 weight part sodium alginates, the Peppermint essential oil of 1.5 weight parts and balance deionized water, mix, stir until become sticky mass at 40 DEG C, be placed in the plastic pattern of multiple 2cm × 2cm × 2cm and extrude, by the time take out after sizing is dry, obtain natural environmental-protective laundry magic square, called after MF-2.
Embodiment 3
It is 100 parts by total weight parts, by the Seed of Chinese Soapberry extracting solution of 50 weight part preparation examples 3,3 parts by weight of activated be the Sumizyme MP of 20U/mg, 8 weight part sodium alginates, the Peppermint essential oil of 3 weight parts and balance deionized water, mix, stir until become sticky mass at 50 DEG C, be placed in the plastic pattern of multiple 2cm × 2cm × 2cm and extrude, by the time take out after sizing is dry, obtain natural environmental-protective laundry magic square, called after MF-3.
Embodiment 4
It is 100 parts by total weight parts, by the Seed of Chinese Soapberry extracting solution of 60 weight part preparation examples 4,5 parts by weight of activated be the Sumizyme MP of 25U/mg, 10 weight part sodium alginates, the Peppermint essential oil of 1 weight part and balance deionized water, mix, stir until become sticky mass at 60 DEG C, be placed in the plastic pattern of multiple 2cm × 2cm × 2cm and extrude, by the time take out after sizing is dry, obtain natural environmental-protective laundry magic square, called after MF-4.
Embodiment 5-8
Replace with except cellulase except by Sumizyme MP, implement embodiment 5-8 with the same way with embodiment 1-4 respectively, obtain natural environmental-protective laundry magic square MF-5, MF-6, MF-7 or MF-8 respectively.
Embodiment 9-12
Replace with except lipase except by Sumizyme MP, implement embodiment 9-12 with the same way with embodiment 1-4 respectively, obtain natural environmental-protective laundry magic square MF-9, MF-10, MF-11 or MF-12 respectively.
Embodiment 13-16
Replace with except starch except by sodium alginate, implement embodiment 13-16 with the same way with embodiment 1-4 respectively, obtain natural environmental-protective laundry magic square MF-13, MF-14, MF-15 or MF-16 respectively.
Embodiment 17-20
Replace with except carrageenin except by sodium alginate, implement embodiment 17-20 with the same way with embodiment 1-4 respectively, obtain natural environmental-protective laundry magic square MF-17, MF-18, MF-19 or MF-20 respectively.
Embodiment 21-24
Replace with except gum arabic except by sodium alginate, implement embodiment 21-24 with the same way with embodiment 1-4 respectively, obtain natural environmental-protective laundry magic square MF-21, MF-22, MF-23 or MF-24 respectively.
Performance test is tested
1, the clean effect test of natural environmental-protective solid laundry magic square of the present invention.
Use that the washing of the laundry of the natural environmental-protective prepared by the present invention magic square speckles with even spot of the same race, measure-alike rectangle band, washing methods is as follows: be put in washing machine by that stained by even spot of the same race, measure-alike rectangle band, then the natural environmental-protective solid laundry magic square of the present invention of equivalent weight is added, after it dissolves, start washing machine, wash the identical time, then use whiteness instrument (blancometer) to measure its fair and clear degree.
Experimental procedure:
(1) test the fair and clear degree of clean band as standard reference, measure and average for three times;
(2) get 10 soiled cotton bars as experimental group, test the fair and clear degree of soiled cotton bar before 10 groups of cleanings respectively, measure and average for three times;
(3) with above-mentioned washing methods, 10 groups of soiled cotton bars are cleaned, then dry, measure the fair and clear degree of soiled cotton bar after cleaning, measure and average for three times;
(4) calculate soil removal efficiency, adopt following formula:
Soil removal efficiency (%)=[(the fair and clear degree of soiled cotton bar before the fair and clear degree-cleaning of the soiled cotton bar after cleaning)/(the fair and clear degree of soiled cotton bar before the fair and clear degree-cleaning of clean band)] × 100%.Experimental result is in table 1.
2, the sterilization effect test of natural environmental-protective solid laundry magic square of the present invention.
Use streptococcus aureus, intestinal bacteria as the bacterial classification of bactericidal assay; The natural environmental-protective prepared by the present invention is used to do washing magic square as bactericidal agent.
Experimental procedure
(1) the natural environmental-protective solid laundry magic square aqueous solution of the present invention being 0.4% respectively with 4.5mL mass concentration by the 0.5mL bacteria suspension being 106cfu/mL containing streptococcus aureus or intestinal bacteria mixes, leave standstill effect 10min, obtain two kinds of bacterium medicine suspensions respectively;
(2) neutralizing agent (sodium thiosulfate solution that described neutralizing agent such as mass concentration is the peroxide acetate aqueous solution of 0.1-0.5%, mass concentration is 0.1-1.0% or mass concentration are the peroxide acetate aqueous solution etc. of 0.1-3.0%) that 0.5mL above-mentioned bacterium medicine suspension joins 4.5mL is respectively got, after mixing, leave standstill effect 8min, then 0.5mL mixing liquid inoculation plate is got respectively, pour into plain agar and mix, cultivate 36 hours at 37 DEG C, counting colony number, calculate sterilizing rate, experimental result is in table 2.
Interpretation of result
The clean effect that washing magic square respectively organized by table 1. compares
From table 1 result: the soil removal efficiency after adopting natural environmental-protective solid laundry magic square of the present invention to wash all reaches more than 80%, the visible suitable selection by component and particular combination, make laundry magic square show excellent clean effect.
The Comparison of effect on sterilization of laundry magic square respectively organized by table 2.
From table 2 result: adopt natural environmental-protective solid laundry magic square of the present invention to carry out bacteriostatic experiment and all obtain the excellent effect that sterilizing rate reaches more than 90%, the visible suitable selection by component and particular combination, make laundry magic square be attended by good sterilizing power.
Comprehensively above-mentioned, natural environmental-protective solid laundry magic square of the present invention have component simple, easy to prepare, use portable many merits, its suitable selection by component and particular combination and show excellent clean effect, and be attended by good sterilizing power simultaneously, achieve beat all effect, there is industrial production prospect and marketable value widely.
Should be appreciated that the purposes of these embodiments is only not intended to for illustration of the present invention limit the scope of the invention.In addition; also should understand; after having read technology contents of the present invention, those skilled in the art can make various change, amendment and/or modification to the present invention, and these all equivalent form of values fall within the protection domain that the application's appended claims limits equally.
Claims (8)
1. a natural environmental-protective solid laundry magic square, described laundry magic square is made up of Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, Peppermint essential oil and deionized water; With 100 parts by weight, its concrete component concentration is as follows:
Seed of Chinese Soapberry extracting solution 30-60
Washing auxiliary detergent 2-5
Thickening material 5-10
Peppermint essential oil 1-3
Deionized water surplus;
Described Seed of Chinese Soapberry extracting solution is prepared by any one method in following A-D:
Preparation method A: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, taking and be a certain amount ofly placed in Erlenmeyer flask, add the water that volume/mass ratio (ml/g) is 14-18 times amount, adopt ultrasonic extraction to extract 45-65min under room temperature, ultrasonic power is 100W, in leaching process, water temperature rising 12-16 DEG C, ultrasonic wave continues to extract 45-65min, finally, and suction filtration removing filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains Seed of Chinese Soapberry extracting solution;
Preparation method B: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, take and be a certain amount ofly placed in Erlenmeyer flask, add the water that volume/mass ratio (ml/g) is 8-12 times amount, when 55-65 DEG C, 5-7h is extracted by wet distillation, continuous extraction 3 times, finally, suction filtration removing filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains Seed of Chinese Soapberry extracting solution;
Preparation method C: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, take and be a certain amount ofly placed in Erlenmeyer flask, add the dehydrated alcohol that volume/mass ratio (ml/g) is 8-12 times amount, when 60-70 DEG C, 4-6h is extracted by wet distillation, continuous extraction 3 times, last suction filtration removing filter residue, rotary evaporation removing ethanol, be concentrated into 3/4 of original solution volume, obtain Seed of Chinese Soapberry extracting solution;
Preparation method D: get Seed of Chinese Soapberry fruit and dry, peel off and pulverize, adopt soxhlet extraction, take and be a certain amount ofly placed in apparatus,Soxhlet's, add the normal hexane that volume/mass ratio (ml/g) is 18-22 times amount, colourless to flow liquid in 80-100 DEG C of refluxing extraction 6-10h, rotary evaporation reclaims normal hexane again, adds anhydrous slufuric acid magnesium dust in liquid, concussion, drying obtains Seed of Chinese Soapberry extracting solution after filtering.
2. natural environmental-protective solid laundry magic square as claimed in claim 1, is characterized in that: described washing auxiliary detergent is one or more in cellulase, proteolytic enzyme, lipase, Sumizyme MP.
3. natural solid environment friendly laundry magic square as claimed in claim 1 or 2, is characterized in that: washing auxiliary detergent is Sumizyme MP.
4. natural environmental-protective solid laundry magic square as claimed in claim 3, is characterized in that: the activity of described Sumizyme MP is 10-30U/mg.
5. natural environmental-protective solid laundry magic square as claimed in claim 1, is characterized in that: described thickening material is one or more in starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide element derivative, sodium alginate, gum arabic.
6. natural environmental-protective solid laundry magic square as claimed in claim 1, is characterized in that: described thickening material is sodium alginate.
7. prepare the method for natural environmental-protective solid laundry magic square described in any one of claim 1-6, it is characterized in that: by Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, Peppermint essential oil and deionized water, by above-mentioned part by weight, stirring and dissolving at 30-60 DEG C of temperature, make for dense fluids, then be placed in mould cooling and make it sizing, obtain laundry magic square.
8. the method for natural environmental-protective solid laundry magic square as claimed in claim 7, is characterized in that: described stirring and dissolving temperature is 45 DEG C.
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| CN104450299A (en) * | 2014-11-19 | 2015-03-25 | 苏州佑君环境科技有限公司 | Environment-friendly bacteriostatic detergent and preparation method thereof |
| CN113549499A (en) * | 2021-06-24 | 2021-10-26 | 苏潮辉 | Sapindus saponin laundry detergent and preparation method thereof |
| CN116004333B (en) * | 2021-10-21 | 2024-06-18 | 中国科学院大连化学物理研究所 | Ultramicro protein powder, ultramicro protein composition, effervescent tablet, preparation method thereof and application thereof in cleaning pesticide residues of fruits and vegetables |
| CN113943616A (en) * | 2021-11-25 | 2022-01-18 | 四川和诚过滤科技集团有限公司 | Extraction and production process of daily chemical soapberry raw material |
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| CN1291635A (en) * | 1999-10-06 | 2001-04-18 | 冼启福 | Detergent powder and its preparing process |
| CN102038793A (en) * | 2010-09-27 | 2011-05-04 | 南京泽朗医药科技有限公司 | Preparation method of soapberry saponin |
| CN102517177A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological eco-friendly multifunctional specific laundry detergent and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1291635A (en) * | 1999-10-06 | 2001-04-18 | 冼启福 | Detergent powder and its preparing process |
| CN102038793A (en) * | 2010-09-27 | 2011-05-04 | 南京泽朗医药科技有限公司 | Preparation method of soapberry saponin |
| CN102517177A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological eco-friendly multifunctional specific laundry detergent and preparation method thereof |
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