CN102127491B - Bactericidal cleaning agent and preparation method thereof - Google Patents
Bactericidal cleaning agent and preparation method thereof Download PDFInfo
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- CN102127491B CN102127491B CN 201010019428 CN201010019428A CN102127491B CN 102127491 B CN102127491 B CN 102127491B CN 201010019428 CN201010019428 CN 201010019428 CN 201010019428 A CN201010019428 A CN 201010019428A CN 102127491 B CN102127491 B CN 102127491B
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- ammonium salt
- amine oxide
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Abstract
The invention relates to a bactericidal cleaning agent. Main components of polysiloxane quaternary ammonium salt, dimethyldodecylamine oxide and fatty alcohol-polyoxyethylene ether, and a proper amount of aid and solubilizer are subjected to processes such as blending, mixing, stirring, dissolving, filtering and the like to be prepared into the bactericidal cleaning agent capable of being packaged under increased pressure or packaged in a common aerosol package. The cleaning agent integrates sterilization and cleaning, is convenient to use, nontoxic and environment-friendly, and meets the requirement of environmental protection; and the raw materials are readily available, and the product manufacturing process is concise. The product is widely applied to places such as households, public places, vehicles, wineshops, hospitals and the like, and has high practicability and good market prospect.
Description
Technical field
The present invention relates to a kind of sterilizing detergent for cleaning, be characterized in having concurrently the function of sterilization when cleaning, is a kind of innovation to traditional clean-out system.The invention still further relates to the preparation method of this sterilizing detergent for cleaning.
Background technology
Washing, just closely linked, closely bound up with people's life since ancient times.It involves industry-by-industry, and each department and field are little of each family, arrives greatly large-scale communal facility and industrial plants all relevant with washing.Along with expanding economy and standard of living improve constantly, various Novel articles use also more and more, also can be more and more higher to the requirement of employed washing composition.Therefore people are the sterilizing detergent for cleaning that clean-out system has again sterilizing function studying and seeking out a kind of, to adapt to the needs of modern market development and variation.
At present, cleaning product on the market, although various in style, of all kinds, it uses on the function and says, or the washing composition of traditional single cleaning performance.Simultaneously, the considerable part product all contains phosphoric acid salt washing assistant in various degree.As everyone knows, because the phosphoric acid salt washing assistant can pollute environment, its liquid enters and caused the madness of algae to increase after rivers and lakes caused extensive use of chemical fertilizer, the balance of broken ring ecotope, and reproached widely.So some countries explicit order limit and forbid containing the phosphoric acid salt washing auxiliary detergent in cleaning products, with the balance of preserving the ecological environment.In such cases, seek a kind of both safe, nontoxic and and environmental harmony, existing efficient scourability has again the washing composition of sterilizing function concurrently, has obvious social and economic benefits.
Summary of the invention
Purpose of the present invention provides a kind ofly take polysiloxane quaternary amine, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether as body material, and has sterilization, mildew-resistant, drives the aq. type sterilizing detergent for cleaning take water as carrier of mite function.Its preparation technology is succinct, product is easy to use, high effect nontoxic, and phosphoric acid salt washing assistant is not free from environmental pollution, meets cleaning product to the needs of environmental protection future development.
A kind of sterilizing detergent for cleaning, take polysiloxane quaternary amine, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether as the main raw material(s) composition, its component and weight percent are as follows:
Ethanol CH
3CH
2OH 1.00-2.50%
Deionized water H
2O 88-92.00%
Starso in the said components, Trisodium Citrate, trolamine and deionized water carry out the pre-mixing dissolving, again dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and deionized water pre-mixing dissolving; Then polysiloxane quaternary amine, propandiol butyl ether pre-mixing; At last three premixs are always mixed and add that essence is hybrid packed forms.
The present invention adopts the classification pre-mixing, and the method for carrying out at last total mix and blend is formulated.
A kind of preparation method of sterilizing detergent for cleaning, its preparation process is as follows:
The pre-mixing of A, inorganic and organic additive
Per-cent according to the weight of recipe ingredient, take by weighing respectively Starso, Trisodium Citrate, trolamine, then throw in 30% deionized water of Total Water, carry out the mix and blend dissolving, make material in the container all be dissolved to as clear as crystal till, 10～20 minutes time, then cross 200 mesh sieves and filter.
The pre-mixing of B, cleaning host
According to the per-cent of weight of prescription, 70% the deionized water that takes by weighing respectively dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and residue Total Water carries out pre-mixing and is dissolved into as clear as crystal liquid.
The pre-mixing of C, sterilant
According to the weight percent of recipe ingredient, take by weighing respectively polysiloxane quaternary amine, propandiol butyl ether and carry out the liquid that the pre-mixing dissolving stirs into homogeneous transparent.
The preparation of D, sterilizing detergent for cleaning
The premixed liquid of B step is rendered in the container that holds the A premixed liquid, stir, make liquid be vitreous state, its pH value is adjusted in the scope of 9.5-10 with citric acid, then the premix liquid of C step preparation is put in the above-mentioned molten device and stirred, call in again the essence blending, filter at last, finished product packing.
The present invention is take polysiloxane quaternary amine, fatty alcohol-polyoxyethylene ether, dimethyl dodecyl amine oxide as main raw, take propandiol butyl ether, ethanol as solubilisation aids, as washing assistant, formulated by production technique such as dissolving, mixing, stirring, filtrations with Starso.Its concrete technology flow process is as follows:
At first Starso, Trisodium Citrate, trolamine are weighed up according to the weight percent in the prescription, be invested in the container, then drop into 30% deionized water of Total Water, fully stir the material that makes in the container and fully be dissolved into as clear as crystal uniform solution, churning time is 10～20 minutes, then crosses 200 mesh sieves; Second step, according to the weight percent of prescription, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, 70% deionized water of ethanol and residue Total Water is blended in one and stirs, and 5～10 minutes time, becomes as clear as crystal liquid; In the 3rd step, the polysiloxane quaternary amine, propandiol butyl ether mixes and stirs according to the per-cent of formulation weight, makes the polysiloxane quaternary amine fully be dissolved into the liquid of homogeneous transparent, churning time 10～20 minutes.
The 4th step, the mixing liquid for preparing in the second step is rendered in the container of first step, fully stir after 10 minutes, after with citric acid pH value being adjusted to 9.5-10.0, again the mixture of third step is also rendered in this container, stir as clear as crystal homogeneous phase solution and add essence, filter and just can be packaged into product.
Polysiloxane season peace salt is one of this product major ingredient in the prescription, and it is a kind of killing bacterium, mildew-resistant, drive the mite agent take water as carrier with special construction.It can pass through to press down the Bactericidal while, and breaks off the nutrition source of mould, suppresses the breeding of acarid.Pass through simultaneously to suppress and stop microbial growth and Decomposition, thereby suppressed the generation of stench.It is not only effective to the bacterium of routine, and some are comparatively had resistance, and the bacterium that difficulty is killed such as methicillin-resistant staphylococcus aureus, Candida albicans also have stronger killing effect.Because the special structure of polysiloxane quaternary amine, its surface of sprawling be just as the bed of the atomic apicule nail of one deck, thereby puncture the cell walls of bacterium and sterilization.Can say that it is to come killing bacteria with the method for machinery rather than with poisonous material.Therefore it can generation can not make the develop immunity to drugs microorganism of particular surroundings of bacterium.
Dimethyl dodecyl amine oxide is a kind of amphoterics, and it has good compound property, and with the consistency of inorganic assistant agent and water-soluble.Simultaneously its removal effect to grease and dust dirt is obvious especially, and it also has certain sterilizing function.Therefore when it and polysiloxane quaternary amine are composite, further strengthen and support the performance of sterilization, anti-mildew and the anti-mite function of polysiloxane quaternary amine, make it become the cleaning disinfectant with premium properties.When the fatty alcohol-polyoxyethylene ether of it and non-ionic type was composite, it had good anti-microbial effect.Simultaneously it has synergistic function with non-ionic surfactant in scourability, plays solubilising in prescription, surely steep, help wash, the effect of sterilization.It also has the to a certain degree function of deodorization and sterilization simultaneously.
Fatty alcohol-polyoxyethylene ether is a kind of non-ionic tensio-active agent, one of its main raw material(s) that conduct is cleaned in prescription, aspect washing, special efficacy is arranged, as the residual alcohol that shows product is few, show certain thickening properties in prescription, the operating temperature range when making it bring into play excellent scourability is wider, and is more stable, and intermiscibility is better, and is particularly good to some obstinate its removal capacities of lipid dirt.So in scourability complementary coordinating effect is arranged all on bactericidal property still.
Sterilizing detergent for cleaning of the present invention both can be made into common sprays, the aerosol agent of the pressurization that also can be made into.
Beneficial effect of the present invention:
Product of the present invention have efficiently, non-toxic nature, it is strong that soil removability is cleaned in its sterilization, material source is extensive.
2. the product free from extraneous odour is fire-retardant.
3. application range of products is wide, is applicable to the usefulness of the sterilizing cleaning of household objects, office products, communal facility and industrial plants, the vehicles.
4. the product use is safe, convenient and swift, harmless, and the noresidue poisonous substance meets the requirement of environmental protection.
Embodiment
Embodiment 1
Preparation 2000 gram sterilizing detergent for cleaning
Weight percent according to each component in the prescription, take by weighing respectively Starso 6 grams, Trisodium Citrate 12 grams, trolamine 7.6 gram drops in the containers, then add total throw 30% of the water yield go dried up, i.e. 558 grams, stir, material in the container is all dissolved, and then churning time 10 minutes crosses 200 mesh sieves; Then second step takes by weighing respectively dimethyl dodecyl amine oxide 34 grams, fatty alcohol-polyoxyethylene ether 20 grams, ethanol 30 gram drops into 70% deionized water of residue Total Water, i.e. 1302 grams, fully stir, make the material in the container dissolve churning time 10 minutes fully; The 3rd step according to the per-cent of formulation weight, took by weighing polysiloxane quaternary amine 10 grams, propandiol butyl ether 20 gram mix and blends, and 5 minutes time, make the dissolving of polysiloxane quaternary amine, the liquid in the container is limpid homogeneous liquid.At last, material in the poly-container of second step is rendered in the container of first step, churning time is 10 minutes, after with citric acid pH value being adjusted to 9.5-10.0, solution in the third step is also put in the container of first step, stirred 5 minutes, and made all materials of filling a prescription in the container evenly be mixed into as clear as crystal liquid, should be without the visible solids.Add 0.4 gram lemon class spices again, make product that good flavor perception be arranged, then packing just is the present invention's product after filtration.
Embodiment 2
Preparation 2000 gram sterilizing detergent for cleaning
Weight percent according to each component in the prescription, take by weighing respectively Starso 12 grams, Trisodium Citrate 16 grams, trolamine 12 grams drop in the container, then 30% of the total throwing of the adding water yield deionized water, i.e. 528 grams, stir, material in the container is all dissolved, and churning time is 10 minutes, then crosses 200 mesh sieves; Then second step takes by weighing respectively dimethyl dodecyl amine oxide 50 grams, fatty alcohol-polyoxyethylene ether 40 grams, and ethanol 50 grams drop into 70% deionized water of residue Total Water, i.e. 1232 grams, churning time 10 minutes is dissolved the material in the container fully; The 3rd step took by weighing respectively polysiloxane quaternary amine 20 grams according to the per-cent of formulation weight, propandiol butyl ether 40 gram mix and blends, and 5 minutes time, the polysiloxane quaternary amine is dissolved fully, the liquid in the container is limpid homogeneous liquid.At last, the material of second step container is put in the container of first step, churning time 10 minutes, after with citric acid pH value being adjusted to 9.5-10, the middle solution of third step is also put in the solution of container of first step, stirred 5 minutes, make that all materials of recipe ingredient evenly are mixed into as clear as crystal liquid in the container, should without the visible solids, then filter and package the product that just becomes the present invention.
Claims (4)
1. sterilizing detergent for cleaning, take organosilicon quaternary ammonium salt, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether as main raw material, its component and weight percent are as follows:
The structure of cationic moiety is in the described organosilicon quaternary ammonium salt:
Starso in the said components, Trisodium Citrate, trolamine and deionized water are carried out the pre-mixing dissolving; Again dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and deionized water are carried out the pre-mixing dissolving; Then organosilicon quaternary ammonium salt, propandiol butyl ether pre-mixing; At last above-mentioned three premixs are always mixed and add that essence is hybrid packed forms.
2. sterilizing detergent for cleaning according to claim 1 is characterized in that dimethyl dodecyl amine oxide replaces with octadecyl dimethyl amine oxide.
3. sterilizing detergent for cleaning according to claim 1 is characterized in that described sterilizing detergent for cleaning makes sprays or pressurized aerosol agent.
4. the preparation method of a sterilizing detergent for cleaning may further comprise the steps:
A. the pre-mixing of auxiliary agent
Weight percent according to prescription takes by weighing respectively Starso, Trisodium Citrate, trolamine, then throws in 30% deionized water of Total Water, carry out the mix and blend dissolving, make material in the container all be dissolved to as clear as crystal till, 10～20 minutes time, then cross 200 mesh sieves and filter;
B. clean the pre-mixing of host
The deionized water that takes by weighing respectively dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and remaining Total Water 70% by proportioning carries out pre-mixing and is dissolved into as clear as crystal liquid;
C. the pre-mixing of sterilant
Take by weighing respectively organosilicon quaternary ammonium salt, propandiol butyl ether by proportioning and carry out the liquid that the pre-mixing dissolving stirs into homogeneous transparent; The structure of cationic moiety is in the described organosilicon quaternary ammonium salt:
D. sterilizing detergent for cleaning is mixed with
The premixed liquid of B step preparation is rendered in the premixed liquid container of splendid attire A step preparation, stir, make liquid be vitreous state, with citric acid its pH value is adjusted to 9.5～10, then the premixed liquid of C step is put in the above-mentioned container and stirred, call in again the essence blending, filter at last finished product packing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019428 CN102127491B (en) | 2010-01-15 | 2010-01-15 | Bactericidal cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019428 CN102127491B (en) | 2010-01-15 | 2010-01-15 | Bactericidal cleaning agent and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN102127491A CN102127491A (en) | 2011-07-20 |
| CN102127491B true CN102127491B (en) | 2013-02-27 |
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| CN 201010019428 Expired - Fee Related CN102127491B (en) | 2010-01-15 | 2010-01-15 | Bactericidal cleaning agent and preparation method thereof |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533461A (en) * | 2011-12-27 | 2012-07-04 | 瑞普（天津）生物药业有限公司 | Composition with effect of cleaning poultry and livestock drinking water system and its preparation method |
| CN103766402A (en) * | 2014-01-23 | 2014-05-07 | 南通苏通分离工程科技有限公司 | Disinfectant and preparation method thereof |
| FR3047488B1 (en) | 2016-02-05 | 2020-02-28 | Laboratoires Anios | DETERGENT COMPOSITIONS FOR CLEANING IN THE COSMETIC AND PHARMACEUTICAL INDUSTRY. |
| CN105838517A (en) * | 2016-05-05 | 2016-08-10 | 马鞍山纽盟知识产权管理服务有限公司 | Towel cleaning agent |
| CN105838518A (en) * | 2016-05-13 | 2016-08-10 | 周家仁 | Antibacterial laundry detergent |
| CN108774598A (en) * | 2018-08-23 | 2018-11-09 | 安庆枝梅化工有限责任公司 | A kind of disinfecting scrub liquid |
| CN109706000A (en) * | 2018-12-26 | 2019-05-03 | 深圳市北岳海威化工有限公司 | A kind of long acting antibiotic liquid detergent and preparation method thereof |
| CN112544697A (en) * | 2020-11-20 | 2021-03-26 | 海南同德食品配送有限公司 | Cold-chain logistics fresh-keeping method for agricultural products |
| CN113214918A (en) * | 2021-05-21 | 2021-08-06 | 大连欧派科技有限公司 | Wet tissue for glasses and preparation method thereof |
| CN113897248B (en) * | 2021-09-22 | 2023-10-31 | 广东御容宫生物科技有限公司 | Degerming and mite-killing laundry detergent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200676A (en) * | 2007-12-10 | 2008-06-18 | 北京绿伞化学有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
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2010
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101200676A (en) * | 2007-12-10 | 2008-06-18 | 北京绿伞化学有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
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| CN102127491A (en) | 2011-07-20 |
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Effective date of registration: 20151123 Address after: 510630, No. 34, No. 202, Suzhou court, Jinan University, Guangzhou, Guangdong, Tianhe District Patentee after: Tan Gang Patentee after: Zou Haiyuan Patentee after: Jiang Shuqing Address before: 510630, No. 34, No. 202, Suzhou court, Jinan University, Guangzhou, Guangdong, Tianhe District Patentee before: Tan Gang Patentee before: Zou Haiyuan Patentee before: Mark.Crone Patentee before: Dell.Casey |
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Granted publication date: 20130227 Termination date: 20170115 |