CN103468419A - Natural and environment-friendly solid clothes-washing magic cube and preparation method thereof - Google Patents
Natural and environment-friendly solid clothes-washing magic cube and preparation method thereof Download PDFInfo
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Abstract
The invention provides a natural and environment-friendly solid clothes-washing magic cube and a preparation method of the natural and environment-friendly solid clothes-washing magic cube. The natural and environment-friendly solid clothes-washing magic cube comprises a soapberry extracting solution, a washing assistant, a thickening agent, mint essential oil and deionized water. Through appropriate selection of components and specific combination, the natural and environment-friendly solid clothes-washing magic cube has the advantages of being simple in component, effective, short in protection process, remarkable in washing effect, convenient to use and carry, environmentally friendly, innocuous, quite strong in dirt-removing capacity and sterilization and disinfection capacity, broad in industrialization prospect and good in market value.
Description
Technical field
The present invention relates to a kind of daily life solid laundry magic square, relate more specifically to a kind of containing natural component, do not add solid laundry magic square of any chemical additive and preparation method thereof, belong to the Betengent product field.
Background technology
Seed of Chinese Soapberry has another name called wood and suffers from son, yellow order etc., contain a large amount of saponin constituents in its pericarp, shell, except thering is good whipability and removing the performance of spot, in some documents, also reported the Seed of Chinese Soapberry saponin also have antibiotic, brighten, nti-freckle, anti-acne, prevent dermopathic medicinal efficacy, can be in various skin care product as the main component of natural active matter.
Up to the present, there have been the many relevant reports that relate to Wu Huan Zi detergen or sanitising agent in prior art, for example:
The Patent Application Publication of CN101177655A a kind of natural surface-active dinnerware washing agent, it is by Seed of Chinese Soapberry actives extracting solution, alkyl polyglycoside (APG), ammonium lauryl sulfate, alkylpolyoxyethylene ammonium sulfate, EDTA, sodium-chlor, Sargassum polysaccharides and form with excess water, have advantages of that the preparation method is simple, material source extensively and be easy to degraded.
The Patent Application Publication of CN101659909A a kind of natural washing particle, it is mixed by powder A component and liquid material B component.Wherein the A component comprises calcium carbonate 2.1-33.5%, natural zeolite powder 1.2-25.9%, spaonin powder 1.9-48.9%, tea saponin 2.5-37.8%, Seed of Chinese Soapberry fruit peel powder 0.2-15.5%; The B component comprises epoxy resin binder 2.6-37.5%, epoxy curing agent 2.6-37.5%.This detergent compositions obtained washing effect good, can repeatedly recycle, the excellent effect such as safety non-toxic.
The Patent Application Publication of CN101880608A a kind of natural solid cleaning agent, its component by kaolin 6-50%, zeolite powder 4-36%, calcite in powder 7-45%, pumice sand 3-40%, Feldspar Powder 4-55%, diatomite 2-17%, polynite powder 3-22%, talcum powder 4-40%, saponin 1-15%, white carbon black 3-18%, water 0-40% forms, and wherein saponin is Chinese honey locust saponin or Seed of Chinese Soapberry saponin.This sanitising agent can be realized clean to metal, pottery, plank, glass etc., and produce simple, easy to use, can effectively remove various spots.
The Patent Application Publication of CN102021086A a kind of natural plant cleanser essence, it is comprised of Seed of Chinese Soapberry extract 2-20%, propylene glycol 5-10%, ethanol 0-10%, Zulkovsky starch 0.5-2%, Xylo-Mucine 0.5-1.5%, potassium sorbate 0.2-0.3% and sodium-chlor, citric acid, excess water, has reached effectively wipe oil and can remove the multi-efficiency of garden stuff pesticide residue and heavy metal contamination again.
The Patent Application Publication of CN101177655A a kind of Seed of Chinese Soapberry washing liquid, it comprises Seed of Chinese Soapberry extracting solution 60-70%, APG0810 alkyl glycoside 10-20%, Oleum Cocois 5-10%, citric acid 0.04-0.08%, Herba Lysimachiae foenumgraeci quintessence oil 0.06-1%, the various ingredients such as deionized water 10-48%, show pungency low, there is natural environmental-protective Phytoremediation activity and anti-microbial activity, to human body and the beneficial functional such as environmentally friendly.
The Patent Application Publication of CN102517177A a kind of biological environmental production multifunction special effect washing liquid, it,, by composite the forming of various ingredients of alkyl glycoside 30-50 part, Oleum Cocois 15-20 part, Sumizyme MP 5-10 part, Seed of Chinese Soapberry soap breast 5-15 part, matrine 1-5 part, natural soap powder 5-10 part, Oleum Cocois LAO 5-10 part, disodium ethylene diamine tetraacetate 0.1-0.5 part, auxiliary agent 5-10 part, sanitas 0.1-0.5 part, essence 0.5-1 part, appropriate citric acid, has the effect that environmentally friendly, comprehensive scourability is outstanding, can remove multiple stain simultaneously.
There are the large drawback of various, the composite difficulty of complicated components in above-mentioned washing composition of the prior art or sanitising agent, cause that production cost is high, technical process is long, other washing powder, washing liquid or washing soap that adopts chemical composition to be prepared from has certain hazardness and easily causes environmental pollution human body skin.
For problems of the prior art, the present invention is intended to develop a kind of natural environmental-protective solid laundry magic square, suitable selection and particular combination by component, make this laundry magic square have that component is simple effectively, Production Flow Chart is short, washing effect is excellent and use portable multiple excellent properties concurrently, the ability of superpower soil removability, adsorptive power, sterilization and disinfection and the ability of mosquito repellent, make it have industrial prospect and marketable value widely.
Summary of the invention
The above-mentioned many defects that exist based on prior art, the inventor, through a large amount of further investigations, after having paid sufficient creative work, has researched and developed a kind of natural environmental-protective solid laundry magic square, thereby has solved above-mentioned many defects of pointing out.
Particularly, the present invention relates generally to two aspects.
First aspect, the present invention relates to a kind of natural environmental-protective solid laundry magic square, and it is comprised of Seed of Chinese Soapberry extracting solution, detergent builder, thickening material, peppermint essential oil and deionized water.
In solid laundry magic square of the present invention, in 100 weight parts, the weight content of its concrete component is as follows:
In solid laundry magic square of the present invention, the parts by weight of Seed of Chinese Soapberry extracting solution are 30-70 part, and this scope has comprised any sub-range scope wherein, as is 32-58 part, 35-55 part, 38-52 part, 40-50 part.
In solid laundry magic square of the present invention, washing auxiliary detergent is one or more in cellulase, proteolytic enzyme, lipase, Sumizyme MP, and its parts by weight are 2-5 part, as is 2 parts, 3 parts, 4 parts or 5 parts.
In solid laundry magic square of the present invention, thickening material is one or more in starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide element derivative, sodium alginate, gum arabic, its parts by weight are 5-10 part, as are 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts.
In solid laundry magic square of the present invention, washing auxiliary detergent is preferably Sumizyme MP.
In solid laundry magic square of the present invention, preferably the activity of Sumizyme MP is 10-30U/mg, is for example 10U/mg, 15U/mg or 20U/mg.
In solid laundry magic square of the present invention, thickening material is preferably sodium alginate.
In solid laundry magic square of the present invention, the parts by weight of peppermint essential oil are 1-3 part, as are 1 part, 1.5 parts, 2 parts, 2.5 parts or 3 parts.
In described solid laundry magic square of the present invention, the Seed of Chinese Soapberry extracting solution adopts any one method preparation in following A-D:
Preparation method A: get Seed of Chinese Soapberry and really dry, peel off and pulverize, take a certain amount of Erlenmeyer flask that is placed in, the water that adds volume/mass doubly to measure for 14-18 than (ml/g), adopt ultrasonic extraction to extract 45-65min under room temperature, ultrasonic power is 100W, in leaching process, water temperature rising 12-16 ℃, ultrasonic wave continues to extract 45-65min, and last, suction filtration is removed filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains the Seed of Chinese Soapberry extracting solution.
Preparation method B: get Seed of Chinese Soapberry and really dry, peel off and pulverize, take a certain amount of Erlenmeyer flask that is placed in, the water that adds volume/mass doubly to measure for 8-12 than (ml/g), in the situation that 55-65 ℃, extract 5-7h by wet distillation, extract 3 times continuously, last, suction filtration is removed filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains the Seed of Chinese Soapberry extracting solution.
Preparation method C: get Seed of Chinese Soapberry and really dry, peel off and pulverize, take a certain amount of Erlenmeyer flask that is placed in, the dehydrated alcohol that adds volume/mass doubly to measure for 8-12 than (ml/g), in the situation that 60-70 ℃, extract 4-6h by wet distillation, extract 3 times continuously, last suction filtration is removed filter residue, and rotary evaporation is removed ethanol, be concentrated into 3/4 of original solution volume, obtain the Seed of Chinese Soapberry extracting solution.
Preparation method D: get Seed of Chinese Soapberry and really dry, peel off and pulverize, adopt soxhlet extraction, take a certain amount of apparatus,Soxhlet's that is placed in, the normal hexane that adds volume/mass doubly to measure for 18-22 than (ml/g), colourless to flow liquid in 80-100 ℃ of refluxing extraction 6-10h, rotary evaporation reclaims normal hexane again, in liquid, adds the anhydrous slufuric acid magnesium dust, concussion, drying obtains the Seed of Chinese Soapberry extracting solution after filtering.
Second aspect, the present invention relates to the preparation method of above-mentioned natural environmental-protective solid laundry magic square, specific as follows: by Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, peppermint essential oil and deionized water, by above-mentioned weight ratio, stirring and dissolving at 30-60 ℃ of temperature, make dense thick liquid, then be placed in cooling the making it of mould and finalize the design, obtain the laundry magic square.
In the preparation method of the described natural environmental-protective solid laundry magic square of invention, described stirring and dissolving temperature is preferably 45 ℃.
Embodiment
Below by specific embodiment, the present invention is described in detail; but the purposes of these exemplary embodiments and purpose only are used for exemplifying the present invention; not real protection scope of the present invention is formed to any type of any restriction, more non-protection scope of the present invention is confined to this.
Preparation example 1: the preparation of Seed of Chinese Soapberry extracting solution
Get Seed of Chinese Soapberry and really dry, peel off and pulverize, take 15g and be placed in Erlenmeyer flask, add water 250mL, adopt ultrasonic extraction to extract 50min under room temperature, ultrasonic power is 100W, in leaching process, water temperature rises 14 ℃, ultrasonic wave continues to extract 50min, and last, suction filtration is removed filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains the concentrated solution that Seed of Chinese Soapberry extracts.
Preparation example 2: the preparation of Seed of Chinese Soapberry extracting solution
Get Seed of Chinese Soapberry and really dry, peel off and pulverize, take 15g and be placed in Erlenmeyer flask, add water 150mL, in the situation that 60 ℃, extract 6h by wet distillation, extract continuously 3 times, last, suction filtration is removed filter residue, and filtrate is concentrated into 3/4 of original solution volume, obtains the Seed of Chinese Soapberry extracting solution.
Preparation example 3: the preparation of Seed of Chinese Soapberry extracting solution
Getting Seed of Chinese Soapberry really dries, peel off and pulverize, taking 15g and be placed in Erlenmeyer flask, adding dehydrated alcohol 150mL, at 65 ℃, extract 5h by wet distillation, extract continuously 3 times, last, suction filtration is removed filter residue, rotary evaporation is removed ethanol, is concentrated into 3/4 of original solution volume, obtains the Seed of Chinese Soapberry extracting solution.
Preparation example 4: the preparation of Seed of Chinese Soapberry extracting solution
Getting Seed of Chinese Soapberry really dries, peel off and pulverize, adopt soxhlet extraction, take 15g and be placed in apparatus,Soxhlet's, add normal hexane 300mL, colourless to flow liquid in 90 ℃ of lower refluxing extraction 8h, rotary evaporation reclaims normal hexane again, in liquid, adds the anhydrous slufuric acid magnesium dust, concussion, drying obtains the Seed of Chinese Soapberry extracting solution after filtering after drying.
Embodiment 1
By total weight parts, it is 100 parts, peppermint essential oil and the surplus deionized water of the Sumizyme MP that is 10U/mg by the Seed of Chinese Soapberry extracting solution of 30 weight part preparation examples 1,3 weight part activity, 5 weight part sodium alginates, 2 weight parts, mix, under 30 ℃, stir until become thick material, be placed in the plastic pattern of a plurality of 2cm * 2cm * 2cm and push, by the time take out after typing is dry, obtain natural environmental-protective laundry magic square, called after MF-1.
Embodiment 2
By total weight parts, it is 100 parts, peppermint essential oil and the surplus deionized water of the Sumizyme MP that is 15U/mg by the Seed of Chinese Soapberry extracting solution of 40 weight part preparation examples 2,4 weight part activity, 7 weight part sodium alginates, 1.5 weight parts, mix, under 40 ℃, stir until become thick material, be placed in the plastic pattern of a plurality of 2cm * 2cm * 2cm and push, by the time take out after typing is dry, obtain natural environmental-protective laundry magic square, called after MF-2.
Embodiment 3
By total weight parts, it is 100 parts, peppermint essential oil and the surplus deionized water of the Sumizyme MP that is 20U/mg by the Seed of Chinese Soapberry extracting solution of 50 weight part preparation examples 3,3 weight part activity, 8 weight part sodium alginates, 3 weight parts, mix, under 50 ℃, stir until become thick material, be placed in the plastic pattern of a plurality of 2cm * 2cm * 2cm and push, by the time take out after typing is dry, obtain natural environmental-protective laundry magic square, called after MF-3.
Embodiment 4
By total weight parts, it is 100 parts, peppermint essential oil and the surplus deionized water of the Sumizyme MP that is 25U/mg by the Seed of Chinese Soapberry extracting solution of 60 weight part preparation examples 4,5 weight part activity, 10 weight part sodium alginates, 1 weight part, mix, under 60 ℃, stir until become thick material, be placed in the plastic pattern of a plurality of 2cm * 2cm * 2cm and push, by the time take out after typing is dry, obtain natural environmental-protective laundry magic square, called after MF-4.
Embodiment 5-8
Except Sumizyme MP is replaced with cellulase, implemented embodiment 5-8 with the same way as with embodiment 1-4 respectively, obtain respectively natural environmental-protective laundry magic square MF-5, MF-6, MF-7 or MF-8.
Embodiment 9-12
Except Sumizyme MP is replaced with lipase, implemented embodiment 9-12 with the same way as with embodiment 1-4 respectively, obtain respectively natural environmental-protective laundry magic square MF-9, MF-10, MF-11 or MF-12.
Embodiment 13-16
Except sodium alginate is replaced with starch, implemented embodiment 13-16 with the same way as with embodiment 1-4 respectively, obtain respectively natural environmental-protective laundry magic square MF-13, MF-14, MF-15 or MF-16.
Embodiment 17-20
Except sodium alginate is replaced with carrageenin, implemented embodiment 17-20 with the same way as with embodiment 1-4 respectively, obtain respectively natural environmental-protective laundry magic square MF-17, MF-18, MF-19 or MF-20.
Embodiment 21-24
Except sodium alginate is replaced with gum arabic, implemented embodiment 21-24 with the same way as with embodiment 1-4 respectively, obtain respectively natural environmental-protective laundry magic square MF-21, MF-22, MF-23 or MF-24.
The performance test experiment
1, the clean effect of natural environmental-protective solid laundry magic square of the present invention test.
Use the prepared natural environmental-protective laundry magic square washing of the present invention to speckle with rectangle band even spot of the same race, measure-alike, washing methods is as follows: will be put in washing machine by even spot of the same race rectangle band that stain, measure-alike, then the natural environmental-protective solid laundry magic square of the present invention that adds equivalent weight, after it dissolves, start washing machine, wash the identical time, then use whiteness instrument (blancometer) to measure its fair and clear degree.
Experimental procedure:
(1) the fair and clear degree of testing clean band, as standard reference, is measured three times and is averaged;
(2) get 10 soiled cotton bars as experimental group, test respectively 10 groups and clean the front fair and clear degree of soiled cotton bar, measure three times and average;
(3) with above-mentioned washing methods, 10 groups of soiled cotton bars are cleaned, then dried, measured the fair and clear degree of soiled cotton bar after cleaning, measure three times and average;
(4) calculate soil removal efficiency, adopt following formula:
Soil removal efficiency (%)=[(the fair and clear degree of soiled cotton bar before the fair and clear degree of the soiled cotton bar after cleaning-cleaning)/(the fair and clear degree of soiled cotton bar before the fair and clear degree of clean band-cleaning)] * 100%.Experimental result is in Table 1.
2, the sterilization effect of natural environmental-protective solid laundry magic square of the present invention test.
Use streptococcus aureus, the intestinal bacteria bacterial classification as bactericidal assay; Use the prepared natural environmental-protective laundry magic square of the present invention as bactericidal agent.
Experimental procedure
(1) the 0.5mL bacteria suspension that will be 106cfu/mL containing streptococcus aureus or intestinal bacteria is 0.4% with the 4.5mL mass concentration respectively, and the natural environmental-protective solid laundry magic square aqueous solution of the present invention mixes, standing effect 10min, obtain respectively two kinds of bacterium medicine suspensions;
(2) respectively get the neutralizing agent (peroxide acetate aqueous solution that the sodium thiosulfate solution that the peroxide acetate aqueous solution that described neutralizing agent such as mass concentration is 0.1-0.5%, mass concentration are 0.1-1.0% or mass concentration are 0.1-3.0% etc.) that the above-mentioned bacterium medicine of 0.5mL suspension joins 4.5mL, after mixing, standing effect 8min, then get respectively 0.5mL mixing liquid inoculation plate, pour into plain agar and mix, under 37 ℃, cultivate 36 hours, the counting colony number, calculate sterilizing rate, experimental result is in Table 2.
Interpretation of result
The clean effect of each group washing magic square of table 1. relatively
From table 1 result: adopt the soil removal efficiency after natural environmental-protective solid laundry magic square washing of the present invention all to reach more than 80%, as seen by suitable selection and the particular combination of component, make the laundry magic square show excellent clean effect.
The Comparison of effect on sterilization of each group laundry magic square of table 2.
From table 2 result: adopt natural environmental-protective solid laundry magic square of the present invention to carry out bacteriostatic experiment and all obtained sterilizing rate and reach the excellent effect more than 90%, visible by suitable selection and the particular combination of component, make the laundry magic square be attended by good sterilization and disinfection ability.
Comprehensively above-mentioned, natural environmental-protective solid laundry magic square of the present invention have component simple, easy to prepare, use portable many merits, its suitable selection by component and particular combination show excellent clean effect, and be attended by good sterilization and disinfection ability simultaneously, obtain beat all effect, there is suitability for industrialized production prospect and marketable value widely.
The purposes that should be appreciated that these embodiment only limits the scope of the invention for the present invention being described but not being intended to.In addition; also should understand; after having read technology contents of the present invention, those skilled in the art can make various changes, modification and/or modification to the present invention, within these all equivalent form of values fall within the protection domain that the application's appended claims limits equally.
Claims (10)
1. a natural environmental-protective solid laundry magic square, described laundry magic square is comprised of Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, peppermint essential oil and deionized water.
2. natural solid environment friendly laundry magic square as claimed in claim 1, it is characterized in that: in 100 weight parts, its concrete component concentration is as follows:
3. natural environmental-protective solid laundry magic square as claimed in claim 1 or 2, it is characterized in that: described washing auxiliary detergent is one or more in cellulase, proteolytic enzyme, lipase, Sumizyme MP.
4. as the described natural solid environment friendly laundry of claim 1-3 any one magic square, it is characterized in that: washing auxiliary detergent is Sumizyme MP.
5. natural environmental-protective solid laundry magic square as claimed in claim 4, it is characterized in that: the activity of described Sumizyme MP is 10-30U/mg.
6. as the described natural environmental-protective solid laundry of claim 1-5 any one magic square, it is characterized in that: described thickening material is one or more in starch, pectin, agar, gelatin, marine alga fat, carrageenin, dextrin, tragacanth gum, polysaccharide element derivative, sodium alginate, gum arabic.
7. as the described natural environmental-protective solid laundry of claim 1-6 any one magic square, it is characterized in that: described thickening material is sodium alginate.
8. as the described natural environmental-protective solid laundry of claim 1-7 any one magic square, it is characterized in that: described Seed of Chinese Soapberry extracting solution is any one method preparation in following A-D:
Preparation method A: get Seed of Chinese Soapberry and really dry, peel off and pulverize, take a certain amount of Erlenmeyer flask that is placed in, the water that adds volume/mass doubly to measure for 14-18 than (ml/g), adopt ultrasonic extraction to extract 45-65min under room temperature, ultrasonic power is 100W, in leaching process, water temperature rising 12-16 ℃, ultrasonic wave continues to extract 45-65min, and last, suction filtration is removed filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains the Seed of Chinese Soapberry extracting solution.
Preparation method B: get Seed of Chinese Soapberry and really dry, peel off and pulverize, take a certain amount of Erlenmeyer flask that is placed in, the water that adds volume/mass doubly to measure for 8-12 than (ml/g), in the situation that 55-65 ℃, extract 5-7h by wet distillation, extract 3 times continuously, last, suction filtration is removed filter residue, filtrate is concentrated into 3/4 of original solution volume, obtains the Seed of Chinese Soapberry extracting solution.
Preparation method C: get Seed of Chinese Soapberry and really dry, peel off and pulverize, take a certain amount of Erlenmeyer flask that is placed in, the dehydrated alcohol that adds volume/mass doubly to measure for 8-12 than (ml/g), in the situation that 60-70 ℃, extract 4-6h by wet distillation, extract 3 times continuously, last suction filtration is removed filter residue, and rotary evaporation is removed ethanol, be concentrated into 3/4 of original solution volume, obtain the Seed of Chinese Soapberry extracting solution.
Preparation method D: get Seed of Chinese Soapberry and really dry, peel off and pulverize, adopt soxhlet extraction, take a certain amount of apparatus,Soxhlet's that is placed in, the normal hexane that adds volume/mass doubly to measure for 18-22 than (ml/g), colourless to flow liquid in 80-100 ℃ of refluxing extraction 6-10h, rotary evaporation reclaims normal hexane again, in liquid, adds the anhydrous slufuric acid magnesium dust, concussion, drying obtains the Seed of Chinese Soapberry extracting solution after filtering.
9. the method for preparing the described natural environmental-protective solid laundry of claim 1-8 any one magic square, it is characterized in that: by Seed of Chinese Soapberry extracting solution, washing auxiliary detergent, thickening material, peppermint essential oil and deionized water, by above-mentioned part by weight, stirring and dissolving at 30-60 ℃ of temperature, make dense thick liquid, then be placed in cooling the making it of mould and finalize the design, obtain the laundry magic square.
10. the method for natural environmental-protective solid laundry magic square as claimed in claim 9, it is characterized in that: described stirring and dissolving temperature is 45 ℃.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104450299A (en) * | 2014-11-19 | 2015-03-25 | 苏州佑君环境科技有限公司 | Environment-friendly bacteriostatic detergent and preparation method thereof |
| CN113549499A (en) * | 2021-06-24 | 2021-10-26 | 苏潮辉 | Sapindus saponin laundry detergent and preparation method thereof |
| CN113943616A (en) * | 2021-11-25 | 2022-01-18 | 四川和诚过滤科技集团有限公司 | Extraction and production process of daily chemical soapberry raw material |
| CN116004333A (en) * | 2021-10-21 | 2023-04-25 | 中国科学院大连化学物理研究所 | Ultramicro protein powder, ultramicro protein composition, effervescent tablet, preparation method thereof and application thereof in cleaning pesticide residues of fruits and vegetables |
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| CN1291635A (en) * | 1999-10-06 | 2001-04-18 | 冼启福 | Detergent powder and its preparing process |
| CN102038793A (en) * | 2010-09-27 | 2011-05-04 | 南京泽朗医药科技有限公司 | Preparation method of soapberry saponin |
| CN102517177A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological eco-friendly multifunctional specific laundry detergent and preparation method thereof |
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| CN1291635A (en) * | 1999-10-06 | 2001-04-18 | 冼启福 | Detergent powder and its preparing process |
| CN102038793A (en) * | 2010-09-27 | 2011-05-04 | 南京泽朗医药科技有限公司 | Preparation method of soapberry saponin |
| CN102517177A (en) * | 2011-12-07 | 2012-06-27 | 广州青能健日用品有限公司 | Biological eco-friendly multifunctional specific laundry detergent and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104450299A (en) * | 2014-11-19 | 2015-03-25 | 苏州佑君环境科技有限公司 | Environment-friendly bacteriostatic detergent and preparation method thereof |
| CN113549499A (en) * | 2021-06-24 | 2021-10-26 | 苏潮辉 | Sapindus saponin laundry detergent and preparation method thereof |
| CN116004333A (en) * | 2021-10-21 | 2023-04-25 | 中国科学院大连化学物理研究所 | Ultramicro protein powder, ultramicro protein composition, effervescent tablet, preparation method thereof and application thereof in cleaning pesticide residues of fruits and vegetables |
| CN113943616A (en) * | 2021-11-25 | 2022-01-18 | 四川和诚过滤科技集团有限公司 | Extraction and production process of daily chemical soapberry raw material |
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| CN103468419B (en) | 2015-11-25 |
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