CN104086117B - A kind of waterborne multicolor true stone paint complex building exterior coating - Google Patents
A kind of waterborne multicolor true stone paint complex building exterior coating Download PDFInfo
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Abstract
The invention discloses a kind of waterborne multicolor true stone paint complex building exterior coating.The preparation method of existing a kind of environment-friendly type aqueous multicolor finish, it needs spraying, and number of channels is many just can reach reasonable effect, and work consuming is consuming time, and difficulty of construction is large.Waterborne multicolor true stone paint complex building exterior coating of the present invention comprises following component raw material and mass percent: true mineral varnish slurry 20-30%, colorful coloured silk point 35-45%, each color sand 30-35%.The present invention only needs the true mineral varnish compound multi-colour paint of twice, adds the self-cleaning finishing paint of twice nanometer resistant and just can complete construction, and form the ageing-resistant performance of existing true mineral varnish excellence, possesses again multicolor finish artificial granite stone effect true to nature simultaneously.
Description
Technical field
The present invention relates to technical field of coatings, especially a kind of waterborne multicolor true stone paint complex building exterior coating.
Background technology
Aqueous colorful stone-like coating along with development in recent years, by means of artificial granite stone effect true to nature, compare with stone material the outward appearance of building own requirement, construct simple and convenient, without the advantage such as dangerous that drops, use as building external paint and had widespread use.And the extensive water-soluble colorful coating construction technology used is mainly the true mineral varnish of twice (or twice emulsion paint) and twice multicolor finish now, then add twice finishing paint.Not only the labour intensity of construction worker is large, and cost of labor is high, the cracking that the matching difference also existing and exist between true mineral varnish (or emulsion paint) and multicolor finish causes or peeling.Water-water coating uses true mineral varnish bottoming, and one, a light face hair side, can produce the effect of light and shade inequality, make to incorporate entirety.And aqueous colorful stone-like coating just solves this kind of problem well, spraying consistence, light and shade consistence.Aqueous colorful stone-like coating has better incorporating property than single water-water coating, the unification more of idea and background colour, imitate verisimilitude more as.
Application number be 201210156035.5 Chinese invention patent provide a kind of preparation method of environment-friendly type aqueous multicolor finish: 1. granulating colloidal solution preparation; 2. color grain preparation, white basis paint, Color mode paint, the preparation of color grain; 3. finished product paint: the preparation of emulsion component C, lacquering obtains water-soluble colorful coating.Its preparation is simple, steady quality, superior performance, and cost is low, good weatherability, and naturalness is high, decoration and protectiveness good.But the method needs spraying, and number of channels is many just can reach reasonable effect, and work consuming is consuming time, and difficulty of construction is large.
Summary of the invention
For existing market main product (priming paint, middlely be coated with that color some paint separately makes, construction) in construction technology numerous and diverse, the weak point such as should not to operate, the object of this invention is to provide a kind of convenient construction, technique is simple, can one shaping waterborne multicolor true stone paint complex building exterior coating.
A kind of waterborne multicolor true stone paint complex building exterior coating, comprises following component raw material and mass percent:
True mineral varnish slurry 20-30%,
Colorful coloured silk point 35-45%,
Each color sand 30-35%,
The preparation process of the colorful complex building exterior coating of the true mineral varnish of described water-based is:
A: the true mineral varnish slurry of formula ratio is dropped in reactor, open 80-120 rev/min and drop into colorful coloured silk point grain, dispersion 1-3 minute, reaches even look grain;
B: add each color sand successively, note interpolation speed, control to add at 10-30 minute, prevent from becoming broken because of metal to-metal contact between colorful coloured silk point and each color sand, stir after adding and same rotating speed can be adopted to stir 2-8 minute, the obtained colorful complex building exterior coating of the true mineral varnish of water-based.
Described true mineral varnish slurry comprises following component raw material and mass percent:
Wherein said Mierocrystalline cellulose is nonionic cellulose; Described film coalescence aid is the one or more combination among ethylene glycol, propylene glycol monobutyl ether (BCS), Lauryl Alcohol ester, and the preparation process of true mineral varnish slurry is:
A: the soft water of formula ratio is added reactor, adds the Mierocrystalline cellulose of 30-50% formula ratio, disperses 3-5 minute with under rotating speed 700-900 rev/min;
B: continue to add remaining Mierocrystalline cellulose, disperse 3-5 minute under same rotational speed, Mierocrystalline cellulose adds film coalescence aid, propylene glycol, biocide mildewcide after breaing up completely successively, stirring velocity 700-900 rev/min of dispersion 2-5 minute, finally add organosilicon crylic acid latex, obtained true mineral varnish slurry.
Described colorful coloured silk point comprises following component raw material and mass percent:
Protecting glue aqueous solution 50-60%,
Assorted base paint 40-50%,
Assorted base paint is the base paint of the different colours color dot of allotment, and the preparation process of described colorful coloured silk point is:
A: first the described protecting glue aqueous solution is joined in reactor, use cutting type three leaf dispersion impellers to stir, control speed is under 100-200 rev/min, by web plate, assorted base paint is joined in reactor successively, stir 3-10 minute, reach required color dot size, obtained mixture;
B: then gained mixture is crossed screen cloth, reaches final required color dot size, soaks 10-24 hour, make color dot reach required hardness.
In described base paint, the weight percent of each component is as follows:
Wherein, the protecting glue aqueous solution of described response type protecting glue to be weight ratio be 6-10%, described Mierocrystalline cellulose is nonionic cellulose; Described defoamer adopts aqueous medium versatility mineral oil defoaming agent;
The preparation process of assorted base paint is:
A: poured into by soft water in reactor, controls rotating speed at 400-600 rev/min, adds Mierocrystalline cellulose, dispersion agent, defoamer stirring 3-5 minute;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, controls rotating speed and stir 20-30 minute under 1000-1200 rev/min;
C: by 100-200 order quartz sand, 200 order quartz sands and mildew-resistant algaecide, flexible silicon acrylic emulsion drop into reactor, control rotating speed and stir 3-5 minute under 700-900 rev/min;
D: under 700-900 rev/min of rotating speed, adds response type protecting glue, wetting agent to reactor, stirs 5-10 minute, obtained base paint;
E: according to the color of marble grouan, adds required aqueous color paste in above-mentioned base paint, is deployed into required color, makes assorted base paint.
The described protecting glue aqueous solution comprises the following raw material being calculated in mass percent calculation:
Wherein, sequestrant is the chelated dispersants TF-510 that Zhejiang Province Chuanhua Co., Ltd produces;
The preparation process of the described protecting glue aqueous solution is:
A: soft water is dropped into reactor, controls rotating speed at 400-600 rev/min, drops into sequestrant dispersion 3-5 minute;
B: drop into trisodium phosphate to reactor, stir 3-5 minute under same rotational speed;
C: drop into protection rubber powder to reactor, stir 20-30 minute under same rotational speed; According to the addition of the soft or hard extent control protection rubber powder of color dot, addition is more, and the hardness of look grain is harder.
The beneficial effect that the present invention has:
The present invention is relative to prior art, the construction of this product only needs the true mineral varnish compound multi-colour paint of twice, add the self-cleaning finishing paint of twice nanometer resistant and just can complete construction, and form the ageing-resistant performance of existing true mineral varnish excellence, possesses again multicolor finish artificial granite stone effect true to nature simultaneously, add nanometer finishing paint stain resistant, self-cleaning function, be conducive to reducing labour intensity, reducing trimming cost.
Embodiment
In order to understand summary of the invention of the present invention, Characteristic further, following case study on implementation of illustrating, and be described in detail as follows:
Embodiment 1
The colorful complex building exterior coating of a kind of true mineral varnish of water-based, the weight percent between composition of raw materials true mineral varnish slurry, colorful color point, each color sand is: 20: 45: 35.
The preparation process of the colorful complex building exterior coating of the true mineral varnish of described water-based is:
A: true mineral varnish slurry is dropped in reactor, opens 100 revs/min and drops into colorful color point, disperse 1 minute, reach even look grain;
B: add each color sand successively, notices that adding procedure speed slowly, will prevent from becoming broken because of metal to-metal contact between colorful coloured silk point with the color sand of high density, stir and can stir 3 minutes by same rotating speed, the obtained colorful complex building exterior coating of the true mineral varnish of water-based after adding;
Component and the weight percent of true mineral varnish slurry are as follows: soft water 35.4, Mierocrystalline cellulose (HBR250) 0.4, film coalescence aid propylene glycol monobutyl ether (BCS) 2, film coalescence aid (TEXANOL) 2, biocide mildewcide (WL-3) 0.2, organosilicon crylic acid latex (RS-991) 60.Its preparation process is:
A: soft water is added reactor, adds the Mierocrystalline cellulose of 30% formula ratio, disperses 5 minutes under rotating speed 800 revs/min;
B: continue to add remaining Mierocrystalline cellulose, disperse 5 minutes under same rotational speed, Mierocrystalline cellulose adds film coalescence aid BCS, film coalescence aid TEXANOL, propylene glycol, biocide mildewcide successively after opening completely, stirring velocity 800 revs/min dispersion 5 minutes, finally add organosilicon crylic acid latex, obtained true mineral varnish slurry.
The weight percent of base paint is as follows: soft water 35, Mierocrystalline cellulose (HBR250) 1, dispersion agent (1124) 0.5; defoamer (NXZ) 0.3; titanium dioxide (R996) 1, calcined kaolin (4000 order kaolin) 15, pH adjusting agent (AMP95) 0.3; 100-200 order quartz sand 10; 200 order quartz sands 10, mildew-resistant algaecide 0.4, flexible silicon acrylic emulsion 31.2; response type protecting glue 15, wetting agent 0.3.
The preparation process of assorted base paint is:
A: poured into by soft water in reactor, controls rotating speed at 400 revs/min, adds Mierocrystalline cellulose, dispersion agent, defoamer stir 5 minutes;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, controls rotating speed and stirs 30 minutes under 1200 revs/min;
C: 100-200 order quartz sand and 200 order quartz sands, mildew-resistant algaecide, flexible silicon acrylic emulsion are dropped into reactor, controls rotating speed and stir 3 minutes at 700 revolutions per minute;
D: under 700 revs/min of rotating speeds, adds the 9% protecting glue aqueous solution, wetting agent to reactor, stirs 5 minutes, obtained base paint;
E: according to the color of marble grouan, adds required aqueous color paste in above-mentioned base paint, is deployed into required color, makes assorted base paint.
Protecting glue aqueous solution weight percent: soft water 90.4, sequestrant 0.3, trisodium phosphate 0.3, protection rubber powder 9.
A: soft water is dropped into reactor, controls rotating speed at 600 revs/min, drops into sequestrant and disperses 3 minutes;
B: drop into trisodium phosphate to reactor, stir 3 minutes under same rotational speed;
C: drop into protection rubber powder to reactor, stir 30 minutes under same rotational speed; According to the addition of the soft or hard extent control protection rubber powder of color dot, addition is more, and the hardness of look grain is harder.
Colorful coloured silk point comprises calculates following raw material by weight percentage:
The protecting glue aqueous solution 50,
Assorted base paint 50,
Assorted base paint is the base paint of the different colours color dot of allotment.
The preparation process of described colorful coloured silk point is:
A: first the described protecting glue aqueous solution is joined in reactor, use cutting type three leaf dispersion impellers to stir, control speed is under 100 revs/min, by web plate, assorted base paint is joined in reactor successively, stir 3 minutes, reach required color dot size, obtained mixture;
B: then gained mixture is crossed screen cloth, reaches final required color dot size, soaks 10 hours, make color dot reach required hardness.
The Performance Detection of the true mineral varnish of water-based of the present invention colorful complex building exterior coating is as follows:
Embodiment 2
The colorful complex building exterior coating of a kind of true mineral varnish of water-based, the weight percent between composition of raw materials true mineral varnish slurry, colorful color point, each color sand is: 30: 35: 35.
The preparation process of the true mineral varnish of water-based colorful complex building exterior coating is as follows:
A: true mineral varnish slurry is dropped in reactor, opens 100 revs/min and drops into colorful coloured silk point grain, disperse 1 minute, reach even look grain;
B: add each color sand successively, notices that adding procedure speed wants slow, stirs and can stir 2 minutes by same rotating speed after adding, the obtained colorful complex building exterior coating of the true mineral varnish of water-based.
Component and the weight percent of true mineral varnish slurry are as follows: soft water 45, Mierocrystalline cellulose (HBR250) 0.4, film coalescence aid propylene glycol monobutyl ether (BCS) 2, film coalescence aid (TEXANOL) 2, biocide mildewcide (WL-3) 0.2, organosilicon crylic acid latex (RS-991) 50.4.
A: soft water is added reactor, adds the Mierocrystalline cellulose of 50% formula ratio, disperses 3 minutes under rotating speed 800 revs/min;
B: continue to add remaining Mierocrystalline cellulose, disperse 3 minutes under same rotational speed, Mierocrystalline cellulose adds BCS, film coalescence aid, propylene glycol, biocide mildewcide after opening completely successively, stirring velocity 800 revs/min dispersion 2 minutes, finally add organosilicon crylic acid latex, obtained true mineral varnish slurry.
The weight percent of base paint component is as follows: soft water 35; Mierocrystalline cellulose (HBR250) 1; dispersion agent (1124) 0.5, defoamer (NXZ) 0.3, titanium dioxide (R996) 1; calcined kaolin (4000 order kaolin) 15; pH adjusting agent (AMP95) 0.3, mildew-resistant algaecide 0.4, flexible silicon acrylic emulsion 31.2; response type protecting glue 15, wetting agent 0.3.
The preparation process of assorted base paint is:
A: poured into by soft water in reactor, controls rotating speed at 600 revs/min, adds Mierocrystalline cellulose, dispersion agent, defoamer stir 3 minutes;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, controls rotating speed and stirs 20 minutes under 1000-1200 rev/min;
C: again 100-200 order quartz sand, 200 order quartz sands, mildew-resistant algaecide, flexible silicon acrylic emulsion are dropped into reactor, controls rotating speed and stirs 3 minutes under 900 revs/min;
D: under 900 revs/min of rotating speeds, adds the 7% protecting glue aqueous solution, wetting agent to reactor, stirs 10 minutes, obtained base paint;
E: according to the color of marble grouan, adds required aqueous color paste in above-mentioned base paint, is deployed into required color, makes assorted base paint.
Protecting glue aqueous solution weight percent: soft water 92.4, sequestrant 0.3, trisodium phosphate 0.3, protection rubber powder 7.
Colorful coloured silk point comprises calculates following raw material by weight percentage:
The protecting glue aqueous solution 60,
Assorted base paint 40,
The preparation process of described colorful coloured silk point is:
A: first the described protecting glue aqueous solution is joined in reactor, use cutting type three leaf dispersion impellers to stir, control speed is under 200 revs/min, by web plate, assorted base paint is joined in reactor successively, stir 10 minutes, reach required color dot size, obtained mixture;
B: then gained mixture is crossed screen cloth, reaches final required color dot size, soaks 24 hours, make color dot reach required hardness.
The Performance Detection of the true mineral varnish of water-based of the present invention colorful complex building exterior coating is as follows:
The above, be only the present invention's true mineral varnish construction embodiment, be not used for limiting scope of the invention process.Doing so all according to the present invention's shape, structure, feature and spirit made a formal request described in scope is all equivalent variations or modification, all should be included in of the present invention making a formal request within the scope of the claims.
Claims (5)
1. a waterborne multicolor true stone paint complex building exterior coating, is characterized in that, comprises following component raw material and mass percent:
True mineral varnish slurry 20-30%,
Colorful coloured silk point 35-45%,
Each color sand 30-35%,
The preparation process of described waterborne multicolor true stone paint complex building exterior coating is:
A: the true mineral varnish slurry of formula ratio is dropped in reactor, opens 80-120 rev/min and drops into colorful color point, and dispersion 1-3 minute, reaches even look grain;
B: add each color sand successively, note interpolation speed, control to add at 10-30 minute, prevent from becoming broken because of metal to-metal contact between colorful coloured silk point and each color sand, stir after adding and namely adopt same rotating speed to stir 2-8 minute, the obtained colorful complex building exterior coating of the true mineral varnish of water-based;
Described true mineral varnish slurry comprises following component raw material and mass percent:
Soft water 35-45%,
Mierocrystalline cellulose 0.2-0.6%,
Film coalescence aid 2-4%,
Propylene glycol 1-2%,
Biocide mildewcide 0.2-0.5%,
Organosilicon crylic acid latex 50-60%;
Described colorful coloured silk point comprises following component raw material and mass percent:
Protecting glue aqueous solution 50-60%,
Assorted base paint 40-50%,
Assorted base paint is the base paint of the different colours color dot of allotment;
In base paint, the mass percent of each component is as follows:
Soft water 30-35%,
Mierocrystalline cellulose 0.7-1%,
Dispersion agent 0.5-0.8%,
Defoamer 0.2-1%,
Titanium dioxide 0-1%,
Calcined kaolin 10-15%,
PH adjusting agent 0.1-0.3%,
100-200 order quartz sand 10-15%,
200 order quartz sand 10-15%,
Mildew-resistant algaecide 0.2-0.4%,
Flexible silicon acrylic emulsion 25-35%,
Response type protecting glue 10-15%,
Wetting agent 0.1-0.3%,
Each constituent mass percentage ratio sum of above-mentioned base paint is 100%,
Wherein, the protecting glue aqueous solution of described response type protecting glue to be weight ratio be 6-10%; Described Mierocrystalline cellulose is nonionic cellulose; Described defoamer adopts aqueous medium versatility mineral oil defoaming agent;
The described protecting glue aqueous solution comprises the following raw material being calculated in mass percent calculation:
Soft water 89-94%,
Sequestrant 0.1-0.3%,
Trisodium phosphate 0.1-0.4%,
Protection rubber powder 6-10%;
Each constituent mass percentage ratio sum of the above-mentioned protecting glue aqueous solution is 100%.
2. waterborne multicolor true stone paint complex building exterior coating according to claim 1, is characterized in that, described Mierocrystalline cellulose is nonionic cellulose; Described film coalescence aid is the one or more combination among ethylene glycol, propylene glycol monobutyl ether, Lauryl Alcohol ester;
The preparation process of described true mineral varnish slurry is:
A: the soft water of formula ratio is added reactor, adds the Mierocrystalline cellulose of 30-50% formula ratio, under rotating speed 700-900 rev/min, disperse 3-5 minute;
B: continue to add remaining Mierocrystalline cellulose, disperse 3-5 minute under same rotational speed, Mierocrystalline cellulose adds film coalescence aid, propylene glycol, biocide mildewcide after breaing up completely successively, stirring velocity 700-900 rev/min of dispersion 2-5 minute, finally add organosilicon crylic acid latex, obtained true mineral varnish slurry.
3. waterborne multicolor true stone paint complex building exterior coating according to claim 1, is characterized in that, the preparation process of described colorful coloured silk point is:
A: first the described protecting glue aqueous solution is joined in reactor, use cutting type three leaf dispersion impellers to stir, control speed is under 100-200 rev/min, by web plate, assorted base paint is joined in reactor successively, stir 3-10 minute, reach required color dot size, obtained mixture;
B: then gained mixture is crossed screen cloth, reaches final required color dot size, soaks 10-24 hour, make color dot reach required hardness.
4. waterborne multicolor true stone paint complex building exterior coating according to claim 3, is characterized in that, the preparation process of assorted base paint is:
A: poured into by soft water in reactor, controls rotating speed at 400-600 rev/min, adds Mierocrystalline cellulose, dispersion agent, defoamer stirring 3-5 minute;
B: titanium dioxide, calcined kaolin, pH adjusting agent are dropped into reactor successively, controls rotating speed and stir 20-30 minute under 1000-1200 rev/min;
C: 100-200 order quartz sand and 200 order quartz sands and mildew-resistant algaecide, flexible silicon acrylic emulsion are dropped into reactor, controls rotating speed and stir 3-5 minute under 700-900 rev/min;
D: under 700-900 rev/min of rotating speed, adds response type protecting glue, wetting agent to reactor, stirs 5-10 minute, obtained base paint;
E: according to the color of marble grouan, adds required aqueous color paste in above-mentioned base paint, is deployed into required color, makes assorted base paint.
5. waterborne multicolor true stone paint complex building exterior coating according to claim 4, is characterized in that: the preparation process of the described protecting glue aqueous solution is:
A: soft water is dropped into reactor, controls rotating speed at 400-600 rev/min, drops into sequestrant dispersion 3-5 minute;
B: drop into trisodium phosphate to reactor, stir 3-5 minute under same rotational speed;
C: drop into protection rubber powder to reactor, stir 20-30 minute under same rotational speed, according to the addition of the soft or hard extent control protection rubber powder of color dot, addition is more, and the hardness of color dot is harder.
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| CN104910737A (en) * | 2015-06-23 | 2015-09-16 | 陈良伢 | Water-based composite multicolor natural stone external wall paint |
| CN106699007B (en) * | 2017-01-05 | 2019-01-29 | 辽宁意邦新型材料科技集团有限公司 | A kind of preparation method and lacquer obtained by this method of lacquer |
| CN107236459A (en) * | 2017-06-05 | 2017-10-10 | 山东华德隆建材科技有限公司 | Colorful former stone stone-like coating |
| CN109988472A (en) * | 2019-03-04 | 2019-07-09 | 江西赛宝莉实业有限公司 | A kind of hilllock mineral varnish of 5D and preparation method thereof |
| CN109988474A (en) * | 2019-04-03 | 2019-07-09 | 福建菲特普环保科技有限公司 | A kind of early stage excellent water resistance water burnt-in sand multicolor finish |
| CN111807759A (en) * | 2019-04-10 | 2020-10-23 | 广东顺德派齐新材料有限公司 | Novel sand-containing multicolor paint and preparation method thereof |
| CN110756100B (en) * | 2019-11-07 | 2022-07-22 | 河南七彩异涂新材料科技有限公司 | Real stone paint coating preparation system, preparation process and components thereof |
| CN111410885A (en) * | 2020-05-12 | 2020-07-14 | 安徽绿梦佳涂料有限公司 | Water-based colorful real stone paint |
| CN115926559A (en) * | 2022-11-10 | 2023-04-07 | 浙江添艺新材料有限公司 | Anti-aging batch-scraping type colorful stone-like paint and preparation method thereof |
| CN116239902A (en) * | 2022-12-30 | 2023-06-09 | 成都富思特新材料有限公司 | High-coverage stone-like paint and preparation method thereof |
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| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN102634257A (en) * | 2012-05-18 | 2012-08-15 | 天津市荣新建筑装饰涂料有限公司 | Environment-friendly aqueous multicolor paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617071A (en) * | 2012-03-23 | 2012-08-01 | 尚怀兴 | High-gloss real stone lacquer and marble simulation lacquer |
| CN102634257A (en) * | 2012-05-18 | 2012-08-15 | 天津市荣新建筑装饰涂料有限公司 | Environment-friendly aqueous multicolor paint and preparation method thereof |
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