CN103276217A - 一种含金银多金属物料的综合回收工艺 - Google Patents
一种含金银多金属物料的综合回收工艺 Download PDFInfo
- Publication number
- CN103276217A CN103276217A CN2013102448732A CN201310244873A CN103276217A CN 103276217 A CN103276217 A CN 103276217A CN 2013102448732 A CN2013102448732 A CN 2013102448732A CN 201310244873 A CN201310244873 A CN 201310244873A CN 103276217 A CN103276217 A CN 103276217A
- Authority
- CN
- China
- Prior art keywords
- silver
- gold
- slag
- bismuth
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 96
- 239000004332 silver Substances 0.000 title claims abstract description 96
- 239000010931 gold Substances 0.000 title claims abstract description 82
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 81
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 81
- 239000000463 material Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 26
- 230000008569 process Effects 0.000 title claims abstract description 23
- 238000004064 recycling Methods 0.000 title claims abstract description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 57
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 54
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000010949 copper Substances 0.000 claims abstract description 46
- 229910052802 copper Inorganic materials 0.000 claims abstract description 45
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 44
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 37
- 229910052718 tin Inorganic materials 0.000 claims abstract description 37
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000002386 leaching Methods 0.000 claims abstract description 22
- 239000011133 lead Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 21
- 238000011084 recovery Methods 0.000 claims abstract description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 15
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000000498 ball milling Methods 0.000 claims abstract description 9
- 238000005660 chlorination reaction Methods 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 90
- 239000007788 liquid Substances 0.000 claims description 88
- 239000002893 slag Substances 0.000 claims description 63
- 238000007654 immersion Methods 0.000 claims description 45
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 44
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 30
- 238000001914 filtration Methods 0.000 claims description 27
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 19
- 238000002791 soaking Methods 0.000 claims description 19
- 229910052742 iron Inorganic materials 0.000 claims description 15
- 238000003723 Smelting Methods 0.000 claims description 13
- 229910052787 antimony Inorganic materials 0.000 claims description 12
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 12
- AHUBLGVDRKDHAT-UHFFFAOYSA-N [Bi]=O.[Cl] Chemical compound [Bi]=O.[Cl] AHUBLGVDRKDHAT-UHFFFAOYSA-N 0.000 claims description 11
- 235000017550 sodium carbonate Nutrition 0.000 claims description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 11
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 10
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 10
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 10
- 239000007787 solid Substances 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 8
- 238000004065 wastewater treatment Methods 0.000 claims description 8
- FQEZLJDDYYNLPP-UHFFFAOYSA-N carbonic acid;tin Chemical compound [Sn].OC(O)=O FQEZLJDDYYNLPP-UHFFFAOYSA-N 0.000 claims description 6
- 238000007670 refining Methods 0.000 claims description 6
- 239000002351 wastewater Substances 0.000 claims description 6
- 235000002505 Centaurea nigra Nutrition 0.000 claims description 5
- 241001073742 Mylopharodon conocephalus Species 0.000 claims description 5
- 229910001245 Sb alloy Inorganic materials 0.000 claims description 5
- 239000002140 antimony alloy Substances 0.000 claims description 5
- 238000006073 displacement reaction Methods 0.000 claims description 4
- 238000005868 electrolysis reaction Methods 0.000 claims description 4
- 229910000978 Pb alloy Inorganic materials 0.000 claims description 3
- YGZCHNRGFZQAKR-UHFFFAOYSA-N [Sn].S(O)(O)=O Chemical compound [Sn].S(O)(O)=O YGZCHNRGFZQAKR-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 claims description 3
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 230000009467 reduction Effects 0.000 claims description 3
- 150000003378 silver Chemical class 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 4
- 229910021607 Silver chloride Inorganic materials 0.000 abstract description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 abstract description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052946 acanthite Inorganic materials 0.000 abstract description 2
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 abstract description 2
- 229940056910 silver sulfide Drugs 0.000 abstract description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 abstract 4
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 abstract 2
- 229910001923 silver oxide Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- QAAXRTPGRLVPFH-UHFFFAOYSA-N [Bi].[Cu] Chemical compound [Bi].[Cu] QAAXRTPGRLVPFH-UHFFFAOYSA-N 0.000 description 6
- ZWFRZGJUJSOHGL-UHFFFAOYSA-N [Bi].[Cu].[Sn] Chemical compound [Bi].[Cu].[Sn] ZWFRZGJUJSOHGL-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000006356 dehydrogenation reaction Methods 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- OGFYIDCVDSATDC-UHFFFAOYSA-N silver silver Chemical compound [Ag].[Ag] OGFYIDCVDSATDC-UHFFFAOYSA-N 0.000 description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 3
- 229910001948 sodium oxide Inorganic materials 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 241000271566 Aves Species 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- WIKSRXFQIZQFEH-UHFFFAOYSA-N [Cu].[Pb] Chemical compound [Cu].[Pb] WIKSRXFQIZQFEH-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KXZJHVJKXJLBKO-UHFFFAOYSA-N chembl1408157 Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=C(O)C=C1 KXZJHVJKXJLBKO-UHFFFAOYSA-N 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 208000029039 cyanide poisoning Diseases 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910001447 ferric ion Inorganic materials 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229910000108 silver(I,III) oxide Inorganic materials 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- -1 thiourea peroxide Chemical class 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
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CN201310244873.2A CN103276217B (zh) | 2013-06-20 | 2013-06-20 | 一种含金银多金属物料的综合回收工艺 |
Publications (2)
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CN103276217A true CN103276217A (zh) | 2013-09-04 |
CN103276217B CN103276217B (zh) | 2014-07-16 |
Family
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103773967A (zh) * | 2014-02-12 | 2014-05-07 | 湘潭大学 | 从钢铁厂烧结灰中回收银、铜和锌的方法 |
CN104611568A (zh) * | 2014-11-18 | 2015-05-13 | 贵州宏达环保科技有限公司 | 一种从硫酸铅渣中提取金属铅、银、锌、铟和锗的方法 |
CN104762479A (zh) * | 2015-04-01 | 2015-07-08 | 郴州雄风环保科技有限公司 | 从含金废料中综合回收金银铂钯稀贵金属的工艺 |
CN104789790A (zh) * | 2015-04-08 | 2015-07-22 | 吉林吉恩镍业股份有限公司 | 尼尔森重选含铅金精矿无铅化冶炼工艺 |
CN104911366A (zh) * | 2015-05-11 | 2015-09-16 | 湖南众兴环保科技有限公司 | 一种用王水回收银铋渣中有价金属的方法 |
CN105039694A (zh) * | 2015-06-24 | 2015-11-11 | 山东国大黄金股份有限公司 | 一种降低锌粉置换结晶物提高贵液处理量的方法 |
CN105032622A (zh) * | 2015-09-04 | 2015-11-11 | 长春黄金研究院 | 一种选矿药剂的两段合成方法 |
CN106967884A (zh) * | 2017-03-20 | 2017-07-21 | 北矿力澜科技咨询(北京)有限公司 | 一种铜阳极泥分银渣分步提取的方法 |
CN108239706A (zh) * | 2017-12-04 | 2018-07-03 | 江苏大学 | 一种铝合金氰化镀银中无效损耗银的环保高效回收方法 |
CN108480647A (zh) * | 2018-01-23 | 2018-09-04 | 珠海纳金科技有限公司 | 一种纳米银颗粒废液的回收利用方法 |
CN109678199A (zh) * | 2019-01-03 | 2019-04-26 | 江西铜业技术研究院有限公司 | 一种以分银渣为原料生产二氧化锡的工艺 |
CN110331296A (zh) * | 2019-08-13 | 2019-10-15 | 长春黄金研究院有限公司 | 一种分离金泥中杂质金属的工艺方法 |
CN111504924A (zh) * | 2020-04-23 | 2020-08-07 | 中国原子能科学研究院 | 一种铅铋合金中铅与铋的去除方法及其镉的测量方法 |
CN112391531A (zh) * | 2020-10-30 | 2021-02-23 | 中南大学 | 一种微波热解废电路板回收有价金属的方法 |
CN112813272A (zh) * | 2020-12-31 | 2021-05-18 | 斯瑞尔环境科技股份有限公司 | 一种废合金刀头中金属锡的回收方法 |
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US4094668A (en) * | 1977-05-19 | 1978-06-13 | Newmont Exploration Limited | Treatment of copper refinery slimes |
CN102363839A (zh) * | 2011-11-21 | 2012-02-29 | 郴州雄风稀贵金属材料股份有限公司 | 从含银烟灰的综合回收银、铅和铋的工艺 |
CN102399989A (zh) * | 2011-11-25 | 2012-04-04 | 昆明理工大学 | 一种从锡电解阳极泥中使锡与锑、铋、砷、铜分离的方法 |
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2013
- 2013-06-20 CN CN201310244873.2A patent/CN103276217B/zh active Active
Patent Citations (3)
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US4094668A (en) * | 1977-05-19 | 1978-06-13 | Newmont Exploration Limited | Treatment of copper refinery slimes |
CN102363839A (zh) * | 2011-11-21 | 2012-02-29 | 郴州雄风稀贵金属材料股份有限公司 | 从含银烟灰的综合回收银、铅和铋的工艺 |
CN102399989A (zh) * | 2011-11-25 | 2012-04-04 | 昆明理工大学 | 一种从锡电解阳极泥中使锡与锑、铋、砷、铜分离的方法 |
Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103773967B (zh) * | 2014-02-12 | 2015-08-19 | 湘潭大学 | 从钢铁厂烧结灰中回收银、铜和锌的方法 |
CN103773967A (zh) * | 2014-02-12 | 2014-05-07 | 湘潭大学 | 从钢铁厂烧结灰中回收银、铜和锌的方法 |
CN104611568B (zh) * | 2014-11-18 | 2016-09-28 | 贵州宏达环保科技有限公司 | 一种从硫酸铅渣中提取金属铅、银、锌、铟和锗的方法 |
CN104611568A (zh) * | 2014-11-18 | 2015-05-13 | 贵州宏达环保科技有限公司 | 一种从硫酸铅渣中提取金属铅、银、锌、铟和锗的方法 |
CN104762479A (zh) * | 2015-04-01 | 2015-07-08 | 郴州雄风环保科技有限公司 | 从含金废料中综合回收金银铂钯稀贵金属的工艺 |
CN104789790A (zh) * | 2015-04-08 | 2015-07-22 | 吉林吉恩镍业股份有限公司 | 尼尔森重选含铅金精矿无铅化冶炼工艺 |
CN104911366A (zh) * | 2015-05-11 | 2015-09-16 | 湖南众兴环保科技有限公司 | 一种用王水回收银铋渣中有价金属的方法 |
CN105039694B (zh) * | 2015-06-24 | 2017-09-19 | 山东国大黄金股份有限公司 | 一种降低锌粉置换结晶物提高贵液处理量的方法 |
CN105039694A (zh) * | 2015-06-24 | 2015-11-11 | 山东国大黄金股份有限公司 | 一种降低锌粉置换结晶物提高贵液处理量的方法 |
CN105032622A (zh) * | 2015-09-04 | 2015-11-11 | 长春黄金研究院 | 一种选矿药剂的两段合成方法 |
CN106967884B (zh) * | 2017-03-20 | 2019-05-21 | 北矿力澜科技咨询(北京)有限公司 | 一种铜阳极泥分银渣分步提取的方法 |
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