CN102949802A - 一种含有有机酸类化合物的灭火组合物 - Google Patents
一种含有有机酸类化合物的灭火组合物 Download PDFInfo
- Publication number
- CN102949802A CN102949802A CN2011102351013A CN201110235101A CN102949802A CN 102949802 A CN102949802 A CN 102949802A CN 2011102351013 A CN2011102351013 A CN 2011102351013A CN 201110235101 A CN201110235101 A CN 201110235101A CN 102949802 A CN102949802 A CN 102949802A
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- Prior art keywords
- acid
- fire
- extinguishing
- organic acid
- acid compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 Organic acid compound Chemical class 0.000 title claims abstract description 40
- 239000000203 mixture Substances 0.000 title claims abstract description 10
- 239000002131 composite material Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 28
- 239000003063 flame retardant Substances 0.000 claims description 25
- 239000002253 acid Substances 0.000 claims description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 12
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 9
- 239000003814 drug Substances 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 claims description 6
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 6
- ICAIHSUWWZJGHD-UHFFFAOYSA-N dotriacontanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O ICAIHSUWWZJGHD-UHFFFAOYSA-N 0.000 claims description 6
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 6
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 claims description 6
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims description 6
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 claims description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 6
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 claims description 6
- 238000000354 decomposition reaction Methods 0.000 claims description 5
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- GEHPRJRWZDWFBJ-FOCLMDBBSA-N (2E)-2-heptadecenoic acid Chemical compound CCCCCCCCCCCCCC\C=C\C(O)=O GEHPRJRWZDWFBJ-FOCLMDBBSA-N 0.000 claims description 3
- ZVRMGCSSSYZGSM-CCEZHUSRSA-N (E)-hexadec-2-enoic acid Chemical compound CCCCCCCCCCCCC\C=C\C(O)=O ZVRMGCSSSYZGSM-CCEZHUSRSA-N 0.000 claims description 3
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims description 3
- OXEDXHIBHVMDST-UHFFFAOYSA-N 12Z-octadecenoic acid Natural products CCCCCC=CCCCCCCCCCCC(O)=O OXEDXHIBHVMDST-UHFFFAOYSA-N 0.000 claims description 3
- LODHFNUFVRVKTH-ZHACJKMWSA-N 2-hydroxy-n'-[(e)-3-phenylprop-2-enoyl]benzohydrazide Chemical compound OC1=CC=CC=C1C(=O)NNC(=O)\C=C\C1=CC=CC=C1 LODHFNUFVRVKTH-ZHACJKMWSA-N 0.000 claims description 3
- KBIWNQVZKHSHTI-UHFFFAOYSA-N 4-n,4-n-dimethylbenzene-1,4-diamine;oxalic acid Chemical compound OC(=O)C(O)=O.CN(C)C1=CC=C(N)C=C1 KBIWNQVZKHSHTI-UHFFFAOYSA-N 0.000 claims description 3
- 235000021357 Behenic acid Nutrition 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 3
- WSWCOQWTEOXDQX-MQQKCMAXSA-N E-Sorbic acid Chemical compound C\C=C\C=C\C(O)=O WSWCOQWTEOXDQX-MQQKCMAXSA-N 0.000 claims description 3
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Natural products OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Natural products OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 3
- 229920001800 Shellac Polymers 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- WESRWUYQBCSUCT-UHFFFAOYSA-N acetic acid;2-methylguanidine Chemical compound CC(O)=O.CNC(N)=N WESRWUYQBCSUCT-UHFFFAOYSA-N 0.000 claims description 3
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims description 3
- 229940116226 behenic acid Drugs 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 229930016911 cinnamic acid Natural products 0.000 claims description 3
- 235000013985 cinnamic acid Nutrition 0.000 claims description 3
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 3
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- XMHIUKTWLZUKEX-UHFFFAOYSA-N hexacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O XMHIUKTWLZUKEX-UHFFFAOYSA-N 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- 239000004208 shellac Substances 0.000 claims description 3
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 3
- 229940113147 shellac Drugs 0.000 claims description 3
- 235000013874 shellac Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims 1
- 150000001649 bromium compounds Chemical group 0.000 claims 1
- 150000003891 oxalate salts Chemical class 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 150000003254 radicals Chemical class 0.000 abstract description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 230000005764 inhibitory process Effects 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 230000000704 physical effect Effects 0.000 abstract description 3
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 238000004904 shortening Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 229920000877 Melamine resin Polymers 0.000 description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 229920004449 Halon® Polymers 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 4
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 description 4
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 4
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 4
- 235000019837 monoammonium phosphate Nutrition 0.000 description 4
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- CHLNHIVUNRZION-UHFFFAOYSA-N (2,3-dibromophenyl) dihydrogen phosphate Chemical compound OP(O)(=O)OC1=CC=CC(Br)=C1Br CHLNHIVUNRZION-UHFFFAOYSA-N 0.000 description 2
- LPKCJFLRJWWIDI-UHFFFAOYSA-N (diaminomethylideneamino)phosphonic acid Chemical compound NC(N)=NP(O)(O)=O LPKCJFLRJWWIDI-UHFFFAOYSA-N 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 239000004277 Ferrous carbonate Substances 0.000 description 2
- KYPYTERUKNKOLP-UHFFFAOYSA-N Tetrachlorobisphenol A Chemical compound C=1C(Cl)=C(O)C(Cl)=CC=1C(C)(C)C1=CC(Cl)=C(O)C(Cl)=C1 KYPYTERUKNKOLP-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- VBIXEXWLHSRNKB-UHFFFAOYSA-N ammonium oxalate Chemical compound [NH4+].[NH4+].[O-]C(=O)C([O-])=O VBIXEXWLHSRNKB-UHFFFAOYSA-N 0.000 description 2
- DWSWCPPGLRSPIT-UHFFFAOYSA-N benzo[c][2,1]benzoxaphosphinin-6-ium 6-oxide Chemical compound C1=CC=C2[P+](=O)OC3=CC=CC=C3C2=C1 DWSWCPPGLRSPIT-UHFFFAOYSA-N 0.000 description 2
- STIAPHVBRDNOAJ-UHFFFAOYSA-N carbamimidoylazanium;carbonate Chemical compound NC(N)=N.NC(N)=N.OC(O)=O STIAPHVBRDNOAJ-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229940116318 copper carbonate Drugs 0.000 description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 2
- QYCVHILLJSYYBD-UHFFFAOYSA-L copper;oxalate Chemical compound [Cu+2].[O-]C(=O)C([O-])=O QYCVHILLJSYYBD-UHFFFAOYSA-L 0.000 description 2
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 2
- 235000019838 diammonium phosphate Nutrition 0.000 description 2
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 description 2
- CEYULKASIQJZGP-UHFFFAOYSA-L disodium;2-(carboxymethyl)-2-hydroxybutanedioate Chemical compound [Na+].[Na+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O CEYULKASIQJZGP-UHFFFAOYSA-L 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229960002413 ferric citrate Drugs 0.000 description 2
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 2
- RAQDACVRFCEPDA-UHFFFAOYSA-L ferrous carbonate Chemical compound [Fe+2].[O-]C([O-])=O RAQDACVRFCEPDA-UHFFFAOYSA-L 0.000 description 2
- 235000019268 ferrous carbonate Nutrition 0.000 description 2
- 229960004652 ferrous carbonate Drugs 0.000 description 2
- 229910000015 iron(II) carbonate Inorganic materials 0.000 description 2
- NPFOYSMITVOQOS-UHFFFAOYSA-K iron(III) citrate Chemical compound [Fe+3].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NPFOYSMITVOQOS-UHFFFAOYSA-K 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 229960001708 magnesium carbonate Drugs 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- UHNWOJJPXCYKCG-UHFFFAOYSA-L magnesium oxalate Chemical compound [Mg+2].[O-]C(=O)C([O-])=O UHNWOJJPXCYKCG-UHFFFAOYSA-L 0.000 description 2
- 239000011656 manganese carbonate Substances 0.000 description 2
- 229940093474 manganese carbonate Drugs 0.000 description 2
- 235000006748 manganese carbonate Nutrition 0.000 description 2
- RGVLTEMOWXGQOS-UHFFFAOYSA-L manganese(2+);oxalate Chemical compound [Mn+2].[O-]C(=O)C([O-])=O RGVLTEMOWXGQOS-UHFFFAOYSA-L 0.000 description 2
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 2
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 239000001508 potassium citrate Substances 0.000 description 2
- 229960002635 potassium citrate Drugs 0.000 description 2
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 2
- 235000011082 potassium citrates Nutrition 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 2
- 229940039790 sodium oxalate Drugs 0.000 description 2
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 239000004964 aerogel Substances 0.000 description 1
- 239000013000 chemical inhibitor Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
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- A—HUMAN NECESSITIES
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Abstract
本发明涉及一种含有有机酸类化合物的灭火组合物，该灭火组合物含有有机酸类化合物；其中有机酸类化合物的含量为50(质量)％以上，优选为70(质量)％～90(质量)％；本发明的有机酸类化合物在高温下可吸热分解，释放出灭火物质，该灭火物质可通过自由基与链式燃烧反应所必需的O·、OH·、H·自由基中的一种或几种进行反应，从而切断了链式燃烧反应，也可通过物理作用减少氧气分压而抑制火焰，或同时发生物理及化学抑制作用共同实现灭火效果，与此同时，其与烟火药剂产生协同增效作用，进一步提高了灭火剂的灭火效能，大大缩短了有效灭火时间。
Description
技术领域
本发明属于气溶胶灭火技术领域，特别是涉及一种受热可分解产生灭火物质的灭火组合物。
背景技术
自从1987年加拿大蒙特利尔公约对各国提出取代哈龙灭火剂的具体目标以来，世界各国都在致力于新的灭火技术的研究，既要灭火效率高，又要对环境无污染的灭火技术是人们努力的方向。气体灭火***，干粉灭火***及水系灭火***等由于对环境无害被作为哈龙灭火剂的替代品得到了广泛使用。
然而，这些灭火***都需要高压贮存，不仅体积较大，在贮存过程中还存在物理***的危险，文献“气体灭火***的安全性分析”(消防科学与技术200221(5))分析了气体灭火***所存在的危险，并列举了贮压气体灭火***在使用中所引发的安全事故。
近年来，人们一直在进行哈龙替代灭火物质的研究，其中美国标准与技术研究院的建筑与防火研究中心的下一代灭火技术项目组(NGP)在寻找新的灭火物质方面做了大量的实验研究工作，他们将氮气，二氧化碳，CF3H加热，高温的这些气体再加热试验物质，试验物质在高温下分解，连同气体一起作用于火焰，实验发现，有些试验物质在加热分解后的产物可显著提高氮气，二氧化碳及CF3H气体的灭火效果(Halon Options Technical Working Conference，April2001，Albuquerque，NM，Suppression of cup-burner diffusion flames by super-effectivechemical inhibitors and inert compounds；Combustion and Flame 129：221-238(2002)Inhibition of Premixed Methane Flame by Manganese and Tin Compounds，HalonOptions Technical Working Conference May 2000，flame inhibition by ferrocene，alone and with CO2 and CF3H)。
然而，该项目组的研究仅是建立在实验室理论研究的基础上，并没有将其用于实际的灭火器应用中。
现有的气溶胶灭火剂主要有S型和K型灭火剂，通过综合分析其性能特点，其不足之处主要有：气溶胶灭火剂均是利用灭火剂发生氧化还原反应释放出大量气体、活性粒子，通过活性粒子的断链反应，大量气体的覆盖窒息，实现化学与物理相结合的灭火目的。气溶胶发生剂在发生燃烧反应释放出灭火物质的同时，释放出大量的热，为有效降低装置和气溶胶的温度，避免发生二次火灾，需增加冷却***，导致装置结构复杂笨重，工艺流程复杂，成本高，但是由于冷却***的存在，使大量活性粒子失去活性，导致灭火性能大大降低。
发明内容
为了解决现有技术中的灭火组合物所存在的技术问题，本发明提供了一种灭火效能更好、安全性能更强的含有有机酸类化合物的灭火组合物。
本发明采用的技术方案是：
一种含有有机酸类化合物的灭火组合物，其特殊之处在于：该灭火组合物含有有机酸类化合物；其中有机酸类化合物的含量为50(质量)％以上，优选为70(质量)％～90(质量)％；本发明的有机酸类化合物在高温下可吸热分解，释放出灭火物质，该灭火物质可通过自由基与链式燃烧反应所必需的O·、OH·、H·自由基中的一种或几种进行反应，从而切断了链式燃烧反应，也可通过物理作用减少氧气分压而抑制火焰，或同时发生物理及化学抑制作用共同实现灭火效果，与此同时，其与烟火药剂产生协同增效作用，进一步提高了灭火剂的灭火效能，大大缩短了有效灭火时间。
为了改善上述主灭火材料即有机酸类化合物的灭火性能，在上述灭火组合物中还可以添加阻燃剂，即溴系阻燃剂、氯系阻燃剂、有机磷系阻燃剂、磷-卤系阻燃剂、氮系及磷-氮系阻燃剂或其他阻燃剂或其任意组合；具体可以是磷酸氢二铵、磷酸二氢铵、双氰胺、三聚氰胺、四溴双酚A、四氯双酚A、十溴二苯醚、DOPO，三(二溴苯基)磷酸酯、三聚氰胺、正磷酸三聚氰胺、磷酸胍、碳酸胍、双氰胺、聚磷酸铵等等；其中阻燃剂在灭火组合物中所占的含量小于50(质量)％，可以在40％以下，优选30％以下，4％～25％为最佳效果。
为了改善上述主灭火材料即有机酸类化合物的加工性能，本发明的灭火组合物还可以添加添加剂；其中添加剂的含量为0.1～10质量％，以0.1～5为佳，该添加剂可以是硬脂酸盐、石墨、高聚物的水溶性复配溶液或其混合物，或也可以是水玻璃、酚醛树脂、虫胶、淀粉中的一种或多种，根据应用情况而定。
本发明的灭火组合物还可以添加辅灭火材料，将其含量可控制为0～30(质量)％，以4％～25％为佳。辅灭火材料可以选自二茂铁或其衍生物或二茂铁和其衍生物的混合，或者还可以是碳酸锰、碱式碳酸铜、碱式碳酸镁、碳酸亚铁、柠檬酸钾、柠檬酸钠、柠檬酸铵、柠檬酸铁铵、草酸钾、草酸钠、草酸铵、草酸铁、草酸镁、草酸锰和草酸铜中的一种或者其组合。
本发明的有机酸类化合物可以是癸酸、十二酸、十四酸、十六酸、十七酸、十八酸、二十酸、二十二酸、二十六酸、三十一酸、三十二酸、丁烯酸、十八烯酸、十七烯酸、十六烯酸、己二烯酸、乙二酸、丙二酸、丁二酸、戊二酸、庚二酸、辛二酸、癸二酸、十三烷二酸、十六烷二酸、顺丁烯酸、反丁烯酸、2-羟基丙酸、2-羟基丁二酸、2，3-二羟基丁二酸、2-羟基-1，2，3-丙烷三羧酸、3-苯基-2-丙烯酸、2-羟基苯甲酸、3，4，5-三羟基苯甲酸、苯甲酸或甲基胍醋酸。
本发明的含有有机酸类化合物的灭火组合物以下优点：
一、本发明的灭火组合物包含有有机酸类化合物，其能够在受热瞬间分解释放出灭火物质，通过灭火物质的物理或化学抑制作用，或物理及化学的协同抑制作用进行灭火，并且对主灭火材料的含量进行优化，可以最大发挥灭火组合物的灭火效能，使得灭火效能大大提高，并且灭火时间缩短，提高了灭火组合物的灭火效率。
二、本发明的灭火组合物中添加阻燃剂、添加剂以及其他的辅灭火材料，进一步提高了主灭火材料即有机酸类化合物的灭火性能和加工性能，使其性能稳定并易于长期贮存。
三、本发明的灭火组合物是采用烟火药剂为热力源，使用更方便。
四、本发明的灭火组合物在受热情况下，即可迅速发生吸热分解，有效快速的降低了烟火药剂燃烧释放的热量，大大降低了灭火装置喷口及喷放物质的温度，更安全。
具体实施方式
现结合实验对本发明所提供的一种含有有机酸类化合物的灭火组合物的实施例进行说明：
该灭火组合物含有有机酸类化合物；其中有机酸类化合物的含量为50(质量)％以上，优选为70(质量)％～90(质量)％；其可以选自癸酸、十二酸、十四酸、十六酸、十七酸、十八酸、二十酸、二十二酸、二十六酸、三十一酸、三十二酸、丁烯酸、十八烯酸、十七烯酸、十六烯酸、己二烯酸、乙二酸、丙二酸、丁二酸、戊二酸、庚二酸、辛二酸、癸二酸、十三烷二酸、十六烷二酸、顺丁烯酸、反丁烯酸、2-羟基丙酸、2-羟基丁二酸、2，3-二羟基丁二酸、2-羟基-1，2，3-丙烷三羧酸、3-苯基-2-丙烯酸、2-羟基苯甲酸、3，4，5-三羟基苯甲酸、苯甲酸或甲基胍醋酸等，其均可在高温下吸热分解，释放出灭火物质，该灭火物质可通过自由基与链式燃烧反应所必需的O·、OH·、H·自由基中的一种或几种进行反应，从而切断了链式燃烧反应，也可通过物理作用减少氧气分压而抑制火焰，或同时发生物理及化学抑制作用共同实现灭火效果，与此同时，其与烟火药剂产生协同增效作用，进一步提高了灭火剂的灭火效能，大大缩短了有效灭火时间。
为了改善上述主灭火材料即有机酸类化合物的灭火性能，在上述灭火组合物中还可以添加阻燃剂，即溴系阻燃剂、氯系阻燃剂、有机磷系阻燃剂、磷-卤系阻燃剂、氮系及磷-氮系阻燃剂或无机阻燃剂或其任意组合；具体可以选自磷酸氢二铵，磷酸二氢铵，双氰胺，三聚氰胺，四溴双酚A，四氯双酚A，十溴二苯醚，DOPO，三(二溴苯基)磷酸酯，三聚氰胺，正磷酸三聚氰胺，磷酸胍，碳酸胍，双氰胺，聚磷酸铵等等，不仅限于此，只要是能够与有机酸类化合物混合并能够很好地起到灭火效果的阻燃剂均可。其中阻燃剂在灭火组合物中所占的含量小于50(质量)％，可以在40％以下，优选30％以下，4％～25％为最佳效果，根据具体的配比进行调整。
本发明的灭火组合物还可以添加添加剂以改善上述主灭火材料即有机酸类化合物的加工性能；其中添加剂的含量为0.1～10质量％，以0.1～5为佳，该添加剂可以是硬脂酸盐、石墨、高聚物的水溶性复配溶液或其混合物，或也可以是水玻璃、酚醛树脂、虫胶、淀粉中的一种或多种，根据应用情况而进行选取。其中添加剂中含有粘合剂，而粘合剂是属于本领域的普通知识，通常其在灭火组合物中的含量控制在15％以下。
本发明的灭火组合物还可以添加辅灭火材料，将含量可控制为0～30(质量)％，以4％～25％为佳，其可以是二茂铁或其衍生物或者两者的组合，或者还可以是碳酸锰、碱式碳酸铜、碱式碳酸镁、碳酸亚铁、柠檬酸钾、柠檬酸钠、柠檬酸铵、柠檬酸铁铵、草酸钾、草酸钠、草酸铵、草酸铁、草酸镁、草酸锰和草酸铜中的一种或者其组合。
将制得的片状灭火组合物65g分别加入装有50gK型热气溶胶发生剂的灭火装置中，分别按照GA86-2009第6.3.2款进行灭火试验，灭火级别选择8B；试验测试结果见表1。对比例选择为50g市售K型热气溶胶发生剂。
表1 各种组分成分比较和试验结果对比
通过表1可以清楚地看出，本发明的实施例1-12的有机酸为主灭火材料的组合物在灭火效率上不仅远远优于对比例的情况，在灭火时间上和发生器喷口温度上也明显优于对比例的情况。
Claims (10)
1.一种含有有机酸类化合物的灭火组合物，其特征在于：所述灭火组合物含有有机酸类化合物；所述有机酸类化合物的含量为50(质量)％以上；
所述灭火组合物是以烟火药剂为热力源和动力源，通过点燃烟火药剂，利用烟火药剂燃烧的高温使该灭火组合物受热发生分解反应，产生出大量的可灭火的物质，该灭火物质随烟火药剂一起从喷口喷出，从而达到灭火的目的。
2.根据权利要求1所述的含有有机酸类化合物的灭火组合物，其特征在于：所述组合物还包括辅灭火材料；所述辅灭火材料是柠檬酸盐、草酸盐、碳酸盐、二茂铁和二茂铁衍生物中的一种或多种，其含量为大于0至小于等于30(质量)％。
3.根据权利要求1所述的含有有机酸类化合物的灭火组合物，其特征在于：所述组合物还包括阻燃剂；所述阻燃剂的含量为大于0至小于等于50(质量)％。
4.根据权利要求1至3任一所述的含有有机酸类化合物的灭火组合物，其特征在于：所述组合物还包括添加剂；所述添加剂的含量为0.1～10(质量)％。
5.根据权利要求4所述的含有有机酸类化合物的灭火组合物，其特征在于：所述添加剂是硬脂酸盐、石墨、高聚物的水溶性复配溶液或其混合物，或是水玻璃、酚醛树脂、虫胶、淀粉中的一种或多种。
6.根据权利要求4所述的含有有机酸类化合物的灭火组合物，其特征在于：所述有机酸类化合物是癸酸、十二酸、十四酸、十六酸、十七酸、十八酸、二十酸、二十二酸、二十六酸、三十一酸、三十二酸、丁烯酸、十八烯酸、十七烯酸、十六烯酸、己二烯酸、乙二酸、丙二酸、丁二酸、戊二酸、庚二酸、辛二酸、癸二酸、十三烷二酸、十六烷二酸、顺丁烯酸、反丁烯酸、2-羟基丙酸、2-羟基丁二酸、2，3-二羟基丁二酸、2-羟基-1，2，3-丙烷三羧酸、3-苯基-2-丙烯酸、2-羟基苯甲酸、3，4，5-三羟基苯甲酸、苯甲酸或甲基胍醋酸。
7.根据权利要求6所述的含有有机酸类化合物的灭火组合物，其特征在于：所述有机酸类化合物的含量优选为70(质量)％～90(质量)％。
8.根据权利要求3所述的含有有机酸类化合物的灭火组合物，其特征在于：所述阻燃剂是溴系阻燃剂、氯系阻燃剂、有机磷系阻燃剂、磷-卤系阻燃剂、氮系及磷-氮系阻燃剂或其他阻燃剂或其任意组合。
9.根据权利要求8所述的含有有机酸类化合物的灭火组合物，其特征在于：所述阻燃剂的含量为大于0至小于30(质量)％。
10.根据权利要求1所述的含有有机酸类化合物的灭火组合物，其特征在于：所述灭火组合物还包含有：
辅灭火材料 4％～25％
阻燃剂 4％～25％
添加剂 0.1％～5％。
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| CN201110235101.3A CN102949802B (zh) | 2011-08-16 | 2011-08-16 | 一种含有有机酸类化合物的灭火组合物 |
| EP12823385.5A EP2742978B1 (en) | 2011-08-16 | 2012-08-14 | Fire-extinguishing composition comprising organic acid compound |
| KR1020147006971A KR101780535B1 (ko) | 2011-08-16 | 2012-08-14 | 유기산계 화합물을 포함한 소화 조성물 |
| RU2014108668/05A RU2580915C2 (ru) | 2011-08-16 | 2012-08-14 | Пламегасящая композиция, содержащая органическую кислоту |
| MYPI2014000432A MY165914A (en) | 2011-08-16 | 2012-08-14 | Fire-extinguishing composition comprising organic acid compound |
| AU2012297385A AU2012297385B2 (en) | 2011-08-16 | 2012-08-14 | Fire-extinguishing composition comprising organic acid compound |
| PCT/CN2012/080091 WO2013023575A1 (zh) | 2011-08-16 | 2012-08-14 | 一种含有有机酸类化合物的灭火组合物 |
| MX2014001818A MX353268B (es) | 2011-08-16 | 2012-08-14 | Composicion extintora de incendios que comprende acido organico. |
| US14/239,112 US20140183399A1 (en) | 2011-08-16 | 2012-08-14 | Fire-extinguishing composition comprising organic acid compound |
| JP2014525294A JP6143756B2 (ja) | 2011-08-16 | 2012-08-14 | 有機酸系化合物を含有する消火組成物 |
| BR112014003657-8A BR112014003657B1 (pt) | 2011-08-16 | 2012-08-14 | Composição extintora de incêndio compreendendo um composto de ácido orgânico |
| IN1965DEN2014 IN2014DN01965A (zh) | 2011-08-16 | 2012-08-14 | |
| CA2845424A CA2845424C (en) | 2011-08-16 | 2012-08-14 | Fire-extinguishing composition comprising an organic acid compound |
| UAA201402597A UA112875C2 (uk) | 2011-08-16 | 2012-08-14 | Вогнегасна композиція, яка включає сполуку органічної кислоти |
| ZA2014/01870A ZA201401870B (en) | 2011-08-16 | 2014-03-14 | Fire-extinguishing composition comprising organic acid compound |
Applications Claiming Priority (1)
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|---|---|---|---|
| CN201110235101.3A CN102949802B (zh) | 2011-08-16 | 2011-08-16 | 一种含有有机酸类化合物的灭火组合物 |
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| CN102949802A true CN102949802A (zh) | 2013-03-06 |
| CN102949802B CN102949802B (zh) | 2016-04-06 |
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| US (1) | US20140183399A1 (zh) |
| EP (1) | EP2742978B1 (zh) |
| JP (1) | JP6143756B2 (zh) |
| KR (1) | KR101780535B1 (zh) |
| CN (1) | CN102949802B (zh) |
| AU (1) | AU2012297385B2 (zh) |
| BR (1) | BR112014003657B1 (zh) |
| CA (1) | CA2845424C (zh) |
| IN (1) | IN2014DN01965A (zh) |
| MX (1) | MX353268B (zh) |
| MY (1) | MY165914A (zh) |
| RU (1) | RU2580915C2 (zh) |
| UA (1) | UA112875C2 (zh) |
| WO (1) | WO2013023575A1 (zh) |
| ZA (1) | ZA201401870B (zh) |
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| CN103736238A (zh) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | 一种含有含硫类有机化合物的灭火组合物 |
| CN103736240A (zh) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | 一种含有饱和烃类化合物及其衍生物的灭火组合物 |
| CN103751943A (zh) * | 2014-01-13 | 2014-04-30 | 西安坚瑞安全应急设备有限责任公司 | 一种含有含氮类有机化合物的灭火组合物 |
| CN103768754A (zh) * | 2014-01-13 | 2014-05-07 | 西安坚瑞安全应急设备有限责任公司 | 一种含有不饱和烃类化合物及其衍生物的灭火组合物 |
| WO2015104006A1 (zh) * | 2014-01-13 | 2015-07-16 | 西安坚瑞安全应急设备有限责任公司 | 一种含有醛酮类化合物的灭火组合物 |
| WO2015104005A1 (zh) * | 2014-01-13 | 2015-07-16 | 西安坚瑞安全应急设备有限责任公司 | 一种含有杂环类化合物的灭火组合物 |
| WO2015104007A3 (zh) * | 2014-01-13 | 2015-08-27 | 西安坚瑞安全应急设备有限责任公司 | 一种含有醇酚类化合物及其衍生物的灭火组合物 |
| CN105288925A (zh) * | 2015-12-01 | 2016-02-03 | 西安坚瑞安全应急设备有限责任公司 | 一种灭火组合物 |
| US9974992B2 (en) | 2014-01-13 | 2018-05-22 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising carboxylic acid derivative |
| CN111888706A (zh) * | 2020-08-12 | 2020-11-06 | 安徽博泰电子材料有限公司 | 一种烷基铝类化合物专用d类干粉灭火剂的制备方法 |
| CN115066277A (zh) * | 2019-12-31 | 2022-09-16 | 普里马利奇解决方案公司 | 具有阻燃性的非聚合物有机组分的混合物、制备方法和用途 |
| CN115317843A (zh) * | 2022-08-31 | 2022-11-11 | 四川省林业科学研究院 | 用于森林防火的灭火剂及其制备方法 |
| CN116474308A (zh) * | 2023-04-25 | 2023-07-25 | 西安庆华民用***器材股份有限公司 | 复合型低温气溶胶灭火剂及其制备方法 |
| CN116943090A (zh) * | 2023-06-13 | 2023-10-27 | 湖北及安盾消防科技有限公司 | 一种化学冷却剂及其在k型气溶胶灭火剂中的应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2014203935A1 (ja) * | 2013-06-18 | 2014-12-24 | 国立大学法人横浜国立大学 | 消火剤および消火方法 |
| KR101335597B1 (ko) * | 2013-06-28 | 2013-12-02 | 주식회사 삼정에이앤에프 | 친환경 중성계 강화액 소화약제 조성물 제조방법 |
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Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9974992B2 (en) | 2014-01-13 | 2018-05-22 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising carboxylic acid derivative |
| CN103736240B (zh) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | 一种含有饱和烃类化合物及其衍生物的灭火组合物 |
| CN103751943A (zh) * | 2014-01-13 | 2014-04-30 | 西安坚瑞安全应急设备有限责任公司 | 一种含有含氮类有机化合物的灭火组合物 |
| CN103768754A (zh) * | 2014-01-13 | 2014-05-07 | 西安坚瑞安全应急设备有限责任公司 | 一种含有不饱和烃类化合物及其衍生物的灭火组合物 |
| WO2015104006A1 (zh) * | 2014-01-13 | 2015-07-16 | 西安坚瑞安全应急设备有限责任公司 | 一种含有醛酮类化合物的灭火组合物 |
| WO2015104005A1 (zh) * | 2014-01-13 | 2015-07-16 | 西安坚瑞安全应急设备有限责任公司 | 一种含有杂环类化合物的灭火组合物 |
| WO2015104007A3 (zh) * | 2014-01-13 | 2015-08-27 | 西安坚瑞安全应急设备有限责任公司 | 一种含有醇酚类化合物及其衍生物的灭火组合物 |
| GB2537312A (en) * | 2014-01-13 | 2016-10-12 | Xi'an J&R Fire Fighting Equipment Co Ltd | Fire extinguishing composition comprising aldoketones compound |
| GB2536849A (en) * | 2014-01-13 | 2016-09-28 | Xi'an J&R Fire Fighting Equipment Co Ltd | Fire extinguishing composition comprising heterocyclic compounds |
| GB2537079A (en) * | 2014-01-13 | 2016-10-05 | Xi'an J&R Fire Fighting Equipment Co Ltd | Fire extinguishing composition comprising alcohol phenol compound and derivative thereof |
| CN103736240A (zh) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | 一种含有饱和烃类化合物及其衍生物的灭火组合物 |
| CN103768754B (zh) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | 一种含有不饱和烃类化合物及其衍生物的灭火组合物 |
| US10092786B2 (en) | 2014-01-13 | 2018-10-09 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising aldoketones compound |
| US10035033B2 (en) | 2014-01-13 | 2018-07-31 | Xi'an Westpeace Fire Technology Co., Ltd. | Fire extinguishing composition comprising alcohol phenol compound and derivative thereof |
| CN103736238A (zh) * | 2014-01-13 | 2014-04-23 | 西安坚瑞安全应急设备有限责任公司 | 一种含有含硫类有机化合物的灭火组合物 |
| WO2017092658A1 (zh) * | 2015-12-01 | 2017-06-08 | 西安威西特消防科技有限责任公司 | 一种灭火组合物 |
| CN105288925A (zh) * | 2015-12-01 | 2016-02-03 | 西安坚瑞安全应急设备有限责任公司 | 一种灭火组合物 |
| CN115066277A (zh) * | 2019-12-31 | 2022-09-16 | 普里马利奇解决方案公司 | 具有阻燃性的非聚合物有机组分的混合物、制备方法和用途 |
| CN111888706A (zh) * | 2020-08-12 | 2020-11-06 | 安徽博泰电子材料有限公司 | 一种烷基铝类化合物专用d类干粉灭火剂的制备方法 |
| CN115317843A (zh) * | 2022-08-31 | 2022-11-11 | 四川省林业科学研究院 | 用于森林防火的灭火剂及其制备方法 |
| CN115317843B (zh) * | 2022-08-31 | 2024-01-19 | 四川省林业科学研究院 | 用于森林防火的灭火剂及其制备方法 |
| CN116474308A (zh) * | 2023-04-25 | 2023-07-25 | 西安庆华民用***器材股份有限公司 | 复合型低温气溶胶灭火剂及其制备方法 |
| CN116943090A (zh) * | 2023-06-13 | 2023-10-27 | 湖北及安盾消防科技有限公司 | 一种化学冷却剂及其在k型气溶胶灭火剂中的应用 |
| CN116943090B (zh) * | 2023-06-13 | 2024-05-28 | 湖北及安盾消防科技有限公司 | 一种化学冷却剂及其在k型气溶胶灭火剂中的应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014527437A (ja) | 2014-10-16 |
| RU2014108668A (ru) | 2015-09-27 |
| BR112014003657A8 (pt) | 2018-04-03 |
| WO2013023575A1 (zh) | 2013-02-21 |
| IN2014DN01965A (zh) | 2015-05-15 |
| CN102949802B (zh) | 2016-04-06 |
| UA112875C2 (uk) | 2016-11-10 |
| EP2742978A1 (en) | 2014-06-18 |
| KR101780535B1 (ko) | 2017-09-21 |
| MX2014001818A (es) | 2014-08-21 |
| MY165914A (en) | 2018-05-18 |
| EP2742978B1 (en) | 2016-10-12 |
| ZA201401870B (en) | 2015-10-28 |
| CA2845424C (en) | 2018-07-31 |
| BR112014003657A2 (zh) | 2017-09-12 |
| RU2580915C2 (ru) | 2016-04-10 |
| MX353268B (es) | 2018-01-08 |
| KR20140072045A (ko) | 2014-06-12 |
| US20140183399A1 (en) | 2014-07-03 |
| AU2012297385B2 (en) | 2015-12-17 |
| EP2742978A4 (en) | 2015-05-06 |
| BR112014003657B1 (pt) | 2021-03-23 |
| AU2012297385A1 (en) | 2014-03-20 |
| CA2845424A1 (en) | 2013-02-21 |
| JP6143756B2 (ja) | 2017-06-07 |
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