WO2017092658A1 - 一种灭火组合物 - Google Patents
一种灭火组合物 Download PDFInfo
- Publication number
- WO2017092658A1 WO2017092658A1 PCT/CN2016/107856 CN2016107856W WO2017092658A1 WO 2017092658 A1 WO2017092658 A1 WO 2017092658A1 CN 2016107856 W CN2016107856 W CN 2016107856W WO 2017092658 A1 WO2017092658 A1 WO 2017092658A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid
- fire extinguishing
- fire
- extinguishing composition
- aromatic organic
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/005—Dispersions; Emulsions
Definitions
- the invention belongs to the field of aerosol fire extinguishing technology, in particular to a hot aerosol fire extinguishing composition.
- Gas fire extinguishing systems, dry powder fire extinguishing systems and water fire extinguishing systems are widely used as substitutes for halon fire extinguishing agents because they are environmentally friendly.
- the fire extinguishing mechanism of carbon dioxide, IG541 and other inert gas fire extinguishing systems is mainly physical fire extinguishing, which is suffocated by reducing the oxygen concentration in the fire area. This kind of fire extinguishing method is easy to pose a threat to personal safety.
- the dry powder fire extinguishing system is under the action of pressurized gas. The sprayed powder is in contact with the flame and undergoes physicochemical inhibition to extinguish the fire.
- the water mist fire extinguishing system achieves the purpose of controlling fire, suppressing fire and extinguishing fire by the triple action of cooling by fine water mist, suffocation and heat radiation.
- the existing hot aerosol fire extinguishing agents mainly have S-type and K-type fire extinguishing agents.
- the fire extinguishing mechanism is that the hot aerosol fire extinguishing agent uses the chemical agent to burn and redox A large amount of gas, active particles, broken chain reaction by active particles, and a large amount of gas covering suffocation should be released to achieve the purpose of combining fire and chemical.
- the shortcoming is that the hot aerosol fire extinguishing agent releases a large amount of heat at the same time as the combustion reaction releases the hot aerosol, which may cause secondary combustion, in order to effectively reduce the temperature of the device and the aerosol, and avoid secondary fires.
- the cooling and cooling material of the existing hot aerosol fire extinguishing device can reduce the temperature of the product and greatly weaken the fire extinguishing performance of the product.
- many products have reduced the fire extinguishing.
- the traditional K-type fire extinguishing agent has high fire-extinguishing efficiency and small volume, but its sediment is corrosive and will cause secondary damage.
- Aromatic organic acid compound 20% ⁇ 90%
- the fire extinguishing composition utilizes a high temperature of combustion of the pyrotechnic agent to cause the fire extinguishing composition to produce a large amount of fire extinguishing material.
- the aromatic organic acid compound is a monovalent aromatic organic acid compound and/or a divalent aromatic organic acid compound.
- the monobasic aromatic organic acid compound includes: 2,5-dimethylbenzoic acid, 2,4-dihydroxybenzoic acid, m-hydroxybenzoic acid, 3-hydroxyphenylacetic acid, 2,4-dimethoxy Benzoic acid, m-methylbenzoic acid, 2-amino-3-methylbenzoic acid, 2,3-dihydroxybenzoic acid, 4-methylsalicylic acid, 2-carboxylic acid pyrazine, 3-hydroxy-4- Methoxybenzoic acid, 3-hydroxy-4-methylbenzoic acid, 4-phenylbenzoic acid, p-tert-butylbenzoic acid, 4-isopropylbenzoic acid, 4'-hydroxybiphenyl-4-carboxylic acid , 3-amino-4-methylbenzoic acid, 2,4,6-trimethylbenzoic acid, 3,4,5-trimethoxybenzoic acid, 2,6-dimethoxybenzoic acid, 4-( Hydroxymethyl)phenoxyacetic acid, 2,6-dimethylbenz
- the binary aromatic organic acid compound comprises: 5-hydroxyisophthalic acid, diphenyl phthalic acid, isophthalic acid, phthalic acid, terephthalic acid, terephthalic acid, 1, 2 -cyclohexanedicarboxylic acid, 1,2-benzenediacetic acid, 1,4-naphthalene dicarboxylic acid, 2,2'-diphenyl phthalic acid, 2,7-naphthalene dicarboxylic acid, 5-methoxyisophthalic acid One or more of formic acid and 1,3-benzenediacetic acid.
- the alcohol compound comprises: p-hydroxybenzyl alcohol, erythritol, milk Sugar alcohol, triphenylmethanol, 3-hydroxy-4-methoxybenzyl alcohol, sorbitol, tebuconazole, 2-hydroxy-5-methyl meta-benzene dimethanol, maltitol, pentaerythritol, dipentaerythritol, tripentaerythritol
- dodecyl diethylene glycol ether tricyclo[3.3.1.1(3,7)]nonan-2-ol, mannitol, and glucose alcohol.
- the mass percentage of each component in the fire extinguishing composition is preferably:
- Aromatic organic acid compound 40% ⁇ 90%
- the alcohol compound is 10% to 60%.
- the fire extinguishing composition further contains an additive having a mass percentage of from more than 0 to less than or equal to 5%.
- the additive is stearate, graphite, water glass, phenolic resin, shellac, starch, dextrin, rubber, epoxy resin, acetal glue, hydroxypropyl methyl cellulose, ethyl cellulose One or several of them.
- each component of the fire extinguishing composition and its mass percentage are preferably:
- each component of the fire extinguishing composition and its mass percentage are preferably:
- Aromatic organic acid compound 40% ⁇ 80%
- the flame suppression mechanism of the fire extinguishing composition of the present invention is as follows:
- the pyrotechnic agent When used, the pyrotechnic agent is used as a heat source and a power source to ignite the pyrotechnics
- the heat released by the fire, the fire extinguishing composition is further decomposed at a high temperature to release a fire extinguishing substance, which can pass one or more of O ⁇ , OH ⁇ , H ⁇ radicals necessary for radical and chain combustion reactions.
- the reaction is carried out, thereby cutting off the chain combustion reaction, and also suppressing the flame by physical action to suppress the partial pressure of oxygen, or simultaneously performing physical and chemical inhibition functions to achieve fire extinguishing, and at the same time, synergistic effect with pyrotechnic agents, further
- the fire extinguishing performance of the fire extinguishing agent is improved, and the effective fire extinguishing time is greatly shortened.
- the aromatic organic acid compound and the alcohol compound in the fire extinguishing composition of the present invention can undergo endothermic sublimation, decomposition and mutual reaction at high temperature, generate a large number of nano-level effective fire-extinguishing particles and various free radicals, and cut off the combustion reaction chain. Together with the reaction products of the hot aerosol generating agent, the fire extinguishing effect is further exerted, thereby further improving the fire extinguishing performance of the fire extinguishing agent and shortening the effective fire extinguishing time.
- the fire extinguishing composition of the invention compensates for the performance loss of the general cooling layer to the aerosol generating agent, and strengthens the fire extinguishing performance of the whole fire extinguishing product, and at the same time reduces the spout temperature of the fire extinguishing device, and the safety is better, and the fire extinguishing personnel are not Causes damage and avoids the occurrence of secondary fires.
- the sediment after spraying of the fire extinguishing composition of the invention has small hygroscopicity and high insulation resistance, and can be applied to a charged place, which does not cause corrosion and other adverse effects on electrical equipment, and avoids secondary damage of electrical equipment.
- the aerosol fire extinguishing device using the fire extinguishing composition of the invention does not need to increase the complicated structure and large volume cooling system, and therefore has the characteristics of light structure, simple process flow and good economy.
- Fire extinguishing composition formula: 35% phthalic acid, 55% mannitol, 9% maltitol, 1% phenolic resin
- Fire extinguishing composition formula: 5-methoxysalicylic acid 10%, isophthalic acid 10%, terephthalic acid 20%, maltitol 28%, pentaerythritol 30%, starch 2%
- Fire extinguishing composition 3-phenyl-2-acrylic acid 50%, pentaerythritol 47%, epoxy resin 3%
- Fire extinguishing composition formula: 76% phthalic acid, 10% dipentaerythritol, 10% mannitol, 4% hydroxypropyl methylcellulose
- Fire extinguishing composition formula: 89% terephthalic acid, 10% dipentaerythritol, 1% ethyl cellulose
- Examples 1-7 were taken in proportion, using water or alcohol as a solvent, granulated with a 20-mesh sieve, dried, added with a release agent, mixed and passed through a 15 mesh sieve, and pelletized, molded,
- the process such as extrusion is formed into a spherical shape, a sheet shape, a strip shape, a block shape, and a honeycomb shape; 60 g is added to a fire extinguishing device equipped with a 50 g type K aerosol generating agent, and a fire extinguishing experiment is performed according to a fire extinguishing experiment model.
- the samples in Comparative Examples 1-4 were placed in a fire extinguishing device, and the fire extinguishing experiment was carried out in accordance with the fire extinguishing experiment model.
- the test method for fire-extinguishing test and insulation resistance of sediment is carried out according to the relevant method in GA499.1-2010 "Aerosol fire extinguishing system Part 1: Hot aerosol fire extinguishing device".
- the fire extinguishing space is 2 cubic meters test box, and 5 boxes are set in the box. For fire cups, the number of fires is the average number of fires after three tests. Record the number of fire extinguishers, spout temperature and insulation resistance value of the sediment.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Dispersion Chemistry (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
Description
Claims (9)
- 一种灭火组合物,其特征在于,所述灭火组合物由如下质量百分含量的物质组成:芳香族有机酸化合物 20%~90%醇类化合物 10%~80%所述灭火组合物利用烟火药剂燃烧的高温使该灭火组合物产生出大量的可灭火物质。
- 根据权利要求1所述的灭火组合物,其特征在于:所述的芳香族有机酸化合物为一元芳香族有机酸化合物和/或二元芳香族有机酸化合物。
- 根据权利要求2所述的灭火组合物,其特征在于,所述一元芳香族有机酸化合物包括:2,5-二甲基苯甲酸、2,4-二羟基苯甲酸、间羟基苯甲酸、3-羟基苯乙酸、2,4-二甲氧基苯甲酸、间甲基苯甲酸、2-氨基-3-甲基苯甲酸、2,3-二羟基苯甲酸、4-甲基水杨酸、2-甲酸吡嗪、3-羟基-4-甲氧基苯甲酸、3-羟基-4-甲基苯甲酸、4-苯基苯甲酸、对叔丁基苯甲酸、4-异丙基苯甲酸、4'-羟基联苯-4-羧酸、3-氨基-4-甲基苯甲酸、2,4,6-三甲基苯甲酸、3,4,5-三甲氧基苯甲酸、2,6-二甲氧基苯甲酸、4-(羟基甲基)苯氧基乙酸、2,6-二甲基苯甲酸、3,4-二甲氧基苯甲酸、2,2-二苯基乙酸、5-甲氧基水杨酸、3,4-二甲基苯甲酸、邻苯甲酰苯甲酸、3-苯基苯甲酸、2,5-二甲基苯乙酸、5-甲基水杨酸、2,6-二羟基苯甲酸、2-羟基-6-萘甲酸、对甲基苯甲酸、对甲氧基苯甲酸、2,3-二甲氧基苯甲酸、3-苯基-2-丙烯酸、3-苯甲酰苯甲酸、香豆酸、2,4,6-三羟基苯甲酸中的一种 或多种。
- 根据权利要求2所述的灭火组合物,其特征在于:所述二元芳香族有机酸化合物包括:5-羟基间苯二甲酸、联苯二甲酸、间苯二甲酸、邻苯二甲酸、对苯二甲酸、对苯二乙酸、1,2-环己烷二甲酸、1,2-苯二乙酸、1,4-萘二甲酸、2,2'-联苯二甲酸、2,7-萘二羧酸、5-甲氧基间苯二甲酸、1,3-苯二乙酸一种或多种。
- 根据权利要求1所述的灭火组合物,其特征在于:所述醇类化合物包括:对羟基苯甲醇、赤藓糖醇、乳糖醇、三苯基甲醇、3-羟基-4-甲氧基苯甲醇、山梨醇、戊唑醇、2-羟基-5-甲基间苯二甲醇、麦芽糖醇、季戊四醇、双季戊四醇、三季戊四醇、十二烷基二乙二醇醚、三环[3.3.1.1(3,7)]癸烷-2-醇、甘露醇、葡萄糖醇中的一种或多种。
- 根据权利要求1所述的灭火组合物,其特征在于,所述灭火组合物中各组分的质量百分含量为:芳香族有机酸化合物 40%~90%醇类化合物 10%~60%。
- 根据权利要求1所述的灭火组合物,其特征在于:所述灭火组合物还含有添加剂,其质量百分比为大于0至小于等于5%。
- 根据权利要求7所述的灭火组合物,其特征在于:所述添加剂为硬脂酸盐,石墨,水玻璃,酚醛树脂、虫胶、淀粉,糊精,橡胶、环氧树脂、缩醛胶、羟丙基甲基纤维素、乙基纤维素中的一种或几种。
- 根据权利要求8中任一项所述的灭火组合物,其特征在于所述灭火组合物中各组分及其质量百分含量为:芳香族有机酸化合物 30%~80%醇类化合物 15%~65%添加剂 0.2%~5%。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2018006686A MX2018006686A (es) | 2015-12-01 | 2016-11-30 | Composicion para extinguir incendios. |
EP16869968.4A EP3384966A4 (en) | 2015-12-01 | 2016-11-30 | EXTINGUISHING MEDIA COMPOSITION |
BR112018011049A BR112018011049A2 (pt) | 2015-12-01 | 2016-11-30 | ?composição extintora de incêndio? |
US15/780,633 US20180361186A1 (en) | 2015-12-01 | 2016-11-30 | Fire-Extinguishing Composition |
AU2018100771A AU2018100771A4 (en) | 2015-12-01 | 2018-06-08 | Fire-extinguishing composition |
Applications Claiming Priority (2)
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CN201510867612.5A CN105288925A (zh) | 2015-12-01 | 2015-12-01 | 一种灭火组合物 |
CN201510867612.5 | 2015-12-01 |
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AU2018100771A Division AU2018100771A4 (en) | 2015-12-01 | 2018-06-08 | Fire-extinguishing composition |
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WO2017092658A1 true WO2017092658A1 (zh) | 2017-06-08 |
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PCT/CN2016/107856 WO2017092658A1 (zh) | 2015-12-01 | 2016-11-30 | 一种灭火组合物 |
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US (1) | US20180361186A1 (zh) |
EP (1) | EP3384966A4 (zh) |
CN (1) | CN105288925A (zh) |
BR (1) | BR112018011049A2 (zh) |
MX (1) | MX2018006686A (zh) |
WO (1) | WO2017092658A1 (zh) |
Families Citing this family (5)
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CN105288925A (zh) * | 2015-12-01 | 2016-02-03 | 西安坚瑞安全应急设备有限责任公司 | 一种灭火组合物 |
CN108245821A (zh) * | 2016-12-28 | 2018-07-06 | 西安威西特消防科技有限责任公司 | 一种灭火组合物 |
CN108245820A (zh) * | 2016-12-28 | 2018-07-06 | 西安威西特消防科技有限责任公司 | 一种灭火组合物 |
ES2837489B2 (es) * | 2019-12-31 | 2022-02-28 | Primalchit Solutions S L | Mezcla de componentes organicos no polimericos con capacidad retardante de llama, metodo de preparacion y uso |
CN114350326B (zh) * | 2022-01-14 | 2024-02-02 | 湖北及安盾消防科技有限公司 | 冷却剂及其制备方法、温敏絮凝胶、气溶胶灭火装置 |
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2015
- 2015-12-01 CN CN201510867612.5A patent/CN105288925A/zh active Pending
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2016
- 2016-11-30 WO PCT/CN2016/107856 patent/WO2017092658A1/zh active Application Filing
- 2016-11-30 MX MX2018006686A patent/MX2018006686A/es unknown
- 2016-11-30 BR BR112018011049A patent/BR112018011049A2/pt not_active Application Discontinuation
- 2016-11-30 EP EP16869968.4A patent/EP3384966A4/en not_active Withdrawn
- 2016-11-30 US US15/780,633 patent/US20180361186A1/en not_active Abandoned
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Also Published As
Publication number | Publication date |
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BR112018011049A2 (pt) | 2019-02-19 |
US20180361186A1 (en) | 2018-12-20 |
EP3384966A1 (en) | 2018-10-10 |
CN105288925A (zh) | 2016-02-03 |
EP3384966A4 (en) | 2019-06-05 |
MX2018006686A (es) | 2018-11-09 |
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