CN102845426A - Bactericide combination containing fluorine ether bacteria amide and chlorothalonil - Google Patents
Bactericide combination containing fluorine ether bacteria amide and chlorothalonil Download PDFInfo
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- CN102845426A CN102845426A CN2012103632057A CN201210363205A CN102845426A CN 102845426 A CN102845426 A CN 102845426A CN 2012103632057 A CN2012103632057 A CN 2012103632057A CN 201210363205 A CN201210363205 A CN 201210363205A CN 102845426 A CN102845426 A CN 102845426A
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- tpn
- acid amides
- bacterium acid
- fluorine
- ether bacterium
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Abstract
The invention provides a bactericide combination containing fluorine ether bacteria amide and chlorothalonil. The bactericide combination is composed of active ingredients and auxiliary materials, wherein the active ingredients are fluorine ether bacteria amide and chlorothalonil, the weight ratio between fluorine ether bacteria amide and chlorothalonil is (1:4)-(4:1), and the total content of the active ingredients is 10%-60%. The bactericide combination is specially used for disease control of vegetables and fruits.
Description
Technical field
The present invention relates to agricultural chemicals, is the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides and tpn.
Background technology
Fluorine ether bacterium acid amides is a kind of amide-type wide-spectrum bactericide, and Oomycete fungi germ is had very high biologically active, has preferably protection and therapeutic action.Fluorine ether bacterium acid amides has stronger interior absorption, can absorb by cauline leaf, is conducted to upper direction by the plant bottom, distributes to whole strain crop along the plant xylem.The applicant studies discovery, and fluorine ether bacterium acid amides and known medicine without interior suction bactericidal activity be composite preferably synergistic effect.For example: tpn is a kind of wide spectrum, protective fungicide; its effect be can with the fungal cell in glyceraldehyde 3-phosphate dehydrogenase have an effect; the protein that contains cysteine in this enzyme combines; thereby destroy this enzymic activity; fungal cell's metabolism is damaged and the power that loses one's life, and this medicine is without interior suction bactericidal activity, although this medicine toxicity is very low; but because long-term the use separately descends gradually to fungus-caused disease-controlling effects such as vegetables downy mildew, the pesticide resistance of disease increases year by year.
Summary of the invention
The purpose of this invention is to provide the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides and tpn, it is exclusively used in the disease control of vegetables and fruit.
The present invention for achieving the above object, be achieved through the following technical solutions: the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides and tpn, formed by active ingredient and auxiliary material, active ingredient is fluorine ether bacterium acid amides and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:4-4:1, and the total content of active ingredient is 10%-60%.
The microbicide compositions of described a kind of fluorine-containing ether bacterium acid amides and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:3-3:1, and the total content of active ingredient is 20%-50%, and surplus is auxiliary material.
The microbicide compositions of described a kind of fluorine-containing ether bacterium acid amides and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:2-2:1, and the total content of active ingredient is 40%-50%, and surplus is auxiliary material.
The microbicide compositions of described a kind of fluorine-containing ether bacterium acid amides and tpn, described auxiliary material be white carbon, diatomite, lauryl sodium sulfate, pull open powder, sodium lignin sulfonate.
The microbicide compositions of described a kind of fluorine-containing ether bacterium acid amides and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:4-4:1, and the total content of active ingredient is 10%-50%, and auxiliary material is filler 20%-45%, wetting agent 5-15% and dispersant 5-15%.
The microbicide compositions of described a kind of fluorine-containing ether bacterium acid amides and tpn, pulls open powder 3% and sodium lignin sulfonate 5% at fluorine ether bacterium acid amides 25%, tpn 25%, white carbon 15%, diatomite 23%, lauryl sodium sulfate 4%.
The microbicide compositions of described a kind of fluorine-containing ether bacterium acid amides and tpn, pulls open powder 3% and sodium lignin sulfonate 3% at fluorine ether bacterium acid amides 10%, tpn 40%, white carbon 20%, diatomite 20%, lauryl sodium sulfate 4%.
Composition of the present invention is exclusively used in the multiple oomycetes disease of vegetables such as preventing and treating cucumber downy mildew, early blight of tomato, tomato late blight, capsicum epidemic disease, potato late blight and downy mildew of garpe and grape, also can also can prevent and treat crop gray mold, leaf spot, powdery mildew, pear scab, fruit white rot of grape, rice sheath blight disease, rice blast, apple anthracnose, ring rot of apple, Leaf Spot Caused by Corynespora cassiicola on Cucumber, cladosporium leaf and fruit mould of tomato and the strawberry fusarium wilts etc. such as vegetables.Present composition bactericidal range is wider, effective than single component bactericidal range, and the synergy of composition is obvious especially, and can delay pathogen to the pesticide resistance of fluorine ether bacterium acid amides.Field experiment shows, improves more than 20% to the preventive and therapeutic effect of disease.
The effect of the phonetic bacterium acid amides of table 1 fluorine and tpn composition field control cucumber downy mildew
The effect of table 2 fluorine ether bacterium acid amides and tpn composition field control downy mildew of garpe
The effect of table 3 fluorine ether bacterium acid amides and tpn composition field control early blight of tomato
The effect of table 4 fluorine ether bacterium acid amides and tpn composition field control gray mold
The effect of the phonetic bacterium acid amides of table 5 fluorine and tpn composition field control rice sheath blight disease
The effect of table 6 fluorine ether bacterium acid amides and tpn composition field control cladosporium leaf and fruit mould of tomato
50% fluorine ether bacterium acid amides wetting powder of the present invention's processing take fluorine ether bacterium acid amides and tpn as active ingredient, 50% tpn wetting powder, 50% fluorine ether bacterium acid amides+tpn wetting powder and 50% fluorine ether bacterium acid amides+tpn wetting powder, two single doses are compared with two composite preparations, composition is under the working concentration of 4000 times of dilutions, the field control cucumber downy mildew, downy mildew of garpe, early blight of tomato, gray mold, the effect of rice sheath blight disease and cladosporium leaf and fruit mould of tomato is all significantly diluted 2000 times preventive effect greater than tpn, show that fluorine ether bacterium acid amides and tpn composition are more suitable for the field control cucumber downy mildew, downy mildew of garpe, early blight of tomato, the multiple oomycetes disease of the vegetables such as tomato late blight and potato late blight also can be prevented and treated the crop gray molds such as vegetables, leaf spot, powdery mildew, pear scab, fruit white rot of grape, rice sheath blight disease, rice blast, apple anthracnose, ring rot of apple, Leaf Spot Caused by Corynespora cassiicola on Cucumber, cladosporium leaf and fruit mould of tomato and strawberry fusarium wilt etc.And can doublely control other disease, can delay pathogen to the pesticide resistance of fluorine ether bacterium acid amides.
The present invention also provides a kind of method of using above-mentioned composition pesticide control cucumber downy mildew, downy mildew of garpe, early blight of tomato, gray mold, rice sheath blight disease, cladosporium leaf and fruit mould of tomato and various plants fungal disease.
The present composition can be processed into and suspending agent, water dispersant and wetting powder according to known method.
Embodiment
The microbicide compositions of a kind of fluorine-containing ether bacterium acid amides of the present invention and tpn, formed by active ingredient and auxiliary material, active ingredient is fluorine ether bacterium acid amides and tpn, and the weight ratio of fluorine ether bacterium acid amides and tpn is 1:4-4:1, and the total content of active ingredient is 10%-60%.
The microbicide compositions of a kind of fluorine-containing ether bacterium acid amides of the present invention and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:3-3:1, and the total content of active ingredient is 20%-50%, and surplus is auxiliary material.
The microbicide compositions of a kind of fluorine-containing ether bacterium acid amides of the present invention and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:2-2:1, and the total content of active ingredient is 40%-50%, and surplus is auxiliary material.
The microbicide compositions of a kind of fluorine-containing ether bacterium acid amides of the present invention and tpn, described auxiliary material be white carbon, diatomite, lauryl sodium sulfate, pull open powder, sodium lignin sulfonate.
The microbicide compositions of a kind of fluorine-containing ether bacterium acid amides of the present invention and tpn, the weight ratio of fluorine ether bacterium acid amides and tpn is 1:4-4:1, the total content of active ingredient is 10%-50%, and auxiliary material is filler 20%-45%, wetting agent 5-15% and dispersant 5-15%.
Percentage of the present invention is weight percentage.Composition of the present invention can have following multiple combination mode, but is not limited to these combinations.
Embodiment:
1, fluorine ether bacterium acid amides 30%, tpn 30%, white carbon 20%, lauryl sodium sulfate 10% and sodium lignin sulfonate 10%.
2, fluorine ether bacterium acid amides 10%, tpn 40%, white carbon 40%, lauryl sodium sulfate 5% and sodium lignin sulfonate 5%.
3, fluorine ether bacterium acid amides 40%, tpn 10%, white carbon 21%, diatomite 19%, lauryl sodium sulfate 5% and sodium lignin sulfonate 5%.
4, fluorine ether bacterium acid amides 10%, tpn 30%, white carbon 20%, diatomite 25%, lauryl sodium sulfate 5% and sodium lignin sulfonate 10%.
5, fluorine ether bacterium acid amides 30%, tpn 10%, white carbon 15%, diatomite 23%, lauryl sodium sulfate 5%, pull open powder 5% and sodium lignin sulfonate 12%.
6, fluorine ether bacterium acid amides 5%, tpn 5%, white carbon 60%, lauryl sodium sulfate 10%, pull open powder 5% and sodium lignin sulfonate 15%.
7, fluorine ether bacterium acid amides 15%, tpn 5%, white carbon 10%, diatomite 40%, lauryl sodium sulfate 15% and sodium lignin sulfonate 15%.
8, fluorine ether bacterium acid amides 10%, tpn 40%, white carbon 20%, diatomite 20%, lauryl sodium sulfate 4%, pull open powder 3% and sodium lignin sulfonate 3%.
9, fluorine ether bacterium acid amides 25%, tpn 25%, white carbon 15%, diatomite 23%, lauryl sodium sulfate 4%, pull open powder 3% and sodium lignin sulfonate 5%.
The preparation method of composition of the present invention gets respectively fluorine ether bacterium acid amides, tpn, white carbon by weight percentage or/and diatomite, lauryl sodium sulfate or/and pull open powder and sodium lignin sulfonate mixes after pulverizing, are made wetting powder.
Claims (7)
1. the microbicide compositions of a fluorine-containing ether bacterium acid amides and tpn, it is characterized in that: formed by active ingredient and auxiliary material, active ingredient is fluorine ether bacterium acid amides and tpn, and the weight ratio of fluorine ether bacterium acid amides and tpn is 1:4-4:1, and the total content of active ingredient is 10%-60%.
2. the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides according to claim 1 and tpn, it is characterized in that: the weight ratio of fluorine ether bacterium acid amides and tpn is 1:3-3:1, and the total content of active ingredient is 20%-50%, and surplus is auxiliary material.
3. the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides according to claim 1 and tpn, it is characterized in that: the weight ratio of fluorine ether bacterium acid amides and tpn is 1:2-2:1, and the total content of active ingredient is 40%-50%, and surplus is auxiliary material.
4. the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides according to claim 1 and tpn is characterized in that: described auxiliary material is white carbon, diatomite, lauryl sodium sulfate, pull open powder, sodium lignin sulfonate.
5. the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides according to claim 1 and tpn, it is characterized in that: the weight ratio of fluorine ether bacterium acid amides and tpn is 1:4-4:1, the total content of active ingredient is 10%-50%, and auxiliary material is filler 20%-45%, wetting agent 5-15% and dispersant 5-15%.
6. according to claim 1, the microbicide compositions of 2 or 3 each described a kind of fluorine-containing ether bacterium acid amides and tpn, it is characterized in that: fluorine ether bacterium acid amides 25%, tpn 25%, white carbon 15%, diatomite 23%, lauryl sodium sulfate 4%, pull open powder 3% and sodium lignin sulfonate 5%.
7. the microbicide compositions of a kind of fluorine-containing ether bacterium acid amides according to claim 1 and tpn is characterized in that: fluorine ether bacterium acid amides 10%, tpn 40%, white carbon 20%, diatomite 20%, lauryl sodium sulfate 4%, pull open powder 3% and sodium lignin sulfonate 3%.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012103632057A CN102845426A (en) | 2012-09-19 | 2012-09-26 | Bactericide combination containing fluorine ether bacteria amide and chlorothalonil |
| CN201310333287.5A CN103355304B (en) | 2012-09-19 | 2013-08-02 | Bactericide composition containing fluoride ether bacteria amide and chlorothalonil |
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| CN201210348801 | 2012-09-19 | ||
| CN201210348801.8 | 2012-09-19 | ||
| CN2012103632057A CN102845426A (en) | 2012-09-19 | 2012-09-26 | Bactericide combination containing fluorine ether bacteria amide and chlorothalonil |
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| CN2012103632057A Pending CN102845426A (en) | 2012-09-19 | 2012-09-26 | Bactericide combination containing fluorine ether bacteria amide and chlorothalonil |
| CN201310333287.5A Active CN103355304B (en) | 2012-09-19 | 2013-08-02 | Bactericide composition containing fluoride ether bacteria amide and chlorothalonil |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104412983A (en) * | 2013-08-28 | 2015-03-18 | 张通 | Efficient bactericidal composition containing fluoride ether bacteria amide |
| CN104412996A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Efficient pesticide composition containing fluoride ether bacteria amide |
| CN104412990A (en) * | 2013-09-03 | 2015-03-18 | 张通 | High-efficiency bactericidal composition containing fluoride ether bacterium amide |
| CN104413019A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Pesticide composition containing fluoride ether bacterium amide |
| CN104413047A (en) * | 2013-09-03 | 2015-03-18 | 张通 | Pesticide composition containing fluoride ether bacterium amide and triazoles |
| CN104655763A (en) * | 2015-03-12 | 2015-05-27 | 崔淑华 | GC-NCI-MS (gas chromatography-negative chemical ionization-mass spectrometry) determination method of residual amount of fluoride ether bacterium amide |
| CN104678023A (en) * | 2015-03-12 | 2015-06-03 | 崔淑华 | Method for measuring fluoroether bacterial amide residues in fruit and vegetable by GC-MS/MS |
| CN105994318A (en) * | 2016-05-26 | 2016-10-12 | 南京华洲药业有限公司 | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite |
| CN105994281A (en) * | 2016-05-26 | 2016-10-12 | 南京华洲药业有限公司 | Antibacterial composition containing C15H8ClF7N2O2 and bupirimate as well as application of antibacterial composition |
| CN104412982B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of compound highly effective bactericidal composition of fluorine-containing ether bacterium amide |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104655764B (en) * | 2015-03-12 | 2016-07-06 | 崔淑华 | The LC-MS/MS assay method of fluorine ether bacterium amide residual in a kind of fruit and vegerable |
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| CN102086173A (en) * | 2010-09-07 | 2011-06-08 | 唐剑峰 | Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing |
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| CN102086173A (en) * | 2010-09-07 | 2011-06-08 | 唐剑峰 | Tetrafluorophenoxy nicotinamide compound as well as preparation method and application thereof for sterilizing |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104412983B (en) * | 2013-08-28 | 2018-08-03 | 张通 | A kind of efficient bactericidal composite of fluorine-containing ether bacterium amide |
| CN104412983A (en) * | 2013-08-28 | 2015-03-18 | 张通 | Efficient bactericidal composition containing fluoride ether bacteria amide |
| CN104412996B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of high-efficient pesticide composition of fluorine-containing ether bacterium amide |
| CN104412996A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Efficient pesticide composition containing fluoride ether bacteria amide |
| CN104413019A (en) * | 2013-09-02 | 2015-03-18 | 张通 | Pesticide composition containing fluoride ether bacterium amide |
| CN104413019B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of composition pesticide of fluorine-containing ether bacterium amide |
| CN104412982B (en) * | 2013-09-02 | 2018-08-03 | 张通 | A kind of compound highly effective bactericidal composition of fluorine-containing ether bacterium amide |
| CN104413047A (en) * | 2013-09-03 | 2015-03-18 | 张通 | Pesticide composition containing fluoride ether bacterium amide and triazoles |
| CN104412990A (en) * | 2013-09-03 | 2015-03-18 | 张通 | High-efficiency bactericidal composition containing fluoride ether bacterium amide |
| CN104412990B (en) * | 2013-09-03 | 2018-10-26 | 张通 | A kind of bactericidal composition of fluorine-containing ether bacterium amide |
| CN104655763B (en) * | 2015-03-12 | 2016-08-24 | 崔淑华 | A kind of GC-NCI-MS assay method of fluorine ether bacterium amide residual quantity |
| CN104678023B (en) * | 2015-03-12 | 2016-08-17 | 崔淑华 | A kind of GC-MS/MS measures the method for fluorine ether bacterium amide residual in fruit and vegerable |
| CN104678023A (en) * | 2015-03-12 | 2015-06-03 | 崔淑华 | Method for measuring fluoroether bacterial amide residues in fruit and vegetable by GC-MS/MS |
| CN104655763A (en) * | 2015-03-12 | 2015-05-27 | 崔淑华 | GC-NCI-MS (gas chromatography-negative chemical ionization-mass spectrometry) determination method of residual amount of fluoride ether bacterium amide |
| CN105994318A (en) * | 2016-05-26 | 2016-10-12 | 南京华洲药业有限公司 | Sterilizing composite containing C15H8ClF7N2O2 and captan as well as application of sterilizing composite |
| CN105994281A (en) * | 2016-05-26 | 2016-10-12 | 南京华洲药业有限公司 | Antibacterial composition containing C15H8ClF7N2O2 and bupirimate as well as application of antibacterial composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103355304A (en) | 2013-10-23 |
| CN103355304B (en) | 2015-03-11 |
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