CN102653189B - Thermal transfer ribbon for edge-pressing printer and preparation method thereof - Google Patents
Thermal transfer ribbon for edge-pressing printer and preparation method thereof Download PDFInfo
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- CN102653189B CN102653189B CN201210110217.9A CN201210110217A CN102653189B CN 102653189 B CN102653189 B CN 102653189B CN 201210110217 A CN201210110217 A CN 201210110217A CN 102653189 B CN102653189 B CN 102653189B
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- Prior art keywords
- wax
- thermal transfer
- adhesive
- release layer
- transfer ribbon
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000011248 coating agent Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000000853 adhesive Substances 0.000 claims abstract description 23
- 230000001070 adhesive effect Effects 0.000 claims abstract description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000006229 carbon black Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920006267 polyester film Polymers 0.000 claims abstract description 4
- 239000001993 wax Substances 0.000 claims description 37
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 30
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 30
- 210000002469 basement membrane Anatomy 0.000 claims description 14
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 12
- -1 fatty acid ester Chemical class 0.000 claims description 10
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 10
- MKYLOMHWHWEFCT-UHFFFAOYSA-N Manthidine Natural products C1C2=CC=3OCOC=3C=C2C2C3=CC(OC)C(O)CC3N1C2 MKYLOMHWHWEFCT-UHFFFAOYSA-N 0.000 claims description 4
- SNFRINMTRPQQLE-JQWAAABSSA-N Montanin Chemical compound O[C@H]([C@@]1(CO)O[C@H]1[C@H]1[C@H]2O3)[C@]4(O)C(=O)C(C)=C[C@H]4[C@]11OC3(CCCCCCCCCCC)O[C@@]2(C(C)=C)C[C@H]1C SNFRINMTRPQQLE-JQWAAABSSA-N 0.000 claims description 4
- SNFRINMTRPQQLE-OFGNMXNXSA-N Montanin Natural products O=C1[C@@]2(O)[C@@H](O)[C@@]3(CO)O[C@H]3[C@@H]3[C@H]4[C@@]5(C(=C)C)O[C@](CCCCCCCCCCC)(O4)O[C@@]3([C@H](C)C5)[C@@H]2C=C1C SNFRINMTRPQQLE-OFGNMXNXSA-N 0.000 claims description 4
- QTZPBQMTXNEKRX-UHFFFAOYSA-N Voacristine pseudoindoxyl Natural products N1C2=CC=C(OC)C=C2C(=O)C21CCN(C1)C3C(C(C)O)CC1CC32C(=O)OC QTZPBQMTXNEKRX-UHFFFAOYSA-N 0.000 claims description 4
- 235000013871 bee wax Nutrition 0.000 claims description 4
- 239000012166 beeswax Substances 0.000 claims description 4
- 239000004203 carnauba wax Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 239000012170 montan wax Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- 239000004170 rice bran wax Substances 0.000 claims description 4
- 235000019384 rice bran wax Nutrition 0.000 claims description 4
- 239000002023 wood Substances 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001470 polyketone Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 238000007639 printing Methods 0.000 abstract description 7
- 238000010023 transfer printing Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000001394 metastastic effect Effects 0.000 description 1
- 206010061289 metastatic neoplasm Diseases 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention relates to a thermal transfer ribbon, in particular to a thermal transfer ribbon for an edge-pressing printer and a preparation method thereof. The thermal transfer printing belt for the edge-pressing printer sequentially comprises an ink layer, a release layer, a base film and a back coating from top to bottom, wherein the release layer is composed of wax and an adhesive in a mass ratio of 10-40:1, the base film is a polyester film, the back coating is acrylic acid-organic silicon resin, and the ink layer is composed of 10-20% of wax, 15-30% of carbon black and 40-70% of adhesive in percentage by mass. The thermal transfer ribbon for the edge-pressing printer can achieve the effect of rapid transfer, can meet the requirement of the wear resistance of printed matters and realize high-speed printing.
Description
Technical field
The present invention relates to a kind of thermal transfer ribbon, be specifically related to a kind of thermal transfer ribbon for limit pressure type printer and preparation method thereof.
Background technology
In recent years, along with hot transfer printing print day by day universal, increasing industry adopts the information of the product that the mode of hot transfer printing marks, for example, the printing modes that adopt hot transfer printing of date of manufacture, product batch number etc. more, but this type of printing is the external packing assigned address at product mostly to make marks, and the content of printing is very limited.Now, market circulation is at most the printer of flat-crushing type, various small-sized, technical grade, this class printer is when carrying out print out task, and label paper and carbon ribbon are synchronous operation, situation about need to print the whole labels page of needs like this, no problem, but to only printing the seldom situation of content in external packing, especially as food service industry, when the date of manufacture is printed in the external packing of product, still adopt in such a way, will cause the waste of carbon ribbon.
Certainly for this situation, can adopt the mode of hot stamping stamp, but hot stamping stamp needs mould, the content of printing is like this just very limited, when content changes, need to make new mould, the digital epoch now, if can print electronic tag, not only can make print What abundanter, change is got up also more quick.
A class printer different from flat-crushing type printer is limit pressure type printer, the carbon ribbon of this type of printer and the wrap-up of label are to control separately, when selecting carbon ribbon to save function, no matter label paper operation how long, carbon ribbon only just moves when carrying out print out task, save greatly carbon ribbon, particularly printed some chromatography labels.The printhead of limit pressure type printer is compared with flat-crushing type, more keeps to the side, and when carrying out print out task, carbon ribbon and label disengaging time interval are ofer short duration, and therefore, common heat transfer printing carbon tape, on this class printer, can not reach good transfer printing effect.
Summary of the invention
The object of the present invention is to provide a kind of thermal transfer ribbon for limit pressure type printer and preparation method thereof.
The present invention is by the following technical solutions:
A kind of thermal transfer ribbon for limit pressure type printer, be followed successively by ink layer, release layer, basement membrane and back coating from top to bottom, release layer is comprised of wax and the adhesive of mass ratio 10-40:1, basement membrane is polyester film, back coating is acrylic acid-organic siliconresin, and ink layer is comprised of the adhesive of the wax of mass percent 10-20%, the carbon black of 15-30% and 40-70%.
The wax of release layer is two kinds of mixing in Brazil wax, candelila wax, rice bran wax, montan wax, montanin wax, wood wax oil, beeswax, fatty acid ester.
The adhesive of release layer is ethylene-vinyl acetate copolymer, and the VA content of ethylene-vinyl acetate copolymer is 28 ~ 60%, and the melt index (MI) of ethylene-vinyl acetate copolymer is 2 ~ 300g/10min.
The adhesive of ink layer is polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, chlorinated polypropylene, ethylene-vinyl acetate copolymer, Petropols, abietic resin, epoxy resin, polyurethane, polystyrene, polyamide or polyketone resin; The wax of ink layer is Brazil wax, candelila wax, rice bran wax, montan wax, montanin wax, wood wax oil, beeswax or fatty acid ester.
The thickness of ink layer is that the thickness of 1-3 μ m, release layer is that the thickness of 0.5-2 μ m, basement membrane is that the thickness of 3-10 μ m and back coating is 0.01-0.1 μ m.
The preparation method who is used for the thermal transfer ribbon of limit pressure type printer: comprise the following steps: the preparation of (1) back coating: acrylic acid-organic siliconresin is dissolved with butanone, then in the coating of the back side of basement membrane, be coated with rear 90 ℃ of oven dry, controlling back coating thickness is 0.01-0.1 μ m; (2) preparation of release layer: wax and adhesive are dissolved in toluene and butanone, then, in the coating of the front of basement membrane, are coated with rear 75 ℃ of oven dry, control release layer thickness 1-3 μ m; (3) preparation of ink layer: wax, carbon black and adhesive are dissolved in toluene and butanone, are then coated with on release layer, be coated with rear 75 ℃ of oven dry, controlling ink film thickness is 1-3 μ m.
In step (1), the mass ratio of acrylic acid-organic siliconresin and butanone is 9:1; Toluene in step (2): butanone: the mass ratio of wax+adhesive is 8:2:3; Toluene in step (3): butanone: the mass ratio of wax+carbon black+adhesive is 2:2:1.
In release layer of the present invention, main component is wax, wax has lower solubility in coating solvent, otherwise can be dissolved in the solvent of ink layer, the wax of selecting is the mixture of the wax of two kinds of different melting points, so not only can reach the effect of fast transfer, can also meet the requirement of printed matter wearability, the thermal transfer ribbon providing just can be used on the printer of limit pressure type printhead, realizes flying print simultaneously.
In addition, in release layer, contain a small amount of adhesive, increase the viscosity of release layer, prevent from mixing with ink layer, in the present invention, release layer is comprised of wax and adhesive, in the process of coating, release layer and ink layer can not mix, and between release layer and ink layer, just can form obvious boundary, and release layer can keep certain thickness, the metastatic that can effectively improve ink, reaches transferred image clearly.
The specific embodiment
Below, for the thermal transfer ribbon embodiment of the present invention for limit pressure type printer, be followed successively by ink layer, release layer, basement membrane and back coating from top to bottom, basement membrane is polyester film, and the composition of ink layer, release layer and back coating is as follows respectively:
Resin in embodiment 1-16 in back coating refers to acrylic acid-organic siliconresin, and the solid material of release layer refers to the gross mass of wax and EVA, and the solid material of ink layer refers to the gross mass of adhesive, carbon black and wax; The VA content of ethylene-vinyl acetate copolymer (EVA) is 28 ~ 60%, and the melt index (MI) of ethylene-vinyl acetate copolymer is 2 ~ 300g/10min.
The thermal transfer ribbon of embodiment 1-16 comprises the following steps while preparing: the preparation of (1) back coating: acrylic acid-organic siliconresin is dissolved with butanone, then, in the coating of the back side of basement membrane, be coated with rear 90 ℃ of oven dry, controlling back coating thickness is 0.01-0.1 μ m; (2) preparation of release layer: wax and adhesive are dissolved in toluene and butanone, then, in the coating of the front of basement membrane, are coated with rear 75 ℃ of oven dry, control release layer thickness 1-3 μ m; (3) preparation of ink layer: wax, carbon black and adhesive are dissolved in toluene and butanone, are then coated with on release layer, be coated with rear 75 ℃ of oven dry, controlling ink film thickness is 1-3 μ m.
evaluation method:
To above embodiment, adopt following evaluation method to evaluate the performance of thermal transfer ribbon of the present invention.The definition of transferred image is adopted to AVERY 6404 limit pressure type printers, respectively under 8IPS, 16IPS, the printing definition evaluation of having carried out on art paper, PET label paper and 3 kinds of different label papers of PP label paper.Wearability is under the loading of 800g, with the speed of 1 time per second, adopts steel ball and two kinds of modes of carton to rub, and when image is damaged, records number of times, take and surpasses 100 times as qualified.The thermal transfer ribbon that the final the present invention of employing makes, not only transferred image is clear, but also wear-resisting.
Claims (7)
1. the thermal transfer ribbon for limit pressure type printer, comprise: be followed successively by ink layer, release layer, basement membrane and back coating from top to bottom, basement membrane is polyester film, back coating is acrylic acid-organic siliconresin, it is characterized in that: release layer is comprised of wax and the adhesive of mass ratio 10-40:1, and ink layer is comprised of the adhesive of the wax of mass percent 10-20%, the carbon black of 20-25% and 55-70%.
2. the thermal transfer ribbon for limit pressure type printer as claimed in claim 1, is characterized in that: the wax of release layer is two kinds of mixing in Brazil wax, candelila wax, rice bran wax, montan wax, montanin wax, wood wax oil, beeswax, fatty acid ester.
3. the thermal transfer ribbon for limit pressure type printer as claimed in claim 1 or 2, it is characterized in that: the adhesive of release layer is ethylene-vinyl acetate copolymer, the VA content of ethylene-vinyl acetate copolymer is 28 ~ 60%, and the melt index (MI) of ethylene-vinyl acetate copolymer is 2 ~ 300g/10min.
4. the thermal transfer ribbon for limit pressure type printer as claimed in claim 1, is characterized in that: the adhesive of ink layer is polyethylene, polypropylene, polyvinyl chloride, polyvinyl acetate, chlorinated polypropylene, ethylene-vinyl acetate copolymer, Petropols, abietic resin, epoxy resin, polyurethane, polystyrene, polyamide or polyketone resin; The wax of ink layer is Brazil wax, candelila wax, rice bran wax, montan wax, montanin wax, wood wax oil, beeswax or fatty acid ester.
5. the thermal transfer ribbon for limit pressure type printer as claimed in claim 1, is characterized in that: the thickness of ink layer is that the thickness of 1-3 μ m, release layer is that the thickness of 0.5-2 μ m, basement membrane is that the thickness of 3-10 μ m and back coating is 0.01-0.1 μ m.
6. the preparation method of the thermal transfer ribbon for limit pressure type printer claimed in claim 1: comprise the following steps: the preparation of (1) back coating: acrylic acid-organic siliconresin is dissolved with butanone, then in the coating of the back side of basement membrane, be coated with rear 90 ℃ of oven dry, controlling back coating thickness is 0.01-0.1 μ m; (2) preparation of release layer: wax and adhesive are dissolved in toluene and butanone, then, in the coating of the front of basement membrane, are coated with rear 75 ℃ of oven dry, control release layer thickness 1-3 μ m; (3) preparation of ink layer: wax, carbon black and adhesive are dissolved in toluene and butanone, are then coated with on release layer, be coated with rear 75 ℃ of oven dry, controlling ink film thickness is 1-3 μ m.
7. the preparation method of the thermal transfer ribbon for limit pressure type printer as claimed in claim 6, is characterized in that: in step (1), the mass ratio of acrylic acid-organic siliconresin and butanone is 9:1; Toluene in step (2): butanone: the mass ratio of wax+adhesive is 8:2:3; Toluene in step (3): butanone: the mass ratio of wax+carbon black+adhesive is 2:2:1.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210110217.9A CN102653189B (en) | 2012-04-16 | 2012-04-16 | Thermal transfer ribbon for edge-pressing printer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210110217.9A CN102653189B (en) | 2012-04-16 | 2012-04-16 | Thermal transfer ribbon for edge-pressing printer and preparation method thereof |
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| Publication Number | Publication Date |
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| CN102653189A CN102653189A (en) | 2012-09-05 |
| CN102653189B true CN102653189B (en) | 2014-09-10 |
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| CN201210110217.9A Active CN102653189B (en) | 2012-04-16 | 2012-04-16 | Thermal transfer ribbon for edge-pressing printer and preparation method thereof |
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| CN103434281B (en) * | 2013-08-01 | 2015-12-02 | 河南卓立膜材料股份有限公司 | Three-primary-color thermal transfer photo carbon ribbon and preparation process thereof |
| CN103587259A (en) * | 2013-11-13 | 2014-02-19 | 河南卓立膜材料股份有限公司 | Thermal transfer ribbon for printing edge crushing resin base bar code and preparing method thereof |
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| CN106183490B (en) * | 2016-06-29 | 2019-03-15 | 河南卓立膜材料股份有限公司 | Thermal transfer printing ribbon with paper as ribbon base and preparation method thereof |
| CN106147410A (en) * | 2016-07-11 | 2016-11-23 | 鹏码实业(上海)有限公司 | A kind of heat transfer colour ribbon of printable high temperature resistant trace and preparation method thereof |
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| CN108583032B (en) * | 2018-04-16 | 2020-10-09 | 南京爱宝文仪有限公司 | Carbon ribbon for edge-pressing printer and manufacturing method thereof |
| CN110193454A (en) * | 2019-04-26 | 2019-09-03 | 深圳市新伟林科技有限公司 | A kind of preparation method of enhanced wax-based ribbon |
| CN110183914B (en) * | 2019-05-14 | 2021-08-17 | 浙江天成工程设计有限公司 | Back coating paint for thermal transfer printing film carrier |
| CN110735358B (en) * | 2019-10-24 | 2022-06-03 | 焦作卓立膜材料股份有限公司 | Film-coated thermal sensitive paper and processing technology thereof |
| CN113442609A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing resin-based carbon ribbon and preparation method thereof |
| CN114261223B (en) * | 2021-12-24 | 2023-03-28 | 湖南鼎一致远科技发展有限公司 | Solvent-resistant and wear-resistant resin carbon ribbon for label printing and preparation method thereof |
| CN114290829A (en) * | 2021-12-30 | 2022-04-08 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing resin thermal transfer ribbon with release layer and preparation method |
| CN115503368A (en) * | 2022-10-12 | 2022-12-23 | 湖南鼎一致远科技发展有限公司 | High-temperature and high-humidity resistant thermal transfer ribbon and preparation method thereof |
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Address after: 454000 Shenzhou Road, Jiaozuo high tech Zone, Henan, No. 2758 Applicant after: Henan Zhuoli Imaging Technology Co., Ltd. Address before: 454000 Shenzhou Road, Jiaozuo high tech Zone, Henan, No. 2758 Applicant before: Zhuoli Thermoprinting Material Co., Ltd., Jianzuo City |
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Effective date of registration: 20191206 Address after: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province (in the hospital of Henan Zhuoli membrane materials Co., Ltd.) Patentee after: Jiaozuo Zhuoli membrane materials Co., Ltd Address before: 454000 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo Patentee before: Henan Zhuoli Imaging Technology Co., Ltd. |
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Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli film material Co.,Ltd. Address before: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province, 454000 Patentee before: Jiaozuo Zhuoli membrane materials Co.,Ltd. |
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