CN102616024B - Heat-transfer wax-based carbon ribbon - Google Patents
Heat-transfer wax-based carbon ribbon Download PDFInfo
- Publication number
- CN102616024B CN102616024B CN201210085688.9A CN201210085688A CN102616024B CN 102616024 B CN102616024 B CN 102616024B CN 201210085688 A CN201210085688 A CN 201210085688A CN 102616024 B CN102616024 B CN 102616024B
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- Prior art keywords
- wax
- coating
- solvent
- base material
- printing
- Prior art date
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract description 5
- 229910052799 carbon Inorganic materials 0.000 title abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 61
- 238000000576 coating method Methods 0.000 claims abstract description 61
- 239000000463 material Substances 0.000 claims abstract description 29
- 239000002904 solvent Substances 0.000 claims abstract description 28
- 239000002270 dispersing agent Substances 0.000 claims abstract description 22
- 239000000049 pigment Substances 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000001993 wax Substances 0.000 claims description 36
- 229920006387 Vinylite Polymers 0.000 claims description 18
- 239000004203 carnauba wax Substances 0.000 claims description 18
- 238000007670 refining Methods 0.000 claims description 18
- 229920000728 polyester Polymers 0.000 claims description 15
- 229920002799 BoPET Polymers 0.000 claims description 14
- 239000005041 Mylar™ Substances 0.000 claims description 14
- 239000004925 Acrylic resin Substances 0.000 claims description 12
- 229920000178 Acrylic resin Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 3
- 239000011247 coating layer Substances 0.000 claims description 2
- 238000007639 printing Methods 0.000 abstract description 19
- 239000000853 adhesive Substances 0.000 abstract description 9
- 230000001070 adhesive effect Effects 0.000 abstract description 9
- 238000010023 transfer printing Methods 0.000 abstract description 6
- 239000000969 carrier Substances 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 6
- 230000003678 scratch resistant effect Effects 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000002469 basement membrane Anatomy 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention belongs to the technical field of thermal transfer printing materials, and particularly relates to a thermal transfer wax-based carbon ribbon. The transfer printing wax-based carbon belt comprises a back coating, a base material, a release coating on the base material and an ink coating on the release coating, wherein the ink coating comprises the following components in percentage by weight: 1 to 10.3 percent of resin, 29 to 34 percent of wax, 9 to 10 percent of pigment, 0.7 to 0.8 percent of dispersant and 51 to 55 percent of solvent. The thermal transfer wax-based carbon ribbon provided by the invention has the advantages of high transfer rate, good adhesive force, scratch resistance and no adhesion, and can be suitable for thermal transfer bar code printers with various speeds, wider printing temperature and different printing carriers.
Description
Technical field
The invention belongs to hot transfer printing printed material technical field, particularly the hot transfer wax ribbon of one.
Background technology
Heat transfer printing carbon tape and bar code printer support the use, and are widely used in sign and the explanatory note of lot number in logistics, electronics, food and commodity industry.Its structure forms primarily of four parts, back coating, base material, release layer, ink coating.Being transferred to completely after requiring its ink coating to be heated at a proper temperature during use undertakes the printing of on carrier, and ink coating has adaptability widely to carrier of undertaking the printing of, and requires that adhesive force is good, scratch-resistant, adhesion.Being in great demand to wax ribbon on domestic market, but current cerul product is not well positioned to meet above-mentioned requirement.
Summary of the invention
The object of the present invention is to provide a kind of hot transfer wax ribbon, can well meet the requirement of market to hot transfer wax ribbon, can be transferred to completely after being heated and undertake the printing of on carrier, layer of ink has adaptability widely to carrier of undertaking the printing of, and adhesive force is good, scratch-resistant.
The technical solution used in the present invention is as follows:
A kind of hot transfer wax ribbon, be made up of the release coating above back coating, base material and base material, the ink coating above release coating, described ink coating is made up of following component by weight percentage: resin 1-10.3%, wax class 29-34%, pigment 9-10%, dispersant 0.7-0.8% and solvent 51-55%.
Described weight resin percentage composition is: vinylite 0-3%, Petropols 1-6%, acrylic resin or mylar 0-1.3%.
Described wax class weight percent is composed as follows: palm wax 16-17%, full refining wax 13-17%.
Preferably, described ink coating is composed as follows: vinylite 2.5%, Petropols 3.9%, acrylic resin 1%, palm wax 16.5%, full refining wax 13.2%, pigment 9.6%, dispersant 0.7%, solvent 52.6%, and described ink coating thickness is 2.2-2.8 μm preferably 2.5 μm.
The weight percent of described release coating consists of: mylar 2-3%, solvent 97-98%, and release coating layer thickness is 0.05-0.06 μm.
Described back coating and release coating lay respectively at the two sides of base material, and the weight percent of described back coating consists of: organosilicon 3-3.5%, solvent 96.5-97%.The thickness of described back coating can be ignored.
Described base material is polyester material, and thickness is 4.2-4.5 μm.
Dispersant major function in ink layer component is the scattering problem solving pigment, and granules of pigments is scattered in system equably.
Described hot transfer wax ribbon is conventionally prepared, and has no special requirements.
Hot transfer wax ribbon provided by the invention, ink coating can be transferred to after applicable energy level is heated undertakes the printing of (transferring rate >95%) on carrier, ink coating has adaptability widely to carrier of undertaking the printing of, and can realize high-quality transfer printing on the carriers of undertaking the printing of such as non-coated paper, coated paper, heat-transferring printing paper; Adhesive force is good, scratch-resistant, adhesion, can be applicable to various speed (2ips, 4ips, 6ips), more extensively print the heat transfer type bar code printer of energy level (the printing gear of bar code printer, generally from 0 to 30, energy level scope of the present invention can be 14-28).Ink coating and release coating have good adhesion simultaneously; Its release coating has good intermediary performance, is less than the adhesive force with ink coating with the adhesive force of base material, and transferability is fine, and transfer printing character edge is neat, has good flexibility.
The present invention, relative to prior art, has following advantage:
Hot transfer wax ribbon provided by the invention, transferring rate is high, and adhesive force is good, scratch-resistant, adhesion, can be applicable to various speed, more extensively print energy level and difference and to undertake the printing of the heat transfer type bar code printer of carrier.
Detailed description of the invention
With specific embodiment, technical scheme of the present invention is described below, but protection scope of the present invention is not limited thereto:
Embodiment 1
Base material is polyester (PET basement membrane), and thickness is 4.5 μm;
Every 100g is composed as follows for ink coating:
| Dispersant | 0.8 |
| Palm wax | 16.5 |
| Vinylite | 2.5 |
| Pigment | 9.6 |
| Full refining wax | 16.8 |
| Petropols | 1.2 |
| Solvent | 52.6 |
Every 100g is composed as follows for release coating:
| Mylar | 2g |
| Solvent | 98g |
Every 100g is composed as follows for back coating:
| Organosilicon | 3g |
| Solvent | 97g |
Vinylite selects the VA-600 of Hunan petrochemistry company, Petropols select the A-1100 of Heng Shi company, the Carnauba-3 of Foncepi company selected by palm wax, the AP-1000 of Heng Shi company selected by full refining wax, the BeBlack6316F1 of Yong Feng company selected by pigment, dispersant selects A4300 and the 1005(A4300:1005 mass ratio=5:2 of refined rich color science and technology), solvent uses toluene.The ES-110 of SK chemical industry selected by mylar.The KR-605 of Ke Lin company selected by organosilicon.
By back coating compositing formula, make mixed solution, by coating apparatus at substrate backside coating film forming, dry under 105 DEG C of conditions.Make hybrid resin solvent by release coating formula again, be coated into by coating apparatus the film that thickness is 0.05-0.06 μm, dry under 105 DEG C of conditions.According to ink layer formula, first dispersant heating for dissolving in a solvent, other components are added again by the order of above-mentioned formula, by grinder, system is uniformly dispersed, be coated in release coating by coating machine, dry at the temperature of 105 DEG C, its thickness is 2.5 μm, forms hot transfer wax ribbon.
Embodiment 2
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.8 |
| Palm wax | 16.5 |
| Vinylite | 2.5 |
| Pigment | 9.6 |
| Full refining wax | 14.4 |
| Petropols | 2.9 |
| Mylar | 0.7 |
| Solvent | 52.6 |
Wherein the ES-812 of SK chemical industry selected by mylar; All the other material therefors are identical with embodiment 1.By as above filling a prescription, first dispersant heating for dissolving in a solvent, add other components in the order by above-mentioned formula, by grinder, system is uniformly dispersed, is coated in release coating by coating machine, dry at the temperature of 105 DEG C, its thickness is 2.5 μm, forms hot transfer wax ribbon.
The composition of release coating, back coating and preparation method are with embodiment 1.
Embodiment 3
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 2.5g |
| Petropols | 3.9g |
| Mylar | 1.0g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 4
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.8g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 14.4g |
| Vinylite | 0g |
| Petropols | 4.9g |
| Mylar | 1.2g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 5
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 1.3g |
| Petropols | 4.9g |
| Mylar | 1.2g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 6
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.8g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 1.3g |
| Petropols | 6.0g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 7
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 14.4g |
| Vinylite | 1.3g |
| Petropols | 3.9g |
| Mylar | 1.0g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 8
Base material is polyester, and thickness is 4.5 μm
Ink coating:
| Dispersant | 0.7g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 1.3g |
| Petropols | 5.5g |
| Mylar | 0.6g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 9
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.8g |
| Pigment | 9.6g |
| Palm wax | 16.5g |
| Full refining wax | 13.2g |
| Vinylite | 2.5g |
| Petropols | 4.3g |
| Mylar | 0.5g |
| Solvent | 52.6g |
Other are with embodiment 1.
Embodiment 10
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 1.3g |
| Pigment | 9.6g |
| Full refining wax | 13.2g |
| Petropols | 4.9g |
| Acrylic resin | 1.2g |
| Solvent | 52.6g |
Wherein acrylic resin selects the 13LP of permanent stone; Other are with embodiment 1.
Embodiment 11
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 1.3g |
| Pigment | 9.6g |
| Full refining wax | 13.2g |
| Petropols | 5.5g |
| Acrylic resin | 0.6g |
| Solvent | 52.6g |
Wherein acrylic resin selects the 13LP of permanent stone, and other are with embodiment 1.
Embodiment 12
Base material is polyester, and thickness is 4.5 μm
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 1.3g |
| Pigment | 9.6g |
| Full refining wax | 14.4g |
| Petropols | 3.9g |
| Acrylic resin | 1.0g |
| Solvent | 52.6g |
Wherein acrylic resin selects the CPP of permanent stone, and other are with embodiment 1.
Embodiment 13
Base material is polyester, and thickness is 4.5 μm;
Ink coating:
| Dispersant | 0.7g |
| Palm wax | 16.5g |
| Vinylite | 2.5g |
| Pigment | 9.6g |
| Full refining wax | 13.2g |
| Petropols | 3.9g |
| Acrylic resin | 1.0g |
| Solvent | 52.6g |
Wherein acrylic resin selects the CPP of permanent stone, and other are with embodiment 1.
effect
The hot transfer wax ribbon that above-described embodiment 1-13 is manufactured observe its transferring effect, with to undertake the printing of the adhesive force of paper and the adaptability to carrier of undertaking the printing of.
Transferring effect is that the transferring rate of ink layer realizes, and is divided into three phases by following benchmark, >95% → A, 95-90% → B, <90% → C by after printing.
Adhesive force is the bistrique with loading 800 grams, rubs 50 times, observe the damaged area of transferred ink layer to paper of undertaking the printing of, with without breakage → A, damaged fewer than half → B, complete breakage → C evaluate damaged area.
The adaptability of carrier of undertaking the printing of does printing test with dissimilar paper of undertaking the printing of, and the rank of its applicability transferring rate is evaluated, >95% → A, 95-90% → B, <90% → C.
Above-described embodiment is the preferred embodiment of the present invention, but embodiments of the present invention are not restricted to the described embodiments, and the change that other any the present invention of not deviating from does all should be equivalent substitute mode, is included within protection scope of the present invention.
Claims (2)
1. a hot transfer wax ribbon, be made up of the release coating above back coating, base material and base material, the ink coating above release coating, it is characterized in that, described ink coating is made up of following component by weight percentage: resin 1-10.3%, wax class 29-34%, pigment 9-10%, dispersant 0.7-0.8% and solvent 51-55%;
Described weight resin percentage composition is: vinylite 0-3%, Petropols 1-6%, acrylic resin or mylar 0-1.3%;
Described wax class weight percent is composed as follows: palm wax 16-17%, full refining wax 13-17%;
The weight percent of described release coating consists of: mylar 2-3%, solvent 97-98%, and release coating layer thickness is 0.05-0.06 μm;
The weight percent of described back coating consists of: organosilicon 3-3.5%, solvent 96.5-97%;
Described base material is polyester material, and thickness is 4.2-4.5 μm.
2. hot transfer wax ribbon as claimed in claim 1, it is characterized in that, described ink coating is composed as follows: vinylite 2.5%, Petropols 3.9%, acrylic resin 1%, palm wax 16.5%, full refining wax 13.2%, pigment 9.6%, dispersant 0.7%, solvent 52.6%; Ink coating thickness is 2.2-2.8 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210085688.9A CN102616024B (en) | 2012-03-28 | 2012-03-28 | Heat-transfer wax-based carbon ribbon |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210085688.9A CN102616024B (en) | 2012-03-28 | 2012-03-28 | Heat-transfer wax-based carbon ribbon |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102616024A CN102616024A (en) | 2012-08-01 |
| CN102616024B true CN102616024B (en) | 2015-06-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210085688.9A Active CN102616024B (en) | 2012-03-28 | 2012-03-28 | Heat-transfer wax-based carbon ribbon |
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| Country | Link |
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| CN (1) | CN102616024B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105034621A (en) * | 2015-09-15 | 2015-11-11 | 河南卓立膜材料股份有限公司 | Magnetic anti-counterfeiting thermal transfer ribbon |
| CN110193454A (en) * | 2019-04-26 | 2019-09-03 | 深圳市新伟林科技有限公司 | A kind of preparation method of enhanced wax-based ribbon |
| CN113442609A (en) * | 2020-03-27 | 2021-09-28 | 湖南鼎一致远科技发展有限公司 | Thermal transfer printing resin-based carbon ribbon and preparation method thereof |
| CN111907235A (en) * | 2020-08-07 | 2020-11-10 | 广州中码科技股份有限公司 | Special bar code printing thermal transfer ribbon and preparation method thereof |
| CN113263850B (en) * | 2021-05-13 | 2022-11-01 | 刘晨 | Latex ink digital printing film material for improving washing fading phenomenon and preparation method thereof |
| CN114312063B (en) * | 2021-12-23 | 2023-12-19 | 湖南鼎一致远科技发展有限公司 | Thermal transfer resin ribbon suitable for traffic sign board, preparation method thereof and traffic sign board |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052450A (en) * | 1990-11-29 | 1991-06-26 | 天津光电通信公司 | At thermosensitive ribbon for transfer print surface of non-absorbent matter |
| CN1351933A (en) * | 2000-11-07 | 2002-06-05 | 潘浦敦 | Heat transfer colour ribbon |
| CN1485217A (en) * | 2002-09-29 | 2004-03-31 | 张振宇 | Blanching pattern mark carbon band |
-
2012
- 2012-03-28 CN CN201210085688.9A patent/CN102616024B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1052450A (en) * | 1990-11-29 | 1991-06-26 | 天津光电通信公司 | At thermosensitive ribbon for transfer print surface of non-absorbent matter |
| CN1351933A (en) * | 2000-11-07 | 2002-06-05 | 潘浦敦 | Heat transfer colour ribbon |
| CN1485217A (en) * | 2002-09-29 | 2004-03-31 | 张振宇 | Blanching pattern mark carbon band |
Non-Patent Citations (1)
| Title |
|---|
| 热转印色带的研制;王永明;《电子计算机与外部设备》;19980415;第22卷(第2期);第16-17，2页 * |
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| Publication number | Publication date |
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| CN102616024A (en) | 2012-08-01 |
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Address after: 454000 Shenzhou Road, Jiaozuo high tech Zone, Henan, No. 2758 Applicant after: Henan Zhuoli Imaging Technology Co., Ltd. Address before: 454000 Shenzhou Road, Jiaozuo high tech Zone, Henan, No. 2758 Applicant before: Zhuoli Thermoprinting Material Co., Ltd., Jianzuo City |
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Free format text: CORRECT: APPLICANT; FROM: ZHUOLI THERMOPRINTING MATERIAL CO., LTD., JIANZUO CITY TO: HENAN ZHUOLI IMAGING TECHNOLOGY CO., LTD. |
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Effective date of registration: 20191206 Address after: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province (in the hospital of Henan Zhuoli membrane materials Co., Ltd.) Patentee after: Jiaozuo Zhuoli membrane materials Co., Ltd Address before: 454000 No. 2758 Shenzhou Road, hi tech Zone, Henan, Jiaozuo Patentee before: Henan Zhuoli Imaging Technology Co., Ltd. |
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Address after: 454000 No. 959, Nanhai West Road, demonstration zone, Jiaozuo City, Henan Province Patentee after: Jiaozuo Zhuoli film material Co.,Ltd. Address before: No. 959, Nanhai West Road, Jiaozuo demonstration area, Henan Province, 454000 Patentee before: Jiaozuo Zhuoli membrane materials Co.,Ltd. |