CN102646484A - Preparation method of conductive aluminum paste for silicon-based thin film solar battery - Google Patents
Preparation method of conductive aluminum paste for silicon-based thin film solar battery Download PDFInfo
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- CN102646484A CN102646484A CN201210115220XA CN201210115220A CN102646484A CN 102646484 A CN102646484 A CN 102646484A CN 201210115220X A CN201210115220X A CN 201210115220XA CN 201210115220 A CN201210115220 A CN 201210115220A CN 102646484 A CN102646484 A CN 102646484A
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Abstract
The invention relates to a preparation method of conductive aluminum paste for a silicon-based thin film solar battery. The preparation method provided by the invention comprises the following steps of: at first, preparing an aluminum powder dispersing agent; preparing aluminum powder colloid through surface modification; uniformly stirring the aluminum powder colloid which is subjected to the surface modification with a glass adhesive and an organic solvent; and finally preparing the conductive aluminum paste for the silicon-based thin film solar battery. According to the preparation method provided by the invention, aluminum powder is subjected to the surface modification through copolymerization, so that the prepared aluminum paste has excellent dispersing property and conduction property.
Description
Technical field
The present invention relates to a kind of conductive silver aluminum slurry, be specifically related to the preparation method of a kind of silicon-based film solar cells with the conductive silver aluminium paste.
Technical background
Energy crisis and problem of environmental pollution have promoted the fast development of solar cell industry.At present solar cell mainly is divided into three major types: the one, and the crystal silicon solar energy battery that is the basis with monocrystalline silicon and polysilicon silicon chip; The 2nd, silica-base film, CIS and cadmium telluride diaphragm solar battery, dye sensitization and other organic solar batteries; The 3rd, comprise novel solar batteries such as SQW, multipotency band, hot carrier, also be in the research and development stage at present.
Crystal silicon solar energy battery has high conversion rate, the production technology comparative maturity, but manufacturing cost is very high, and enterprise needs relying on government subsidy.The manufacturing cost that how to reduce solar cell is the important means that solar cell improves the market competitiveness with improving optoelectronic transformation efficiency.The operation principle of silicon-based film solar cells and crystal silicon solar energy battery is identical; Just structure is slightly variant; Be that silicon-based film solar cells needs substrate for relying on, wherein substrate can be divided into hard substrates (like glass, stainless steel etc.) and flexible substrate (polyimide, metal forming etc.).With the flexible material be the silicon-based film solar cells of substrate tool has great advantage aspect the solar cell cost reducing, can realize Scroll large-scale production, its technology is simple, energy consumption is low, production efficiency is high, be solar cell following give priority to direction.
The silicon-based film solar cells structure mainly is made up of substrate, transparent electrode layer, photoelectric conversion layer and dorsum electrode layer.The effect of dorsum electrode layer is to collect the photoelectron that produces because of photovoltaic effect in the photoelectric conversion layer, and these photoelectrons are derived battery, so dorsum electrode layer also is one of the core material that is directly connected to the photoelectric conversion rate of flexible thin-film solar cell.Dorsum electrode layer mainly is made up of metal films such as silver, aluminium or metal oxide films such as ITO, ZnO.
Chinese patent (CN 101937933A) discloses a kind of high-viscosity solar cell backplate silver aluminium paste and preparation method thereof, and its component and percentage by weight are: conductive silver aluminium powder 75～85%; Glass glue 2～10%; Organic carrier 5.5～10%.Its preparation method just mixes silver powder, aluminium powder and glass glue; Be ground to the outward appearance exquisiteness; Add organic carrier again during evenly no particle and stir, adopt the method for this physics limited, will certainly reduce the electric conductivity of slurry for the dispersion effect of silver powder and aluminium powder.
Summary of the invention
The present invention is in order to solve the silver powder that exists in the background technology and the limited problem of aluminium powder dispersion effect and the preparation method of a kind of silicon-based film solar cells with the conductive silver aluminium paste is provided.
Realize through following technical scheme for realizing the object of the invention:
The present invention at first makes silver-colored aluminium powder dispersion liquid; Make silver-colored aluminium powder colloid through surface modification treatment then; Silver-colored aluminium powder colloid that this surface modification treatment is crossed and glass glue and organic solvent stir, and make silicon-based film solar cells at last and use the conductive silver aluminium paste.
A kind of silicon-based film solar cells is used the conductive silver aluminium paste, and its concrete preparation method is following:
Step 1: with mass fraction is that 0.05～0.2% gelatin joins in the aqueous isopropanol that concentration is 0.2 mol, stirs, and using concentration is that the salpeter solution regulation system pH value of 0.0001 mol is 2～5; Wherein gelatin is (0.05～0.2) with the ratio of aqueous isopropanol quality: 1; Under ultrasonic dispersion condition, stir on one side, in prepared gelatin solution, add silver powder and aluminium powder on one side; Stirred 30～60 minutes; Make silver-colored aluminium powder dispersion liquid, wherein silver powder is (0.3～0.5) with the ratio of gelatin solution quality: 1, and aluminium powder is (0.1～0.3) with the ratio of gelatin solution quality: 1;
Step 2: stir on one side; In the prepared silver-colored aluminium powder dispersion liquid of step 1, add methyl ethylene cyclosiloxane monomer, chlorobutadiene monomer successively on one side; Wherein the methyl ethylene cyclosiloxane is (0.5～0.8) with the ratio of silver-colored aluminium powder dispersion liquid quality: 1, and the chlorobutadiene monomer is (0.2～0.5) with the ratio of methyl ethylene cyclosiloxane monomer mass: 1, then add emulsifying agent; Wherein emulsifying agent is (0.1～0.2) with the ratio of methyl ethylene cyclosiloxane quality: 1; Begin to heat up, keep 70～85 ℃ of system temperatures, stirred 30～60 minutes; Then add organic acid catalyst and ammonium persulfate initiator; Insulation reaction 2～4 hours, wherein catalyst is (0.04～0.1) with the ratio of methyl ethylene cyclosiloxane quality: 1, ammonium persulfate is (0.5～1.5) with the ratio of methyl ethylene cyclosiloxane and chlorobutadiene monomer gross mass: 1;
Step 3: with the prepared solution of step 2 through vacuum filtration; Dehydration; Make the silver-colored aluminium powder colloid of surface modification treatment, this through the silver-colored aluminium powder colloid of surface modification treatment and glass binder, organic solvent mixing and stirring, is promptly obtained silicon-based film solar cells and use the conductive silver aluminium paste; Wherein silver-colored aluminium powder colloid with the ratio of the quality of glass binder is: (5～8): 1, and organic solvent with the ratio of the quality of glass binder is: (0.5～0.8): 1.
Silver powder described in the step 1 and aluminium powder, its average grain diameter are 0.1～0.5 μ m;
Methyl ethylene cyclosiloxane described in the step 2 is trimethyl trivinyl cyclotrisiloxane or tetramethyl tetrem thiazolinyl cyclotetrasiloxane; Described emulsifying agent is polyvinyl alcohol or OPEO; Described organic acid catalyst is DBSA or p-methyl benzenesulfonic acid;
Glass binder described in the step 3 is Bi
2O
3, ZnO, Al
2O
3, SiO
2And TiO
2Mixture; Described organic solvent is butanone or benzinum.
The invention has the beneficial effects as follows:
The present invention use copolymerization method on the organosilicon strand grafting polychlorobutadiene molecule segment; Increased the organosilyl degree of cross linking; Polychlorobutadiene itself also has good adhesive property simultaneously; Further improve the adhesive property between silver-colored aluminium powder colloid and glass binder and the organic solvent, thereby improved the electric conductivity of silver-colored aluminium paste.
2. the present invention is scattered in the reactant of organosilicon and chlorobutadiene in the silver-colored aluminium powder dispersion liquid and carries out polymerization reaction, and this more helps the dispersiveness of silver-colored aluminium powder, thereby improves the conductivity of silver-colored aluminium paste.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail.
Embodiment 1
1. 20 gram gelatin are joined in the 100 gram aqueous isopropanols; Stir; With concentration is that the salpeter solution regulation system pH value of 0.0001 mol is 3; Under ultrasonic dispersion condition; Stir on one side; In the gelatin solution of gained, add 60 gram silver powder and 36 gram aluminium powders on one side, mechanical agitation 60 minutes makes modification silver aluminium powder dispersion liquid;
2. get the prepared modification silver of step 1 aluminium powder dispersion liquid 60 grams, stir on one side, add 48 gram trimethyl trivinyl cyclotrisiloxane monomers, 24 gram chlorobutadiene monomers on one side successively; Then add 9.6 gram polyvinyl alcohol, begin to heat up, keep 85 ℃ of system temperatures; Stirred 60 minutes, and then added 4.8 gram DBSAs and 108 gram ammonium persulfate initiator, insulation reaction 4 hours; Vacuum filtration dewaters, and makes the silver-colored aluminium powder colloid of surface modification treatment.
3. take by weighing 5 grams, 45%～54%Bi
2O
3, 6.5%～9.5%ZnO, 15%～20%Al
2O
3, 6%～9%SiO
2With 7.5%～12.0%TiO
2Homogeneous mixture is heated to 1000 ℃, is incubated 1 hour; Pour in the cold water then and quench; The material ball milling that quenches 3 hours, discharging oven dry, add silver-colored aluminium powder colloid 40 grams of the prepared surface modification treatment of step 2; Add 6 gram benzinum mixing and stirring, promptly obtain silicon-based film solar cells and use the conductive silver aluminium paste.
Embodiment 2
1. 10 gram gelatin are joined in the 100 gram aqueous isopropanols; Stir; With concentration is that the salpeter solution regulation system pH value of 0.0001 mol is 2; Under ultrasonic dispersion condition; Stir on one side; In the gelatin solution of gained, add 44 gram silver powder and 22 gram aluminium powders on one side, mechanical agitation 60 minutes makes modification silver aluminium powder dispersion liquid;
2. get the prepared modification silver of step 1 aluminium powder dispersion liquid 40 grams, stir on one side, add 24 gram tetramethyl tetrem thiazolinyl cyclotetrasiloxane monomers, 8 gram chlorobutadiene monomers on one side successively; Then add 3.6 gram polyvinyl alcohol, begin to heat up, keep 80 ℃ of system temperatures; Stirred 45 minutes, and then added 1.2 gram p-methyl benzenesulfonic acids and 32 gram ammonium persulfate initiator, insulation reaction 3 hours; Vacuum filtration dewaters, and makes the silver-colored aluminium powder colloid of surface modification treatment.
3. take by weighing 6 grams, 45%～54%Bi
2O
3, 6.5%～9.5%ZnO, 15%～20%Al
2O
3, 6%～9%SiO
2With 7.5%～12.0%TiO
2Homogeneous mixture is heated to 1000 ℃, is incubated 1 hour; Pour in the cold water then and quench; The material ball milling that quenches 3 hours, discharging oven dry, add silver-colored aluminium powder colloid 40 grams of the prepared surface modification treatment of step 2; Add 4 gram benzinum mixing and stirring, promptly obtain silicon-based film solar cells and use the conductive silver aluminium paste.
Embodiment 3
1. 5 gram gelatin are joined in the 100 gram aqueous isopropanols; Stir; With concentration is that the salpeter solution regulation system pH value of 0.0001 mol is 5; Under ultrasonic dispersion condition; Stir on one side; In the gelatin solution of gained, add 32 gram silver powder and 10 gram aluminium powders on one side, mechanical agitation 30 minutes makes modification silver aluminium powder dispersion liquid;
2. get the prepared modification silver of step 1 aluminium powder dispersion liquid 30 grams, stir on one side, add 15 gram tetramethyl tetrem thiazolinyl cyclotetrasiloxane monomers, 3 gram chlorobutadiene monomers on one side successively; Then add 1.5 gram OPEOs, begin to heat up, keep 70 ℃ of system temperatures; Stirred 30 minutes, and then added 0.6 gram p-methyl benzenesulfonic acid and 9 gram ammonium persulfate initiator, insulation reaction 2 hours; Vacuum filtration dewaters, and makes the silver-colored aluminium powder colloid of surface modification treatment.
3. take by weighing 6 grams, 45%～54%Bi
2O
3, 6.5%～9.5%ZnO, 15%～20%Al
2O
3, 6%～9%SiO
2With 7.5%～12.0%TiO
2Homogeneous mixture is heated to 1000 ℃, is incubated 1 hour; Pour in the cold water then and quench; The material ball milling that quenches 3 hours, discharging oven dry, add silver-colored aluminium powder colloid 30 grams of the prepared surface modification treatment of step 2; Add 3 gram butanone mixing and stirring, promptly obtain silicon-based film solar cells and use the conductive silver aluminium paste.
With above-mentioned foundation desirable embodiment of the present invention is enlightenment, and through above-mentioned description, the related work personnel can carry out various change and modification fully in the scope that does not depart from this invention technological thought.The technical scope of this invention is not limited to the content on the specification, must confirm its technical scope according to the claim scope.
Claims (4)
1. a silicon-based film solar cells is characterized in that with the preparation method of conductive silver aluminium paste step is following:
Step 1: with mass fraction is that 0.05 ~ 0.2% gelatin joins in the aqueous isopropanol that concentration is 0.2 mol, stirs, and using concentration is that the salpeter solution regulation system pH value of 0.0001 mol is 2 ~ 5; Wherein gelatin is (0.05 ~ 0.2) with the ratio of aqueous isopropanol quality: 1; Under ultrasonic dispersion condition, stir on one side, in prepared gelatin solution, add silver powder and aluminium powder on one side; Stirred 30 ~ 60 minutes; Make silver-colored aluminium powder dispersion liquid, wherein silver powder is (0.3 ~ 0.5) with the ratio of gelatin solution quality: 1, and aluminium powder is (0.1 ~ 0.3) with the ratio of gelatin solution quality: 1;
Step 2: stir on one side, to step 1 prepared silver-colored aluminium powder dispersion liquid in successively add methyl ethylene cyclosiloxane monomer, chlorobutadiene monomer on one side, wherein the methyl ethylene cyclosiloxane is (0.5 ~ 0.8) with the ratio of silver-colored aluminium powder dispersion liquid quality: 1; The chlorobutadiene monomer is (0.2 ~ 0.5) with the ratio of methyl ethylene cyclosiloxane monomer mass: 1; Then add emulsifying agent, wherein emulsifying agent is (0.1 ~ 0.2) with the ratio of methyl ethylene cyclosiloxane quality: 1, begin to heat up; Keep 70 ~ 85 ℃ of system temperatures; Stirred 30 ~ 60 minutes, and then added organic acid catalyst and ammonium persulfate initiator, insulation reaction 2 ~ 4 hours; Wherein catalyst is (0.04 ~ 0.1) with the ratio of methyl ethylene cyclosiloxane quality: 1, and ammonium persulfate is (0.5 ~ 1.5) with the ratio of methyl ethylene cyclosiloxane and chlorobutadiene monomer gross mass: 1;
Step 3: with the prepared solution of step 2 through vacuum filtration; Dehydration; Make the silver-colored aluminium powder colloid of surface modification treatment, this through the silver-colored aluminium powder colloid of surface modification treatment and glass binder, organic solvent mixing and stirring, is promptly obtained silicon-based film solar cells and use the conductive silver aluminium paste; Wherein silver-colored aluminium powder colloid with the ratio of the quality of glass binder is: (5 ~ 8): 1, and organic solvent with the ratio of the quality of glass binder is: (0.5 ~ 0.8): 1.
2. a kind of silicon-based film solar cells according to claim 1 is characterized in that with the preparation method of conductive silver aluminium paste: described silver powder of step 1 and aluminium powder, its average grain diameter are 0.1 ~ 0.5 μ m.
3. a kind of silicon-based film solar cells according to claim 1 is characterized in that with the preparation method of conductive silver aluminium paste: the described methyl ethylene cyclosiloxane of step 2 is a kind of of trimethyl trivinyl cyclotrisiloxane or tetramethyl tetrem thiazolinyl cyclotetrasiloxane; Described emulsifying agent is a kind of of polyvinyl alcohol or OPEO; Described organic acid catalyst is DBSA or p-methyl benzenesulfonic acid.
4. a kind of silicon-based film solar cells according to claim 1 is characterized in that with the preparation method of conductive silver aluminium paste: the described glass binder of step 3 is Bi
2O
3, ZnO, Al
2O
3, SiO
2And TiO
2Mixture; Described organic solvent is a kind of of butanone or benzinum.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI665209B (en) * | 2017-02-09 | 2019-07-11 | 南韓商三星Ｓｄｉ股份有限公司 | Composition for forming solar cell electrode and electrode prepared using the same |
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| US20080090082A1 (en) * | 2006-10-11 | 2008-04-17 | Samsung Electro-Mechanics Co., Ltd. | Methods for surface modification of non-dispersible metal nanoparticles and modified metal nanoparticles for inkjet by the same method |
| JP2010199034A (en) * | 2009-02-27 | 2010-09-09 | Dic Corp | Conductive paste for solar cell and manufacturing method therefor |
| CN102248176A (en) * | 2011-07-15 | 2011-11-23 | 云南铜业科技发展股份有限公司 | Preparation method of flake silver powder with low burning loss |
| WO2012015283A2 (en) * | 2010-07-30 | 2012-02-02 | Lg Innotek Co., Ltd. | Solar cell and paste composition for rear electrode of the same |
| CN102407341A (en) * | 2011-10-27 | 2012-04-11 | 浙江光达电子科技有限公司 | surface modified particle diameter mixed silver powder and preparation method thereof |
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2012
- 2012-04-19 CN CN 201210115220 patent/CN102646484B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080090082A1 (en) * | 2006-10-11 | 2008-04-17 | Samsung Electro-Mechanics Co., Ltd. | Methods for surface modification of non-dispersible metal nanoparticles and modified metal nanoparticles for inkjet by the same method |
| JP2010199034A (en) * | 2009-02-27 | 2010-09-09 | Dic Corp | Conductive paste for solar cell and manufacturing method therefor |
| WO2012015283A2 (en) * | 2010-07-30 | 2012-02-02 | Lg Innotek Co., Ltd. | Solar cell and paste composition for rear electrode of the same |
| CN102248176A (en) * | 2011-07-15 | 2011-11-23 | 云南铜业科技发展股份有限公司 | Preparation method of flake silver powder with low burning loss |
| CN102407341A (en) * | 2011-10-27 | 2012-04-11 | 浙江光达电子科技有限公司 | surface modified particle diameter mixed silver powder and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI665209B (en) * | 2017-02-09 | 2019-07-11 | 南韓商三星Ｓｄｉ股份有限公司 | Composition for forming solar cell electrode and electrode prepared using the same |
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Address after: Gaogang city in Jiangsu province Taizhou City Road 225300 No. 67 Patentee after: CHANGSHU RESEARCH INSTITUTE CO LTD OF NANJING University OF SCIENCE AND TECHNOLOGY Address before: The Science Park Research Institute of Jiangsu province Suzhou City Road 215513, Changshou City economic and Technological Development Zone No. 5 Patentee before: CHANGSHU RESEARCH INSTITUTE CO LTD OF NANJING University OF SCIENCE AND TECHNOLOGY |
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Address after: The Science Park Research Institute of Jiangsu province Suzhou City Road 215513, Changshou City economic and Technological Development Zone No. 5 Patentee after: CHANGSHU RESEARCH INSTITUTE CO LTD OF NANJING University OF SCIENCE AND TECHNOLOGY Address before: Gaogang city in Jiangsu province Taizhou City Road 225300 No. 67 Patentee before: CHANGSHU RESEARCH INSTITUTE CO LTD OF NANJING University OF SCIENCE AND TECHNOLOGY |
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Effective date of registration: 20221018 Address after: Room 208, Science and Technology Innovation Park, Changshu Economic and Technological Development Zone, Suzhou City, Jiangsu Province, 215513 Patentee after: CHANGSHU HI-TECH INNOVATION SERVICE Co.,Ltd. Address before: 215513 No.5, research institute road, kechuangyuan, Changshu Economic and Technological Development Zone, Suzhou City, Jiangsu Province Patentee before: CHANGSHU RESEARCH INSTITUTE CO LTD OF NANJING University OF SCIENCE AND TECHNOLOGY |