CN102597348B - Pile fabric and process for producing same - Google Patents

Pile fabric and process for producing same Download PDF

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Publication number
CN102597348B
CN102597348B CN200980162337.XA CN200980162337A CN102597348B CN 102597348 B CN102597348 B CN 102597348B CN 200980162337 A CN200980162337 A CN 200980162337A CN 102597348 B CN102597348 B CN 102597348B
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China
Prior art keywords
fiber
pile
organized
pile fabric
wire gauze
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CN200980162337.XA
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Chinese (zh)
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CN102597348A (en
Inventor
西田宗平
三好正明
楠和也
德本裕幸
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Kaneka Corp
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Kaneka Corp
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Priority to CN201510113172.4A priority Critical patent/CN104695159B/en
Publication of CN102597348A publication Critical patent/CN102597348A/en
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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D27/00—Woven pile fabrics
    • D03D27/12—Woven pile fabrics wherein pile tufts are inserted during weaving
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02—Pile fabrics or articles having similar surface features
    • D04B1/025—Pile fabrics or articles having similar surface features incorporating loose fibres, e.g. high-pile fabrics or artificial fur
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/587—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads adhesive; fusible
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D27/00—Woven pile fabrics
    • D03D27/02—Woven pile fabrics wherein the pile is formed by warp or weft
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/02—Pile fabrics or articles having similar surface features
    • D04B1/04—Pile fabrics or articles having similar surface features characterised by thread material
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B21/00—Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/02—Pile fabrics or articles having similar surface features
    • D04B21/04—Pile fabrics or articles having similar surface features characterised by thread material
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/04—Heat-responsive characteristics
    • D10B2401/041—Heat-responsive characteristics thermoplastic; thermosetting
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00—Details of fabric structure established in the fabric forming process
    • D10B2403/01—Surface features
    • D10B2403/011—Dissimilar front and back faces
    • D10B2403/0111—One hairy surface, e.g. napped or raised
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23907—Pile or nap type surface or component
    • Y10T428/2395—Nap type surface

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Knitting Of Fabric (AREA)
  • Woven Fabrics (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Laminated Bodies (AREA)

Abstract

A pile fabric in which specific areas only have been fusion-bonded and the pile fibers are thereby prevented from falling off, without impairing the texture; and a process for producing the pile fabric. The pile fabric (5) comprises a ground weave and pile fibers (2) twisted around the ground yarns (1) that constitute the ground weave and rising on the front surface of the ground weave, wherein the pile fibers (2) are fibers of at least one kind selected from a group consisting of acrylic fibers and modacrylic fibers, the pile fibers (2) have a lower softening point than the fibers constituting the ground weave, and among the pile fibers (2) twisted around the ground yarns (1) constituting the ground weave, at least some of the pile fibers (2) located outside the ground yarns (1) constituting the ground weave have been fusion-bonded and the pile fibers (2); rising on the front surface of the ground weave have not been fusion-bonded. The process for pile fabric production involves the step of conducting contact heating/pressing from the back side of the ground weave at a temperature which is equal to or higher than the softening point of the pile fibers (2) but is less than the softening point of the fibers constituting the ground weave.

Description

Pile fabric and manufacture method thereof
Technical field
The present invention relates to the pile fabric falling hair and manufacture method thereof that prevent pile fiber.
Background technology
It is known that pile fabric is in the past referred to as with imitated furs or the name such as Fake Furs, neckpiece the cloth and silk being similar to fur outward appearance.They are made up of pile braided fabric, fleece.When weaving pile, mainly with sealed round rib machine, Wool top feeding type lint braiding machine (sliver knitting, circular knitter) braiding, all carry out cut pile.When the dual La Sheer warp loom braiding with warp knitting machine, by organizing with being formed doubly, between tie line being organized with being entangled in simultaneously, the centre of tie line being cut off and weaves.When knitting method for making, using cut velvet loom, undercoat suede loom to organize upper and lower two panels in-between with tie line winding, cutting off between upper and lower base cloth with cutter, be made into 2 textiless (non-patent literature 1) simultaneously., commonly there is the many problems of hair in these textiless.If it is many to fall hair, be then attached on shirt or be shed on the ground, aesthetic appearance is poor, and health also has problems.
In order to prevent such falling hair, proposing and in pile fiber, mixing low-melting fiber (patent document 1), in the wire gauze organized with forming, mix the methods such as low-melting fiber (patent document 2 ~ 3)., these motions due to be all with the fusing point of above-mentioned low-melting fiber more than temperature cloth and silk entirety is heated, therefore entirely tissue or pile fiber also fuse, there is the problem of wiriness.
Prior art document
Patent document
Patent document 1: Japanese Unexamined Patent Publication 6-081248 publication
Patent document 2: Japanese Unexamined Patent Publication 2000-314048 publication
Patent document 3: Japanese Unexamined Patent Publication 7-048765 publication
Non-patent literature
Non-patent literature 1: " the 3rd edition fiber brief guide " is compiled by fiber association, ball is apt to, Heisei distribution on December 15th, 16,341-342 page
Summary of the invention
Invent problem to be solved
The present invention solves above-mentioned problem in the past, provides a kind of specific part by only fusing pile fabric, thus prevents when not damaging feel pile fiber to fall pile fabric and the manufacture method thereof of hair.
The means of dealing with problems
The feature of pile fabric of the present invention is: be organize with containing and be wrapped in form on the wire gauze organized above-mentionedly and erect the pile fabric of the pile fiber on ground tissue surface, above-mentioned pile fiber is at least one fiber be selected among acrylic fiber and acrylic fibers, and the softening point of above-mentioned pile fiber is lower more above-mentionedly than the softening point forming the fiber organized; Be wrapped in the pile fiber formed on above-mentioned the wire gauze organized, the pile fiber be at least partially positioned at outside the wire gauze that forms and organize above-mentionedly is fused, and erects and is not fused in the pile fiber of above-mentioned ground tissue surface.
The feature of the manufacture method of pile fabric of the present invention is: be organize with containing and be wrapped in form on the wire gauze organized above-mentionedly and erect the manufacture method of the pile fabric of the pile fiber on ground tissue surface, above-mentioned pile fiber is at least one fiber be selected among acrylic fiber and acrylic fibers, and the softening point of above-mentioned pile fiber is lower more above-mentionedly than the softening point forming the fiber organized; By the rear side from ground tissue more than the softening point of above-mentioned pile fiber and lower than form above-mentioned the fiber organized softening point temperature under carry out contact heating and pressurize, make be wrapped in the pile fiber formed on above-mentioned the wire gauze organized, be positioned at the pile fiber at least partially formed outside the wire gauze organized to be fused above-mentionedly, erect and do not fused in the pile fiber of above-mentioned ground tissue surface.
The effect of invention
The effect of pile fabric of the present invention is, it is at least one fiber be selected among acrylic fiber and acrylic fibers by pile fiber, pile fiber at least partially outside the wire gauze organized with being positioned at formation is fused, and the pile fiber erected on ground tissue surface does not fuse, thus can prevent pile fiber from falling hair when not damaging feel.In addition, in the manufacture method of pile fabric of the present invention, pressurize by carrying out contact heating at the temperature of the rear side from ground tissue more than the softening point of pile fiber and lower than the softening point of fiber organized with forming, due to only make outside the wire gauze organized with being positioned at formation be defined partially fused, and do not make the pile fiber erected on ground tissue surface fuse, what thus can prevent pile fiber when not damaging feel falls hair.
Accompanying drawing explanation
Fig. 1 be the pile fabric of one embodiment of the invention outline figure.
Fig. 2 is the weave diagram of the fur knitting thing of one embodiment of the invention.
Fig. 3 is the weave diagram of the Wool top feeding type fabric of one embodiment of the invention.
Fig. 4 is the manufacturing procedure picture of one embodiment of the invention.
Fig. 5 is the photo (multiplying power 50) of the sweep electron microscope (SEM) of the thickness of the pile fiber represented outside the wire gauze organized with being positioned at formation in one embodiment of the invention.
Fig. 6 is the thickness of the pile fiber represented outside the wire gauze organized with being positioned at formation in one embodiment of the invention and the curve map of relation falling hair.
Detailed description of the invention
Pile fabric of the present invention organizes and be wrapped in that to form the wire gauze (hereinafter referred to as wire gauze) organized upper and erect the pile fabric of the pile fiber at above-mentioned ground tissue surface above-mentionedly.This pile fabric can adopt sealed round rib machine, Wool top feeding type lint braiding machine (circular knitter), fur knitting machine (circular knitter), dual La Sheer warp loom, cut velvet weaving loom, undercoat suede weaving loom etc. to make.As pile fabric of the present invention, there is no particular limitation, can list plush, fur suede and tufted carpet etc., preferred plush and fur suede, more preferably plush.
The softening point of pile fiber is lower than the softening point of the fiber (hereinafter referred to as ground organizational composition fiber) organized with forming, be wrapped in the pile fiber on wire gauze, pile fiber at least partially outside wire gauze is fused, and erects and do not fused in the pile fiber of above-mentioned ground tissue surface.As its means, as long as it is just passable to fuse the pile fiber be at least partially positioned at outside wire gauze, there is no particular limitation, but from the rear side of ground tissue, temperature namely from the rear side of pile fabric more than the softening point of pile fiber and lower than the softening point of above-mentioned ground organizational composition fiber, preferably carry out contact heat and pressurize.
In the present invention, so-called " outside the wire gauze organized with forming ", in face pile fiber erected as being rear side during surface, is the outside beyond wire gauze.In addition, about the pile fiber be wrapped on wire gauze, a part of fiber embeds wire gauze sometimes, as long as but remainder is present in outside wire gauze, just comprise this fiber.
Above-mentioned pile fiber is at least one fiber be selected among acrylic fiber and acrylic fibers.Being at least one fiber be selected among acrylic fiber and acrylic fibers by making pile fiber, the pile fabric of excellent touch can be obtained.When adopting thermoplastic fibre as pile fiber, usually, if carry out polishing at the temperature more than the fusing point of thermoplastic fibre, then the pile fiber fusing on pile fabric surface, can not obtain having good outward appearance, the pile fabric of feel.In addition, if carry out polishing at the temperature below the fusing point of thermoplastic fibre, then the crispaturaing of pile fiber on pile fabric surface is not stretched flat, and thus can not obtain having good outward appearance, the pile fabric of feel.In contrast, even if because the temperature of crispaturaing below softening point of acrylic fiber and acrylic fibers is also stretched flat, therefore when adopting at least one fiber that is selected among acrylic fiber and acrylic fibers as pile fiber, can at the temperature below softening point, such as carry out polishing at 150 ~ 160 DEG C.Therefore, when at least one fiber that employing is selected among acrylic fiber and acrylic fibers is as pile fiber, in polishing, the pile fiber on pile fabric surface can not fuse, and can obtain having good outward appearance, the pile fabric of feel.And, if pile fiber is except acrylic fiber and acrylic fibers, it is also the thermoplastic fibre of less than 160 DEG C containing softening point, such as softening point is the low melting point polyester fiber etc. of less than 160 DEG C, during polishing then at 150 ~ 160 DEG C, the low melting point polyester fiber on pile fabric surface melts away, and is difficult to obtain having good outward appearance, the pile fabric of feel.
As long as above-mentioned pile fiber softening point is lower than the softening point of the fiber forming ground tissue just passable, there is no particular limitation, but the difference of the softening point of above-mentioned ground organizational composition fiber and above-mentioned pile fiber is preferably more than 10 DEG C, is more preferably more than 20 DEG C, more preferably more than 30 DEG C.If there is the difference of more than 10 DEG C, just more easily only makes to be positioned at the fibre fusion at least partially outside the wire gauze that forms and organize above-mentionedly, and do not make the pile fiber erected at above-mentioned ground tissue surface fuse.
Above-mentioned pile fiber can be all softening at an established temperature fiber, also can be the blended fiber of the fiber softened at different temperature.And, when pile fiber is the blended fiber of the fiber softened at different temperature, preferably, more than fibers mixture 20 % by weight (wt%) softening at relatively low temperatures, make the fibre fusion softened at relatively low temperatures.
In the present invention, so-called softening point is fusing or the softening temperature before decomposing.Such as, the softening point of acrylic fiber is 190 ~ 232 DEG C, and the softening point of acrylic fibers is 150 ~ 220 DEG C of (" chemical voluminous dictionary ", altogether vertical publication, 727 ~ 729 pages, distribution on June 1st, 1993.Hereinafter referred to as " literature value ").So-called acrylic fiber, refers to the fiber of acrylonitrile containing more than 85 % by weight.In addition, so-called acrylic fibers, refer to by containing more than 35 % by weight and lower than 85 % by weight acrylonitrile, containing more than 15 % by weight and the fiber that forms of the condensate of other copolymerizable monomer of less than 65 % by weight.Here, other copolymerizable monomer so-called, can list: with vinyl chloride, vinylidene chloride, bromine ethene, the halogen ethene that inclined bromine ethene etc. are representative and vinylidene halide, with allyl sulphonic acid, methallyl sulfonic acid, styrene sulfonic acid, isoprene sulfonic acid, 2-acrylamide-2-methyl propane sulfonic acid etc. are representative containing the monomer of sulfonic acid and their metallic salt and amine salt, acrylic acid and methacrylic acid and their lower alkyl esters, the aminoalkyl ester that N or N, N-alkyl replaces and glycidic ester, acrylamide and Methacrylamide and their N or N, N-alkyl replace body, with acrylic acid, the carboxylic vinyl monomer that methacrylic acid and itaconic acid etc. are representative and their sodium salt, the anionic property such as sylvite or ammonium salt vinyl monomer, the cationic vinyl monomer headed by 4 grades of aminoalkyl esters of acrylic acid and methacrylic acid, or containing the lower alkyl ether of vinyl, take vinylacetate as the low-carbon carboxylate containing vinyl of representative, styrene etc.These monomers can be used alone, and also can mix two or more and use.Wherein, preferably use more than one the monomer among the metallic salt being selected from halogen ethene, vinylidene halide and the monomer containing sulfonic acid, more preferably use more than one the monomer be selected among vinyl chloride, vinylidene chloride and Sodium styrene sulfonate.In addition, as acrylic fibers, improvement acrylic acid (modacrylic fiber) fiber is preferably adopted.So-called modacrylic fiber, refer to by containing more than 35 % by weight and lower than 85 % by weight acrylonitrile and add up to containing more than 15 % by weight and the fiber that forms of the condensate being selected from more than one monomer among vinyl chloride and vinylidene chloride and other copolymerizable monomer of less than 65 % by weight.
In pile fabric of the present invention, the pile fiber at least partially outside above-mentioned wire gauze is fused and is crimped.Here, what is called is crimped, such as, as shown in the SEM photo of the pile fabric of the Production Example 5,11 and 17 after the contact heating pressurized treatments of Fig. 5, the pile fiber tangle up that the pile fiber referring to 1 root merges combination or 1 root separately forms block and the state of smoothing.In addition, in pile fabric of the present invention, the whole pile fiber outside preferred above-mentioned wire gauze is fused and is crimped.This is because the more excellent effect preventing hair can be obtained.
Above-mentionedly to be fused and the thickness of the pile fiber be positioned at outside wire gauze be crimped is preferably less than 300 μm, be more preferably less than 250 μm, more preferably less than 200 μm.If the thickness of the pile fiber outside above-mentioned wire gauze is below 300 μm, then can be fixing with the fusion of good intensity each other by pile fiber.In addition, in the present invention, the thickness of the pile fiber outside above-mentioned wire gauze such as can measure by the following stated.First, when cutting off pile fabric, vertically cut off relative to the weaving direction of wire gauze after only pile surface portion being fixed with bonding agent to not upset pile shape.Cutting line is the position of the coil of crosscut wire gauze, such as in figure 3, represents with I-I line.Then, with the back side of ground tissue for upside (making Fig. 1 reverse), sweep electron microscope (SEM) is adopted to observe section by multiplying power 50, to such as measuring with the thickness that the beeline between parallel lines 19a and 19b represents in Figure 5.The mean value that obtains will be measured as thickness at 10 places.
Have again, in the mensuration of thickness, when adopting sweep electron microscope (SEM) to observe section, when being difficult to difference wire gauze and pile fiber, also can such as by using the light microscope that can carry out with the multiplying power of more than 50 observing or laser microscope etc. to distinguish wire gauze and pile fiber abreast.
In the present invention, preferably backing resin is impregnated with at the back side of pile fabric.If be impregnated with backing resin, then can from the rear side of ground tissue, namely carry out contacting heating pressurization from the rear side of pile fabric operation before, carry out the process erecting pile arranging pile fiber.
As above-mentioned backing resin, the latex of acrylic ester resin, polyurethane series resin etc., emulsion, dispersion liquid etc. can be used.About the infiltration amount of backing resin, in order to prevent hair, by resin solid content concentration as an example, usually make its 50g/m that infiltrates 2left and right, but the present invention is owing to having the effect preventing hair brought by the fusion of the privileged site of pile fiber, therefore can be about 1/2 ~ 1/3 of common infiltration amount.That is, as long as make its 17 ~ 25g/m that infiltrates by resin solid content densimeter 2left and right is just passable.The polishing of pile fiber can be carried out before the fusion of the privileged site of pile fiber, but do not come off in order to now fiber, backing resin can be used temporarily to be fixed.So resin impregnated amount can be little.
Then, the manufacture method of pile fabric of the present invention is described.The manufacture method of pile fabric of the present invention carries out contacting the operation of heating pressurization comprising the temperature from the rear side of ground tissue more than the softening point of above-mentioned pile fiber and lower than the softening point of ground organizational composition fiber.Thus, the pile fiber be at least partially positioned at outside above-mentioned wire gauze be wrapped in the pile fiber on above-mentioned wire gauze is fused and is crimped.Preferred above-mentioned contact is forced through warm-up mill or heating plate carries out.As long as warm-up mill or heating plate, just can carry out the contact heat treated of short time, the pile fiber at least partially that only fusion, crimping are positioned at outside above-mentioned wire gauze.And the heating of the degree melted owing to not carrying out making the pile fiber on pile fabric surface, the pile fiber therefore erected on ground tissue surface can not fuse.
In addition, when above-mentioned pile fiber is the blended fiber of the fiber softened at different temperature, preferably, carry out contact heating pressurization more than the softening point of the pile fiber of softening at relatively low temperatures from the rear side of ground tissue and lower than the temperature of the softening point of pile fiber softening at relatively high temperature, the pile fiber of softening at relatively low temperatures is fused.Except preventing except hair, also easily obtain the pile fabric of excellent touch.
Preferably when carrying out contact heating pressurization from above-mentioned the rear side organized and/or after having carried out contacting heating pressurization, the above-mentioned pile fiber side that erects is cooled.In addition, preferably after having carried out contacting heating pressurization from above-mentioned the rear side organized, cool from above-mentioned the rear side organized.As above-mentioned cooling way, be preferably that the cut velvet face of chill roll to pile fiber of the water of less than 30 DEG C cools with passing into water temperature.If so cooled, the stability of size can be kept, and the damage of heat to pile fiber can also be alleviated.
As above-mentioned ground organizational composition fiber, as long as its softening point is more passable than above-mentioned pile fiber higher position, there is no particular limitation, can adopt the synthetic fiber and cotton yarn that are made up of mylar such as polyethylene terephthalate.
In the present invention, adopting such as polyethylene terephthalate (PET, softening point is approximately 258 DEG C) fiber as ground organizational composition fiber time, as pile fiber, more than one the fiber be selected among acrylic fibers and acrylic fiber can be used, preferably use the blended fiber of acrylic fibers or acrylic fibers and acrylic fiber.In addition, as acrylic fibers, following fiber can preferably be used.
(1) chloride-acrylonitrile series fiber (softening point is 150 ~ 220 DEG C, literature value for such as Kaneka Co., Ltd. system, trade name " Kanekalon ")
(2) vinylidene chloride-acrylic fibre (softening point is 150 ~ 220 DEG C, literature value)
In the present invention, when such as using cotton yarn (kapok) (not having softening point) fiber as ground organizational composition fiber, acrylic fiber (such as Exlan Co., Ltd. system preferably can be used as pile fiber, trade name " Exlan K691 ", softening point is 190 ~ 232 DEG C, literature value).
Accompanying drawing is adopted to be described below.Fig. 1 be the pile fabric of one embodiment of the invention outline figure.Pile fabric 5 by wire gauze 1 and to be wrapped on wire gauze 1 and ground tissue surperficial fibrillation and form the pile fiber 2 erecting pile 3 and form.In addition, at the back side of pile fabric 5, in the outside of wire gauze 1, being fused at least partially of pile fiber 2, forms fused portion 4, is crimped on wire gauze 1.In addition, also can at the back side of pile fabric 5 infiltration backing resin.
Fig. 2 is the weave diagram of fur knitting thing.This pile fabric 25 by wire gauze 21 and to be wrapped on wire gauze 21 and ground tissue surperficial fibrillation and form the pile fiber 22 erecting pile and form.Fig. 3 is the weave diagram of Wool top feeding type fabric.This pile fabric 35 by wire gauze 31 and to be wrapped on wire gauze 31 and ground tissue surperficial fibrillation and form the pile fiber 32 erecting pile and form.Contact heating pressurized treatments is carried out at the back side of opposing face, the i.e. pile fabric of any one pile side that all opposed, by the pile fiber fusion outside wire gauze.
Fig. 4 is the manufacturing procedure picture of one embodiment of the invention.The processing unit (plant) 10 used in the method comprises: be coated with the warm-up mill 11 of the fluororesin such as polytetrafluoroethylene (PTFE), warm-up mill 11 is pressurizeed and inside pass into the cooling water of 30 DEG C cooling rubber rollers 12, cooling rubber rollers 12 to be pressurizeed and inside passes into metal cooling roller 13,14 and the deflector roll 15 of the cooling water of 30 DEG C.Pile fabric raw material sheet 18 is drawn from container 16, contacts with warm-up mill to make back side 18b, surface (erecting pile side) 18a with cool the mode that contacts of rubber rollers 12 and supply.The pile fabric 5 finishing to process is accommodated in container 17.Further, contact heating pressurized treatments is not limited to the processing unit (plant) shown in Fig. 4, also can adopts and the device, heating plate and other device that change are formed to the part of the processing unit (plant) shown in Fig. 4.In contact heating pressurized treatments, as long as the softening point of heating-up temperature such as more than the softening point of pile fiber and lower than ground organizational composition fiber is just passable, preferred plus-pressure counts 0.01 ~ 100Kgf/cm by line pressure 2, the feed speed of raw material sheet is 0.1 ~ 20m/ minute, and the heater contacts time was 1 ~ 60 second.In addition, from the view point of the damage on surface alleviating pile fabric, more preferably plus-pressure counts 0.05 ~ 7Kgf/cm by line pressure 2, the heater contacts time was 2 ~ 10 seconds.
The gross weight that falls of pile fabric of the present invention is preferably 0.6g/m 2below, 0.3g/m is more preferably 2below.In the present invention, as falling gross weight, the surface of pile fabric is used to hairbrush (trade name " Prescale mat ", 5mm(particle diameter), longitudinal 4cm, the horizontal 10.5cm of rubber, Fuji Photo Film Co., Ltd.'s system) apply 600g load (14.3kg/cm 2) constantly acting load, with the stroke of wide 30cm, to rubbing 10 times with the hands to by the surface of pile fabric along cant, to rubbing with the hands 10 times, recycle hair with adhesive gel band in the other direction, by by every 1m 2conversion obtains its weight as falling gross weight.
Embodiment
By the following examples the present invention is specifically described.Further, the present invention is not limited to following embodiment.
< assay method >
1. fall gross weight
Use the hairbrush (trade name " Prescale mat ", 5mm(particle diameter) of rubber, longitudinal 4cm, horizontal 10.5cm, Fuji Photo Film Co., Ltd.'s system) 600g load (14.3kg/cm is applied to the surface of pile fabric 2) constantly acting load, with the stroke of wide 30cm, to rubbing 10 times with the hands to by the surface of pile fabric along cant, to rubbing with the hands 10 times, recycle hair with adhesive gel band in the other direction, by by every 1m 2conversion obtains its weight as falling gross weight.
2. fall hair evaluation
Based on falling gross weight, evaluate by the grade with 4 ranks shown below.
A:0.3g/m 2below (very good level)
B: more than 0.3g/m 2and at 0.6g/m 2below (good level)
C: more than 0.6g/m 2and at 1.0g/m 2below (not too good level)
D: more than 1.0g/m 2(bad level)
3. softening point
By the fiber detaching of each 1g used in following Production Example, be placed on be heated to arbitrary temperature heating plate on, with 0.07Kgf/cm 33 second of exert pressure time, temperature when being combined because of softening respectively by the single fiber in the face contacted with heating plate and form tabular is as the softening point of fiber.
4. the thickness of the pile fiber outside the wire gauze organized with being positioned at formation
Only pile surface portion being fixed with bonding agent to not upset pile shape when cutting off pile fabric, then vertically cutting off relative to the weaving direction of wire gauze.Cutting line is the position of the coil of crosscut wire gauze, such as in figure 3, represents with I-I line.Then, with the back side of ground tissue for upside (making Fig. 1 reverse), sweep electron microscope (SEM) is adopted to observe section by multiplying power 50, to such as measuring with the thickness that the beeline between parallel lines 19a and 19b represents in Figure 5.The mean value that obtains will be measured as thickness at 10 places.
5. feel
By shown below with the grade evaluation feel of 4 ranks.
A: erecting not fusion in the pile fiber on ground tissue surface, is equal level with the pile fabric of not heat-treating
B: slightly poor compared with grade A, but erect not fusion in the pile fiber on ground tissue surface, level no problem in practicality
C: slightly thick and stiff, practicality has problem (defective)
D: very thick and stiff, can not practical (defective)
The fiber > used in < Production Example
1. pile fiber
(1) trade name " Kanekalon AH " (hereinafter referred to as AH), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is that below 3.3deci tex(describes as dtex)
(2) trade name " Kanekalon FHS " (hereinafter referred to as FHS), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 2.2dtex.
(3) trade name " Kanekalon RMK(801) " (hereinafter referred to as RMK(801)), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 12dtex.
(4) trade name " Kanekalon SL " (hereinafter referred to as SL), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 3.3dtex.
(5) trade name " K691 ", Exlan Co., Ltd. system
Acrylic fiber, softening point is 250 ~ 260 DEG C, and fiber number is 3.3dtex.
(6) trade name " Kanekalon CC " (hereinafter referred to as CC), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 3.3dtex.
(7) trade name " Kanekalon fmu " (hereinafter referred to as fmu), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 1.5dtex.
(8) trade name " Kanekalon MS " (hereinafter referred to as MS), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 5.0dtex.
(9) trade name " Kanekalon MCS " (hereinafter referred to as MCS), Kaneka Co., Ltd. system
Acrylic fibers (chloride-acrylonitrile series fiber), softening point is 180 ~ 190 DEG C, and fiber number is 2.2dtex.
(10) trade name " Tetoron SD ", Di Ren Inc.
Polyester complex fiber, softening point is 90 ~ 100 DEG C, and fiber number is 4.4dtex.
(11) trade name " Unitika 1680 ", Unitika Co., Ltd. system
Polyester complex fiber, softening point is 220 DEG C, and fiber number is 3.3dtex.
2. organizational composition fiber (wire gauze)
(1) polyester fiber silk
The multifilament that uses total fiber number to be 334dtex (being the filament of tow two plying of 167dtex by the fiber number be made up of the polyester filaments of 50).Softening point is 258 DEG C.
(2) kapok yarn
By yarn count be textile strand 2 plying of No. 40 use.Kapok does not have softening point, at high temperature decomposes.
(Production Example 1 ~ 30)
In Production Example 1 ~ 30, Production Example 1,7,13,19,23 and 27 is comparative example, and other Production Example is embodiment.Use the Wool top feeding type lint braiding machine (circular knitter) being used for making artificial fur, use above-mentioned polyester fiber as wire gauze, supply the pile fiber sliver (10 ~ 14g/m) be made up of the acrylic fibers shown in following table 1 respectively, the pile fiber of braiding Production Example 1 ~ 30.The pile loop number of the file of ground tissue is defined as 16 ~ 17/inch, the pile loop number of line is defined as 22 ~ 33/inch, other is the condition shown in following table 1.Then, make backing resin impregnated at the back side of above-mentioned pile fabric.As backing resin, using with acrylate is the emulsified copolymer latex of principal component, is the aqueous solution (emulsion) of 40wt% as latex concentration, to infiltrate attachment 25g/m by resin solid content densimeter in embodiment goods 2, infiltration attachment 50g/m in comparative example goods 2, then make it dry.Then, the pile fiber on the surface of pile fabric is arranged by polishing, brushing and cropping.Specifically, first, carry out 2 polishings at 155 DEG C, then carry out 2 brushings, then at 150 DEG C, 145 DEG C, 130 DEG C and 120 DEG C, respectively carry out 1 polishing, then carry out 2 cropping, finally at 100 DEG C, carry out 2 polishings.Then, except comparative example, adopt heating plate to implement contact heating pressurized treatments to the back side of pile fabric.The condition of contact heating pressurized treatments is as shown in table 1 below.
Production Example 1 ~ 6 adopts identical pile fiber and wire gauze, and Production Example 1 is do not carry out contacting the comparative example of heating pressurized treatments, and Production Example 2 ~ 6 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 7 ~ 12 adopts identical pile fiber and wire gauze, and Production Example 7 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 8 ~ 12 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 13 ~ 18 adopts identical pile fiber and wire gauze, and Production Example 13 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 14 ~ 18 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 19 ~ 22 adopts identical pile fiber and wire gauze, and Production Example 19 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 20 ~ 22 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 23 ~ 26 adopts identical pile fiber and wire gauze, and Production Example 23 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 24 ~ 26 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 27 ~ 30 adopts identical pile fiber and wire gauze, and Production Example 27 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 28 ~ 30 is the embodiments of having carried out different contact heating pressurized treatments respectively.
(Production Example 31 ~ 40)
Except adopting the pile fiber sliver be made up of acrylic fiber shown in following table 2 and carrying out, except contact heating pressurized treatments, obtaining the pile fabric of Production Example 31 ~ 35 in the same manner as Production Example 1 ~ 30 under the condition shown in following table 2.In addition, except adopting above-mentioned kapok yarn as wire gauze, adopting the pile fiber sliver be made up of acrylic fiber shown in following table 2 and carry out, except contact heating pressurized treatments, obtaining the pile fabric of Production Example 36 ~ 40 in the same manner as Production Example 1 ~ 30 under the condition shown in following table 2.Production Example 31 ~ 35 adopts same pile fiber and wire gauze, Production Example 31 does not carry out contacting the comparative example of heating pressurized treatments, Production Example 32 ~ 34 is under the set point of temperature of the softening point lower than pile fiber, carried out contacting the comparative example of heating pressurized treatments respectively, and Production Example 35 has carried out contacting the embodiment of heating pressurized treatments under the set point of temperature more than the softening point of pile fiber.In addition, Production Example 36 ~ 40 adopts same pile fiber and wire gauze, and Production Example 36 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 37 ~ 40 is the embodiments of having carried out different contact heating pressurized treatments respectively.
(Production Example 41 ~ 52)
Except adopting the pile fiber sliver be made up of the blended fiber of acrylic fibers and acrylic fiber shown in following table 3 and carrying out, except contact heating pressurized treatments, obtaining the pile fabric of Production Example 41 ~ 52 in the same manner as Production Example 1 ~ 30 under the condition shown in following table 3.Production Example 41 ~ 44 adopts same pile fiber and wire gauze, and Production Example 41 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 42 ~ 44 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 45 ~ 48 adopts same pile fiber and wire gauze, and Production Example 45 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 46 ~ 48 is the embodiments of having carried out different contact heating pressurized treatments respectively.In addition, Production Example 49 ~ 52 adopts same pile fiber and wire gauze, and Production Example 49 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 50 ~ 52 is the embodiments of having carried out different contact heating pressurized treatments respectively.Further, in an embodiment, all contact heating pressurized treatments are all more than the softening point of acrylic fibers and carry out lower than at the temperature of the softening point of acrylic fiber.
The result fallen gross weight, fall the thickness (hereinafter also referred to as thickness) of the pile fiber outside hair evaluation and feel and wire gauze of the pile fabric of Production Example 1 ~ 52 has been shown in following table 1 ~ 3.Further, in table 1 ~ 3, * mark represents comparative example, also identical below.
In addition, the comparative example of Production Example 1(shown in Fig. 5), Production Example 5(embodiment), Production Example 7(comparative example), Production Example 11(embodiment), Production Example 13(comparative example), Production Example 17(embodiment) sweep electron microscope (SEM) photo (multiplying power 50) of pile fabric.In Figure 5,19a-19b represents the thickness of the pile fiber outside wire gauze.The thickness of pile fiber is also shown in Fig. 5 and falls gross weight.Learn from Fig. 5: by contact heating pressurized treatments, the thickness of the pile fiber outside ground organizational composition fiber be part, and fall gross weight and significantly reduce.
In addition, the result of table 1 ~ 3 is learnt: by the contact heating pressurized treatments of carrying out at the temperature more than the softening point of pile fiber and lower than the softening point of ground organizational composition fiber, the embodiment goods that pile fiber at least partially outside ground organizational composition fiber is fused, be crimped to fall hair few, feel is also good.In addition, the thickness of the pile fiber outside the wire gauze above-mentionedly to be fused, be crimped be the embodiment goods of less than 300 μm to fall hair few, feel is also good.Further, can confirm that the pile fiber at least partially outside wire gauze is fused, is crimped by the SEM photo (multiplying power 50) that Fig. 5 is such.
In addition, if sum up the thickness of the pile fiber outside wire gauze according to the result of table 1 ~ 3 and fall the relation of hair, be then the curve shown in Fig. 6.Learnt by Fig. 6: if the thickness of the pile fiber outside above-mentioned wire gauze is below 300 μm, then falls gross weight and significantly reduce.
(Production Example 53)
Except not making backing resin impregnated, in the same manner as Production Example 26, obtain the pile fabric of Production Example 53.The result fallen gross weight, fall hair evaluation, feel and thickness etc. of the pile fabric of Production Example 53 shown in following table 4.Further, also illustrate Production Example 23(comparative example in the lump in table 4) result.From Production Example 23(comparative example) and Production Example 53(embodiment) relatively learn: even if do not make backing resin impregnated, fall gross weight and also significantly reduce.That is, learn: organize back side contact heating pressurized treatments with only passing through, fall gross weight and just significantly reduce.
(Production Example 54 ~ 55)
As wire gauze, adopt above-mentioned polyester fiber silk, adopt the pile fiber be made up of the blended fiber of acrylic fibers shown in following table 5, by the method same with the manufacture method of common fur suede, obtain the pile fabric of Production Example 54 and 55.Shown in following table 5, condition when contacting heating pressurized treatments carried out to the back side of the ground tissue of fur suede and fall the result that hair falls hair evaluation, feel and thickness etc.Further, Production Example 54 and 55 adopts same pile fiber and wire gauze, Production Example 54 does not carry out contacting the comparative example of heating pressurized treatments, and Production Example 55 has carried out contacting the embodiment of heating pressurized treatments.
As expressed in table 5, because fur suede botany is knitting, therefore thickness is natively thin, falls gross weight little, but makes thickness more thinning by contact heating pressurized treatments, therefore has the tendency that gross weight also reduces more.Further, in Production Example, except Production Example 54 and 55, it is all the Production Example of plush.
(Production Example 56 ~ 59)
Except adopting above-mentioned polyester fiber silk as wire gauze, adopting the pile fiber shown in following table 6, adopting the processing unit (plant) shown in Fig. 4 to carry out, except contact heating pressurized treatments, obtaining the pile fabric of Production Example 56 ~ 59 in the same manner as Production Example 16 under the condition shown in following table 6.Shown in following table 6 contact heating pressurized treatments condition and fall gross weight, fall the result of hair evaluation, feel and thickness etc.Further, also illustrate the result of Production Example 13 in table 6 in the lump.
Learn from the result of table 6: if pressure during contact heating pressurized treatments increases, then prevent the effect of hair more excellent, but the tendency having feel to decline, pressure during contact heating pressurized treatments is at 0.01 ~ 100Kgf/cm 2scope in, prevent the effect of hair, feel all excellent.
(Production Example 60 ~ 95)
Except adopting polyester fiber silk as wire gauze, adopting the blended fiber of the low melting point polyester fiber shown in following table 7 or low melting point polyester fiber and acrylic fiber to carry out contacting under the condition shown in following table 7 as pile fiber and heat except pressurized treatments, obtain the pile fabric of Production Example 60 ~ 95 in the same manner as Production Example 1 ~ 30.Shown in following table 7 contact heating pressurized treatments condition and fall gross weight, fall the result of hair evaluation, feel and thickness etc.Further, Production Example 60 ~ 95 is all comparative example.
Learn from table 7: if the content of the low melting point polyester fiber pile fiber (Tetoron SD) is lower than 25 % by weight, even if then more than the softening point of low melting point polyester fiber and lower than carry out at the temperature of the softening point of acrylic fiber contact heating pressurized treatments, the effect preventing hair can not be obtained.In addition, when the content of the low melting point polyester fiber (Tetoron SD) in pile fiber is more than 25 % by weight, has along with increase in temperature during contact heating pressurized treatments, curb the tendency of hair, but handling property is poor.In addition, if containing low melting point polyester fiber (Tetoron SD) in pile fiber, then in the polishing operation when the manufacture of pile fabric, low melting point polyester fiber melts away, and can not obtain good outward appearance.
(Production Example 96 ~ 107)
Except adopting polyester fiber silk as wire gauze, adopting the blended fiber of the low melting point polyester fiber shown in following table 8 or low melting point polyester fiber and acrylic fiber as pile fiber, carrying out contacting under the condition shown in following table 8 and heat except pressurized treatments, obtain the pile fabric of Production Example 96 ~ 107 in the same manner as Production Example 1 ~ 30.Shown in following table 8 contact heating pressurized treatments condition and fall gross weight, fall the result of hair evaluation, feel and thickness etc.Further, Production Example 96 ~ 107 is all comparative example.
Learn from table 8: when the content of the low melting point polyester fiber (Unitika 1680) pile fiber is below 20 % by weight, even if more than the softening point of low melting point polyester fiber and lower than carry out at the temperature of the softening point of acrylic fiber contact heating pressurized treatments, the effect of hair can not be prevented significantly.
(Production Example 108)
Adopt polyester fiber silk as wire gauze, the low melting point polyester fiber of content more than 20 % by weight (Unitika 1680) of employing low melting point polyester fiber (Unitika 1680) and the blended fiber of acrylic fiber " K691 " are as pile fiber, attempt the manufacture of the pile fabric of Production Example 108, but can not pile fabric be processed into.By compared with acrylic fiber and acrylic fibers, find that the body bone of low melting point polyester fiber (Unitika 1680) is strong, namely the elasticity of staple fibre is strong, crispatura also strong, also sense of fullness is had, therefore think if the content of the low melting point polyester fiber in pile fiber (Unitika 1680) is more than 20 % by weight, then the processability of pile fabric is deteriorated.In addition, think if crispaturaing of low melting point polyester fiber (Unitika 1680) is not stretched out in polishing process, the content of the low melting point polyester fiber (Unitika 1680) in pile fiber is more than 20 % by weight, then in polishing thereafter, have the problems such as resistance is large, generation circumvolution, the processability of pile fabric declines.
Utilizability in industry
The present invention can be applicable to except prevent pile fiber fall except hair, the pile fabric such as Fake Furs, fur suede, car mat, carpet that feel is also excellent is all.
Symbol description
1,21,31 wire gauzes
2,22,32 pile fiber
3 erect pile
4 fused portions
5,25,35 pile fabrics
10 processing unit (plant)s
11 warm-up mills
12 cooling rubber rollers
13,14 metal cooling rollers
15 deflector rolls
16,17 containers
18 pile fabric raw material sheet
18a pile fabric raw material sheet surface
The 18b pile fabric raw material sheet back side

Claims (9)

1. a pile fabric, is characterized in that, is to organize with containing and be wrapped in form on the wire gauze organized describedly and erect the pile fabric of the pile fiber on described ground tissue surface,
Described pile fabric is plush or fur suede,
Described pile fiber is the blended fiber of acrylic fibers or acrylic fibers and acrylic fiber, and the softening point of described pile fiber is lower more describedly than the softening point forming the fiber organized,
Form the fiber organized is the synthetic fiber or cotton yarn that are made up of polyester fiber describedly,
Be wrapped in the pile fiber formed on described the wire gauze organized, the pile fiber be at least partially positioned at outside the wire gauze that forms and organize describedly is fused, and the pile fiber erected on described ground tissue surface is not fused.
2. pile fabric according to claim 1, wherein, be positioned at and form being crimped by the pile fiber fused outside the wire gauze organized describedly, describedly to be fused and the thickness of pile fiber outside being positioned at of the being crimped wire gauze that forms and organize describedly is less than 300 μm.
3. pile fabric according to claim 1, wherein, described pile fiber prevents hair.
4. pile fabric according to claim 1, wherein, is impregnated with backing resin at the back side of described pile fabric.
5. a manufacture method for pile fabric, is characterized in that, is to organize with containing and be wrapped in form on the wire gauze organized describedly and erect the manufacture method of the pile fabric of the pile fiber on described ground tissue surface,
Described pile fabric is plush or fur suede,
Described pile fiber is the blended fiber of acrylic fibers or acrylic fibers and acrylic fiber, the softening point of described pile fiber lower than the softening point forming described the fiber organized,
Form the fiber organized is the synthetic fiber or cotton yarn that are made up of polyester fiber describedly,
By from described the rear side organized more than the softening point of described pile fiber and lower than form described the fiber organized softening point temperature under carry out contact heating and pressurize, make be wrapped in the pile fiber formed on described the wire gauze organized, be positioned at the pile fiber at least partially formed outside the wire gauze organized to be fused, the pile fiber erected on described ground tissue surface is not fused describedly.
6. the manufacture method of pile fabric according to claim 5, wherein, described contact heating is forced through warm-up mill or heating plate carries out.
7. the manufacture method of pile fabric according to claim 5, wherein, when carrying out contact heating pressurization from described the rear side organized and/or after having carried out contacting heating pressurization, cools the described pile fiber side that erects.
8. the manufacture method of pile fabric according to claim 5, wherein, after having carried out contacting heating pressurization from described the rear side organized, has cooled from described the rear side organized.
9. the manufacture method of the pile fabric according to any one of claim 5 ~ 8, wherein, at the back side of described pile fabric infiltration backing resin, by described pile fiber fibrillation and after putting in order, carries out contact heating from described the rear side organized and pressurizes.
CN200980162337.XA 2009-11-09 2009-11-09 Pile fabric and process for producing same Active CN102597348B (en)

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US20120219751A1 (en) 2012-08-30
UA101779C2 (en) 2013-04-25
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EA023898B1 (en) 2016-07-29
EP2500455A1 (en) 2012-09-19
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JP5461572B2 (en) 2014-04-02
CN201942838U (en) 2011-08-24

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