CN102585450A - Coloring master batch used for polyester - Google Patents
Coloring master batch used for polyester Download PDFInfo
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- CN102585450A CN102585450A CN2012100313420A CN201210031342A CN102585450A CN 102585450 A CN102585450 A CN 102585450A CN 2012100313420 A CN2012100313420 A CN 2012100313420A CN 201210031342 A CN201210031342 A CN 201210031342A CN 102585450 A CN102585450 A CN 102585450A
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- color concentrate
- acid
- polyester
- polyol ester
- master batch
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Abstract
The invention discloses a coloring master batch used for polyester, which is composed of the following components with the weight percentage: polyol ester carrier 20-99%, a coloring agent 0.5-80% and a function additive 0-40%. Silicon oxide is not needed to be added into the liquid master batch to adjust viscosity, and good processing performance and storage performance of the liquid master batch are achieved. The liquid coloring master batch is applied to polyester products including polyethylene terephthalate (PET), polybutylece terephthalate (PBT), polyethylene terephtalate glycol-modified (PETG), polythy-lene naphtalate (PEN) and the like.
Description
Technical field
The present invention relates to field of plastic coloring, relate to a kind of carrier that is used for the liquid color concentrate of polyester plastics specifically.
Background technology
Vibrin (PET, PETG, PBT, PEN etc.) is widely used in fields such as packing business, electronic apparatus, health care, building, automobile, weaving.
Polyester is painted to have that painted, the granular look mother of toner is painted, liquid look mother is painted.Liquid look female painted and the painted no dust pollution of comparing of toner, with granular look female painted compare dispersed better, particularly transparent color, liquid look female painted no flow liner, stain are favored by the user more.At present, the liquid look is female, and painted just to be widely used in polyester painted, and particularly light polyester is painted, and liquid look female addition is low, and is less to the performance impact of material.The many mixtures with sorbitan monooleate and Octyl adipate of existing liquid look mother are as carrier.But these product viscosity are lower, during prolonged preservation, and the easy layering of tinting material and carrier, and then possibly cause pigmented polyester to produce aberration.
In order to overcome the demixing phenomenon in the preservation process, adding Si oxide usually among the polyester liquid look mother increases viscosity, but processing conditions is difficult to control.To disclose a kind of Macrogol 200 female as the liquid look of carrier for CN200880107776 for this reason, the demixing phenomenon when this liquid look mother has enough viscosity and prevents prolonged preservation, and can avoid the use of Si oxide thickening material.But still used silica thickener in this patent working example.
Summary of the invention
In order to overcome above-mentioned unfavorable factor, the present invention solves the problem of this area through using polyol ester as the female carrier of the liquid look of polyester article.
To achieve these goals, the present invention adopts following technical scheme:
A kind of color concentrate that is used for polyester is made up of following component and weight percentage: polyol ester carrier 20-99%, tinting material 0.5%-80% and functional agent 0-40%.
Above-mentioned polyol ester carrier comprises polyol esters of fatty acids, lipid acid hexanodioic acid polyol ester or both mixtures of weight-average molecular weight with 500-10000 and zero pour≤70 ℃.
Above-mentioned polyvalent alcohol comprises that molecular weight is more than one the mixture in the polyoxyethylene glycol of 150-8000, W 166 that molecular weight is 200-8000, USP Kosher, TriMethylolPropane(TMP), tetramethylolmethane, NSC 65881 etc., that described lipid acid comprises is sad, in capric acid, LAURIC ACID 99 MIN, palmitinic acid, Triple Pressed Stearic Acid, oleic acid, montanic acid etc. more than one mixture.
Above-mentioned tinting material comprises pigment, dyestuff or both mixtures.Wherein pigment comprises one or more the mixture in carbon black, white titanium pigment, metallic pigment, pearly pigment, azo pigment, pyrene series pigments, benzimidazolone pigment, the quinacridone pigment etc.; Dyestuff comprises one or more the mixture in anthraquinone dyes, disazo dyes, Naphtocyclinon dyestuff, pyrazolone dye, purple cyclic ketones dyestuff, the quinophthalone dyestuff etc.
In order to improve the performance of liquid look mother of the present invention or vibrin; Can add functional agent as required; These auxiliary agents comprise more than one the mixture in photostabilizer (like UV328, UV234, UV3638:Uvinul 4092 H etc.), oxidation inhibitor (as: 1010,1076,168 etc.), static inhibitor (cationic surfactant, aniorfic surfactant, amphoteric surfactant etc.), filler etc.; Usually, those skilled in the art need not too much just to test to confirm suitable concentration.
Liquid look mother of the present invention can pass through conventional dispersing apparatus preparation such as three-roll grinder, dispersion machine, sand mill.
Liquid look mother of the present invention is mainly used in the painted of vibrin such as PET, PETG, PBT, PEN, and its addition is the 0.01%-2.0% of vibrin weight.
Advantage of the present invention is need not add Si oxide to regulate viscosity.Suitable viscosity be can reach through the combination of different polyol esters, liquid look female good processibility and storage property realized.
Embodiment
Following table has provided embodiment and Comparative Examples prescription and viscosity test, and the liquid look female three-roll grinder that adopts prepares.Can find out that from experimental result embodiment 1,2 is higher than Comparative Examples viscosity respectively, be beneficial to prolonged storage and alleviate pumping.
| Composition | Embodiment 1 | Embodiment 2 | Comparative Examples |
| Solvent violet 13 | 1.33% | 1.33% | 1.33% |
| Solvent blue 97 | 0.88% | 0.88% | 0.88% |
| PEG200 | ? | ? | 97.79% |
| Oleic acid hexanodioic acid polyol ester | 97.79% | ? | ? |
| Triple Pressed Stearic Acid hexanodioic acid polyol ester | ? | 5% | ? |
| The PEG200 laurate | ? | 91.79% | ? |
| Antioxidant 1076 | ? | 1% | ? |
| Viscosity (CPS) | 1500 | 1000 | 100 |
Claims (8)
1. a color concentrate that is used for polyester is characterized in that being made up of following component and weight percentage: polyol ester carrier 20-90%, tinting material 0.5%-80% and auxiliary agent 0-40%.
2. color concentrate as claimed in claim 1 is characterized in that said polyol ester carrier comprises polyol esters of fatty acids, lipid acid hexanodioic acid polyol ester or both mixtures.
3. color concentrate as claimed in claim 1 is characterized in that said polyol ester carrier has weight-average molecular weight and zero pour≤70 ℃ of 500-10000.
4. color concentrate as claimed in claim 2 is characterized in that said polyvalent alcohol comprises that molecular weight is one or more the mixture in the polyoxyethylene glycol of 150-8000, W 166 that molecular weight is 200-8000, USP Kosher, TriMethylolPropane(TMP), tetramethylolmethane, the NSC 65881; That described lipid acid comprises is sad, one or more the mixture in the capric acid, LAURIC ACID 99 MIN, palmitinic acid, Triple Pressed Stearic Acid, oleic acid, montanic acid.
5. color concentrate as claimed in claim 1 is characterized in that described tinting material comprises pigment, dyestuff or both mixtures.
6. color concentrate as claimed in claim 1 is characterized in that described auxiliary agent comprises one or more the mixture in dispersion agent, UV light absorber, photostabilizer, oxidation inhibitor, static inhibitor, the filler.
7. color concentrate as claimed in claim 1 is characterized in that said polyester comprises PET, PETG, PBT or PEN.
8. color concentrate as claimed in claim 7, the addition that it is characterized in that described color concentrate is the 0.01%-2.0% of weight polyester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210031342.0A CN102585450B (en) | 2012-02-13 | 2012-02-13 | Coloring master batch used for polyester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210031342.0A CN102585450B (en) | 2012-02-13 | 2012-02-13 | Coloring master batch used for polyester |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102585450A true CN102585450A (en) | 2012-07-18 |
| CN102585450B CN102585450B (en) | 2014-07-02 |
Family
ID=46474727
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210031342.0A Active CN102585450B (en) | 2012-02-13 | 2012-02-13 | Coloring master batch used for polyester |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102585450B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802114A (en) * | 2016-03-28 | 2016-07-27 | 李伟雄 | Plastic liquid coloring agent and preparation technology thereof |
| CN110964281A (en) * | 2019-10-25 | 2020-04-07 | 广东波斯科技股份有限公司 | Metal spraying-free liquid color master and preparation method and application thereof |
| CN111621159A (en) * | 2020-05-25 | 2020-09-04 | 上海翰晖新材料有限公司 | Ultraviolet absorbent for PET packaging and preparation method of PET plastic packaging |
| US10941257B2 (en) | 2016-09-26 | 2021-03-09 | Chroma Color Corporation | Versatile color concentrate for clear polymers |
| WO2021051180A1 (en) | 2019-09-18 | 2021-03-25 | Clariant Plastics & Coatings Brazil | Additive containing liquid masterbatch formulations for polymer articles |
| CN113896912A (en) * | 2021-11-15 | 2022-01-07 | 苏州世名科技股份有限公司 | Liquid color master batch and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475695A (en) * | 2008-12-29 | 2009-07-08 | 王文广 | Wholly-degradable primary color master batch and preparation thereof |
| WO2010117268A1 (en) * | 2009-04-07 | 2010-10-14 | Holland Colours N.V. | Additive concentrate for polymers |
-
2012
- 2012-02-13 CN CN201210031342.0A patent/CN102585450B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475695A (en) * | 2008-12-29 | 2009-07-08 | 王文广 | Wholly-degradable primary color master batch and preparation thereof |
| WO2010117268A1 (en) * | 2009-04-07 | 2010-10-14 | Holland Colours N.V. | Additive concentrate for polymers |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802114A (en) * | 2016-03-28 | 2016-07-27 | 李伟雄 | Plastic liquid coloring agent and preparation technology thereof |
| US10941257B2 (en) | 2016-09-26 | 2021-03-09 | Chroma Color Corporation | Versatile color concentrate for clear polymers |
| WO2021051180A1 (en) | 2019-09-18 | 2021-03-25 | Clariant Plastics & Coatings Brazil | Additive containing liquid masterbatch formulations for polymer articles |
| CN110964281A (en) * | 2019-10-25 | 2020-04-07 | 广东波斯科技股份有限公司 | Metal spraying-free liquid color master and preparation method and application thereof |
| CN111621159A (en) * | 2020-05-25 | 2020-09-04 | 上海翰晖新材料有限公司 | Ultraviolet absorbent for PET packaging and preparation method of PET plastic packaging |
| CN113896912A (en) * | 2021-11-15 | 2022-01-07 | 苏州世名科技股份有限公司 | Liquid color master batch and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102585450B (en) | 2014-07-02 |
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| Inorganic | HEALTH & SAFETY |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 510530 Guangdong city of Guangzhou province Luogang District Yun Hing Road No. 7 Applicant after: Guangdong Persia Technology Co., Ltd. Address before: 510530, C1, No. 22, Po Po (Baiyun) Industrial Zone, Guangzhou, Guangdong Applicant before: Guangzhou Bosi Plastic Pigments Limited Co., Ltd. |
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| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: GUANGZHOU BOSI PLASTIC PIGMENTS CO., LTD. TO: GUANGDONG BOSI TECHNOLOGY CO., LTD. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |