CN101709185A - Waterborne general color paste and preparation method thereof - Google Patents
Waterborne general color paste and preparation method thereof Download PDFInfo
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- CN101709185A CN101709185A CN200910155350A CN200910155350A CN101709185A CN 101709185 A CN101709185 A CN 101709185A CN 200910155350 A CN200910155350 A CN 200910155350A CN 200910155350 A CN200910155350 A CN 200910155350A CN 101709185 A CN101709185 A CN 101709185A
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Abstract
The invention relates to a chemical color paste used in industries of textile coatings and synthetic leather and a preparation method thereof. The waterborne general color paste consists of the following components in percentage by weight: 30 to 50 percent of deionized water, 5 to 10 percent of emulsifying agent, 25 to 40 percent of toner, 2 to 5 percent of dispersing agent, 1 to 5 percent of defoaming agent, 0.1 to 2 percent of mildew inhibitor, 1 to 5 percent of humectant and 1 to 5 percent of antifreezing agent. The invention also discloses a method for preparing the matt coating. Compared with the traditional various waterborne color pastes used in textile coatings and synthetic leather, the color paste of the invention can form a smooth dry film, has improved viscosity, can be stored for a long time without getting mildew and avoids agglomerating at a low temperature; and the color paste has the characteristics of wide application range, good compatibility, stable long-time storage and the like.
Description
Technical field
The present invention relates to a kind of chemical industry mill base that is used for spinning coating, synthetic leather industry and preparation method thereof.
Background technology
Traditional oil pastes is because the use of organic solvent is far longer than aqueous color paste to environment damage with to the able-bodied harm of workman.In recent years also because aqueous polyurethane and latex are increasing in spinning coating, synthetic leather industry usage quantity, so the painted welcome that more and more is subjected to people of use mill base.The aqueous color paste that now is used for spinning coating, synthetic leather industry on the market, because single carrier series mill base is difficult to and spinning coating, the various performances of use for synthetic leather, the resin compatible of kind, cause having only the corresponding and single coloring resin of single serial mill base, single serial mill base can not be general in spinning coating, the various resins of synthetic leather industry.
Summary of the invention
The object of the present invention is to provide a kind of precipitation that in water, is difficult for, steady in a long-term and with the waterborne general color paste of various water-based spinning coatings, synthetic leather resin compatible.
Another object of the present invention is to provide the preparation method of this waterborne general color paste.
Waterborne general color paste of the present invention, composed of the following components by weight percentage:
Deionized water 30-50% emulsifying agent 5-10% toner 25-40%
Dispersion agent 2-5% defoamer 1-5% mould inhibitor 0.1-2%
Wetting Agent for Printing Inks 1-5% frostproofer 1-5%.
Wherein, deionized water plays the various auxiliary agents of dissolving, toner as solvent; Emulsifying agent can play emulsifying effect in water, a kind of carrier promptly is provided; Toner plays painted effect; Dispersion agent can make toner homodisperse in system, helps grinding; Defoamer is used for preventing the whipping process phenomenon of bubbling; Mould inhibitor prevents that mill base is mouldy because of long-time placement; The volatilization of the anti-sealing of wetting Agent for Printing Inks; Put and freeze agent and prevent that mill base from luming at low temperatures.
The preferred content of deionized water is 36-42% in the above-mentioned composition; The preferred content of emulsifying agent is 6-7%; The preferred content of toner is 32.9-37.9%; The preferred content of emulsifying agent is 6-8%; Wherein emulsifying agent is tributyl phenol Soxylat A 25-7, styroyl phenol polyethenoxy ether; Dispersion agent is Sodium hexametaphosphate 99, tripoly phosphate sodium STPP; Defoamer is tributyl phosphate, phenylethyl alcohol oleic acid ester; Mould inhibitor is sodium pentachlorophenate, hydroxybenzoate; Wetting Agent for Printing Inks is ethylene glycol, glycerine; Frostproofer is glycol ether, alkyl succinimide.
The method for preparing waterborne general color paste of the present invention, this method comprises the steps:
1. with in 70% the deionized water adding reactor, add emulsifying agent, dispersion agent, stir, add toner then, stir half an hour, make its preliminary dispersion;
2. with above-mentioned preliminary dispersive mill base, put into three-roll grinder and grind, get the higher work in-process mill base of viscosity;
3. remaining deionized water is joined in the above-mentioned work in-process mill base, add defoamer, stir;
4. add wetting Agent for Printing Inks, frostproofer, mould inhibitor after stirring, stirred 10-30 minute;
5. after stirring, filter, promptly get waterborne general color paste of the present invention.
The present invention compares with existing various spinning coatings, use for synthetic leather aqueous color paste, and mill base can form smooth dry film, and mill base viscosity improves, and mill base can be placed and not mouldy for a long time, and mill base does not lump at low temperatures; Have characteristics such as applied widely, that consistency is good, standing storage is stable; Be applicable to that various spinning coatings, synthetic leather are painted; Simultaneously owing to be aqueous color paste, so the viscosity of mill base can be not enough, general all is the viscosity that increases aqueous color paste by the adding thickening material, but adding thickening material at first is to have increased cost, and mill base lumps easily behind the adding thickening material,, the present invention reaches the adjusting of the slurry viscosity of checking colors so not adding thickening material by the content of adjusting emulsifying agent, the present invention determines the content of emulsifying agent by a large amount of experiments, both made toner can be good at being suspended in deionized water, in the system that emulsifying agent forms, the viscosity of whole mill base is suitable simultaneously, at spinning coating, can be in the leather printing because of the viscosity of mill base too high and influence printing.
Embodiment
Embodiment 1, remove ionized water 50% by weight, tributyl phenol Soxylat A 25-7 emulsifying agent 5.5%, phthalocyanine blue (15:1 type) toner 33.3%, Sodium hexametaphosphate 99 dispersion agent 2%, tributyl phosphate defoamer 3%, sodium pentachlorophenate mould inhibitor 0.1%, ethylene glycol wetting Agent for Printing Inks 1.1%, glycol ether frostproofer 5%.
The method for preparing the blue slurry of above-mentioned waterborne general is:
1. with in 70% the deionized water adding reactor, add tributyl phenol Soxylat A 25-7 emulsifying agent, Sodium hexametaphosphate 99 dispersion agent, stir, add phthalocyanine blue (15:1 type) toner then, stir half an hour, make its preliminary dispersion;
2. with above-mentioned preliminary dispersive mill base, put into three-roll grinder and grind, get the higher work in-process mill base of viscosity;
3. remaining deionized water is joined in the above-mentioned work in-process mill base, add the tributyl phosphate defoamer, stir;
4. the back adding ethylene glycol that stirs wetting Agent for Printing Inks, glycol ether frostproofer, sodium pentachlorophenate mould inhibitor stirred 10-30 minute;
1. after stirring, filter, promptly get the blue slurry of waterborne general of the present invention.
Embodiment 2, remove ionized water 44.5% by weight, styroyl phenol polyethenoxy ether emulsifying agent 8.7%, pigment yellow 83 toner 28.4%, Sodium hexametaphosphate 99 dispersion agent 4.3%, tributyl phosphate defoamer 5%, sodium pentachlorophenate mould inhibitor 1.6%, ethylene glycol wetting Agent for Printing Inks 3.7%, glycol ether frostproofer 3.8%, the preparation method of the above embodiments obtains the yellow slurry of waterborne general as described in embodiment 1.
Embodiment 3, remove ionized water 42.8% by weight, tributyl phenol Soxylat A 25-7 emulsifying agent 6%, pigment Violet 23 toner 32.9%, Sodium hexametaphosphate 99 dispersion agent 3.8%, tributyl phosphate defoamer 5%, sodium pentachlorophenate mould inhibitor 2%, ethylene glycol wetting Agent for Printing Inks 3.8%, glycol ether frostproofer 3.7%, the preparation method of the above embodiments obtains waterborne general purple slurry as described in embodiment 1.
Embodiment 4, remove ionized water 35.8% by weight, styroyl phenol polyethenoxy ether emulsifying agent 8%, pigment yellow 13 toner 37.9%, Sodium hexametaphosphate 99 dispersion agent 3.8%, tributyl phosphate defoamer 5%, sodium pentachlorophenate mould inhibitor 1.5%, ethylene glycol wetting Agent for Printing Inks 3.3%, glycol ether frostproofer 4.7%, the preparation method of the above embodiments obtains the yellow slurry of waterborne general as described in embodiment 1.
Embodiment 5, remove ionized water 34% by weight, styroyl phenol polyethenoxy ether emulsifying agent 10%, No. 170 toners 39% of Pigment red, Sodium hexametaphosphate 99 dispersion agent 5%, tributyl phosphate defoamer 1%, sodium pentachlorophenate mould inhibitor 2%, ethylene glycol wetting Agent for Printing Inks 5%, glycol ether frostproofer 4%, the preparation method of the above embodiments obtains the red slurry of waterborne general as described in embodiment 1.
By above-mentioned prescription do aqueous color paste through the experiment and detection show,
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
Solid content | 28.9% | 31.1% | 30.1% | 30.8% | 29.7% |
Viscosity | 5600mPa·s | 7100mPa·s | 6200mPa·s | 6400mPa·s | 6100mPa·s |
Solid content and viscosity are all comparatively suitable, and toner can be suspended in the system uniformly for a long time, and printing effect is better when being used for spinning coating, leather printing.
Simultaneously tinting strength is higher by 20% than market like product, and fineness is less than 7 μ m, and toner can keep suspended state greater than 5 months in system, and the present invention can mix with water-base resin more than 95% on the market.
Claims (10)
1. a waterborne general color paste is characterized in that, and is composed of the following components by weight percentage:
Deionized water 30-50% emulsifying agent 5-10% toner 25-40%
Dispersion agent 2-5% defoamer 1-5% mould inhibitor 0.1-2%
Wetting Agent for Printing Inks 1-5% frostproofer 1-5%.
2. a kind of waterborne general color paste according to claim 1 is characterized in that, described deionized water content is 36.8-42.8%; Emulsifier content is 6-7%; Toner content is 32.9-37.9%.
3. a kind of waterborne general color paste according to claim 1 is characterized in that, described emulsifier content is 6-8%.
4. according to claim 1 or 2 or 3 described a kind of waterborne general color pastes, it is characterized in that wherein emulsifying agent is tributyl phenol Soxylat A 25-7, styroyl phenol polyethenoxy ether.
5. according to claim 1 or 2 or 3 described a kind of waterborne general color pastes, it is characterized in that wherein dispersion agent is Sodium hexametaphosphate 99, tripoly phosphate sodium STPP.
6. according to claim 1 or 2 or 3 described a kind of waterborne general color pastes, it is characterized in that wherein defoamer is tributyl phosphate, phenylethyl alcohol oleic acid ester.
7. according to claim 1 or 2 or 3 described a kind of waterborne general color pastes, it is characterized in that wherein mould inhibitor is sodium pentachlorophenate, hydroxybenzoate.
8. according to claim 1 or 2 or 3 described a kind of waterborne general color pastes, it is characterized in that wherein wetting Agent for Printing Inks is ethylene glycol, glycerine.
9. according to claim 1 or 2 or 3 described a kind of waterborne general color pastes, it is characterized in that wherein frostproofer is glycol ether, alkyl succinimide.
10. prepare the method for the described waterborne general color paste of claim 1, it is characterized in that, this method comprises the steps:
1. with in 70% the deionized water adding reactor, add emulsifying agent, dispersion agent, stir, add toner then, stir half an hour, make its preliminary dispersion;
2. with above-mentioned preliminary dispersive mill base, put into three-roll grinder and grind, get the higher work in-process mill base of viscosity;
3. remaining deionized water is joined in the above-mentioned work in-process mill base, add defoamer, stir;
4. add wetting Agent for Printing Inks, frostproofer, mould inhibitor after stirring, stir after 10-30 minute, add thickening material;
5. after stirring, filter, promptly get waterborne general color paste of the present invention.
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CN2009101553504A CN101709185B (en) | 2009-12-17 | 2009-12-17 | Waterborne general color paste and preparation method thereof |
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CN2009101553504A CN101709185B (en) | 2009-12-17 | 2009-12-17 | Waterborne general color paste and preparation method thereof |
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CN101709185B CN101709185B (en) | 2011-09-28 |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101845252A (en) * | 2010-06-08 | 2010-09-29 | 丽王化工(南通)有限公司 | Water-based color paste and preparation method thereof |
CN102358811A (en) * | 2011-07-26 | 2012-02-22 | 天津市宝坻区天海印染助剂厂 | Multifunctional environment-friendly color paste |
CN102618125A (en) * | 2012-03-23 | 2012-08-01 | 东莞大宝化工制品有限公司 | Environment-friendly water-based universal bright red color paste and preparation method for same |
CN103694791A (en) * | 2013-12-06 | 2014-04-02 | 上海德粼水性油墨有限公司 | Special waterborne ink for sealing cigarette packs and preparation method thereof |
CN103773114A (en) * | 2014-01-11 | 2014-05-07 | 江门骅弘颜料有限公司 | General water-based color paste and preparation method thereof |
CN105419492A (en) * | 2015-12-17 | 2016-03-23 | 苏州奥莱鑫建材有限公司 | Multifunctional and environment-friendly nano color paste |
CN107503192A (en) * | 2017-08-18 | 2017-12-22 | 天守(福建)超纤科技股份有限公司 | A kind of preparation method of the panchromatic slurries of PU that can be equivalent with panchromatic powder |
CN108055854A (en) * | 2016-07-26 | 2018-05-18 | 江门骅弘科技股份有限公司 | A kind of general color chips of emulsion-type |
CN109679410A (en) * | 2018-12-21 | 2019-04-26 | 河北晨阳工贸集团有限公司 | A kind of waterborne general color paste and preparation method thereof |
CN110862717A (en) * | 2019-11-19 | 2020-03-06 | 江西三越新材料有限公司 | Preparation method of novel environment-friendly color paste |
CN112745719A (en) * | 2021-01-29 | 2021-05-04 | 南京信彩科技有限公司 | Preparation process of environment-friendly color paste for spinning |
-
2009
- 2009-12-17 CN CN2009101553504A patent/CN101709185B/en not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101845252A (en) * | 2010-06-08 | 2010-09-29 | 丽王化工(南通)有限公司 | Water-based color paste and preparation method thereof |
CN102358811A (en) * | 2011-07-26 | 2012-02-22 | 天津市宝坻区天海印染助剂厂 | Multifunctional environment-friendly color paste |
CN102618125A (en) * | 2012-03-23 | 2012-08-01 | 东莞大宝化工制品有限公司 | Environment-friendly water-based universal bright red color paste and preparation method for same |
CN103694791A (en) * | 2013-12-06 | 2014-04-02 | 上海德粼水性油墨有限公司 | Special waterborne ink for sealing cigarette packs and preparation method thereof |
CN103694791B (en) * | 2013-12-06 | 2016-04-27 | 上海德粼水性油墨有限公司 | Tobacco bale sealing aqueous ink special and preparation method thereof |
CN103773114A (en) * | 2014-01-11 | 2014-05-07 | 江门骅弘颜料有限公司 | General water-based color paste and preparation method thereof |
CN105419492A (en) * | 2015-12-17 | 2016-03-23 | 苏州奥莱鑫建材有限公司 | Multifunctional and environment-friendly nano color paste |
CN108055854A (en) * | 2016-07-26 | 2018-05-18 | 江门骅弘科技股份有限公司 | A kind of general color chips of emulsion-type |
CN107503192A (en) * | 2017-08-18 | 2017-12-22 | 天守(福建)超纤科技股份有限公司 | A kind of preparation method of the panchromatic slurries of PU that can be equivalent with panchromatic powder |
CN109679410A (en) * | 2018-12-21 | 2019-04-26 | 河北晨阳工贸集团有限公司 | A kind of waterborne general color paste and preparation method thereof |
CN110862717A (en) * | 2019-11-19 | 2020-03-06 | 江西三越新材料有限公司 | Preparation method of novel environment-friendly color paste |
CN112745719A (en) * | 2021-01-29 | 2021-05-04 | 南京信彩科技有限公司 | Preparation process of environment-friendly color paste for spinning |
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