CN103351647B - Preparation method of water and oil applicable, nano transparent iron oxide yellow paste - Google Patents
Preparation method of water and oil applicable, nano transparent iron oxide yellow paste Download PDFInfo
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- CN103351647B CN103351647B CN201310267879.1A CN201310267879A CN103351647B CN 103351647 B CN103351647 B CN 103351647B CN 201310267879 A CN201310267879 A CN 201310267879A CN 103351647 B CN103351647 B CN 103351647B
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Abstract
The invention relates to a preparation method of water and oil applicable, nano transparent iron oxide yellow paste. The yellow paste is composed of following raw materials in percentage by weight: 10% to 35% of deionized water, 3% to 10% of cosolvent, 1% to 3% of surface conditioning agent, 15 to 25% of dispersion resin, 8% to 20% of wetting dispersant, 0.1% to 0.6% of pH value conditioning agent, 20% to 40% of transparent iron oxide yellow, 0.1% to 1.0% of thickening and anti-settling agent, 0.1% to 0.3% of bactericide, and 0.2% to 1% of antifoaming agent. The particle size D50 of the water and oil applicable nano transparent iron oxide yellow paste is smaller than 1 [mu]m. The nano transparent iron oxide yellow paste has the characteristics of storage stability, transparency, compatibility and environmental-friendliness, is capable of replacing metal complex dye, and is widely applied to the areas of aqueous or oily woodenware paint, automobile finish, plastic paint, metal paint, construction paint, children toys, painting materials, high temperature glass printing ink, and the like.
Description
Technical field
The present invention relates to a kind of preparation method of transparent ferric oxide yellow pulp, particularly relate to a kind of nanometer transparent iron oxide yellow mill base of water and oil applicable.
Background technology
As everyone knows, iron oxide pigment has best light stability, the transparent Indium iron rule of nanometer particle size has the ultraviolet ability of stronger absorption, therefore transparent iron oxide pigment not only own optical stablize, and improve the ageing resistance of all kinds of superpolymer because absorbing ultraviolet.The transparent ferric oxide of nanometer particle size changes common ferric oxide at the absorption of visible light part and scattering property, thus has very high saturation ratio and tinctorial strength.Transparent ferric oxide maintains chemical constitution and the crystal formation of iron oxide pigment, thus has good chemical stability, and have excellent acidproof, alkaline-resisting, solvent resistant, water-fast and oil-proofness, transparent yellow iron oxide has more the resistance toheat more than 300 DEG C.
Transparent ferric oxide mill base used is divided into aqueous color paste and solvent-borne type mill base on the market at present, makes troubles to the use of client; And above-mentioned mill base particularly solvent-borne type saturating iron mill base contain a large amount of VOC compositions, be disadvantageous to environment, the transparent ferric oxide mill base therefore developing a kind of water and oil applicable is necessary.
Summary of the invention
The present invention selects the fatty acid modified polymkeric substance of self-emulsifying type as dispersion resin, this dispersion resin is suitable for water-based and solvent based coating system, have good dispersion stabilization, be better than conventional surfactants far away to disperse particles surface coverage and encapsulating effect, its dispersion system more tends towards stability, flows.Therefore the mill base made has the features such as package stability is good, tinting strength is high, consistency is good.
This dispersion agent is containing pigment affinity groups segmented copolymer, as EFKA-4560, EFKA-4540, BYK-180, BYK-183, BYK-185, HSM-3091 etc., has good dispersing property to mineral dye.
In order to solve technical problem recited above, the present invention takes following technical scheme: the present invention relates to a kind of water and oil applicable nanometer transparent iron oxide yellow mill base, its basic recipe is: deionized water 10% ~ 35%, solubility promoter 3% ~ 10%, surface treatment agent 1% ~ 3%, dispersion resin 15% ~ 25%, wetting dispersing agent 8% ~ 20%, pH value conditioning agent 0.1% ~ 0.6%, transparent yellow iron oxide 20% ~ 40%, thickening anti-settling agent 0.1% ~ 1.0%, sterilant 0.1% ~ 0.3%, defoamer 0.2% ~ 1%.
Wherein, the one of propylene glycol, Macrogol 200, Liquid Macrogol selected by solubility promoter.
Surface treatment agent selects the one of silane coupling agent, boric acid ester coupler, titanate coupling agent.
The fatty acid modified polymkeric substance of self-emulsifying type selected by dispersion resin, preferred EFKA-1502, EFKA-1503.
Wetting dispersing agent is selected containing pigment affinity groups segmented copolymer, the one of preferred EFKA-4560, EFKA-4540, BYK-180, BYK-183, BYK-185, TEGO752W, HSM-3091 or its combination.
Thickening anti-settling agent selects one or its combination of modified alta-mud, urethane, aluminum magnesium silicate, aerosil and HEC.
The present invention proposes a kind of preparation method of water and oil applicable nanometer transparent iron oxide yellow mill base, preparation technology is as follows: add deionized water by formulation weight ratio, sterilant, solubility promoter, surface treatment agent, dispersion resin, wetting dispersing agent, speed with 500r/min in high speed dispersor stirs, then under the high speed of 1000 ~ 1200r/min, transparent ferric oxide bloom is added, high speed dispersion 45min, forward tapered or bar type sand mill circular grinding 6 ~ 10h again to until fineness < 1 μm qualified after, pH value conditioning agent is added under 600 ~ 800r/min in tune cylinder, thickening anti-settling agent stirs 15 ~ 30min, add defoamer under low speed, after viscosity fineness is qualified, filters and packages and obtain water and oil applicable nanometer transparent iron oxide yellow mill base.
The features such as the water and oil applicable nanometer transparent iron oxide yellow mill base package stability that the present invention makes, the transparency, consistency, the feature of environmental protection are good.Be widely used in the field such as water-based or oiliness wood lacquer, automobile finish, plastic paint, metallic paint, building coating, toy for children, picture material, high temp glass ink.
Embodiment
Prepare material according to the component formula of table 1 to implement.
Table 1: three embodiment component formula mass parts
| Material name | Example 1 | Example 2 | Example 3 |
| Deionized water | 22.6 | 22.6 | 14.5 |
| Sterilant | 0.2 | 0.2 | 0.2 |
| Propylene glycol | 5 | 5 | 6 |
| Titanate coupling agent CT115A | 1.5 | 1.5 | 1.5 |
| Dispersion resin EFKA-1502 | 24 | - | - |
| Dispersion resin EFKA-1503 | - | 25 | 25 |
| BYK-180 | 10 | - | - |
| EFKA4560 | - | 10 | - |
| TEGO752W | - | - | 12 |
| Transparent yellow iron oxide | 36 | 35 | 40 |
| AMP-95 | 0.4 | 0.4 | 0.4 |
| BYK-024 | 0.2 | 0.2 | 0.3 |
| Gas phase SiO 2 | 0.1 | 0.1 | 0.1 |
Embodiment 1:
Deionized water, sterilant, propylene glycol, CT-115A, EFKA-1502, BYK-180 is added by formulation weight ratio according to example in table 11, speed with 500r/min in high speed dispersor stirs, then under the high speed of 1000 ~ 1200r/min, transparent ferric oxide bloom, high speed dispersion 45min is added, forward tapered or bar type sand mill circular grinding 6 ~ 10h again to until fineness < 1 μm qualified after, in tune cylinder, add AMP-95, gas phase SiO under 600 ~ 800r/min
2stir 15 ~ 30min; Add BYK-024 under low speed, after viscosity fineness is qualified, filters and packages and obtain water and oil applicable nanometer transparent iron oxide yellow mill base.
Embodiment 2, embodiment 3 preparation process is with reference to embodiment 1.
According to relevant national standard, detect the performance of water and oil applicable nanometer transparent iron oxide yellow mill base of the present invention, test result is as shown in table 2.
Table 2 water and oil applicable nanometer transparent iron oxide yellow mill base fundamental property test result
The versatility of mill base of the present invention is checked by compatibility test method, be specially: the mill base amount by 5% joins in the coating made by all kinds of emulsion and resin, the wet film device mixing rear use 200 μm carries out film making sheet, test by the finger method of grinding, refer to grind region without loose colour or grow diming phenomenon after dry, refer to grind region and value of chromatism △ E≤0.5 of non-abrasive areas be considered as qualified.
Table 3 water and oil applicable nanometer transparent iron oxide yellow mill base compatibility test result
| Emulsion or resinous type | Compatibility test | △E |
| Benzene emulsion | Qualified | 0.32 |
| Pure-acrylic emulsion | Qualified | 0.26 |
| Acrylate and vinyl acetate emulsion | Qualified | 0.38 |
| Tertiary acrylic emulsion | Qualified | 0.32 |
| Aqueous polyurethane emulsion | Qualified | 0.4 |
| Aqueous alkide resin | Qualified | 0.4 |
| Oiliness acrylic resin | Qualified | 0.42 |
| Long oil alkyd | Qualified | 0.36 |
| Oiliness urethane resin | Qualified | 0.46 |
Although the present invention has been explained in detail and has quoted embodiment as proof, for those of ordinary skill in the art, the various schemes obviously can made according to above-mentioned explanation, amendment and change, within the scope that all should be included in claim.
Claims (4)
1. a water and oil applicable nanometer transparent iron oxide yellow mill base, it is characterized in that: by weight percentage, it consists of: deionized water 22.6%, co-solvents propylene glycol 5%, surface treatment agent titanate coupling agent 1.5%, EFKA-1502 self-emulsifying type dispersion resin 24%, BYK-180 wetting dispersing agent 10%, pH value regulator 0.4%, transparent yellow iron oxide 36%, gas phase SiO
20.1%, sterilant 0.2%, BYK-024 defoamer 0.2%; The particle diameter of described water and oil applicable nanometer transparent iron oxide yellow mill base is D
50< 1 μm.
2. a water and oil applicable nanometer transparent iron oxide yellow mill base, it is characterized in that: by weight percentage, it consists of: deionized water 22.6%, co-solvents propylene glycol 5%, surface treatment agent titanate coupling agent 1.5%, EFKA-1503 self-emulsifying type dispersion resin 25%, EFKA-4560 wetting dispersing agent 10%, pH value regulator 0.4%, transparent yellow iron oxide 35%, gas phase SiO
20.1%, sterilant 0.2%, BYK-024 defoamer 0.2%; The particle diameter of described water and oil applicable nanometer transparent iron oxide yellow mill base is D
50< 1 μm.
3. a water and oil applicable nanometer transparent iron oxide yellow mill base, it is characterized in that: by weight percentage, it consists of: deionized water 14.5%, co-solvents propylene glycol 6%, surface treatment agent titanate coupling agent 1.5%, EFKA-1503 self-emulsifying type dispersion resin 25%, TEGO-752W wetting dispersing agent 12%, pH value regulator 0.4%, transparent yellow iron oxide 40%, gas phase SiO
20.1%, sterilant 0.2%, BYK-024 defoamer 0.3%; The particle diameter of described water and oil applicable nanometer transparent iron oxide yellow mill base is D
50< 1 μm.
4. as claim 1, a kind of water and oil applicable nanometer transparent iron oxide yellow mill base described in 2 or 3, it is characterized in that: described preparation method comprises: add deionized water by formulation weight ratio, sterilant, solubility promoter, surface treatment agent, dispersion resin, wetting dispersing agent, speed with 500r/min in high speed dispersor stirs, then under the high speed of 1000 ~ 1200r/min, transparent ferric oxide bloom is added, high speed dispersion 45min, forward tapered or bar type sand mill circular grinding 6 ~ 10h again to until fineness < 1 μm qualified after, pH value regulator is added under 600 ~ 800r/min in tune cylinder, thickening anti-settling agent stirs 15 ~ 30min, add defoamer under low speed, after viscosity fineness is qualified, filters and packages and obtain water and oil applicable nanometer transparent iron oxide yellow mill base.
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| CN105885658B (en) * | 2016-05-04 | 2018-04-13 | 雅图高新材料有限公司 | A kind of aqueous one-component automobile coating containing iron oxide pigment and preparation method thereof |
| CN106189367A (en) * | 2016-07-27 | 2016-12-07 | 升华集团德清华源颜料有限公司 | A kind of easily dispersion lipophile iron oxide yellow |
| CN106243781A (en) * | 2016-07-27 | 2016-12-21 | 升华集团德清华源颜料有限公司 | A kind of preparation method of easy dispersion lipophile iron oxide yellow |
| CN109996849A (en) * | 2016-09-26 | 2019-07-09 | 图像电子公司 | The ink-jet of construction material is decorated |
| CN109627854A (en) * | 2018-12-21 | 2019-04-16 | 河北晨阳工贸集团有限公司 | A kind of waterborne general color paste and preparation method thereof |
| CN113956680B (en) * | 2021-11-24 | 2023-09-22 | 浙江纳美新材料股份有限公司 | Universal color concentrate for odor-free water and oil and preparation method thereof |
| CN114213903A (en) * | 2021-12-16 | 2022-03-22 | 抚州贝尔斯涂料有限公司 | Water-oil universal color paste and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569982A (en) * | 2003-07-21 | 2005-01-26 | 深圳市海川实业股份有限公司 | Hydrophobic ferric oxide aqueous color paste |
| CN101469153A (en) * | 2007-12-24 | 2009-07-01 | 深圳市海川实业股份有限公司 | Environment friendly transparent iron oxide black superfine aqueous color sizing dispersion and preparation thereof |
| CN102977688A (en) * | 2012-11-27 | 2013-03-20 | 东莞大宝化工制品有限公司 | Water and oil available color paste and preparation method of same |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1569982A (en) * | 2003-07-21 | 2005-01-26 | 深圳市海川实业股份有限公司 | Hydrophobic ferric oxide aqueous color paste |
| CN101469153A (en) * | 2007-12-24 | 2009-07-01 | 深圳市海川实业股份有限公司 | Environment friendly transparent iron oxide black superfine aqueous color sizing dispersion and preparation thereof |
| CN102977688A (en) * | 2012-11-27 | 2013-03-20 | 东莞大宝化工制品有限公司 | Water and oil available color paste and preparation method of same |
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Effective date of registration: 20151203 Address after: 513000 office building C407, Qingyuan overseas Chinese Industrial Park, Donghua Town, Yingde Town, Qingyuan, Guangdong Patentee after: YINGDE KEDI PIGMENT TECHNOLOGY CO., LTD. Address before: 511442 Guangdong, Panyu District, Tai Lung Street, tea village, Dongxing Road, No. four, No. 1, No. 5 road, one of the road Patentee before: Guangzhou Fanyu Keytec Colors Co., Ltd. |