CN102336522A - Preparation method for lake blue crystal bead embryo - Google Patents
Preparation method for lake blue crystal bead embryo Download PDFInfo
- Publication number
- CN102336522A CN102336522A CN2011101741074A CN201110174107A CN102336522A CN 102336522 A CN102336522 A CN 102336522A CN 2011101741074 A CN2011101741074 A CN 2011101741074A CN 201110174107 A CN201110174107 A CN 201110174107A CN 102336522 A CN102336522 A CN 102336522A
- Authority
- CN
- China
- Prior art keywords
- parts
- blue crystal
- lake water
- pearl embryo
- crystal pearl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Dental Preparations (AREA)
- Farming Of Fish And Shellfish (AREA)
Abstract
The invention relates to the field of artificial crystal products, and especially to a preparation method for lake blue crystal bead embryos. The invention aims to overcome the shortcomings of poor coloring reproducibility, instable product quality, low production efficiency and unsuitability for continuous tank furnace production operation in existing preparation processes for lake blue crystal bead embryos and provides the preparation method for lake blue crystal bead embryos with the advantages of good coloring reproducibility, stable product quality, high production efficiency and suitability for continuous tank furnace production operation. The technical key point of the invention is as follows: raw materials for preparing lake blue crystal bead embryos comprise, by weight, 50 to 70 parts of quartz sand, 5 to 15 parts of soda ash, 4 to 16 parts of potassium phosphate, 2 to 9 parts of potassium nitrate, 2 to 5 parts of boric acid, no more than 10 parts of lead silicate, no more than 3 parts of aluminum hydroxide, no more than 3 parts of calcium carbonate, no more than 1 part of lithium carbonate, no more than 5 parts of barium carbonate, no more than 5 parts of titanium dioxide, no more than 3 parts of magnesium carbonate and no more than 2 parts of copper oxide.
Description
Technical field
The present invention relates to the artificial crystal production field, the preparation method of the blue crystal pearl embryo of particularly a kind of lake water.
Background technology
The blue crystal pearl embryo of lake water is the work in-process that are used for preparing lake water blue crystal product; Be to adopt cupric ion painted in the blue crystal pearl embryo of the existing preparation lake water technology; Cupric ion is provided by CuO, adopt product ubiquity that the blue crystal pearl embryo of existing preparation lake water explained hereafter goes out color reproduction poor, unstable product quality; Production efficiency is low, is not suitable for the weak point of the production operation of continuous tank furnace.In addition, in the blue crystal pearl embryo of existing preparation lake water technology, in the composition of raw materials of the blue crystal pearl embryo of lake water, the red lead component is arranged, red lead is volatile, can cause environmental pollution.
Summary of the invention
It is poor to the objective of the invention is to existing above-mentioned the color reproduction of the blue crystal pearl embryo of existing preparation lake water technology; Unstable product quality, production efficiency is low, is not suitable for the weak point of the production operation of continuous tank furnace; Provide a kind of color reproduction good; Constant product quality, production efficiency is high, can be fit to the preparation method of the blue crystal pearl embryo of lake water of the production operation of continuous tank furnace.
The technical scheme that the present invention adopted is accomplished through following mode: the preparation method of the blue crystal pearl embryo of a kind of lake water, the weight proportion of the blue crystal pearl embryo of this lake water raw material is: 50～70 parts of silica sands, 5～15 parts of soda ash, 4～16 parts of potassiumphosphates, 2～9 parts in saltpetre, 2～5 parts of boric acid, lead silicate≤10 part, white lake≤3 part, lime carbonate≤3 part, Quilonum Retard≤1 part, barium carbonate≤5 part, white titanium pigment≤5 part, magnesiumcarbonate≤3 part, cupric oxide≤2 part.
In the preparation method of the blue crystal pearl embryo of above-mentioned lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, keep oxidizing atmosphere and glass quartz liquation liquid level stabilizing when founding;
(4) the glass quartz liquation is molded into turq water after the homogenizing cooling and bores the pearl embryo.
In the preparation method of the blue crystal pearl embryo of above-mentioned lake water, in the preparation process (3) of the blue crystal pearl embryo of lake water, temperature is controlled at 1300 ℃～1500 ℃ when founding.
In the preparation method of the blue crystal pearl embryo of above-mentioned lake water, in the preparation process (4) of the blue crystal pearl embryo of lake water, cooling temperature is controlled at 550 ℃～1030 ℃, and is preferred: 750 ℃～900 ℃.
The preparation method of the blue crystal pearl embryo of lake water of the present invention compares with the blue crystal pearl embryo of existing preparation lake water technology, has following characteristics:
1, adopts the blue crystal pearl embryo of lake water of the present invention composition of raw materials, make the redox equilibrium of cupric ion in the process of founding keep stable, thereby obtain to have the lake water of well reproduced property blue.
2, the preparation method of the blue crystal pearl embryo of lake water of the present invention has reduced plumbous content in the crystal pearl embryo, adopts the Na-K-B-Si system to reach the optical property requirement of high refractive index.
3, in the blue crystal pearl embryo of lake water of the present invention composition of raw materials, replace red lead with lead silicate, lead silicate is more stable, and is not volatile, has environment protection significance.
4, the present invention can carry out the continuous working kiln production operation, has improved efficient and production capacity.
Embodiment
Through embodiment the present invention is made further below and specifying.
Embodiment 1
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 50 parts of silica sands, 5 parts of soda ash, 4 parts of potassiumphosphates, 2 parts in saltpetre, 2 parts of boric acid, 1 part in lead silicate, 1 part in white lake, 1 part in lime carbonate, 1 part of Quilonum Retard, 2 parts of barium carbonates, 2 parts of white titanium pigments, 1 part in magnesiumcarbonate, 1 part of cupric oxide;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 550 ℃～1030 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 2
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 70 parts of silica sands, 15 parts of soda ash, 16 parts of potassiumphosphates, 9 parts in saltpetre, 5 parts of boric acid, 10 parts in lead silicate, 3 parts in white lake, 3 parts in lime carbonate, 1 part of Quilonum Retard, 5 parts of barium carbonates, 5 parts of white titanium pigments, 3 parts in magnesiumcarbonate, 2 parts of cupric oxide;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 550 ℃～1030 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 3
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 60 parts of silica sands, 10 parts of soda ash, 9 parts of potassiumphosphates, 6 parts in saltpetre, 3 parts of boric acid, 5 parts in lead silicate, 2 parts in white lake, 1 part in lime carbonate, 0.5 part of Quilonum Retard, 2 parts of barium carbonates, 3 parts of white titanium pigments, 1 part in magnesiumcarbonate, 1 part of cupric oxide;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 4
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 55 parts of silica sands, 7 parts of soda ash, 8 parts of potassiumphosphates, 4 parts in saltpetre, 4 parts of boric acid, 3 parts in white lake, 2 parts in lime carbonate, 5 parts of barium carbonates, 5 parts of white titanium pigments, 3 parts in magnesiumcarbonate, 2 parts of cupric oxide;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 5
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 65 parts of silica sands, 13 parts of soda ash, 4 parts of potassiumphosphates, 2 parts in saltpetre, 3 parts of boric acid, lead silicate≤10 part, lime carbonate≤3 part, Quilonum Retard≤1 part, white titanium pigment≤5 part, magnesiumcarbonate≤3 part, cupric oxide≤2 part;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 6
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 57 parts of silica sands, 6 parts of soda ash, 6 parts of potassiumphosphates, 3 parts in saltpetre, 4 parts of boric acid, 9 parts in lead silicate, 3 parts in white lake, 0.2 part of Quilonum Retard, 0.5 part of barium carbonate, 3 parts of white titanium pigments, 0.2 part of cupric oxide;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 7
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 68 parts of silica sands, 12 parts of soda ash, 9 parts of potassiumphosphates, 4 parts in saltpetre, 5 parts of boric acid, 10 parts in lead silicate, 3 parts in white lake, 3 parts in lime carbonate, 1 part of Quilonum Retard, 5 parts of barium carbonates, 3 parts in magnesiumcarbonate, cupric oxide≤2 part;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into turq water and bore the pearl embryo.
Embodiment 8
The preparation method of the blue crystal pearl embryo of a kind of lake water, the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes; Wherein, the composition of raw materials (weight ratio) of the blue crystal pearl embryo of lake water is: 62 parts of silica sands, 9 parts of soda ash, 10 parts of potassiumphosphates, 5 parts in saltpetre, 2 parts of boric acid, 3 parts in lead silicate, 2 parts in white lake, 1 part in lime carbonate, 1 part of Quilonum Retard, 4 parts of barium carbonates, 3 parts of white titanium pigments, 2 parts in magnesiumcarbonate;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, when founding, temperature is controlled at 1300 ℃～1500 ℃, keeps oxidizing atmosphere and glass quartz liquation liquid level stabilizing;
(4) with the glass quartz liquation when homogenizing is cooled to 750 ℃～900 ℃, be molded into turq water and bore the pearl embryo.
Claims (4)
1. the preparation method of the blue crystal pearl embryo of a lake water is characterized in that the weight proportion of the blue crystal pearl embryo of this lake water raw material is: 50～70 parts of silica sands, 5～15 parts of soda ash, 4～16 parts of potassiumphosphates, 2～9 parts in saltpetre, 2～5 parts of boric acid, lead silicate≤10 part, white lake≤3 part, lime carbonate≤3 part, Quilonum Retard≤1 part, barium carbonate≤5 part, white titanium pigment≤5 part, magnesiumcarbonate≤3 part, cupric oxide≤2 part.
2. the preparation method of the blue crystal pearl embryo of lake water according to claim 1 is characterized in that the preparation method of the blue crystal pearl embryo of lake water may further comprise the steps:
(1) after being weighed up by weight ratio, the raw material of the blue crystal pearl embryo of lake water mixes;
(2) the blue crystal pearl embryo of the lake water that mixes raw material is carried out granulation through tablets press;
(3) will process the blue crystal pearl embryo of granular lake water raw material and put into the glass quartz tank furnace and found, keep oxidizing atmosphere and glass quartz liquation liquid level stabilizing when founding;
(4) the glass quartz liquation is molded into turq water after the homogenizing cooling and bores the pearl embryo.
3. the preparation method of the blue crystal pearl embryo of lake water according to claim 2 is characterized in that temperature is controlled at 1300 ℃～1500 ℃ when founding in the preparation process (3) of the blue crystal pearl embryo of lake water.
4. the preparation method of the blue crystal pearl embryo of lake water according to claim 2 is characterized in that cooling temperature is controlled at 550 ℃～1030 ℃ in the preparation process (4) of the blue crystal pearl embryo of lake water, and is preferred: 750 ℃～900 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101741074A CN102336522A (en) | 2011-06-27 | 2011-06-27 | Preparation method for lake blue crystal bead embryo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101741074A CN102336522A (en) | 2011-06-27 | 2011-06-27 | Preparation method for lake blue crystal bead embryo |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102336522A true CN102336522A (en) | 2012-02-01 |
Family
ID=45512529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101741074A Pending CN102336522A (en) | 2011-06-27 | 2011-06-27 | Preparation method for lake blue crystal bead embryo |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102336522A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082648A (en) * | 2016-06-15 | 2016-11-09 | 浙江伟兴水晶有限公司 | A kind of crystal bead blank of lake water orchid color and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN101186437A (en) * | 2006-11-17 | 2008-05-28 | 山东省药用玻璃股份有限公司 | Neutral boron silicate glass used for medicinal mold-formed bottle and manufacturing method thereof |
| JP2010083721A (en) * | 2008-09-30 | 2010-04-15 | Reiseki:Kk | Method for storing granulate or powdery object to be stored |
| CN101857355A (en) * | 2010-06-02 | 2010-10-13 | 天台精工西力玻璃珠有限公司 | Method for producing glass beads used for curing high-level nuclear wastes |
-
2011
- 2011-06-27 CN CN2011101741074A patent/CN102336522A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5656559A (en) * | 1994-06-23 | 1997-08-12 | Saint-Gobain Vitrage | Clear glass composition intended for the production of panes |
| CN101186437A (en) * | 2006-11-17 | 2008-05-28 | 山东省药用玻璃股份有限公司 | Neutral boron silicate glass used for medicinal mold-formed bottle and manufacturing method thereof |
| JP2010083721A (en) * | 2008-09-30 | 2010-04-15 | Reiseki:Kk | Method for storing granulate or powdery object to be stored |
| CN101857355A (en) * | 2010-06-02 | 2010-10-13 | 天台精工西力玻璃珠有限公司 | Method for producing glass beads used for curing high-level nuclear wastes |
Non-Patent Citations (3)
| Title |
|---|
| 周琦等: "《镍渣微晶玻璃制备及铁的回收利用》", 《兰州理工大学学报》 * |
| 李佳颍: "《不同氧化物对SiO_2-B_2O_3-R_2O系无铅水晶玻璃性能的影响》", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑 》 * |
| 西北轻工业学院: "《玻璃工艺学》", 31 January 2000, 中国轻工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106082648A (en) * | 2016-06-15 | 2016-11-09 | 浙江伟兴水晶有限公司 | A kind of crystal bead blank of lake water orchid color and preparation method thereof |
| CN106082648B (en) * | 2016-06-15 | 2018-06-26 | 浙江伟兴水晶有限公司 | A kind of crystal bead blank of lake water orchid color and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102503126A (en) | Preparation method for smoky yellow crystal bead blanks | |
| CN102515532A (en) | Preparation method of light-peach-colored crystal bead blanks | |
| CN102503127A (en) | Preparation method for light blue crystal bead blanks | |
| CN102442779A (en) | Method for preparing peacock blue crystal bead embryo | |
| CN102515473A (en) | Preparation method for transparent black crystal ball blank | |
| CN102674694B (en) | Preparation method for modena crystal bead blank | |
| CN103922594B (en) | A kind of large red color crystal bead blank and preparation method thereof | |
| CN104556698B (en) | A kind of cigarette yellow crystal pearl embryo and preparation method thereof | |
| CN102367199B (en) | Preparation method of lilac crystal bead stock | |
| CN102336522A (en) | Preparation method for lake blue crystal bead embryo | |
| CN102515531B (en) | Preparation method of dark green crystal bead blanks | |
| CN102531340A (en) | Preparation method of light pink crystal bead embryo | |
| CN102320747A (en) | Preparation method of shallow crystal and yellow crystal bead blank | |
| CN102372433B (en) | Preparation method of yellow crystal ball blank | |
| CN102372432B (en) | Preparation method of dark blue crystal ball blank | |
| CN104556699B (en) | A kind of red-purple crystal bead blank and preparation method thereof | |
| CN104478214B (en) | A kind of pale pink look crystal bead blank and preparation method thereof | |
| CN102718387A (en) | Preparation method of large black crystal bead semi-finished product | |
| CN103936282B (en) | A kind of shallow large red color crystal bead blank and preparation method thereof | |
| CN104556696B (en) | A kind of rosy quartz pearl embryo and preparation method thereof | |
| CN104496178B (en) | A kind of rose crystal bead blank and preparation method thereof | |
| CN102503128B (en) | Preparation method for light green crystal bead blank | |
| CN103922593B (en) | A kind of deep-red coloration crystal bead blank and preparation method thereof | |
| CN104556697B (en) | A kind of golden yellow crystal bead blank and preparation method thereof | |
| CN103922592B (en) | A kind of orange color crystal bead blank and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120201 |