CN102298475B - Indium tin oxide (ITO) through hole integrated capacitive touch screen and production method thereof - Google Patents

Indium tin oxide (ITO) through hole integrated capacitive touch screen and production method thereof Download PDF

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CN102298475B
CN102298475B CN201110234546A CN201110234546A CN102298475B CN 102298475 B CN102298475 B CN 102298475B CN 201110234546 A CN201110234546 A CN 201110234546A CN 201110234546 A CN201110234546 A CN 201110234546A CN 102298475 B CN102298475 B CN 102298475B
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ito
electrode
thickness
ethylmercurichlorendimides
hole
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CN102298475A (en
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曹晓星
李晗
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SHENZHEN BAOMING TECHNOLOGY Co Ltd
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SHENZHEN BAOMING TECHNOLOGY Co Ltd
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Priority to PCT/CN2012/077351 priority patent/WO2013023491A1/en
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    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/044Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
    • G06F3/0443Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using a single layer of sensing electrodes
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/044Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means
    • G06F3/0446Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means by capacitive means using a grid-like structure of electrodes in at least two directions, e.g. using row and column electrodes
    • GPHYSICS
    • G06COMPUTING; CALCULATING OR COUNTING
    • G06FELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04103Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices

Abstract

The invention discloses an indium tin oxide (ITO) through hole integrated capacitive touch screen and a production method thereof. The ITO through hole integrated capacitive touch screen comprises a transparent glass substrate, and a black resin layer, an ITO electrode, a first insulating layer, an ITO through hole electrode, a metal electrode and a second insulating layer which are sequentially stacked on the transparent glass substrate. The ITO electrode comprises an ITO electrode 1 and an ITO electrode 2 and has a regular pattern structure, wherein the ITO electrode 1 and the ITO electrode 2 are arranged on the same layer, are independent to each other, are insulated with each other and are designed perpendicularly. The transparent substrate comprises a window area and a non-window area. The black resin layer is distributed in the non-window area of the display screen. The line of the metal electrode is only wired in the area of the black resin layer. By reasonably designing the stacking structure and the ITO conduction method of the capacitive touch screen and by adopting an ITO through hole method to conduct ITO signal electrodes up and down, the light transmittance, the working stability and the touch sensitivity of the capacitive touch screen are effectively improved.

Description

ITO through hole integral type capacitance touch screen and manufacturing approach
Technical field
The present invention relates to the capacitance touch screen technical field, especially relate to a kind of integral type capacitance touch screen and manufacturing approach thereof through the ITO via design.
Background technology
Along with the development of electronics technology, the keyboard of mobile phone, digital camera, handheld device, vehicle-carrying DVD, MP3, instrument etc. or mouse are touched gradually to shield and substitute at present.The product of touch-screen is not very burning hot several years ago, and Along with people's is more and more for the contact of touch screen product, is also approved that speed of development was accelerated gradually in nearly 2 years by more people.Touch-screen is grown up rapidly, has not only evoked fierce more industry competition, has also promoted technological development indirectly, and the mode of operation of its multi-point touch has risen to a new height to the influence power of touch-screen product especially, is also paid close attention to by people gradually.
Touch-screen is mainly formed by touching detection part and touch screen controller, touches detection part and is installed in the indicator screen front, is used to detect user touch location, send touch screen controller after the reception; And the main effect of touch screen controller is to receive touch information from touch point detection device, and converts it to contact coordinate, gives CPU again, and its can receive simultaneously the order that CPU sends and carry out.
According to the principle of work of touch-screen medium with transmission information; Touch-screen can be divided into four kinds; Be respectively resistance-type, capacitor induction type, infrared-type and surface acoustic wave type, current what be widely used is resistive touch screen, and it utilizes pressure sensitive to carry out resistance control; Resistive touch screen is a kind of laminated film of multilayer, and its major part is a resistance film screen that cooperates very much with display surface.Resistance film screen be with one deck glass or duroplasts flat board as basic unit, the surface scribbles layer of transparent oxidized metal (transparent conductive resistance) ITO (tin indium oxide) conductive layer, is stamped the smooth anti-friction plastic layer of one deck outside surface cure process above again; Its inside surface also scribbles one deck ITO coating; Between them, have the transparent isolating points of many tiny (less than 1/1000 inches) to separate insulation to two conductive layers, when the finger touch screen, two conductive layers has just had contact in the position, touch point; Resistance changes; On X and Y both direction, produce signal, send touch screen controller, controller to detect this contact then and calculate (X; Y) position, the mode according to analog mouse operates again.
The ultimate principle of capacitive touch screen is to utilize the induction by current of human body to carry out work, and capacitive touch screen is two layers of compound glass screen, and the inside surface interlayer of glass screen scribbles ITO (tin indium oxide) conducting film (plated film electro-conductive glass); Outermost layer is a skim silicon soil glassivation, and the ITO coating is drawn four electrodes as workplace on four angles; When finger touch was on screen, because people's bulk electric field, user and touch screen surface formed a coupling capacitance; For high-frequency current, electric capacity is direct conductor, so finger siphons away a very little electric current from contact point; This electric current flows out the electrode from four jiaos of touch-screen respectively; And the electric current of these four electrodes of flowing through is directly proportional with the distance of pointing four jiaos, and controller draws touch point position through the accurate Calculation to these four current ratios.
In capacitive touch screen, projection-type capacitive touch screen is that current application is a kind of comparatively widely, has characteristics such as simple in structure, transmittance height.The touch sensible parts of projection-type capacitive touch screen are generally a plurality of column electrodes and the row electrode is staggered to form the induction matrix.Usually the design that adopts comprises the two sides that column electrode and row electrode is separately positioned on same transparency carrier, prevents short circuit to occur at intervening portion; Perhaps column electrode and row electrode are arranged on the homonymy of same transparency carrier; Be formed on the same conducting film (being generally the ITO conducting film); Separate through the mode that insulation course and frame conducting bridge are set at column electrode and the staggered position of row electrode; Column electrode and row electrode are separated and guarantee conducting on direction separately, can prevent effectively that it is in the intervening portion short circuit.
Usually the design proposal that adopts is: one of column electrode or row electrode are provided with on conducting film continuously; Then another electrode electrode with continuous setting on conducting film serves as to be arranged to some electrode blocks at interval; Position at cross-point is electrically connected adjacent electrode block through conducting bridge, thereby forms the continuous electrode on the other direction; Separate by insulation course between the electrode of conducting bridge and setting continuously, thereby effectively stop column electrode and row electrode in the cross-point short circuit.Usually the design proposal that adopts is: (1) stepped construction is followed successively by transparency carrier, first direction electrode, insulation course, conducting bridge; Perhaps (2) stepped construction is followed successively by transparency carrier, conducting bridge, insulation course, first direction electrode.
But can there be the defective of the not high and poor work stability of transmittance in the capacitive touch screen that adopts traditional design proposal; The capacitive touch screen transmittance of traditional design proposal is difficult to break through 80%; And during whole stressed flexural deformation; Occur at the interface easily separating, cause electrode to open circuit and touch inefficacy, touch sensible parts damages.
Summary of the invention
One of the object of the invention is to provide a kind of ITO through hole integral type capacitance touch screen; Stepped construction and ITO conduction mode through to capacitance touch screen reasonably design; The mode of employing ITO through hole is conducting ITO signal electrode up and down; Effectively improve transmittance, job stability and the touch sensitivity of capacitive touch screen.
For realizing above-mentioned purpose, the present invention adopts following technical scheme:
A kind of ITO through hole capacitance touch screen comprises transparency carrier, stacks gradually black resin layer, ITO electrode, first insulation course, ITO through hole electrode, metal electrode and second insulation course in transparency carrier; Described ITO electrode comprises that capacitance plate drives (ITO electrode 1) and induction electrode (ITO electrode 2), has the regular figure structure;
ITO electrode 1 and ITO electrode 2 are in same aspect, and be separate, mutually insulated, vertical design;
Said transparency carrier comprises viewfinder area and non-viewfinder area, and black resin layer is distributed in the non-viewfinder area of display screen; Described metal electrode circuit wiring is only at the black resin layer region.
Described ITO through hole electrode comprises the through hole electrode 1 and black resin layer edge through hole electrode 2 of display screen vision area, has the regular figure structure, and the number of through hole can be one or several; The through hole electrode mode has circular punching, oval punching, triangle punching; Trapezoidal punching; Hole knockouts such as rectangle, purpose make the ITO through hole electrode contact more stable, more reliable with ITO electrode (containing ITO1 and ITO2 electrode).Said through hole is opened on first insulation course (position that needs the ITO through hole).
Described ITO electrode comprises that capacitance plate drives (ITO electrode 1) and induction electrode (ITO electrode 2) partial electrode can overlap above black resin, and the ITO electrode needs to climb to the black resin top layer from the glass bottom.
Preferably: described transparency carrier is a thickness at 0.5~2.0 millimeter chemically reinforced glass substrate; Said ITO electrode regular texture is a rhombus, or bar shaped, or box-shaped, or snowflake type, or regular structure such as cross.
Described black resin layer can effectively block the figure layer of non-visible area, can shading, and the visible of products such as metal wire below.First insulation course makes ITO electrode and ITO through hole electrode be in insulation status, not conducting mutually.The ITO through hole electrode plays ITO conducting effect, and the conducting capacitance plate drives or the induction line electrode, has the regular figure structure.The FPC nation of ITO electrode signal conducting decides the zone passage metal electrode and realizes.The second dielectric protection layer metal electrode and ITO lead make it and air insulation.
Two of the object of the invention is to provide a kind of manufacturing approach of ITO through hole integral type capacitance touch screen, adopts following technical scheme:
The formation of black resin layer: black resin is uniformly coated on the transparency carrier through the rotary coating mode or the formula coating method of scraping, and coating thickness is 0.3um~5um, and is roasting in advance through well heater, and exposure is developed, and makes it to form required black resin zone; The black resin zone is the non-viewfinder area of display screen, and purpose is the figure layer that blocks non-visible area, can shading, and the visible of products such as metal electrode below; Said black resin be photonasty protective seam photoresist (commodity by Taiwan forever photochemistry produced EK410); It is a kind of black negativity photoresist; Principal ingredient is: acrylic resin, epoxy resin, negative photosensitive agent; Acetate propylene glycol monomethyl ether ester and black pigment, concrete ratio is a resene: acetate propylene glycol monomethyl ether ester: black pigment and negative photosensitive agent=15~30: 60~80: 1~10.
Said black resin layer is trapezium structure; Interior thickness is 0.3um~5um; Its bevel angle is that angle is mild between 6~60 degree, and purpose is that ITO electrode (drive wire ITO electrode 1 with line of induction ITO electrode 2) can be owing to difference in thickness causes the ITO lead rupture greatly during through the slope.The black resin zone is the non-viewfinder area of display screen, and purpose is for blocking metal electrode.
The formation of ITO electrode: transparency carrier is carried out chemical enhanced, pass through the ITO plated film again, make on glass substrate, to form layer of transparent and the uniform ITO rete of thickness, its thickness is 50 Ethylmercurichlorendimides~2000 Ethylmercurichlorendimides;
Through the transparency carrier of ITO plated film, at the transparency carrier of its ITO plated film, at the uniform positivity photoresist of its ITO surface coated one layer thickness, the photoresistance coating thickness is 1um~5um;
Roasting in advance through photoresistance, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 50~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm) and regular ITO pattern or electrode.
Described ITO electrode comprises that capacitance plate drives (ITO electrode 1) and induction electrode (ITO electrode 2), has the regular figure structure; ITO electrode 1 and ITO electrode 2 are in same aspect, and be separate, mutually insulated, vertical design.
Described ITO electrode comprises that capacitance plate drives (ITO electrode 1) and induction electrode (ITO electrode 2) partial electrode can overlap above black resin, and the ITO electrode needs to climb to the black resin top layer from the glass bottom.
The formation of first insulation course:
Process ITO crosses the transparency carrier behind the bridge electrode, is coated with the uniform negativity photoresist of a layer thickness at its ITO face, and the photoresistance coating thickness is 0.5um~3um;
Roasting in advance through photoresistance, exposure is developed, and finally forming thickness is the insulating layer pattern of 0.5~3um and rule.
Described pattern perforate mode and quantity are the position of ITO through hole, and the regular figure of pattern is respectively round hole, oval aperture, triangle perforate, trapezoidal perforate, modes such as rectangle perforate.
The formation of ITO through hole electrode layer:
Form the transparency carrier of first insulation course, pass through the ITO plated film once more, make on glass substrate, to form layer of transparent and the uniform ITO rete of thickness, its thickness is 50 Ethylmercurichlorendimides~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm);
Through the transparency carrier of ITO plated film, at the uniform positivity photoresist of its ITO surface coated one layer thickness, the photoresistance coating thickness is 1um~5um;
Roasting in advance through photoresistance, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 50~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm) and regular ITO pattern or electrode.
Described ITO through hole electrode comprises the through hole electrode 1 and black resin layer edge through hole electrode 2 of display screen vision area, has the regular figure structure, and the number of through hole can be one or several; The through hole electrode mode has circular punching, oval punching, triangle punching; Trapezoidal punching; Hole knockouts such as rectangle, purpose make the ITO through hole electrode contact more stable, more reliable with ITO electrode (containing ITO electrode 1 and ITO electrode 2).Through hole electrode 1 and through hole electrode 2 are at same one deck, and be separate, mutually insulated.Said through hole is opened on first insulation course (position that needs the ITO through hole).
ITO through hole electrode 1 conduction mode: ITO electrode 1 is through the through hole electrode 1 upwards conducting of first insulation course; Connecting through ITO through hole electrode 1 level on first insulation course; Through hole electrode 1 through first insulation course is conducting to ITO electrode 1 downwards again, makes ITO electrode 1 form the capacitance plate driving access.ITO electrode 2 direct film forming are on glass substrate, and single ITO electrode links to each other, directly conducting.
ITO through hole electrode 2 conduction modes: film forming is in the through hole electrode 2 upwards conductings of the ITO at black resin edge electrode (containing ITO electrode 1 and ITO electrode 2) through first insulation course; Through hole electrode 2 conducting that links to each other with metal electrode again; Make ITO electrode (containing ITO electrode 1 and ITO electrode 2) and metal electrode conducting, form the capacitance plate function signal.
The formation of metal electrode layer: form the transparency carrier of ITO electrode layer, through metal coating, make it on transparency carrier, to form a layer thickness even metal rete, its thickness is 500 Ethylmercurichlorendimides~4000 Ethylmercurichlorendimides.
Transparency carrier through metal coating is coated with the uniform positivity photoresist of a layer thickness in its metal surface, the photoresistance coating thickness is 1um~5um;
Roasting in advance through photoresistance, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 500~4000 Ethylmercurichlorendimides and regular metal pattern or electrode.
The formation of second insulation course:
Transparency carrier through behind the metal electrode is coated with the uniform negativity photoresist of a layer thickness at its metal face, and the photoresistance coating thickness is 0.5um~3um;
Roasting in advance through photoresistance, exposure is developed, and finally forming thickness is the insulating layer pattern of 0.5~3um and rule.
Preferably: described transparency carrier be thickness the chemically reinforced glass substrate; Described ITO is made up of In2O3 and SnO2, and its mass ratio is 85~95: 5~15.The mode of ITO plated film can adopt the vacuum magnetic control sputter, chemical vapour deposition technique, hot vapor deposition, collosol and gel.
Described positivity photoresist major component is an acetate propylene glycol monomethyl ether ester, epoxy resin and positivity emulsion (TR400 that commodity Taiwan new Ying Cai company by name produces); Negativity photoresist major component is an acetate propylene glycol monomethyl ether ester, the acrylic resin, and epoxy resin and negative photosensitive agent (commodity Taiwan Da Xing company by name produces POC A46) coating photoresist mode has roller coating, spin coating, modes such as blade coating.
Coating photoresist mode has roller coating, spin coating, modes such as blade coating.
The metallic diaphragm of described metal coating is MoNb; AlNd; MoNb piles up the sandwich structure that forms; Thickness is in 50 Ethylmercurichlorendimides~500 Ethylmercurichlorendimides: 500 Ethylmercurichlorendimides~3000 Ethylmercurichlorendimides: 50 Ethylmercurichlorendimides~500 Ethylmercurichlorendimide ratios collocation, and wherein Mo and Nb mass ratio are 85~95: 5~15 in the MoNb alloy material, Al and Nd mass ratio are 95~98: 2~5 in the AlNd alloy material.
The metal material type selecting also can be made up of silver alloy or aldary, and composition combines by a certain percentage.The metallic diaphragm plated film is the vacuum magnetic control sputter.
The present invention compared with prior art has following advantage and beneficial effect:
The present invention is through reasonably being provided with stepped construction; On one deck glass substrate, accomplish touch function signal electrode and black resin overlayer, comprise the order of ITO through hole electrode layer etc. and the mode of pattern, can significantly promote the yield of product; Reduce cost, promote product reliability.ITO through hole integral type capacitance touch screen of the present invention has only the layer of transparent substrate, between thickness of glass 0.5mm~2.0mm, has thin thickness, advantages such as light weight; Through appropriate design, make transmitance to reach more than 90% to each layer.The present invention adopts ITO through hole mode characteristics: can reduce the ITO electrode greatly at the probability of climbing with the descending fracture, increase its conducting yield.
Description of drawings
Fig. 1 is the structural representation of ITO through hole capacitance touch screen of the present invention;
Fig. 2 is the described glass substrate structural representation of the embodiment of the invention;
Fig. 3 is the local structure for amplifying synoptic diagram of ITO through hole figure;
Fig. 4 is the cross-sectional view of ITO through hole integral type capacitance touch screen of the present invention.
Embodiment
Below in conjunction with specific embodiment the present invention is done further explain.
Like Fig. 1 and shown in Figure 2; Described ITO through hole capacitance touch screen; Comprise thickness at 0.5~2.0 millimeter chemically reinforced glass substrate 11, stack gradually black resin layer 12 in transparent glass substrate, ITO electrode 13, first insulation course 14, ITO through hole electrode 15, metal electrode 16 and second insulation course 17; Described ITO electrode 13 comprises that capacitance plate drives (ITO electrode 1) 42 and induction electrode (ITO electrode 2) 43, has the regular figure structure; ITO electrode 1 and ITO electrode 2 are in same aspect, and be separate, mutually insulated, vertical design.Said hardened glass substrate 11 comprises viewfinder area 21 and non-viewfinder area 22, and black resin layer 12 is distributed in the non-viewfinder area of display screen; Described metal electrode lines 16 tunnel wirings are only at black resin layer region 47.
Fig. 3 and shown in Figure 4 is the partial structurtes enlarged diagram or the cross-sectional view of the said ITO gap bridge of present embodiment capacitance touch screen: black resin layer 47 can effectively block the figure layer of non-visible area, can shading, and the visible of products such as metal wire below.First insulation course 45 makes ITO electrode 13 and ITO through hole electrode 46 be in insulation status, not conducting mutually; ITO electrode 13 comprises that capacitance plate drives (ITO electrode 1) 42 and induction electrode (ITO electrode 2) 43, has the regular figure structure; Be complementary with the ITO shape of through holes.The ITO through hole electrode plays ITO conducting effect, and the conducting capacitance plate drives or the induction line electrode, has the regular figure structure; The number of through hole can be one or several, and the through hole electrode mode has circular punching, oval punching; The triangle punching, trapezoidal punching, hole knockouts such as rectangle; Purpose makes the ITO through hole electrode contact more stable, more reliable with ITO electrode (containing ITO1 and ITO2 electrode).Said through hole is opened on first insulation course (position that needs the ITO through hole).。The FPC nation of ITO electrode signal conducting decides zone passage metal electrode 48 and realizes.Second insulation course, 44 protection metal electrodes 48 and ITO lead make it and air insulation.
Its preparation technology is following:
The formation of black resin layer: black resin is uniformly coated on the transparent glass substrate 41 (11) through the rotary coating mode or the formula coating method of scraping; Coating thickness is 0.3um~5um, and is roasting in advance through well heater, exposure; Develop, make it to form required black resin zone; Be trapezium structure, interior thickness is 0.3um~5um, and its bevel angle is that angle is mild between 6~60 degree, and purpose is that ITO electrode (drive wire ITO electrode 1 with line of induction ITO electrode 2) can be owing to difference in thickness causes the ITO lead rupture greatly during through the slope.The black resin zone is the non-viewfinder area of display screen, and purpose is for blocking metal electrode.Said black resin be photonasty protective seam photoresist (commodity by Taiwan forever photochemistry produced EK410); It is a kind of black negativity photoresist; Principal ingredient is: acrylic resin, epoxy resin, negative photosensitive agent; Acetate propylene glycol monomethyl ether ester and black pigment, concrete ratio is a resene: acetate propylene glycol monomethyl ether ester: black pigment and negative photosensitive agent=15~30: 60~80: 1~10.
In advance roasting temperature and time scope is: 60 degree~150 degree, and 50 seconds to 200 seconds, exposure energy adopted 100mj to 500mj, and it is alkaline solution that developer solution adopts Na system or Ka, and the temperature of development adopts 20~40 degree constant temperature operations.It is roasting firmly to pass through black resin layer again, and condition is 200 to spend to 300 degree, and the time is half an hour to 3 hour, and through behind the above-mentioned processing procedure, finally forming thickness is 0.3um~5um, the black resin layer of figure rule.
The formation of ITO electrode: transparent glass substrate is carried out chemical enhanced, pass through the ITO plated film again, make on glass substrate, to form layer of transparent and the uniform ITO rete of thickness, its thickness is 50 Ethylmercurichlorendimides~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm); The ITO material is made up of In2O3 and SnO2, and its mass ratio is 85~95: 5~15.The mode of ITO plated film has the vacuum magnetic control sputter, chemical vapour deposition technique, hot vapor deposition, collosol and gel.
Through the transparent glass substrate of ITO plated film, at the uniform positivity photoresist of its ITO surface coated one layer thickness, the photoresistance coating thickness is 1um~5um; Positivity photoresist major component is acetate propylene glycol monomethyl ether ester, epoxy resin and positivity emulsion.The photoresistance coating thickness is 1um~5um.Coating photoresist mode has roller coating, spin coating, modes such as blade coating.
Roasting in advance through photoresistance through product after the above-mentioned processing procedure, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 50~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm) and regular ITO pattern or electrode.In advance roasting temperature and time scope is: 60 degree~150 degree, and 50 seconds to 200 seconds, exposure energy adopted 100mj to 500mj, and it is alkaline solution that developer solution adopts Na system or Ka, and the temperature of development adopts 20~40 degree constant temperature operations.The soup that the ITO etching solution adopts hydrochloric acid and nitric acid to mix by a certain percentage drops between 1~3 its sour pH value, etch temperature operation between 40~50 degree.Take off photoresistance film liquid and adopt dimethyl sulfoxide and monoethanolamine to mix according to a certain percentage, number percent is 70%:30%, the operation between 40~80 degree of demoulding temperature.
Described ITO electrode comprises that capacitance plate drives (ITO electrode 1) and induction electrode (ITO electrode 2), has the regular figure structure; ITO electrode 1 and ITO electrode 2 are in same aspect, and be separate, mutually insulated, vertical design.Described ITO electrode comprises that capacitance plate drives (ITO electrode 1) and induction electrode (ITO electrode 2) partial electrode can overlap above black resin, and the ITO electrode needs to climb to the black resin top layer from the glass bottom.
The formation of first insulation course:
Through the transparent glass substrate behind the ITO electrode; Be coated with the uniform negativity photoresist of a layer thickness at its ITO face; Negativity photoresist major component is an acetate propylene glycol monomethyl ether ester; The acrylic resin, epoxy resin and negative photosensitive agent (commodity Taiwan Da Xing company by name produces POC A46), the photoresistance coating thickness is 0.5um~3um; Coating photoresist mode has spin coating, modes such as blade coating.
Described pattern perforate mode and quantity are the position of ITO through hole, and the regular figure of pattern is respectively round hole, oval aperture, triangle perforate, trapezoidal perforate, modes such as rectangle perforate.
Roasting in advance through photoresistance through product after the above-mentioned processing procedure, exposure is developed, and finally forming thickness is the insulating layer pattern of 0.5~3um and rule.In advance roasting temperature and time scope is: 60 degree~150 degree, and 50 seconds to 200 seconds, exposure energy adopted 100mj to 500mj, and it is alkaline solution that developer solution adopts Na system or Ka, and the temperature of development adopts 20~40 degree constant temperature operations.
It is roasting firmly to pass through insulation course again, and condition is 200 to spend to 300 degree, and the time is half an hour to 3 hour, and through behind the above-mentioned processing procedure, finally forming thickness is 0.5um~3um, the insulation course 1 of figure rule.
The formation of ITO through hole electrode layer:
Form the transparent glass substrate of first insulation course, pass through the ITO plated film once more, make on glass substrate, to form layer of transparent and the uniform ITO rete of thickness, its thickness is 50 Ethylmercurichlorendimides~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm); The ITO material is made up of In2O3 and SnO2, and its mass ratio is 85~95: 5~15.The mode of ITO plated film has the vacuum magnetic control sputter, chemical vapour deposition technique, hot vapor deposition, collosol and gel.
Glass substrate through the ITO plated film; At the uniform positivity photoresist of its ITO surface coated one layer thickness; Positivity photoresist major component is an acetate propylene glycol monomethyl ether ester, epoxy resin and positivity emulsion (TR400 that commodity Taiwan new Ying Cai company by name produces); The photoresistance coating thickness is 1um~5um.Coating photoresist mode has roller coating, spin coating, modes such as blade coating.
Roasting in advance through photoresistance through product after the above-mentioned processing procedure, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 50~2000 Ethylmercurichlorendimides (face resistance is 10~430 ohm) and regular ITO pattern or electrode.In advance roasting temperature and time scope is: 60 degree~150 degree, and 50 seconds to 200 seconds, exposure energy adopted 100mj to 500mj, and it is alkaline solution that developer solution adopts Na system or Ka, and the temperature of development adopts 20~40 degree constant temperature operations.The soup that the ITO etching solution adopts hydrochloric acid and nitric acid to mix by a certain percentage drops between 1~3 its sour pH value, etch temperature operation between 40~50 degree.Take off photoresistance film liquid and adopt dimethyl sulfoxide and monoethanolamine to mix according to a certain percentage, number percent is 70%: 30%, the operation between 40~80 degree of demoulding temperature.
Described ITO through hole electrode comprises the through hole electrode 1 and black resin layer edge through hole electrode 2 of display screen vision area, has the regular figure structure, and the number of through hole can be one or several; The through hole electrode mode has circular punching, oval punching, triangle punching; Trapezoidal punching; Hole knockouts such as rectangle, purpose make the ITO through hole electrode contact more stable, more reliable with ITO electrode (containing ITO electrode 1 and ITO electrode 2).Through hole electrode 1 and through hole electrode 2 are at same one deck, and be separate, mutually insulated.Said through hole is opened on first insulation course (position that needs the ITO through hole).
ITO through hole electrode 1 conduction mode: ITO electrode 1 is through the through hole electrode 1 upwards conducting of first insulation course; Connecting through ITO through hole electrode 1 level on first insulation course; Through hole electrode 1 through first insulation course is conducting to ITO electrode 1 downwards again, makes ITO electrode 1 form the capacitance plate driving access.ITO electrode 2 direct film forming are on glass substrate, and single ITO electrode links to each other, directly conducting.
ITO through hole electrode 2 conduction modes: film forming is in the through hole electrode 2 upwards conductings of the ITO at black resin edge electrode (containing ITO electrode 1 and ITO electrode 2) through first insulation course; Through hole electrode 2 conducting that links to each other with metal electrode again; Make ITO electrode (containing ITO electrode 1 and ITO electrode 2) and metal electrode conducting, form the capacitance plate function signal.
The formation of metal electrode layer:
Form the glass substrate of ITO electrode layer, pass through metal coating again, make on glass substrate, to form a layer thickness even metal rete, its thickness is 500 Ethylmercurichlorendimides~4000 Ethylmercurichlorendimides.The metallic diaphragm material is MoNb; AlNd; MoNb piles up the sandwich structure that forms; Thickness is in 50 Ethylmercurichlorendimides~500 Ethylmercurichlorendimides: 500 Ethylmercurichlorendimides~3000 Ethylmercurichlorendimides: 50 Ethylmercurichlorendimides~500 Ethylmercurichlorendimide ratios collocation, and wherein Mo and Nb mass ratio are 85~95: 5~15 in the MoNb alloy material, Al and Nd mass ratio are 95~98: 2~5 in the AlNd alloy material.The metal material type selecting also can be made up of silver alloy or aldary, and composition combines by a certain percentage.Metal coating is the vacuum magnetic control sputter.
Glass substrate through metal coating; Be coated with the uniform positivity photoresist of a layer thickness in its metal surface; Described positivity photoresist major component is an acetate propylene glycol monomethyl ether ester; Epoxy resin and positivity emulsion (TR400 that commodity Taiwan new Ying Cai company by name produces), the photoresistance coating thickness is 1um~5um.Coating photoresist mode has roller coating, spin coating, modes such as blade coating.Roasting in advance through photoresistance through product after the above-mentioned processing procedure, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 500~4000 Ethylmercurichlorendimides and regular metal pattern or electrode.In advance roasting temperature and time scope is: 60 degree~150 degree, and 50 seconds to 200 seconds, exposure energy adopted 100mj to 500mj, and it is alkaline solution that developer solution adopts Na system or Ka, and the temperature of development adopts 20~40 degree constant temperature operations.The soup that metal etch liquid adopts phosphoric acid, acetic acid and nitric acid to mix by a certain percentage, etch temperature operation between 40~50 degree.Take off photoresistance film liquid and adopt dimethyl sulfoxide and monoethanolamine to mix according to a certain percentage, number percent is 70%: 30%, the operation between 40~80 degree of demoulding temperature.
The formation of second insulation course:
Through the glass substrate behind the metal electrode; Be coated with the uniform negativity photoresist of a layer thickness at its metal face; Negativity photoresist major component is an acetate propylene glycol monomethyl ether ester, acrylic resin, epoxy resin and negative photosensitive agent (commodity Taiwan Da Xing company by name produces POC A46); The photoresistance coating thickness is 0.5um~3um.Coating photoresist mode has spin coating, modes such as blade coating.
Roasting in advance through photoresistance through product after the above-mentioned processing procedure, exposure is developed, and finally forming thickness is the insulating layer pattern of 0.5~3um and rule.In advance roasting temperature and time scope is: 60 degree~150 degree, and 50 seconds to 200 seconds, exposure energy adopted 100mj to 500mj, and it is alkaline solution that developer solution adopts Na system or Ka, and the temperature of development adopts 20~40 degree constant temperature operations.It is roasting firmly to pass through insulation course again, and condition is 200 to spend to 300 degree, and the time is 0.5 hour to 3 hours, and through behind the above-mentioned processing procedure, finally forming thickness is 0.5um~3um, second insulation course of figure rule.
Above content is to combine concrete preferred implementation to the further explain that the present invention did, and can not assert that practical implementation of the present invention is confined to these explanations.For the those of ordinary skill of technical field under the present invention, under the prerequisite that does not break away from the present invention's design, can also make some simple deduction or replace, all should be regarded as belonging to protection scope of the present invention.

Claims (9)

1. an ITO through hole integral type capacitance touch screen comprises transparency carrier, stacks gradually black resin layer, ITO electrode, first insulation course, ITO through hole electrode, metal electrode and second insulation course in transparency carrier; Described ITO electrode comprises ITO electrode 1 and ITO electrode 2, has the regular figure structure; ITO electrode 1 and ITO electrode 2 are in same aspect, and be separate, mutually insulated, vertical design; Described metal electrode layer is the film formed layer thickness even metal rete of glass substrate process metal-plated at the ITO electrode layer; Described metallic diaphragm is MoNb; AlNd, MoNb pile up the sandwich structure form, and three's thickness is by 50 Ethylmercurichlorendimides ~ 500 Ethylmercurichlorendimides: 500 Ethylmercurichlorendimides ~ 3000 Ethylmercurichlorendimides: 50 Ethylmercurichlorendimides ~ 500 Ethylmercurichlorendimide ratios are arranged in pairs or groups; Wherein Mo and Nb mass ratio are 85 ~ 95:5 ~ 15 in the MoNb alloy material, and Al and Nd mass ratio are 95 ~ 98:2 ~ 5 in the AlNd alloy material;
Said transparency carrier comprises viewfinder area and non-viewfinder area, and black resin layer is distributed in the non-viewfinder area of display screen; Described metal electrode circuit wiring is only at the black resin layer region.
2. ITO through hole integral type capacitance touch screen as claimed in claim 1 is characterized in that: described transparency carrier is the chemically reinforced glass substrate of thickness at 0.5mm ~ 2.0mm; The number of the through hole of said ITO through hole electrode can be one or several, and the through hole electrode mode has circular punching, oval punching, triangle punching, trapezoidal punching, or rectangle punching.
3. ITO through hole integral type capacitance touch screen as claimed in claim 2, it is characterized in that: described black resin layer thickness is 0.3um ~ 5um; The ITO electrode layers thickness is 50 ~ 2000 Ethylmercurichlorendimides; The thickness of first insulation course is 0.5 ~ 3um; Described ITO through hole electrode thickness is 50 Ethylmercurichlorendimides ~ 2000 Ethylmercurichlorendimides; The thickness of metal electrode layer is 500 ~ 4000 Ethylmercurichlorendimides; Second thickness of insulating layer is 0.5 ~ 3um.
4. ITO through hole integral type capacitance touch screen as claimed in claim 3, it is characterized in that: described ITO comprises In2O3 and SnO2, its mass ratio is 85 ~ 95:5 ~ 15.
5. method for preparing ITO through hole integral type capacitance touch screen comprises step:
The formation of black resin layer: black resin is uniformly coated on the transparency carrier through the rotary coating mode or the formula coating method of scraping, and coating thickness is 0.3um ~ 5um, and is roasting in advance through well heater, and exposure is developed, and makes it to form required black resin zone; Said black resin is a photonasty protective seam photoresist, and said photoresist comprises the acrylic resin, epoxy resin, negative photosensitive agent, acetate propylene glycol monomethyl ether ester and black pigment; Its ratio is a resene: acetate propylene glycol monomethyl ether ester: black pigment and negative photosensitive agent=15 ~ 30:60 ~ 80:1 ~ 10;
The formation of ITO electrode: transparency carrier is carried out chemical enhanced, pass through the ITO plated film again, make on glass substrate, to form layer of transparent and the uniform ITO rete of thickness, its thickness is 50 Ethylmercurichlorendimides ~ 2000 Ethylmercurichlorendimides;
Through the transparency carrier of ITO plated film, at the uniform positivity photoresist of its ITO surface coated one layer thickness, the photoresistance coating thickness is 1um ~ 5um;
Roasting in advance through photoresistance, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 50 ~ 2000 Ethylmercurichlorendimides and regular ITO pattern or electrode;
Described ITO electrode comprises ITO electrode 1ITO electrode 2, has the regular figure structure; ITO electrode 1 and ITO electrode 2 are in same aspect, and be separate, mutually insulated, vertical design;
The formation of first insulation course:
Transparency carrier through behind the ITO electrode is coated with the uniform negativity photoresist of a layer thickness at its ITO face, and the photoresistance coating thickness is 0.5um ~ 3um;
Roasting in advance through photoresistance, exposure is developed, and finally forming thickness is the insulating layer pattern of 0.5 ~ 3um and rule;
The formation of ITO through hole electrode:
Form the transparency carrier of first insulation course, pass through the ITO plated film once more, make on glass substrate, to form layer of transparent and the uniform ITO rete of thickness, its thickness is 50 Ethylmercurichlorendimides ~ 2000 Ethylmercurichlorendimides;
Through the transparency carrier of ITO plated film, at the uniform positivity photoresist of its ITO surface coated one layer thickness, the photoresistance coating thickness is 1um ~ 5um;
Roasting in advance through photoresistance, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 50 ~ 2000 Ethylmercurichlorendimides and regular ITO pattern or electrode;
The formation of metal electrode layer:
Form the transparency carrier of ITO electrode layer, through metal coating, make it on transparency carrier, to form a layer thickness even metal rete, its thickness is 500 Ethylmercurichlorendimides ~ 4000 Ethylmercurichlorendimides;
Transparency carrier through metal coating is coated with the uniform positivity photoresist of a layer thickness in its metal surface, the photoresistance coating thickness is 1um ~ 5um;
Roasting in advance through photoresistance, exposure is developed, and the photoresistance film is taken off in etching, and finally forming thickness is 500 ~ 4000 Ethylmercurichlorendimides and regular metal pattern or electrode;
The formation of second insulation course:
Transparency carrier through behind the metal electrode is coated with the uniform negativity photoresist of a layer thickness at its metal face, and the photoresistance coating thickness is 0.5um ~ 3um;
Roasting in advance through photoresistance, exposure is developed, and finally forming thickness is the insulating layer pattern of 0.5 ~ 3um and rule.
6. the method for preparing ITO through hole integral type capacitance touch screen as claimed in claim 5 is characterized in that: described transparency carrier is a thickness at 0.5 ~ 2.0 millimeter chemically reinforced glass substrate; Described ITO comprises In2O3 and SnO2, and its mass ratio is 85 ~ 95:5 ~ 15.
7. the method for preparing ITO through hole integral type capacitance touch screen as claimed in claim 6 is characterized in that: described positivity photoresist major component is an acetate propylene glycol monomethyl ether ester, epoxy resin and positivity emulsion; Negativity photoresist major component is acetate propylene glycol monomethyl ether ester, acrylic resin, epoxy resin and negative photosensitive agent.
8. the method for preparing ITO through hole integral type capacitance touch screen as claimed in claim 7 is characterized in that:
The metallic diaphragm of described metal coating is MoNb; AlNd; MoNb piles up the sandwich structure that forms; Thickness is in 50 Ethylmercurichlorendimides ~ 500 Ethylmercurichlorendimides: 500 Ethylmercurichlorendimides ~ 3000 Ethylmercurichlorendimides: 50 Ethylmercurichlorendimides ~ 500 Ethylmercurichlorendimide ratios collocation, and wherein Mo and Nb mass ratio are 85 ~ 95:5 ~ 15 in the MoNb alloy material, Al and Nd mass ratio are 95 ~ 98:2 ~ 5 in the AlNd alloy material.
9. the method for preparing ITO through hole integral type capacitance touch screen as claimed in claim 8 is characterized in that: the mode of described ITO plated film is the vacuum magnetic control sputter, perhaps is chemical vapour deposition technique, perhaps is hot vapor deposition, perhaps is collosol and gel.
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