CN102206048B - 一种自组装氧化钒薄膜的制备方法 - Google Patents
一种自组装氧化钒薄膜的制备方法 Download PDFInfo
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- CN102206048B CN102206048B CN201110093811A CN201110093811A CN102206048B CN 102206048 B CN102206048 B CN 102206048B CN 201110093811 A CN201110093811 A CN 201110093811A CN 201110093811 A CN201110093811 A CN 201110093811A CN 102206048 B CN102206048 B CN 102206048B
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- solution
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- vanadium oxide
- oxide film
- self
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- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 229910001935 vanadium oxide Inorganic materials 0.000 title claims abstract description 24
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 238000001338 self-assembly Methods 0.000 title claims abstract description 16
- 239000000758 substrate Substances 0.000 claims abstract description 26
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000004506 ultrasonic cleaning Methods 0.000 claims abstract description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 11
- VGBWDOLBWVJTRZ-UHFFFAOYSA-K cerium(3+);triacetate Chemical compound [Ce+3].CC([O-])=O.CC([O-])=O.CC([O-])=O VGBWDOLBWVJTRZ-UHFFFAOYSA-K 0.000 claims abstract description 10
- XAYGUHUYDMLJJV-UHFFFAOYSA-Z decaazanium;dioxido(dioxo)tungsten;hydron;trioxotungsten Chemical compound [H+].[H+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O XAYGUHUYDMLJJV-UHFFFAOYSA-Z 0.000 claims abstract description 10
- WCWRAWMYDYYCRZ-UHFFFAOYSA-N toluene;trichloro(octadecyl)silane Chemical compound CC1=CC=CC=C1.CCCCCCCCCCCCCCCCCC[Si](Cl)(Cl)Cl WCWRAWMYDYYCRZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000032683 aging Effects 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- 238000007669 thermal treatment Methods 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 6
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 6
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000000243 solution Substances 0.000 claims description 39
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 9
- -1 polyoxyethylene Polymers 0.000 claims description 9
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 238000005352 clarification Methods 0.000 claims description 5
- 238000004090 dissolution Methods 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 239000011550 stock solution Substances 0.000 claims description 5
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 4
- 239000004065 semiconductor Substances 0.000 abstract description 4
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 239000002243 precursor Substances 0.000 abstract description 3
- 230000001988 toxicity Effects 0.000 abstract description 3
- 231100000419 toxicity Toxicity 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 230000036541 health Effects 0.000 abstract description 2
- 239000008204 material by function Substances 0.000 abstract description 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 1
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 229920001223 polyethylene glycol Polymers 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- 229910021542 Vanadium(IV) oxide Inorganic materials 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 description 2
- YXOLAZRVSSWPPT-UHFFFAOYSA-N Morin Chemical compound OC1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 YXOLAZRVSSWPPT-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 description 1
- 235000007708 morin Nutrition 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
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- Formation Of Insulating Films (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
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CN201110093811A CN102206048B (zh) | 2011-04-14 | 2011-04-14 | 一种自组装氧化钒薄膜的制备方法 |
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CN201110093811A CN102206048B (zh) | 2011-04-14 | 2011-04-14 | 一种自组装氧化钒薄膜的制备方法 |
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CN102206048A CN102206048A (zh) | 2011-10-05 |
CN102206048B true CN102206048B (zh) | 2012-10-03 |
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CN105543810B (zh) * | 2015-12-30 | 2018-06-12 | 湖北大学 | 一种具有超亲水自清洁、智能控温功能的纳米vo2薄膜及其制备方法 |
CN106892573A (zh) * | 2017-03-20 | 2017-06-27 | 武汉理工大学 | 一种环保型热致变色二氧化钒薄膜的制备方法 |
CN114859611B (zh) * | 2022-05-13 | 2024-01-09 | 厦门大学 | 一种多彩电致变色薄膜、器件及其制备方法 |
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JP2508779B2 (ja) * | 1987-12-28 | 1996-06-19 | 日本板硝子株式会社 | ガラス基体表面に酸化錫薄膜を形成する方法 |
TW593187B (en) * | 1999-10-25 | 2004-06-21 | Nippon Sheet Glass Co Ltd | Method for preparing article covered with light absorption pattern film and article covered with light absorption pattern film |
JP2007022839A (ja) * | 2005-07-14 | 2007-02-01 | Nippon Sheet Glass Co Ltd | 調光ガラスの製造方法 |
CN101255015B (zh) * | 2008-04-03 | 2014-04-02 | 中国科学院广州能源研究所 | 玻璃衬底上彩色二氧化钒热色玻璃的制备方法 |
CN101570396B (zh) * | 2009-06-11 | 2010-12-08 | 河北理工大学 | 锗酸盐玻璃发光薄膜及制备方法 |
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Owner name: PINGXIANG COLLEGE Free format text: FORMER OWNER: XU XIAOYONG Effective date: 20120829 |
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Effective date of registration: 20120829 Address after: 337055 Pingxiang Research Institute, Anyuan New District, Jiangxi, China Patentee after: Pingxiang University Address before: 337055 Pingxiang Research Institute, Anyuan New District, Jiangxi, China Patentee before: Xu Xiaoyong |
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