CN102127491A - Bactericidal cleaning agent and preparation method thereof - Google Patents
Bactericidal cleaning agent and preparation method thereof Download PDFInfo
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- CN102127491A CN102127491A CN2010100194282A CN201010019428A CN102127491A CN 102127491 A CN102127491 A CN 102127491A CN 2010100194282 A CN2010100194282 A CN 2010100194282A CN 201010019428 A CN201010019428 A CN 201010019428A CN 102127491 A CN102127491 A CN 102127491A
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- Prior art keywords
- mixing
- cleaning
- deionized water
- amine oxide
- fatty alcohol
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- 238000002360 preparation method Methods 0.000 title claims description 13
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 5
- 239000012459 cleaning agent Substances 0.000 title abstract 4
- 230000001954 sterilising effect Effects 0.000 claims abstract description 28
- 238000004140 cleaning Methods 0.000 claims abstract description 27
- 238000002156 mixing Methods 0.000 claims abstract description 25
- -1 polysiloxane Polymers 0.000 claims abstract description 21
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 20
- 238000003756 stirring Methods 0.000 claims abstract description 19
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 15
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 15
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000000443 aerosol Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 21
- 239000003599 detergent Substances 0.000 claims description 18
- 150000001412 amines Chemical group 0.000 claims description 17
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 238000005303 weighing Methods 0.000 claims description 12
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 9
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 8
- 239000001509 sodium citrate Substances 0.000 claims description 8
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 8
- 229940038773 trisodium citrate Drugs 0.000 claims description 8
- 229960004418 trolamine Drugs 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims 1
- UTTVXKGNTWZECK-UHFFFAOYSA-N n,n-dimethyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)[O-] UTTVXKGNTWZECK-UHFFFAOYSA-N 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 231100000252 nontoxic Toxicity 0.000 abstract description 4
- 230000003000 nontoxic effect Effects 0.000 abstract description 4
- 238000001914 filtration Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 11
- 230000006870 function Effects 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 150000003016 phosphoric acids Chemical class 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 230000002147 killing effect Effects 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000222122 Candida albicans Species 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical group CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical group COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- RJQXTJLFIWVMTO-TYNCELHUSA-N Methicillin Chemical compound COC1=CC=CC(OC)=C1C(=O)N[C@@H]1C(=O)N2[C@@H](C(O)=O)C(C)(C)S[C@@H]21 RJQXTJLFIWVMTO-TYNCELHUSA-N 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- VFFDVELHRCMPLY-UHFFFAOYSA-N dimethyldodecyl amine Natural products CC(C)CCCCCCCCCCCN VFFDVELHRCMPLY-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 229960003085 meticillin Drugs 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The invention relates to a bactericidal cleaning agent. Main components of polysiloxane quaternary ammonium salt, dimethyldodecylamine oxide and fatty alcohol-polyoxyethylene ether, and a proper amount of aid and solubilizer are subjected to processes such as blending, mixing, stirring, dissolving, filtering and the like to be prepared into the bactericidal cleaning agent capable of being packaged under increased pressure or packaged in a common aerosol package. The cleaning agent integrates sterilization and cleaning, is convenient to use, nontoxic and environment-friendly, and meets the requirement of environmental protection; and the raw materials are readily available, and the product manufacturing process is concise. The product is widely applied to places such as households, public places, vehicles, wineshops, hospitals and the like, and has high practicability and good market prospect.
Description
Technical field
The present invention relates to a kind of sterilizing detergent for cleaning, be characterized in having germ-resistant function concurrently when cleaning, is a kind of innovation to traditional clean-out system.The invention still further relates to the preparation method of this sterilizing detergent for cleaning.
Background technology
Washing, just closely linked, closely bound up since ancient times with people's life.It involves industry-by-industry, and each department and field are little of each family, and it is all relevant with washing to arrive large-scale communal facility and industrial plants greatly.Along with expanding economy and standard of living improve constantly, various novel article use also more and more, also can be more and more higher to the requirement of employed washing composition.Therefore people are the sterilizing detergent for cleaning that clean-out system has sterilizing function again studying and seeking out a kind of, with the needs that adapt to the modern market development and change.
At present, cleaning product on the market, though various in style, of all kinds, say on its functions of use, still the washing composition of traditional single cleaning performance.Simultaneously, the considerable part product all contains phosphoric acid salt washing assistant in various degree.As everyone knows, because the phosphoric acid salt washing assistant can pollute environment, its liquid enters and caused the madness of algae to increase after rivers and lakes caused extensive use of chemical fertilizer, the balance of broken ring ecotope, and be subjected to reproaching widely.So some countries explicit order limit and forbid containing the phosphoric acid salt washing auxiliary detergent in cleaning products, with the balance of preserving the ecological environment.In such cases, seek a kind of both safe, nontoxic and and environmental harmony, existing scourability efficiently has the washing composition of sterilizing function again concurrently, has obvious social and economic benefits.
Summary of the invention
Purpose of the present invention, providing a kind of is body material with polysiloxane quaternary amine, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, and has sterilization, mildew-resistant, what drive the mite function is the aq. type sterilizing detergent for cleaning of carrier with water.Its preparation technology is succinct, product is easy to use, high effect nontoxic, and phosphoric acid salt washing assistant is not free from environmental pollution, meets the needs that cleaning product develops to the environmental protection direction.
A kind of sterilizing detergent for cleaning is the main raw material(s) composition with polysiloxane quaternary amine, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, and its component and weight percent are as follows:
Ethanol CH
3CH
2OH 1.00-2.50%
Deionized water H
2O 88-92.00%
Starso in the said components, Trisodium Citrate, trolamine and deionized water carry out the pre-mixing dissolving, again dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and deionized water pre-mixing dissolving; Then polysiloxane quaternary amine, the pre-mixing of propylene glycol butyl ether; At last three premixs are always mixed and add that essence is hybrid packed forms.
The present invention adopts the classification pre-mixing, and it is formulated always to mix stirring method at last.
A kind of preparation method of sterilizing detergent for cleaning, its preparation process is as follows:
The pre-mixing of A, inorganic and organic additive
Per-cent according to the weight of recipe ingredient, take by weighing Starso, Trisodium Citrate, trolamine respectively, throw in 30% deionized water of Total Water then, mix stirring and dissolving, make material in the container all be dissolved to as clear as crystal till, 10～20 minutes time, cross 200 mesh sieves then and filter.
The pre-mixing of B, cleaning host
According to the per-cent of weight of prescription, 70% the deionized water that takes by weighing dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and residue Total Water respectively carries out pre-mixing and is dissolved into as clear as crystal liquid.
The pre-mixing of C, sterilant
According to the weight percent of recipe ingredient, take by weighing polysiloxane quaternary amine, propylene glycol butyl ether respectively and carry out the liquid that the pre-mixing dissolving stirs into homogeneous transparent.
The preparation of D, sterilizing detergent for cleaning
The premixed liquid of B step is rendered in the container that holds the A premixed liquid, stir, make liquid be vitreous state, its pH value is adjusted in the scope of 9.5-10 with citric acid, then the premix liquid of C step preparation is put in the above-mentioned molten device and stirred, call in the essence blending again, filter at last, finished product packing.
The present invention is a main raw with polysiloxane quaternary amine, fatty alcohol-polyoxyethylene ether, dimethyl dodecyl amine oxide, with propylene glycol butyl ether, ethanol is solubilisation aids,, formulated with Starso by production technique such as dissolving, mixing, stirring, filtrations as washing assistant.Its concrete technical process is as follows:
At first Starso, Trisodium Citrate, trolamine are weighed up according to the weight percent in the prescription, be invested in the container, drop into 30% deionized water of Total Water then, fully stir the material that makes in the container and fully be dissolved into as clear as crystal uniform solution, churning time is 10～20 minutes, crosses 200 mesh sieves then; Second step, according to the weight percent of prescription, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, 70% deionized water of ethanol and residue Total Water is blended in one and stirs, and 5～10 minutes time, becomes as clear as crystal liquid; In the 3rd step, the polysiloxane quaternary amine, the propylene glycol butyl ether mixes and stirs, and makes the polysiloxane quaternary amine fully be dissolved into the liquid of homogeneous transparent, churning time 10～20 minutes according to the per-cent of formulation weight.
The 4th step, the mixing liquid for preparing in second step is rendered in the container of first step, fully stir after 10 minutes, after with citric acid pH value being adjusted to 9.5-10.0, again the mixture of third step is also rendered in this container, stir as clear as crystal homogeneous phase solution and add essence, filter and just can be packaged into product.
Polysiloxane season peace salt is one of this product major ingredient in the prescription, and it is that a kind of what have special construction is killing bacterium, mildew-resistant, driving the mite agent of carrier with water.It can pass through to press down the Bactericidal while, and breaks off the nutrition source of mould, suppresses the breeding of acarid.Pass through simultaneously to suppress and stop microbial growth and Decomposition, thereby suppressed malodorous generation.It is not only effective to the bacterium of routine, and some are comparatively had resistance, and bacterium that difficulty is killed such as methicillin-resistant staphylococcus aureus, Candida albicans also have stronger killing effect.Because the special structure of polysiloxane quaternary amine, its surface of sprawling be just as the bed of the atomic apicule nail of one deck, thereby puncture the cell walls of bacterium and sterilization.We can say that it is to come killing bacteria with the method for machinery rather than with deleterious material.Therefore it can generation can not make the develop immunity to drugs microorganism of particular surroundings of bacterium.
Dimethyl dodecyl amine oxide is a kind of amphoterics, and it has good compound property, and with the consistency of inorganic assistant agent and water-soluble.Its removal effect to grease and dust dirt simultaneously is obvious especially, and it also has certain sterilizing function.Therefore when it and polysiloxane quaternary amine are composite, further strengthen and support the performance of sterilization, anti-mildew and the anti-mite function of polysiloxane quaternary amine, make it become cleaning disinfectant with premium properties.When the fatty alcohol-polyoxyethylene ether of it and non-ionic type was composite, it had good anti-microbial effect.Simultaneously it has synergistic function with non-ionic surfactant on scourability, plays solubilising in prescription, surely steep, help wash, sterilization effects.It also has the to a certain degree function of deodorization and sterilization simultaneously.
Fatty alcohol-polyoxyethylene ether is a kind of non-ionic tensio-active agent, one of its main raw material(s) that conduct is cleaned in prescription, aspect washing, special efficacy is arranged, as the residual alcohol that shows product is few, show certain thickening properties in prescription, the operating temperature range when making it bring into play excellent scourability is wideer, more stable, and intermiscibility is better, and is particularly good to its removal performance of some obstinate lipid dirts.So complementary coordinating effect is still all arranged on bactericidal property in scourability.
Sterilizing detergent for cleaning of the present invention both can be made into common sprays, the aerosol agent of the pressurization that also can be made into.
Beneficial effect of the present invention:
1. product of the present invention has efficiently, non-toxic nature, and its sterilization cleaning soil removability is strong, and material source is extensive.
2. the product free from extraneous odour is fire-retardant.
3. application range of products is wide, is applicable to the usefulness of the sterilizing cleaning of household objects, office products, communal facility and industrial plants, the vehicles.
4. product is safe in utilization, convenient and swift, and is harmless, and the noresidue poisonous substance meets requirements of green environmental protection.
Embodiment
Embodiment 1
Preparation 2000 gram sterilizing detergent for cleaning
Weight percent according to each component in the prescription, take by weighing Starso 6 grams respectively, Trisodium Citrate 12 grams, trolamine 7.6 gram drops in the containers, add then total throw 30% of the water yield go dried up, i.e. 558 grams, stir, material in the container is all dissolved, and churning time 10 minutes is crossed 200 mesh sieves then; Then second step, take by weighing dimethyl dodecyl amine oxide 34 grams respectively, fatty alcohol-polyoxyethylene ether 20 grams, ethanol 30 gram drops into 70% deionized water of residue Total Water, i.e. 1302 grams, fully stir, make the material in the container dissolve churning time 10 minutes fully; The 3rd step according to the per-cent of formulation weight, took by weighing polysiloxane quaternary amine 10 grams, and propylene glycol butyl ether 20 grams mix stirring, 5 minutes time, make the dissolving of polysiloxane quaternary amine, and the liquid in the container is limpid homogeneous liquid.At last, material in the poly-container of second step is rendered in the container of first step, churning time is 10 minutes, after with citric acid pH value being adjusted to 9.5-10.0, solution in the third step is also put in the container of first step, stirred 5 minutes, and made all material uniform mixing of filling a prescription in the container, should not have the visible solids to as clear as crystal liquid.Add 0.4 gram lemon class spices again, make product that good flavor perception be arranged, packing just is the present invention's product after filtration then.
Embodiment 2
Preparation 2000 gram sterilizing detergent for cleaning
Weight percent according to each component in the prescription, take by weighing Starso 12 grams respectively, Trisodium Citrate 16 grams, trolamine 12 grams drop in the container, then 30% of the total throwing of the adding water yield deionized water, i.e. 528 grams, stir, material in the container is all dissolved, and churning time is 10 minutes, crosses 200 mesh sieves then; Then second step, take by weighing dimethyl dodecyl amine oxide 50 grams respectively, fatty alcohol-polyoxyethylene ether 40 grams, ethanol 50 grams drop into 70% deionized water of residue Total Water, i.e. 1232 grams, churning time 10 minutes is dissolved the material in the container fully; The 3rd step took by weighing polysiloxane quaternary amine 20 grams respectively according to the per-cent of formulation weight, and propylene glycol butyl ether 40 grams mix stirring, 5 minutes time, and the polysiloxane quaternary amine is dissolved fully, the liquid in the container is limpid homogeneous liquid.At last, the material of the second step container is put in the container of first step, churning time 10 minutes, after with citric acid pH value being adjusted to 9.5-10, the middle solution of third step is also put in the solution of container of first step, stirred 5 minutes, make all material uniform mixing of recipe ingredient in the container to as clear as crystal liquid, should not have the visible solids, filter and package the product that just becomes the present invention then.
Claims (4)
1. a sterilizing detergent for cleaning is a main raw material with polysiloxane quaternary amine, dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, and its component and weight percent are as follows:
Starso 0.3～0.6%
Trisodium Citrate 0.4～0.8%
Trolamine 0.3～0.6%
Dimethyl dodecyl amine oxide 1.5～2.5%
Fatty alcohol-polyoxyethylene ether 1.0～2.0%
Polysiloxane quaternary amine 0.5～1.0%
Propylene glycol butyl ether 1.0～2.0%
Ethanol 1.0～2.5%
Essence 0.02～0.03%
Deionized water 88～92%
Starso in the said components, Trisodium Citrate, trolamine and deionized water are carried out the pre-mixing dissolving; Again dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and deionized water are carried out the pre-mixing dissolving; Then polysiloxane quaternary amine, the pre-mixing of propylene glycol butyl ether; At last above-mentioned three premixs are always mixed.
2. sterilizing detergent for cleaning according to claim 1 is characterized in that dimethyl dodecyl amine oxide can replace with octadecyl dimethyl amine oxide.
3. sterilizing detergent for cleaning according to claim 1 is characterized in that this sterilizing detergent for cleaning can be made into sprays or pressurized aerosol agent.
4. the preparation method of a sterilizing detergent for cleaning may further comprise the steps:
A. the pre-mixing of auxiliary agent
Weight percent according to prescription takes by weighing Starso, Trisodium Citrate, trolamine respectively, throws in 30% deionized water of Total Water then, mix stirring and dissolving, make material in the container all be dissolved to as clear as crystal till, 10～20 minutes time, cross 200 mesh sieves then and filter;
B. clean the pre-mixing of host
The deionized water that takes by weighing dimethyl dodecyl amine oxide, fatty alcohol-polyoxyethylene ether, ethanol and remaining Total Water 70% respectively by proportioning carries out pre-mixing and is dissolved into as clear as crystal liquid;
C. the pre-mixing of sterilant
Take by weighing polysiloxane quaternary amine, propylene glycol butyl ether respectively by proportioning and carry out the liquid that the pre-mixing dissolving stirs into homogeneous transparent;
D. sterilizing detergent for cleaning is mixed with
The premixed liquid of B step preparation is rendered in the premixed liquid container of splendid attire A step preparation, stir, make liquid be vitreous state, with citric acid its pH value is adjusted to 9.5～10, then the premixed liquid of C step is put in the above-mentioned container and stirred, call in the essence blending again, filter finished product packing at last.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019428 CN102127491B (en) | 2010-01-15 | 2010-01-15 | Bactericidal cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010019428 CN102127491B (en) | 2010-01-15 | 2010-01-15 | Bactericidal cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102127491A true CN102127491A (en) | 2011-07-20 |
| CN102127491B CN102127491B (en) | 2013-02-27 |
Family
ID=44265766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010019428 Expired - Fee Related CN102127491B (en) | 2010-01-15 | 2010-01-15 | Bactericidal cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN102127491B (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533461A (en) * | 2011-12-27 | 2012-07-04 | 瑞普（天津）生物药业有限公司 | Composition with effect of cleaning poultry and livestock drinking water system and its preparation method |
| CN103766402A (en) * | 2014-01-23 | 2014-05-07 | 南通苏通分离工程科技有限公司 | Disinfectant and preparation method thereof |
| CN105838518A (en) * | 2016-05-13 | 2016-08-10 | 周家仁 | Antibacterial laundry detergent |
| CN105838517A (en) * | 2016-05-05 | 2016-08-10 | 马鞍山纽盟知识产权管理服务有限公司 | Towel cleaning agent |
| CN108774598A (en) * | 2018-08-23 | 2018-11-09 | 安庆枝梅化工有限责任公司 | A kind of disinfecting scrub liquid |
| CN109477036A (en) * | 2016-02-05 | 2019-03-15 | 艺康美国股份有限公司 | Detergent composition for the cleaning in cosmetics and pharmaceuticals industry |
| CN109706000A (en) * | 2018-12-26 | 2019-05-03 | 深圳市北岳海威化工有限公司 | A kind of long acting antibiotic liquid detergent and preparation method thereof |
| CN112544697A (en) * | 2020-11-20 | 2021-03-26 | 海南同德食品配送有限公司 | Cold-chain logistics fresh-keeping method for agricultural products |
| CN113214918A (en) * | 2021-05-21 | 2021-08-06 | 大连欧派科技有限公司 | Wet tissue for glasses and preparation method thereof |
| CN113897248A (en) * | 2021-09-22 | 2022-01-07 | 广东御容宫生物科技有限公司 | Degerming and mite-removing laundry detergent and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100532526C (en) * | 2007-12-10 | 2009-08-26 | 北京绿伞化学股份有限公司 | Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof |
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2010
- 2010-01-15 CN CN 201010019428 patent/CN102127491B/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533461A (en) * | 2011-12-27 | 2012-07-04 | 瑞普（天津）生物药业有限公司 | Composition with effect of cleaning poultry and livestock drinking water system and its preparation method |
| CN103766402A (en) * | 2014-01-23 | 2014-05-07 | 南通苏通分离工程科技有限公司 | Disinfectant and preparation method thereof |
| US11685878B2 (en) | 2016-02-05 | 2023-06-27 | Ecolab Usa Inc. | Detergent compositions for cleaning in the cosmetic and pharmaceutical industry |
| CN109477036A (en) * | 2016-02-05 | 2019-03-15 | 艺康美国股份有限公司 | Detergent composition for the cleaning in cosmetics and pharmaceuticals industry |
| US11746305B2 (en) | 2016-02-05 | 2023-09-05 | Ecolab Usa Inc. | Detergent compositions for cleaning in the cosmetic and pharmaceutical industry |
| CN105838517A (en) * | 2016-05-05 | 2016-08-10 | 马鞍山纽盟知识产权管理服务有限公司 | Towel cleaning agent |
| CN105838518A (en) * | 2016-05-13 | 2016-08-10 | 周家仁 | Antibacterial laundry detergent |
| CN108774598A (en) * | 2018-08-23 | 2018-11-09 | 安庆枝梅化工有限责任公司 | A kind of disinfecting scrub liquid |
| CN109706000A (en) * | 2018-12-26 | 2019-05-03 | 深圳市北岳海威化工有限公司 | A kind of long acting antibiotic liquid detergent and preparation method thereof |
| CN112544697A (en) * | 2020-11-20 | 2021-03-26 | 海南同德食品配送有限公司 | Cold-chain logistics fresh-keeping method for agricultural products |
| CN113214918A (en) * | 2021-05-21 | 2021-08-06 | 大连欧派科技有限公司 | Wet tissue for glasses and preparation method thereof |
| CN113897248A (en) * | 2021-09-22 | 2022-01-07 | 广东御容宫生物科技有限公司 | Degerming and mite-removing laundry detergent and preparation method thereof |
| CN113897248B (en) * | 2021-09-22 | 2023-10-31 | 广东御容宫生物科技有限公司 | Degerming and mite-killing laundry detergent and preparation method thereof |
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