CN101200676A - Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof - Google Patents

Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof Download PDF

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Publication number
CN101200676A
CN101200676A CNA200710179038XA CN200710179038A CN101200676A CN 101200676 A CN101200676 A CN 101200676A CN A200710179038X A CNA200710179038X A CN A200710179038XA CN 200710179038 A CN200710179038 A CN 200710179038A CN 101200676 A CN101200676 A CN 101200676A
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aeo
fatty alcohol
polyoxyethylene ether
sterilizing function
detergent
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CNA200710179038XA
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CN100532526C (en
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冯秀节
张辉
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Beijing green umbrella Technology Co.,Ltd.
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BEIJING LVSAN CHEMICAL Co Ltd
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Abstract

The present invention provides a nontoxic grade floor and furniture detergent with the function of sterilization and a preparation method thereof and relates to the detergent field. The nontoxic grade floor and furniture detergent with the function of sterilization is made by compounding double-arc bactericide, sterilization and infiltration accelerator and emulsifying agent and can achieve floor cleaning, decontamination, sterilization and disinfection synchronously. The nontoxic grade floor and furniture detergent with the function of sterilization is confected by the raw materials of fatty alcohol polyoxyethylene ether (9) AEO-9, polyhexamethylene biguanide PHMB, dodecyl dimethyl betaine (BS-12), dodecyl dimethyl benzyl sal ammoniac 1227, branch chain type fatty alcohol polyoxyethylene ether XP-90, alkyl polyglucoside APG, the fatty alcohol polyoxyethylene ether (7) AEO-7, the fatty alcohol polyoxyethylene ether (5) AEO-5, the fatty alcohol polyoxyethylene ether (3) AEO-3, amine oxide, dialkyl quaternary ammonium salt etc. The preparation method is that deionized water is added into a material dissolving vessel to be dissolved with the raw materials to obtain the product. The present invention has good sterilization effect and wide application range, which is innocuous to human body under the using concentration.

Description

A kind of non-toxic class floor furniture detergent and preparation method thereof with sterilizing function
Technical field
The invention belongs to detergent applications, particularly a kind of non-toxic class floor furniture detergent and preparation method thereof with sterilizing function.
Background technology
Along with modern people's growth in the living standard, increasing family adopts floor finiss.But dirts such as oil stain, fruit juice, milk stain, dust, food are stained with in regular meeting on the floor, and are not only dirty ugly, and easy breed bacteria.Can remove a part but decontamination is not thorough with clear water, more especially be difficult for the oily dirt seen, actual being difficult to removed, and be all the more so on some not too slick floors such as abrasive floor.Also can decontamination with washing powder or dish detergent, but washing powder generally is alkalescence, and life-time service can be detrimental to the floor.In addition, washing powder is solids, may residual " white powder " after doing, and dish detergent then may residual causing be clamminess.And; the floor; often can gather, grow, breed a large amount of bacteriums on the furniture; wherein many harmful to HUMAN HEALTH and household goods; common streptococcus aureus, intestinal bacteria, Candida albicans are main representatives; in Ministry of Health's 2002 " disinfection technology standard " also them as the representative bacterial classification of estimating disinfection product bactericidal property, if promptly can killing power be arranged, then most germs are had sterilizing ability to these three kinds of bacteriums.
Be used for the germ-resistant material of floor furniture at present, mainly contain four classes:
The first kind: chlorine-containing disinfectant, hypochlorous sodium are representative, and they have the good sterilization effect, but serious pungency is arranged, and many materials are faded, and generally do not re-use.
Second class: PCMX (parachlormetaxylenol), it just has sterilization effect (usually more than 1000PPM) preferably under higher effective concentration, relatively poor to fungies such as Candida albicans, mould sterilization effect.Because it is water insoluble,, cause cost to increase so need a large amount of solvents and tensio-active agent to come solubilising; Again because it must carry out the increase that causes working condition limited (under the acidic conditions) and pollute under neutral and weak basic condition.
The 3rd class: the negatively charged ion quaternary amine, they are relatively gentle, toxicity is low relatively, but sterilization effect is relatively poor, must and the compound economic worth that practicality is just arranged of other sterilant.
The 4th class PHMB (poly hexamethylene biguanide), it all has effect to gram-positive microorganism, negative bacterium, and nontoxic non-stimulated, and is especially effective to fungies such as Candida albicans, mould, in that pH value is effective widely, sterilization effect is arranged all in 5~100ppm scope.After using for some time, because its polymer molecular structure, can be adsorbed onto the floor, furniture surface, therefore lasting antibacterial effect is arranged, but can not use with anion surfactant, many nonionogenic tensides also can influence its sterilizing power, therefore, independent use can not reach and not only clean but also can sterilization effects.
The invention solves this problem, adopt two arc series bactericidal agents and sterilization penetration enhancer and emulsifying agent to be composited, can finish cleaning decontamination, sterilization and disinfection simultaneously the floor.
Summary of the invention
The purpose of this invention is to provide a kind of non-toxic class floor furniture detergent and preparation method thereof with sterilizing function.This non-toxic class floor furniture detergent with sterilizing function adopts two arc series bactericidal agents and sterilization penetration enhancer and emulsifying agent to be composited, and can finish cleaning decontamination, sterilization and disinfection to the floor simultaneously.
Technical scheme of the present invention is achieved in that
A kind of non-toxic class floor furniture detergent with sterilizing function is characterized in that, this non-toxic class floor furniture detergent with sterilizing function is that proportioning is prepared from according to the following number of weight ratio:
The title ratio of weight and number
Fatty alcohol-polyoxyethylene ether (9) AEO-9 0.1~10
Poly hexamethylene biguanide PHMB (20%) 0.1~4.0
Varion CDG-K (BS-12) (30%) 0.1~10
Dodecyl dimethyl benzyl ammonia chloride 1227 (45%) 0.1~4.0
Branched chain type fatty alcohol-polyoxyethylene ether XP-90 0.1~10
Alkyl-glucoside APG (50%) 0.1~10
Fatty alcohol-polyoxyethylene ether (7) AEO-7 0.1~10
Fatty alcohol-polyoxyethylene ether (5) AEO-5 0.1~5
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.1~2
Amine oxide 0.1~10
Two alkyl quaternary amine salt 0.1~6
Hydrochloric acid HCL (30%) 0.001~2
Deionized water 40~70
A kind of preparation method with non-toxic class floor furniture detergent of sterilizing function is characterized in that, this non-toxic class floor furniture detergent with sterilizing function prepares by following step:
1. change material
(1) in changing the material still, adds 30~40%50~60 ℃ of deionized waters, add BS-12, APG, amine oxide, XP-90, AEO-9, AEO-7, AEO-5, the AEO-3 described in the prescription of above-mentioned non-toxic class floor furniture detergent successively, stirring and dissolving with sterilizing function.
(2) supply PHMB, 1227, the two alkyl quaternary amine salt described in the prescription that adds above-mentioned non-toxic class floor furniture detergent after the deionized water at normal temperature again, stir with sterilizing function.
(3) adjust pH value 5.5~6.5 with the HCL described in the prescription of above-mentioned non-toxic class floor furniture detergent, filter standby with sterilizing function.
2. the non-toxic class floor furniture detergent with sterilizing function behind the describedization material is detected, filling bottle decals, check vanning.
Filtration in described (3) step is to adopt 200 order nylon screens to filter.
Technology controlling and process point of the present invention:
1. accurately take by weighing industrial chemicals and deionized water.
2. strict reinforced in proper order according to changing material.
3.pH value (stoste): 5.5~6.5, adjust with HCl solution.
Product performance of the present invention:
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.3%): streptococcus aureus 99.57%, intestinal bacteria 99.36%, Candida albicans 96.97%.
The normal temperature quality guaranteed period is 24 months.
The characteristics of the present invention's prescription:
1. the nonionogenic tenside AEO-9 that selects for use of the present invention, AEO-7 has extremely strong soil-removing action.
2. the AEO-5 that selects for use of the present invention, AEO-3, XP-90 can obviously reduce surface tension, promotes sterilant to move to the bacterial cell surface and is penetrated into inside, strengthens germicidal action.
3. BS-12 and the amine oxide itself selected for use of the present invention has certain germicidal action, has the decontamination synergistic effect again.
4. two alkyl quaternary amine salt and 1227 of selecting for use of the present invention itself are sterilant.With the compound sterilization effect that improves of PHMB.
5. the APG that selects for use of the present invention is the alkyl-glucoside of performance gentleness, except increasing detersive power, also has strong spreading ability, reduces the sticky sense on the surface.
Compared with the prior art the present invention has following advantage:
1. the present invention adopts two arc series bactericidal agents and sterilization penetration enhancer and emulsifying agent to be composited, and can finish cleaning decontamination, sterilization and disinfection to the floor simultaneously.Sterilization effect is thorough, is up to state standards.
2. the present invention also can be used for the cleaning-sterilizing of furniture, door and window, and use range is extensive.
3. the present invention is that totally nontoxic is harmless under working concentration, even children's skin contact can not come to harm yet, more can not damage the floor.
Description of drawings:
Fig. 1 is a process flow sheet of the present invention.
Embodiment
The present invention is described further below in conjunction with embodiment, and embodiment only means never that for indicative it limits the scope of the invention by any way.
Embodiment 1:
The prescription that the non-toxic class floor furniture detergent with sterilizing function that present embodiment provides adopts is as follows:
Prepare described non-toxic class floor furniture detergent 50kg with sterilizing function, proportioning comprises following component by weight:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 2kg
Poly hexamethylene biguanide PHMB (20%) 1.6kg
Varion CDG-K (BS-12) (30%) 4kg
Dodecyl dimethyl benzyl ammonia chloride 1227 (45%) 1kg
Branched chain type fatty alcohol-polyoxyethylene ether XP-90 0.5kg
Alkyl-glucoside APG (50%) 1kg
Fatty alcohol-polyoxyethylene ether (7) AEO-7 3kg
Fatty alcohol-polyoxyethylene ether (5) AEO-5 0.1kg
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.4kg
Amine oxide 1kg
Two alkyl quaternary amine salt 2.5kg
Hydrochloric acid HCL (30%) 0.05~0.15kg
Deionized water 32.75~32.85kg
Above-described various raw material is technical grade.
Preparation technology:
1. change material
(1) in changing the material still, adds 30~40%50~60 ℃ of deionized waters, add BS12, APG, amine oxide, XP-90, AEO-9, AEO-7, AEO-5, the AEO-3 described in the prescription of above-mentioned non-toxic class floor furniture detergent successively, stirring and dissolving with sterilizing function.
(2) supplying PHMB, 1227, the two alkyl quaternary amine salt described in the prescription that adds the above-mentioned non-toxic class floor furniture detergent with sterilizing function after the deionized water at normal temperature again stirs.
(3) adjust pH value 5.5~6.5 with the HCL described in the prescription of above-mentioned non-toxic class floor furniture detergent, filter standby with 200 order nylon screens with sterilizing function.
2. the non-toxic class floor furniture detergent with sterilizing function behind the describedization material is detected, filling bottle decals, check vanning.
The present embodiment product performance:
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.5%): streptococcus aureus 99.98%, intestinal bacteria 99.87%, Candida albicans 99.0%.
Embodiment 2:
The prescription that the non-toxic class floor furniture detergent with sterilizing function that present embodiment provides adopts is as follows:
Prepare described non-toxic class floor furniture detergent 50kg with sterilizing function, proportioning comprises following component by weight:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 4kg
Poly hexamethylene biguanide PHMB (20%) 2kg
Varion CDG-K (BS-12) (30%) 4.5kg
Dodecyl dimethyl benzyl ammonia chloride 1227 (45%) 2kg
Branched chain type fatty alcohol-polyoxyethylene ether XP-90 2.5kg
Alkyl-glucoside APG (50%) 4kg
Fatty alcohol-polyoxyethylene ether (7) AEO-7 3.5kg
Fatty alcohol-polyoxyethylene ether (5) AEO-5 1.5kg
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.5kg
Amine oxide 0.05~5kg
Two alkyl quaternary amine salt 2.5kg
30% hydrochloric acid HCL, 0.0005~1kg
Deionized water 17~23kg
Above-described various raw material is technical grade.
Present embodiment preparation technology is with embodiment 1.
The present embodiment product performance:
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.5%): streptococcus aureus 99.98%, intestinal bacteria 99.98%, Candida albicans 99.0%.
Embodiment 3:
The prescription that the non-toxic class floor furniture detergent agent with sterilizing function that present embodiment provides is adopted is as follows:
Prepare described non-toxic class floor furniture detergent 50kg with sterilizing function, proportioning comprises following component by weight:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 3kg
Poly hexamethylene biguanide PHMB (20%) 0.75kg
Varion CDG-K (BS-12) (30%) 2.5kg
Branched chain type fatty alcohol-polyoxyethylene ether XP-90 1.5kg
Alkyl-glucoside APG (50%) 2kg
Fatty alcohol-polyoxyethylene ether (7) AEO-7 2.5kg
Fatty alcohol-polyoxyethylene ether (5) AEO-5 1kg
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.25kg
Amine oxide 2kg
Hydrochloric acid HCL (30%) 0.1~0.25kg
Deionized water 34.25~34.4kg
Above-described various raw material is technical grade.
Preparation technology:
1. change material
(1) in changing the material still, adds 30~40%50~60 ℃ of deionized waters, add BS12, APG, amine oxide, XP-90, AEO-9, AEO-7, AEO-5, the AEO-3 described in the prescription of above-mentioned non-toxic class floor furniture detergent successively, stirring and dissolving with sterilizing function.
(2) supplying the PHMB described in the prescription that adds the above-mentioned non-toxic class floor furniture detergent with sterilizing function after the deionized water at normal temperature again stirs.
(3) adjust pH value 5.5~6.5 with the HCL described in the prescription of above-mentioned non-toxic class floor furniture detergent, filter standby with 200 order nylon screens with sterilizing function.
2. the non-toxic class floor furniture detergent with sterilizing function behind the describedization material is detected, filling bottle decals, check vanning.
The present embodiment product performance:
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.5%): streptococcus aureus 98.0%, intestinal bacteria 99.1%, Candida albicans 70%.
This shows that do not add 1227 in the present embodiment, two alkyl quaternary amine salt, sterilizing power is low.Therefore, 1227, two alkyl quaternary amine salt is the indispensable component of the present invention.
Embodiment 4:
The prescription that the non-toxic class floor furniture detergent with sterilizing function that present embodiment provides adopts is as follows:
Prepare described non-toxic class floor furniture detergent 50kg with sterilizing function, proportioning comprises following component by weight:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 3kg
Poly hexamethylene biguanide PHMB (20%) 0.4kg
Varion CDG-K (BS-12) (30%) 0.5kg
Dodecyl dimethyl benzyl ammonia chloride 1227 (45%) 0.5kg
Branched chain type fatty alcohol-polyoxyethylene ether XP-90 0.05kg
Alkyl-glucoside APG (50%) 0.05kg
Fatty alcohol-polyoxyethylene ether (7) AEO-7 0.1kg
Fatty alcohol-polyoxyethylene ether (5) AEO-5 0.1kg
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.15kg
Amine oxide 0.5kg
Two alkyl quaternary amine salt 0.1kg
30% hydrochloric acid HCL, 0.0005~0.0015kg
Deionized water 44.55kg
Above-described various raw material is technical grade.
Present embodiment preparation technology is with embodiment 1.
The present embodiment product performance:
Sterilizing power (Ministry of Health 2002 " disinfection technology standard ") (90 days, 37 ℃, 0.5%): streptococcus aureus 97.65%, intestinal bacteria 98.42%, Candida albicans 65%.
This shows that component concentration such as PHMB, 1227, two alkyl quaternary amine salt is few in the present embodiment, sterilizing power is low.Therefore, each component rational proportion is very important among the present invention.

Claims (5)

1. the non-toxic class floor furniture detergent with sterilizing function is characterized in that, described non-toxic class floor furniture detergent with sterilizing function proportioning by weight comprises following component:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 0.1~10
20% poly hexamethylene biguanide PHMB 0.1~4.0
30% Varion CDG-K BS-12 0.1~10
45% dodecyl dimethyl benzyl ammonia chloride 1,227 0.1~4.0
Branched chain type fatty alcohol-polyoxyethylene ether (9) XP-90 0.1~10
50% alkyl-glucoside APG 0.1~10
Fatty alcohol-polyoxyethylene ether (7) AEO-7 0.1~10
Fatty alcohol-polyoxyethylene ether (5) AEO-5 0.1~5
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.1~2
Amine oxide 0.1~10
Two alkyl quaternary amine salt 0.1~6
30% hydrochloric acid HCL 0.001~2
Deionized water 40~70.
2. a kind of non-toxic class floor furniture detergent with sterilizing function according to claim 1 is characterized in that, described non-toxic class floor furniture detergent with sterilizing function proportioning by weight comprises following component:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 4
20% poly hexamethylene biguanide PHMB 3.2
30% Varion CDG-K BS-12 8
45% dodecyl dimethyl benzyl ammonia chloride 1,227 2
Branched chain type fatty alcohol-polyoxyethylene ether (9) XP-90 1
50% alkyl-glucoside APG 2
Fatty alcohol-polyoxyethylene ether (7) AEO-7 6
Fatty alcohol-polyoxyethylene ether (5) AEO-5 0.2
Fatty alcohol-polyoxyethylene ether (3) AEO-3 0.8
Amine oxide 2
Two alkyl quaternary amine salt 5
30% hydrochloric acid HCL 0.1~0.3
Deionized water 65.5~65.7.
3. a kind of non-toxic class floor furniture detergent with sterilizing function according to claim 1 is characterized in that, described non-toxic class floor furniture detergent with sterilizing function proportioning by weight comprises following component:
Fatty alcohol-polyoxyethylene ether (9) AEO-9 8
20% poly hexamethylene biguanide PHMB 4.0
30% Varion CDG-K BS-12 9
45% dodecyl dimethyl benzyl ammonia chloride 1,227 4.0
Branched chain type fatty alcohol-polyoxyethylene ether (9) XP-90 5
50% alkyl-glucoside APG 8
Fatty alcohol-polyoxyethylene ether (7) AEO-7 7
Fatty alcohol-polyoxyethylene ether (5) AEO-5 3
Fatty alcohol-polyoxyethylene ether (3) AEO-3 1
Amine oxide 0.1
Two alkyl quaternary amine salt 5
30% hydrochloric acid HCL 0.2~0.6
Deionized water 45.3~45.7.
4. one kind by the described preparation method with non-toxic class floor furniture detergent of sterilizing function of claim 1, it is characterized in that described preparation method's processing step is:
A. in changing the material still, add 30~40%50~60 ℃ of deionized waters, add BS12, APG, amine oxide, XP-90, AEO-9, AEO-7, AEO-5, the AEO-3 described in the prescription of above-mentioned non-toxic class floor furniture detergent successively, stirring and dissolving with sterilizing function;
B. supplying PHMB, 1227, the two alkyl quaternary amine salt described in the prescription that adds the above-mentioned non-toxic class floor furniture detergent with sterilizing function after the deionized water at normal temperature again stirs;
C. adjust pH value 5.5~6.5 with the HCL described in the prescription of above-mentioned non-toxic class floor furniture detergent and filter standby getting product with sterilizing function.
5. a kind of preparation method with non-toxic class floor furniture detergent of sterilizing function according to claim 4 is characterized in that, the filtration in the described c step is to adopt 200 order nylon screens to filter.
CNB200710179038XA 2007-12-10 2007-12-10 Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof Active CN100532526C (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101818104A (en) * 2010-05-17 2010-09-01 北京绿伞化学股份有限公司 Neutral cleaning agent for bathroom equipment and preparation method thereof
CN102127491B (en) * 2010-01-15 2013-02-27 谭钢 Bactericidal cleaning agent and preparation method thereof
CN103038325A (en) * 2010-06-17 2013-04-10 约翰逊父子公司 Anti-bacterial cleaning composition
CN103194326A (en) * 2013-04-28 2013-07-10 北京绿伞化学股份有限公司 Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent
WO2015091163A1 (en) * 2013-12-16 2015-06-25 Henkel Ag & Co. Kgaa Disinfectant composition with excellent foam profile
WO2015091164A1 (en) * 2013-12-16 2015-06-25 Henkel Ag & Co. Kgaa Disinfectant composition with excellent foam profile and cleaning power
CN105567460A (en) * 2015-12-11 2016-05-11 天津璞誉环保科技开发有限公司 Furniture cleaner with mosquito repelling function
CN106434002A (en) * 2016-09-14 2017-02-22 芜湖成德龙过滤设备有限公司 Sleeve decontaminant and preparation method thereof
CN106833950A (en) * 2016-12-28 2017-06-13 于文 Antibacterial floor cleaner and preparation method thereof

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CN103060135B (en) * 2012-12-27 2014-04-16 上海艳紫化工科技有限公司 Floor cleaning agent

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102127491B (en) * 2010-01-15 2013-02-27 谭钢 Bactericidal cleaning agent and preparation method thereof
CN101818104A (en) * 2010-05-17 2010-09-01 北京绿伞化学股份有限公司 Neutral cleaning agent for bathroom equipment and preparation method thereof
CN103038325A (en) * 2010-06-17 2013-04-10 约翰逊父子公司 Anti-bacterial cleaning composition
CN103038325B (en) * 2010-06-17 2015-07-15 约翰逊父子公司 Anti-bacterial cleaning composition
CN103194326A (en) * 2013-04-28 2013-07-10 北京绿伞化学股份有限公司 Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent
CN103194326B (en) * 2013-04-28 2015-06-17 北京绿伞化学股份有限公司 Disinfecting laundry detergent with compound cationic and anionic surfactant and preparation method of laundry detergent
WO2015091163A1 (en) * 2013-12-16 2015-06-25 Henkel Ag & Co. Kgaa Disinfectant composition with excellent foam profile
WO2015091164A1 (en) * 2013-12-16 2015-06-25 Henkel Ag & Co. Kgaa Disinfectant composition with excellent foam profile and cleaning power
CN105567460A (en) * 2015-12-11 2016-05-11 天津璞誉环保科技开发有限公司 Furniture cleaner with mosquito repelling function
CN106434002A (en) * 2016-09-14 2017-02-22 芜湖成德龙过滤设备有限公司 Sleeve decontaminant and preparation method thereof
CN106833950A (en) * 2016-12-28 2017-06-13 于文 Antibacterial floor cleaner and preparation method thereof

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Denomination of invention: Non-toxic class floor furniture detergent having sterilizing function and preparation method thereof

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Change date: 20130129

Registration number: 2011990000498

Pledgee after: Haidian Beijing science and technology enterprise financing Company limited by guarantee

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Address after: 100094 block B, building 1, yard 2, Yongcheng North Road, Yongfeng Industrial base, Haidian District, Beijing

Patentee after: Beijing green umbrella Technology Co.,Ltd.

Address before: 100094, No. 3, North Road, Yongfeng industrial base, Beijing, Haidian District

Patentee before: Beijing Lvsan Chemistry Co.,Ltd.

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