CN102056587A - 染发剂组合物 - Google Patents
染发剂组合物 Download PDFInfo
- Publication number
- CN102056587A CN102056587A CN2008801297997A CN200880129799A CN102056587A CN 102056587 A CN102056587 A CN 102056587A CN 2008801297997 A CN2008801297997 A CN 2008801297997A CN 200880129799 A CN200880129799 A CN 200880129799A CN 102056587 A CN102056587 A CN 102056587A
- Authority
- CN
- China
- Prior art keywords
- preparation composition
- hair coloring
- coloring preparation
- ascorbic acid
- dose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 94
- 238000002360 preparation method Methods 0.000 title claims abstract description 86
- 239000000118 hair dye Substances 0.000 title abstract description 19
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims abstract description 106
- 239000000975 dye Substances 0.000 claims abstract description 81
- 235000010323 ascorbic acid Nutrition 0.000 claims abstract description 69
- 239000011668 ascorbic acid Substances 0.000 claims abstract description 69
- 229960005070 ascorbic acid Drugs 0.000 claims abstract description 69
- -1 ascorbic acid compound Chemical class 0.000 claims abstract description 56
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 43
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 38
- 230000003647 oxidation Effects 0.000 claims abstract description 32
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 32
- 230000037308 hair color Effects 0.000 claims description 82
- 239000003513 alkali Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 32
- 238000004043 dyeing Methods 0.000 description 30
- 239000000543 intermediate Substances 0.000 description 21
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 17
- 241001080929 Zeugopterus punctatus Species 0.000 description 15
- 239000004094 surface-active agent Substances 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000003921 oil Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- 229920001296 polysiloxane Polymers 0.000 description 10
- 239000007822 coupling agent Substances 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- 235000002639 sodium chloride Nutrition 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 235000010352 sodium erythorbate Nutrition 0.000 description 6
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 5
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 235000011187 glycerol Nutrition 0.000 description 5
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 230000001590 oxidative effect Effects 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
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- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- 239000004166 Lanolin Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical class [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
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- 235000019388 lanolin Nutrition 0.000 description 3
- 229940039717 lanolin Drugs 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- ODHCTXKNWHHXJC-UHFFFAOYSA-N 5-oxoproline Chemical compound OC(=O)C1CCC(=O)N1 ODHCTXKNWHHXJC-UHFFFAOYSA-N 0.000 description 2
- DHHFDKNIEVKVKS-MVUYWVKGSA-N Betanin Natural products O=C(O)[C@@H]1NC(C(=O)O)=C/C(=C\C=[N+]/2\[C@@H](C(=O)[O-])Cc3c\2cc(O)c(O[C@H]2[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O2)c3)/C1 DHHFDKNIEVKVKS-MVUYWVKGSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 235000021360 Myristic acid Nutrition 0.000 description 2
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 2
- 241001597008 Nomeidae Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- BKDZVPVJIXZYBH-UHFFFAOYSA-N [Na].C(C)(=O)O.NC(=N)N Chemical compound [Na].C(C)(=O)O.NC(=N)N BKDZVPVJIXZYBH-UHFFFAOYSA-N 0.000 description 2
- HJCUCLCJVVFBTD-UHFFFAOYSA-N [Na].[Na].S(O)(O)(=O)=O Chemical compound [Na].[Na].S(O)(O)(=O)=O HJCUCLCJVVFBTD-UHFFFAOYSA-N 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 2
- POJWUDADGALRAB-UHFFFAOYSA-N allantoin Chemical compound NC(=O)NC1NC(=O)NC1=O POJWUDADGALRAB-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 235000001014 amino acid Nutrition 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 239000001654 beetroot red Substances 0.000 description 2
- 235000012677 beetroot red Nutrition 0.000 description 2
- 235000002185 betanin Nutrition 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 2
- 150000007529 inorganic bases Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
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- 230000035699 permeability Effects 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- CPJSUEIXXCENMM-UHFFFAOYSA-N phenacetin Chemical compound CCOC1=CC=C(NC(C)=O)C=C1 CPJSUEIXXCENMM-UHFFFAOYSA-N 0.000 description 2
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- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 2
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- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明提供了一种染发剂组合物,其包含第一剂和第二剂,所述的第一剂含有氧化染料和碱剂,所述的第二剂包含过氧化氢,该染发剂组合物在第一剂和第二剂混合后使用。染发剂组合物包含抗坏血酸化合物和过氧化氢,质量含量分别为1.0-5.0%和0.3-1.6%。碱剂含量为每100g染发剂组合物含有3.0-30mmol碱剂。
Description
技术领域
本发明涉及染发剂组合物,更具体地,涉及在不降低染发剂活性的同时防止皮肤着色的染发剂组合物。
背景技术
已知美发组合物,其在混合多种剂后会变得有活性。作为这类美发组合物的实例,一种已知的染发剂组合物含有第一剂和第二剂,其中第一剂包含氧化染料和碱剂,第二剂包含如过氧化氢的氧化剂。碱剂能促进第二剂中氧化剂的作用。另外,碱剂使头发膨胀并提高氧化染料渗入头发的渗透性。从而增强了染发剂的活性。氧化剂在碱剂的作用下分解,释放活性氧并氧化氧化染料产生颜色。
使用氧化染料的染发剂组合物具有优异的染色性能。因此,在染发过程中使皮肤着色的染发剂不易去除。为了应付这种情况,已知专利文献1公开了一种包含过量抗坏血酸的染发剂组合物。在染发过程中使用该染发剂组合物,过量的抗坏血酸防止皮肤着色而不降低染发剂的染发活性。
然而,根据专利文献1,尽管该染发剂组合物包含了过量的抗坏血酸,还含有相对较大量的碱剂和氧化剂以获得所需要的染发活性。
专利文献1:日本特许申请公开号2002-29946。
发明内容
发明人发现,对于包含氧化染料的染发剂组合物,一种组分可实现期望的染发活性并防止皮肤着色,即使减少氧化剂、碱剂和抗坏血酸各自的含量。本发明的目的是提供一种包含氧化染料的染发剂组合物,其能防止皮肤着色而不降低染发活性。
为实现该目的,本发明一方面提供了一种染发剂组合物,该染发剂组合物包含第一剂和第二剂,第一剂包含氧化染料和碱剂,第二剂包含过氧化物,该染发剂组合物在第一剂和第二剂混合后使用。染发剂组合物包含抗坏血酸化合物和过氧化氢,其质量含量分别为1.0-5.0%和0.3-1.6%。每100g染发剂组合物中碱剂含量为3.0-30mmol。
氧化染料优选包含染料中间体,其中染发剂组合物中含有的染料中间体与抗坏血酸化合物的质量比优选为0.7-1.0。
染发剂组合物中抗坏血酸化合物质量含量优选为1.2-4.5%。
染发剂组合物pH优选为6.5-9.5。
染发剂组合物中碱剂与抗血酸化合物的摩尔比优选为0.5-2.8。
附图说明
图1显示了在上臂部位分别施用染发剂组合物然后洗掉的照片。
具体实施方式
根据本发明,染发剂组合物的具体实施方式将在在下文中具体描述。根据本实施方式的染发剂组合物是包含第一剂和第二剂的双剂类型的美发剂。
第一剂
第一剂包含氧化染料和碱剂。第一剂包含,例如,抗坏血酸化合物。氧化染料通过第二剂中含有的过氧化氢引起的氧化聚合作用而产生颜色。该氧化染料可分为染料中间体和偶联剂。氧化染料优选包含染料中间体。
染料中间体的实例包括:对-苯二胺、甲苯-2,5-二胺、N-苯基-对苯二胺、4,4′-二氨基二苯胺、对-氨基苯酚、邻-氨基苯酚、对-甲氨基苯酚、N,N-二(2-羟乙基)-对-苯二胺、2-羟乙基-对-苯二胺、邻-氯-对-苯二胺、4-氨基-间-甲基苯酚、2-氨基-4-羟乙基氨基苯甲醚、2,4-二氨基苯酚,以及它们的盐。这些染料中间体的实例,可单独使用,也可两种或者更多种组合使用。
偶联剂通过与染料中间体偶联呈现颜色。偶联剂的实例包括:5-氨基-邻-甲基苯酚、间-氨基苯酚、5-(2-羟乙基氨基)-2-甲基苯酚、间-苯二胺、2,4-二氨基苯氧基乙醇、甲苯-3,4-二胺、2,6-二氨基嘧啶、二苯胺、N,N-二乙基-间-氨基苯酚、苯基甲基吡唑啉酮,以及它们的盐。这些偶联剂的实例,可单独使用也可两种或者更多种组合使用。
氧化染料可提供多种头发色调。氧化染料优选由至少一种选自上述实例的染料中间体和至少一种选自上述实例的偶联剂组成。第一剂可包含,例如,选自氧化染料(由“Iyakubugaihin Genryo Kikaku”(日本化妆品成分标准)(Japanese Standards of Quasi-drug Ingredients)(Yakuji Nippo Limited于1991六月出版)中列举)和直接染料的至少一种。
染发剂组合物中的氧化染料的质量含量优选为0.02-25%,更优选的质量含量为0.12-15%。如果氧化染料的质量含量低于0.02%,就不能获得足够的染发活性。另一方面,如果氧化染料的质量含量超过25%,染发活性不会进一步增加,因而不经济。
染发剂组合物中染料中间体的质量含量优选为0.01-15%,更优选为0.1-10%。如果染料中间体的质量含量低于0.01%,就不能获得足够的染发活性。另一方面,如果染料中间体的质量含量高于15%,染发活性不会进一步增加,因而不经济。
染发剂组合物中偶联剂的质量含量优选为0.01-10%,更优选为0.02-5%。如果偶联剂的质量含量低于0.01%,就不能获得足够的染发活性。另一方面,如果偶联剂的质量含量高于10%,染发活性不会进一步增加,因而不经济。
碱剂可促进第二剂中过氧化氢的作用。另外,碱剂膨胀头发以提高染料渗入头发的渗透性。有助于增强染发剂的活性。碱剂的实例包括氨、烷醇胺、有机胺、无机碱、碱性氨基酸及其盐。烷醇胺的实例包括单乙醇胺、异丙醇胺、2-氨基-2-甲基丙醇、二乙醇胺和三乙醇胺。有机胺的实例包括2-氨基-2-甲基-1,3-丙二醇和胍。无机碱的实例包括氢氧化钠、氢氧化钾、碳酸钠和碳酸钾。碱性氨基酸的实例包括精氨酸和赖氨酸。盐的实例包括铵盐。这些碱剂的实例,可单独使用也可两种或者更多种组合使用。
每100g染发剂组合物中的碱剂含量为3.0-30mmol,优选为10-30mmol。如果每100g染发剂组合物中的碱剂含量小于3.0mmol,染发剂活性降低。另一方面,如果每100g染发剂组合物中的碱剂含量大于30mmol,就不能充分防止皮肤着色。
抗坏血酸化合物用来防止皮肤着色。抗坏血酸化合物可包含在第二剂中。抗坏血酸化合物的实例包括:抗坏血酸、异抗坏血酸及其盐和其衍生物。抗坏血酸和异抗坏血酸的盐的实例包括抗坏血酸钠、抗坏血酸钾、抗坏血酸钙、抗坏血酸铵、抗坏血酸单乙醇胺、抗坏血酸二乙醇胺和异抗坏血酸钠。抗坏血酸和异抗坏血酸的衍生物的实例包括抗坏血酸硫酸二钠、异抗坏血酸硫酸二钠、抗坏血酸磷酸镁、抗坏血酸棕榈酸酯、抗坏血酸硬脂酸酯、抗坏血酸二棕榈酸酯、抗坏血酸四-2-己基癸酸酯、抗坏血酸豆蔻酸酯、抗坏血酸月桂酸酯、抗坏血酸乙酯、抗坏血酸丙酸酯、抗坏血酸酒石酸酯、抗坏血酸柠檬酸酯、抗坏血酸琥珀酸酯、抗坏血酸苯甲酸酯、磷酸抗坏血酸酯生育酚酯钾、抗坏血酸乙酯、尿囊素抗坏血酸(allantoin ascorbate)、壳聚糖抗坏血酸、抗坏血酸甲基硅烷醇酯、四癸基己基抗坏血酸(ascorbyl tetradecylhexyl)、氨基丙基抗坏血酸磷酸酯、多肽抗坏血酸、抗坏血酸葡糖苷和抗坏血酸甲基硅烷醇果胶酸酯。以上抗坏血酸化合物中,尤其优选抗坏血酸、异抗坏血酸及其盐。
染发剂组合物中抗坏血酸化合物的质量含量为1.0-5.0%,优选为1.2-4.5%,更优选为1.2-3.0%。如果抗坏血酸的质量含量少于1%,就不足以避免皮肤着色。如果抗坏血酸的质量含量超过5.0%,染发活性下降。
通过以预定的比例混合第一和第二剂得到的染发剂组合物,包含的染料中间体与抗坏血酸化合物的质量比(染料中间体/抗坏血酸化合物)优选为0.7-1.0,更优选为0.7-0.9。通过将染料中间体与抗坏血酸化合物的质量比限制在该范围,进一步改善防止皮肤着色的作用。
通过以预定的比例混合第一剂和第二剂而制备的染发剂组合物,所含的碱剂和抗坏血酸的摩尔比(碱剂/抗坏血酸)优选为0.5-2.8,更优选为1.0-2.8。通过将碱剂和抗坏血酸的摩尔比限制在该范围内,进一步改善防止皮肤着色的作用。
根据需要,第一剂除了可包含上述成分外,还可包含例如,水、水溶性聚合物、油组分、多元醇、表面活性剂、糖、防腐剂、螯合剂、稳定剂、pH调节剂、植物提取物、生药提取物、维生素、芳香剂、不同于上述的抗氧化剂、及紫外线吸收剂。
水用作各组分的溶剂。水溶性聚合物的实例包括阴离子聚合物、阳离子聚合物、非离子聚合物和天然的或者合成的两性聚合物。
油组分给予头发以润湿感。第一剂因此优选包含油组分。油组分的实例包括油脂、蜡、高级醇、烃、高级脂肪酸、烷基甘油基醚、酯和硅酮。
油脂的实例包括橄榄油、山茶油、乳木果油、杏仁油、红花油、葵花籽油、大豆油、棉花籽油、芝麻油、玉米油、菜籽油、米糠油、米胚芽油、葡萄籽油、鳄梨油、夏威夷果油、蓖麻油、椰子油、月见草油。蜡的实例包括蜂蜡、小烛树蜡、巴西棕榈蜡、荷荷芭油和羊毛脂。高级醇的实例包括鲸蜡醇(十六醇)、2-己基癸醇、硬脂醇、异硬脂醇、十八十六醇、油醇、花生醇、山萮醇、2-辛基十二烷醇、月桂醇、肉豆蔻醇、癸基十四醇、和羊毛脂醇。
烃的实例包括石蜡、烯烃低聚物、聚异丁烯、氢化聚异丁烯、矿物油、角鲨烷、聚丁烯、聚乙烯、微晶蜡和凡士林。高级脂肪酸的实例包括月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、山萮酸、异硬脂酸、12-羟基硬脂酸、油酸和羊毛脂酸。烷基甘油基醚的实例包括鲨肝醇、鲛肝醇、鲨油醇、异硬脂基甘油基***。
酯的实例包括己二酸二异丙基酯、肉豆蔻酸异丙基酯、辛酸十六酯、异壬酸异壬酯、肉豆蔻酸辛基十二酯、棕榈酸异丙酯、硬脂酸硬脂酯、豆蔻酸豆蔻酯、肉豆蔻酸异十三酯、棕榈酸2-乙基己基酯、蓖麻醇酸辛基十二醇酯、C10到C30脂肪酸胆甾醇/羊毛甾醇酯、乳酸十六酯、乙酰羊毛脂、二-2-乙基己酸乙二醇酯、脂肪酸的季戊四醇酯、脂肪酸的二季戊四醇酯、癸酸十六酯、三辛酸甘油酯、二异硬脂苹果酸酯和琥珀酸二辛酯。
硅酮的实例包括二甲基聚硅氧烷(二甲基硅油)、甲基苯基聚硅氧烷、十甲基环五硅氧烷、十二甲基环六硅氧烷、羟基端基经过改性的聚二甲硅氧烷、平均聚合度为650-10,000的高度聚合硅氧烷、聚醚改性的硅酮、氨基改性的硅酮、甜菜碱改性的硅酮、烷基改性的硅酮、烷氧基改性的硅酮、巯基改性的硅酮、羧基改性的硅酮、和氟改性的硅酮。实例中的油组分,可单独使用也可两种或者更多种组合使用。
多元醇的实例中包括乙二醇类和甘油类化合物。乙二醇类化合物的实例包括乙二醇、二甘醇、三甘醇、聚乙二醇、丙二醇、二丙二醇、异戊二二醇和1,3-丁二醇。甘油类化合物的实例包括甘油、双甘油、和聚甘油。
表面活性剂用作各组分的乳化剂或者增溶剂。更具体地,表面活性剂乳化或者溶解染料组合物,调节粘度和改善粘度稳定性。表面活性剂的实例包括阴离子表面活性剂、阳离子表面活性剂、两性表面活性剂、和非离子表面活性剂。阴离子表面活性剂的实例包括烷基醚硫酸盐、烷基硫酸盐、烯基醚硫酸盐、烯基硫酸盐、烯烃磺酸盐、烷烃磺酸盐、饱和的或者不饱和的脂肪酸盐、烷基或者烯基醚羧酸盐、α-砜脂肪酸盐、N-酰基氨基酸表面活性剂、磷酸单酯或者二酯表面活性剂、和磺基琥珀酸盐。表面活性剂的阴离子基团的抗衡离子的实例包括钠离子、钾离子和三乙醇胺。烷基硫酸盐的实例包括月桂基硫酸钠。
阳离子表面活性剂的实例包括烷基三甲基铵盐、烯基三甲基铵盐、二烷基二甲基铵盐、二烯基二甲基铵盐、羊毛脂脂肪酸氨基丙基乙基二甲基铵、烷氧基氨基丙基二甲胺、烷基吡啶盐、和苄烷铵盐。表面活性剂的阳离子基团的抗衡离子的实例包括氯离子、溴离子、烷基硫酸离子、和糖精。烷基三甲基铵盐的实例包括十八烷基三甲基氧化铵、十六烷基三甲基氯化铵、和十二烷基三甲基氯化铵。苄烷铵盐的实例包括苯扎氯铵。
两性表面活性剂的实例包括椰油基甜菜碱、月桂酰氨基丙基甜菜碱、椰油酰基丙基甜菜碱、月桂酰两性基乙酸钠、椰油酰两性基乙酸钠和十二烷基甜菜碱(十二烷基二甲基氨基乙酰基甜菜碱)。
非离子表面活性剂的实例包括聚氧化烯烷基醚、聚氧化烯烯基醚、聚氧化乙烯(POE)山梨聚糖脂肪酸酯、蔗糖脂肪酸酯、失水山梨糖醇脂肪酸酯、烷基糖类表面活性剂、甘油脂肪酸酯、POE硬化蓖麻油、脂肪酸烷醇酰胺(alcanolamide)、聚醚改性的硅胶和烷基胺氧化物。聚氧化烯烷基醚的实例包括聚乙二醇单十二醚(POE十二烷基醚)、鲸蜡醇聚醚(POE鲸蜡基醚)、硬脂醇聚醚(POE硬脂醇醚)、油醇聚醚(POE油醇醚)及烷醇聚醚(POE烷基(C12-15)醚)。实例中的表面活性剂,可单独使用也可两种或者更多种组合使用。
糖的实例包括山梨糖醇和麦芽糖。防腐剂的实例包括对羟苯甲酸酯。螯合剂的实例包括乙二胺四醋酸二钠(EDTA-2Na)、1-羟基乙烷-1,1-双膦酸及其盐。稳定剂的实例包括非那西丁、8-羟基喹啉、乙酰苯胺、焦磷酸钠、巴比妥酸、尿酸和丹宁酸。pH调节剂的实例包括乳酸、乙酰丙酸、羟基乙酸、酒石酸、苹果酸、吡咯烷酮羧酸(PCA)、琥珀酸、柠檬酸及谷氨酸。抗氧化剂的实例包括亚硫酸盐(酯)。
第一剂的形态并无特殊限制,其具体实例包括液态、凝胶、泡沫、和膏剂。液态的实例包括水溶液、分散液和乳液。
第二剂
第二剂含有过氧化氢。过氧化氢漂白头发中的黑色素和对氧化染料进行氧化以显色。染发剂组合物中过氧化氢的质量含量为0.3-1.6%,优选质量含量为0.3-1.4%。如果过氧化氢的质量含量低于0.3%,氧化染料就不能充分氧化。如果过氧化氢的质量含量超过1.6%,防止皮肤着色的活性就会降低。
为提高过氧化氢的稳定性,第二剂优选包含稳定剂,例如乙二醇苯醚(苯氧乙醇)、和1-羟基乙烷-1,1-双膦酸或者其盐。1-羟基乙烷-1,1-双膦酸的实例包括1-羟基乙烷-1,1-二磷酸四钠盐和1-羟基乙烷-1,1-二磷酸二钠盐。第二剂可包含常规染发剂组合物中含有的、且不会干扰前述各组分作用的成分。第二剂可包含,例如,第一剂中含有的除氧化染料和碱剂外的成分。
第二剂的形态无特殊限制,其具体的实例包括液态、凝胶态、泡沫态、和膏状。液态的实例包括水溶液、分散液和乳液。
为使用该染发剂组合物,首先混合第一剂和第二剂。然后,将第一剂和第二剂的混合物抹在梳子或者刷子上,再施用到头发上。染发剂组合物,即第一剂和第二剂的混合物的pH优选为6.5-9.5,更优选为7.0-9.5。如果染发剂组合物中的pH低于6.5,染发活性会下降。另一方面,如果染发剂组合物中的pH高于9.5,就不能防止皮肤着色。染发剂组合物的pH通过碱剂的含量和第一剂中含有的pH调节剂的含量来调节。
本具体实施方式中的染发剂组合物具有以下优点:
(1)通过混合第一剂和第二剂得到的染发剂组合物含有质量分数为1.0-5.0%的抗坏血酸化合物和质量分数为0.3-1.6%的过氧化氢。另外,每100g染发剂组合物中的碱剂的含量为3.0-30mmol。基于上述,染发剂在防止皮肤着色的同时染色活性不会降低。
(2)优选地,染发剂组合物含有氧化染料,该氧化染料包含染料中间体,染料中间体与抗坏血酸化合物的质量比为0.7-1.0。在这种情况下,进一步增强了防止皮肤着色的作用。
(3)优选地,染发剂组合物中的抗坏血酸化合物的质量含量为1.2-4.5%。在这种情况下,进一步增强了防止皮肤着色的作用。
(4)优选地,染发剂组合物的pH为6.5-9.5。在这种情况下,可防止皮肤着色而不降低染发剂活性。
(5)优选地,染发剂组合物中含有的碱剂和抗坏血酸化合物的摩尔比为0.5-2.8。在这种情况下,进一步增强了防止皮肤着色的作用。
实施方案可以按以下方式改变。
根据实施方案中的染发剂组合物,抗坏血酸化合物含在第一剂中。然而,抗坏血酸化合物也可包含在第一剂和第二剂中。即,抗坏血酸化合物可只包含在第一剂中,也可包含在第一剂和第二剂中。为获得抗坏血酸化合物的更好的储存稳定性,抗坏血酸化合物优选包含在第一剂中。
实施例:
接下来,将以实施例和比较例的方式更具体地说明实施方案。
首先,制备包含表1和表2中所示的组分的第一和第二剂。然后,实施例1-14和比较例1-9中的染发剂组合物分别通过以质量比1∶1混合第一剂和第二剂而制备。表1和表2各行内列出的数据代表相应组分的含量。该含量以质量百分数表示。实施例及比较例中每种染发剂组合物通过刷子施用到由Beaulax Co.,Ltd.生产的白种人头发束上(以下称作“发束”)。当涂覆染发剂组合物后,发束在室温(25℃)下静置15分钟。然后,用水洗去发束上的染发剂组合物,以洗发精洗两次,再以护发素处理一次。最后,在暖空气流中干燥发束,并放置一天,从而得到经染发剂组合物处理过的发束。使用这些发束,评价了实施例和比较例中的各染发剂组合物的染发活性。
表1和表2的上面部分显示了第一剂的组分。表1和表2内第一剂的引用字符(A)代表氧化染料组分,其中对-苯二胺和甲苯-2,5-二胺为染料中间体,间-氨基苯酚、5-氨基-邻-甲基苯酚、和2,6-二氨基吡啶为偶联剂。在各种第一剂中,除含有氧化染料(A)外,还含有用作碱剂(B)的氨水和单乙醇胺,也含有抗坏血酸(D)和其他多种组分。表1和表2的中间部分显示了第二剂的组分。各种第二剂含有过氧化氢(C)和其他多种组分。表1和表2的下面部分分别显示了通过混合第一剂和第二剂制备的染发剂组合物中含有的抗坏血酸和过氧化氢的含量,及每100g染发剂组合物中碱剂(B)的摩尔数,染料中间体的质量比,使用过程中染发剂的pH,和碱剂的摩尔比。在实施例中,第一剂和第二剂的混合质量比为1∶1,因此染发剂组合物中抗坏血酸的含量是第一剂中抗坏血酸(D)的含量的一半。相似地,染发剂组合物中过氧化氢的含量是第二剂中过氧化氢(C)的含量的一半。“染料中间体的质量比”表示染发剂组合物中含有的染料中间体与抗坏血酸(D)的质量比,即染料中间体/抗坏血酸(D)的含量比。“碱剂的摩尔比”表示染发剂组合物中含有的碱剂(B)与抗坏血酸(D)的摩尔比,即碱剂(B)/抗坏血酸(D)的含量比。表1和表2的底部显示了染发剂活性和防止皮肤着色的评价结果。
<染发活性>
如上所述,经各种染发剂组合物染发处理后的发束的L*a*b*值(L1、a1和b1)通过分光光度计(型号:CM-508d,生产厂商:Minolta Co.,Ltd.)测量得到。对于未经染色的发束的L*a*b*值和经染发剂处理的各发束的L*a*b*值,根据以下公式(1)计算得到未经染色的发束与经染发剂处理的发束的颜色差值(ΔE1)。
ΔE1={(L1-L0)2+(a1-a0)2+(b1-b0)2}1/2…(1)
在公式(1)中,L1、a1、和b1分别代表经染发剂处理的各发束的L*值、a*值、和b*值,L0、a0、和b0分别代表未经染发剂处理的发束的L*值、a*值和b*值。表1和表2的底部,显示了未经染色的发束与经染发剂处理的发束的颜色差值(ΔE1)值,该值代表了染发活性(ΔE)。
<防止皮肤着色效果>
将各种染发即组合物施用于上臂部分,静置30分钟,然后洗去。上臂部分的L值通过分光光度计(型号:CM-508d,生产厂商:Minolta Co.,Ltd.)测量得到。从未使用染发剂组合物的上臂部分的L值和使用染发剂组合物并洗掉后的上胳臂部分的L值,计算得到ΔL*值。如果对上臂部分的染色较弱,ΔL*值接近0,但是如果对上臂部分的染色较强,ΔL*值高于0。相应地,在该评价中,如果ΔL*值等于0或者高于0小于1.5,标记为++;如果ΔL*值等于1.5或者高于1.5小于2.5,标记为+;如果ΔL*值等于2.5或者高于2.5小于3.5,标记为±;如果ΔL*值等于3.5或者高于3.5小于4.5,标记为-;且如果值大于等于4.5,标为--。在表1和表2的底部,显示了皮肤着色的评价结果,一起也显示了染发活性(ΔE)。图1显示了分别施用根据例1(标记为++)、例6(标记为+)、例9(标记为±)、比较例6(标记为-)、和比较例7(标记为--)的染发剂组合物然后洗掉后的上臂部分的照片。
表1
表1(续)
表2
如表1所示,实施例中各染发剂组合物中染发活性(ΔE)均高于45。相似地,对于皮肤着色,ΔL*值小于3.5。这些结果表明,实施例中的染发剂组合物显示了优异的染发活性和防止皮肤着色的作用。
如表2所示,比较例1中的染发剂组合物,其不包含碱剂,其染发活性(ΔE)比所有实施例低。同时,比较例2-4和9中的染发剂组合物,其包含碱剂大于30mmol/100g,其防止皮肤着色的作用比所有实施例低。另外,比较例5中的染发剂组合物,其过氧化氢的质量含量低于0.3%,其染发活性(ΔE)比所有实施例低。比较例6-8中的染发剂组合物,其过氧化氢的质量含量高于1.6%,其防止皮肤着色的作用比所有实施例低。
从图1可明显看出,实施例1、6和9中的染发剂组合物,几乎未在上臂上染色。更特别地,实施例1未发生染色。在实施例6中,也无明显可见的染色。在实施例9中,上臂部分(图中央)有可接受水平的轻微染色。相反地,在比较例6和7中,上胳臂部分(图中央)有明显可见的染色。因此,以分光光度计测量的有关皮肤着色的评价结果在图1中得到了支持。
Claims (5)
1.染发剂组合物,包括:
第一剂,包含氧化染料和碱剂;和
第二剂,包含过氧化氢,该染发剂组合物在所述第一剂和第二剂混合后使用,
所述染发剂组合物特征在于包含抗坏血酸化合物和过氧化氢,质量含量分别为1.0-5.0%和0.3-1.6%,
其中每100g染发剂组合物含有3.0-30mmol碱剂。
2.根据权利要求1所述的染发剂组合物,其特征在于所述的氧化染料含有染料中间体,其中所述染发剂组合物中染料中间体与抗坏血酸化合物的质量比为0.7-1.0。
3.根据权利要求1或者2所述的染发剂组合物,其特征在于所述的染发剂组合物中抗坏血酸化合物的质量含量为1.2-4.5%。
4.根据权利要求1-3中任一项所述的染发剂组合物,其特征在于所述的染发剂组合物的pH为6.5-9.5。
5.根据权利要求1-4中任一项所述的染发剂组合物,其特征为,所述的染发剂组合物中碱剂和抗坏血酸化合物的摩尔比为0.5-2.8。
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US (1) | US7998223B2 (zh) |
JP (1) | JP5685441B2 (zh) |
CN (1) | CN102056587B (zh) |
BR (1) | BRPI0822897B1 (zh) |
GB (1) | GB2471253B (zh) |
WO (1) | WO2010016105A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107440933A (zh) * | 2016-05-25 | 2017-12-08 | 朋友株式会社 | 氧化染发剂组合物 |
CN108852877A (zh) * | 2015-01-22 | 2018-11-23 | 朋友株式会社 | 染发剂组合物以及染发剂组合物的色调稳定化方法 |
Families Citing this family (5)
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EP2476405A1 (en) * | 2011-01-18 | 2012-07-18 | The Procter & Gamble Company | Hair coloring compositions with a non-ammonia alkalizing agent |
JP6376766B2 (ja) * | 2014-02-10 | 2018-08-22 | ホーユー株式会社 | 酸化染毛剤組成物及び染毛方法 |
US10413491B2 (en) | 2014-04-02 | 2019-09-17 | Merz Pharma Gmbh & Co. Kgaa | In vivo accelerated degradation of polysaccharide-containing fillers |
MX2021015622A (es) * | 2019-06-28 | 2022-05-16 | Oreal | Composición cosmética para el teñido oxidativo de fibras de queratina. |
FR3111553A1 (fr) * | 2020-06-22 | 2021-12-24 | L'oreal | Procédé de coloration des fibres kératiniques mettant en œuvre un colorant direct et un sel de saccharinate et composition les comprenant |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1020068C (zh) * | 1988-08-10 | 1993-03-17 | 张德山 | 可使染发、烫发一次完成之染发、烫发剂配方 |
JP4642976B2 (ja) * | 2000-07-14 | 2011-03-02 | ホーユー株式会社 | 酸化染毛剤組成物 |
JP4083701B2 (ja) * | 2004-04-09 | 2008-04-30 | ホーユー株式会社 | 酸化染毛剤組成物 |
JP4083703B2 (ja) * | 2004-04-14 | 2008-04-30 | ホーユー株式会社 | 酸化染毛剤組成物 |
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2008
- 2008-08-04 JP JP2010523664A patent/JP5685441B2/ja active Active
- 2008-08-04 GB GB1018307.7A patent/GB2471253B/en active Active
- 2008-08-04 US US12/993,219 patent/US7998223B2/en active Active
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- 2008-08-04 CN CN2008801297997A patent/CN102056587B/zh active Active
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108852877A (zh) * | 2015-01-22 | 2018-11-23 | 朋友株式会社 | 染发剂组合物以及染发剂组合物的色调稳定化方法 |
CN108852877B (zh) * | 2015-01-22 | 2021-08-17 | 朋友株式会社 | 染发剂组合物以及染发剂组合物的色调稳定化方法 |
CN107440933A (zh) * | 2016-05-25 | 2017-12-08 | 朋友株式会社 | 氧化染发剂组合物 |
CN107440933B (zh) * | 2016-05-25 | 2023-02-17 | 朋友株式会社 | 氧化染发剂组合物 |
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US7998223B2 (en) | 2011-08-16 |
WO2010016105A1 (ja) | 2010-02-11 |
BRPI0822897A2 (pt) | 2018-06-05 |
GB2471253B (en) | 2013-02-20 |
JPWO2010016105A1 (ja) | 2012-01-12 |
CN102056587B (zh) | 2012-08-22 |
GB201018307D0 (en) | 2010-12-15 |
JP5685441B2 (ja) | 2015-03-18 |
BRPI0822897B1 (pt) | 2018-08-28 |
US20110061178A1 (en) | 2011-03-17 |
GB2471253A (en) | 2010-12-22 |
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