CN102010798A - Detergent for washing tableware or vegetables and fruits by hands - Google Patents
Detergent for washing tableware or vegetables and fruits by hands Download PDFInfo
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- CN102010798A CN102010798A CN 201010574177 CN201010574177A CN102010798A CN 102010798 A CN102010798 A CN 102010798A CN 201010574177 CN201010574177 CN 201010574177 CN 201010574177 A CN201010574177 A CN 201010574177A CN 102010798 A CN102010798 A CN 102010798A
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Abstract
The invention relates to a detergent for washing tableware or vegetables and fruits by hands, belonging to the technical field of detergents. The detergent comprises the following components in parts by weight: 3-20 parts of tea saponin crystal, 4-8 parts of sodium alcohol ether sulphate (AES), 1-7 parts of cocoanut fatty acid diethanolamide (6501), 1-3 parts of sulfoacid, 0.1-0.3 part of caustic soda flasks, 1-3 parts of sodium alpha-olefin sulfonate (AOS), 0.1-0.3 part of EDTA-2Na, 0.1-0.4 part of Kathon, 0.2-0.5 part of essence, 1-3 parts of ethanol and 60-80 parts of deionized water. By utilizing the detergent, clingage on the tableware or residual pesticide on the vegetables and fruits can be effectively washed, and fruit wax which is used on the surfaces of the vegetables and fruits for retaining freshness can be removed rapidly; and the detergent is not harmful to human bodies and does not cause pollution to the environment.
Description
Technical field
The invention belongs to the washing composition technical field, be specifically related to the washing composition of a kind of manual dishwashing or vegetable and fruit.
Background technology
The existing washing composition overwhelming majority is synthetic as main raw material by sodium laurylsulfonate, in their product description, all be marked with: " precaution: please be positioned over the place that children do not reach,, please promptly drink a large amount of clear water dilutions and timely the prescription on individual diagnosis as careless mistake drink." in the daily use, during with the detergent washing tableware, need rinsing repeatedly, perhaps chemical substance that also can residual minute quantity is accumulated over a long period, and the people is suffered damage.Equally, because the remains of pesticide in the vegetables, fruit is subjected to paying close attention to widely to health effects always, contain the remains of pesticide vegetables because of eating, fruit causes that the incident of food poisoning also happens occasionally.People also attempt to wash vegetables, fruit with common washing composition, though with common washing composition energy flush away part remains of pesticide, but it is inoperative that vegetables, fruit surface are used for the cured removal of fresh-keeping fruit, and washing composition itself is residual also can have a negative impact to HUMAN HEALTH.In addition, washing, rinsing liquid is discharged to water drain, and biodegradability is poor, also can cause to a certain degree pollution to environment.Therefore, press on the market a kind of can wash dining set, effectively remove fruit-vegetable pesticide residues, again to the harmless multiduty washing composition of HUMAN HEALTH.
In order to address the above problem, state's invention patent publication No. CN 1563313A discloses the natural scavenging agent of a kind of vegetable and fruit remains of pesticide in 12 days January in 2005, is to use tea saponin, and yellow soda ash and sodium bicarbonate are that main raw material is formulated; We can check in and know from the encyclopaedic knowledge handbook, and the yellow soda ash puckery cleans vegetable and fruit and can cause food band astringent taste.Eczema, dermatitis, corn shape ulcer and cutis laxa can take place in the solution that long-time use of yellow soda ash or contact contain yellow soda ash.
Summary of the invention
Based on the problems referred to above, technical problem to be solved by this invention is to provide the washing composition of a kind of manual dishwashing or vegetable and fruit, use the present invention effectively wash dining set grease or removing fruit-vegetable pesticide residues, can also remove vegetables rapidly, that fruit surface is used for fresh-keeping fruit is cured, harmless to HUMAN HEALTH, environment is not polluted.
The washing composition of described a kind of manual dishwashing or vegetable and fruit is characterized in that, is in harmonious proportion by following raw materials by weight percent component and makes: tea saponin crystal 3～20, AES 4～8,65011～7, sulfonic acid 1～3, sheet alkali 0.1～0.3, AOS 1～3, EDTA-2Na 0.1～0.3, and is triumphant loose 0.1～0.4, essence 0.2～0.5, ethanol 1～3, deionized water 60～80; Its manufacturing process is: with deionized water and sheet alkali modulation damping fluid, damping fluid adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, sulfonic acid, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature, add ethanol then and stir, get washing composition; Through packing, after the check, the finished product warehouse-in.
Use when of the present invention, in water, add above-mentioned washing composition number droplet, with tableware or vegetables or fruit soak 2～5 minutes, clean with clear water and get final product again; If drip a little on rag with the present invention, directly clean the surface of tableware or vegetables or fruit, to clean with clear water again, effect is better.
Tea saponin crystal of the present invention is a kind of glycoside compound that extracts from the seed of plant of theaceae, is a kind of of saponin.It is by aglucon (C
30H
50O
6), a kind of pentacyclic triterpene saponin of constituting of sugared body and organic acid basic structure, molecular formula is C
57H
90O
26, molecular weight 1191.28.The solution of tea saponin crystal allotment is a kind of natural nonionic surface active agent, have good emulsifying, dispersion, foaming, wetting isoreactivity effect, be widely used on the production industries such as wool spinning, knitting, daily-use chemical industry, medicine, can be used as emulsifying agent, whipping agent, also can make washing composition, but the present invention is a purpose to clean decontamination mainly.
AES of the present invention, its chemical name is a polyoxyethylenated alcohol sodium sulfate, English name: Sodium Alcohol Ether Sulphate molecular formula: RO (CH
2CH
2O) n-SO
3Na; Performance: soluble in water, have good decontamination, emulsification, foam performance and anti-performance of hard water, gentle washing character can injured skin.Mainly being used in meal in household chemicals field and washing, is exactly common liquid detergent.MSDS (material safety evaluation report) according to AES shows that AES is nontoxic product.Be purpose mainly in the present invention with emulsification, foaming.
Of the present invention 6501 is cocoanut fatty acid diethanolamides, belongs to nonionogenic tenside, does not have cloud point.Proterties be faint yellow to amber thick liquid, soluble in water, have functions such as good foaming, steady bubble, infiltration decontamination, anti-hard water.Belong to nonionogenic tenside, the compatibility thickening effectiveness is obvious especially with it when anion surfactant is acidity, can with kinds of surface promoting agent compatibility.Belong to thickening material in the present invention.
Sulfonic acid of the present invention is a kind of organic acid, general formula R-SO
3H, the R representation hydrocarbyl, strongly-acid has bigger water-solublely, and the general character of acid is arranged.Sulfonic acid plays anti-hard water in the present invention.
AOS of the present invention, another name alpha-olefin sodium sulfonate, AOS has good surfactivity, and in the finite concentration scope, AOS can be with the surface tension of water from 72mN.m
-1Reduce to 30～40mN.m
-1About.The wetting power of AOS and foaminess are good, and resistance to hard water is strong; Its biodegradation rate and ultimate biodegradation degree height can be degraded fully in 5-7 days in physical environment and disappeared, and do not pollute the environment.AOS has good clean effect to sebum dirt and oiliness and powdery dirt.In washing composition of the present invention as active ingredient.
EDTA-2Na of the present invention, chemical name: disodium ethylene diamine tetraacetate, English name: EDTADisodium Salt is white or the oyster white crystallization or the granulated powders of tasteless odorless or little one-tenth.Water-soluble, be insoluble to ethanol, ether.Purposes: make heavy metal detoxification medicine, complexing agent, antioxidant synergist, stablizer and tenderizer etc.In the present invention as the complexing agent component.
Triumphant pine of the present invention, its active part is the isothiazolinone compounds, can effectively suppress and go out except that mushroom and various microorganism.Be widely used in the products such as senior tonic cosmeticses such as shampoo of hair washing and conditioning, body lotion and various skin moisten, protective skin cream, cream, breast, lipstick and Liquid soap, dish detergent, tableware cleaning essence, hair dye, fur clothing lustering agent, softening agent, glue, external-applied ointment, agricultural chemicals.Play the bactericidal effect in the present invention.
Essence of the present invention plays the flavouring effect.
It is cured that ethanol of the present invention plays the dissolving fruit, the disinfectant effect.
The present invention carries out scientific and reasonable combination with mentioned component, the cleaning product of making is to people and animals' nontoxicity, environmentally safe, the clearance rate of the residual organochlorine pesticide of vegetable and fruit being matched red residual quantity can reach 86.1%, clearance rate to residual organophosphorus pesticide chlopyrifos residue amount can reach 93.8%, and has the effect of certain sterilization, complexing heavy metal.
Embodiment
The following stated embodiment describes the present invention in detail.In these embodiments, unless otherwise indicated, all per-cents all are weight percentage.
Embodiment 1
The washing composition of a kind of manual dishwashing or vegetable and fruit is characterized in that, is in harmonious proportion by following material component and makes: the tea saponin crystal 3, and AES 8,6,501 1, sulfonic acid 2, sheet alkali 0.2, AOS 3, and EDTA-2Na 0.2, and is triumphant loose 0.1, essence 0.5, ethanol 2, deionized water 80;
Its manufacturing process is: with deionized water and sheet alkali modulation damping fluid, damping fluid adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, sulfonic acid, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature, add ethanol then and stir, get washing composition; Through packing, after the check, the finished product warehouse-in.
Embodiment 2
The washing composition of a kind of manual dishwashing or vegetable and fruit is characterized in that, is in harmonious proportion by following material component and makes: tea saponin crystal 11, and AES 6,65013, sulfonic acid 3, sheet alkali 0.3, AOS 2, and EDTA-2Na 0.1, and is triumphant loose 0.2, essence 0.4, ethanol 2, deionized water 72;
Its manufacturing process is with embodiment 1.
Embodiment 3
The washing composition of a kind of manual dishwashing or vegetable and fruit is characterized in that, is in harmonious proportion by following material component and makes: tea saponin crystal 9, and AES 4,65017, sulfonic acid 1, sheet alkali 0.1, AOS 1, and EDTA-2Na 0.3, and is triumphant loose 0.4, essence 0.2, ethanol 1, deionized water 76;
Its manufacturing process is with embodiment 1.
Embodiment 4
The washing composition of a kind of manual dishwashing or vegetable and fruit is characterized in that, is in harmonious proportion by following material component and makes: tea saponin crystal 20, and AES 7,65015, sulfonic acid 2, sheet alkali 0.2, AOS 2, and EDTA-2Na 0.2, and is triumphant loose 0.3, essence 0.3, ethanol 3, deionized water 60;
Its manufacturing process is with embodiment 1.
The washing composition removing effect test and the toxicity test of above-mentioned manual dishwashing or vegetable and fruit are as follows:
Spray equably on " Shanghai green grass or young crops " vegetables to match red 1000 times of liquid and 1000 times of liquid of Chlorpyrifos 94 respectively, pluck the dish leaf after 3 days and test.Get above-mentioned dish leaf 500 grams respectively, at 2000 times of liquid of above-mentioned four routine washing composition, certain contrasts in each 2 kilograms in 2000 times of liquid of common cleaning agent and the clear water and soaked 10 minutes, take out with the clear water rinsing totally, dry, survey pesticide residue.Test three times.Testing data and analysis conclusion are as follows:
The washing composition of manual dishwashing or vegetable and fruit is to the elimination effect of the red residual quantity of match in the vegetables
The washing composition of manual dishwashing or vegetable and fruit is to the elimination effect of the dead tick residual quantity of vegetable poisoning
Above-mentioned testing data shows, different embodiment proportionings to match red residual clearance rate with embodiment 4 washing composition soak 10 minutes the highest, reach 86.1%, clear water soaks that can only to remove 33.4% match pellet in 10 minutes residual, contrast common cleaning agent and also have only 51.2%, be starkly lower than the washing composition of manual dishwashing or vegetable and fruit matching red residual clearance rate.Equally, different embodiment proportionings to the clearance rate of chlopyrifos residue with embodiment 4 washing composition soak 10 minutes the highest, 2000 times of liquid of the washing composition of embodiment 4 reach 93.8%.As seen, red and organophosphorus pesticide Chlorpyrifos 94 all has and removes effect preferably the washing composition of manual dishwashing or vegetable and fruit to organochlorine pesticide match.
Carry out the washing composition rabbit eye irritant test of the reaction test of washing composition rabbit acute skin irritation, embodiment 4 manual dishwashings or vegetable and fruit of washing composition rat acute percutaneous toxicity test method toxicity test, embodiment 4 manual dishwashings or vegetable and fruit of washing composition rat acute per os toxicity test, embodiment 4 manual dishwashings or the vegetable and fruit of the manual dishwashing of embodiment 4 or vegetable and fruit by GB7919-87 " safety evaluation of cosmetics program and method ", testing data and to analyze conclusion as follows:
The washing composition rat acute per os toxicity test result of embodiment 4 manual dishwashings or vegetable and fruit
| The rat hero is female | Dosage (mg/kg) | Number of animals (only) | Death toll (only) | LD 50And fiducial limit |
| Male | 5000 | 5 | 0 | ＞5000 |
| Female | 5000 | 5 | 0 | ＞5000 |
The washing composition rat acute percutaneous toxicity test result of embodiment 4 manual dishwashings or vegetable and fruit
| The rat hero is female | Dosage (mg/kg) | Number of animals (only) | Death toll (only) | LD 50And fiducial limit |
| Male | 5000 | 5 | 0 | ＞5000 |
| Female | 5000 | 5 | 0 | ＞5000 |
The washing composition rabbit acute skin irritation reaction test result of embodiment 4 manual dishwashings or vegetable and fruit
The washing composition rabbit eye irritant test result of embodiment 4 manual dishwashings or vegetable and fruit
Above-mentioned testing data is according to the acute toxicity grading criteria evaluation of chemical substance in GB7919-87 safety evaluation of cosmetics and the method, the all true border of female male rat acute per os toxicity of the washing composition of embodiment 4 manual dishwashings or vegetable and fruit is nontoxic, the all true border of female male rat acute percutaneous toxicity of the washing composition of embodiment 4 manual dishwashings or vegetable and fruit is nontoxic, the washing composition of embodiment 4 manual dishwashings or vegetable and fruit belongs to nonirritant to the stimulus intensity of skin, and the washing composition of embodiment 4 manual dishwashings or vegetable and fruit belongs to slight pungency to the stimulus intensity of eye.
Claims (1)
1. the washing composition of manual dishwashing or vegetable and fruit is characterized in that, is in harmonious proportion by following raw materials by weight percent component and makes: tea saponin crystal 3～20, AES 4～8,65011～7, sulfonic acid 1～3, sheet alkali 0.1～0.3, AOS 1～3, EDTA-2Na 0.1～0.3, and is triumphant loose 0.1～0.4, essence 0.2～0.5, ethanol 1～3, deionized water 60～80; Its manufacturing process is: with deionized water and sheet alkali modulation damping fluid, damping fluid adds tea saponin crystal, stirring and dissolving in the time of 80～90 ℃ earlier; Add AES, 6501, sulfonic acid, AOS, EDTA-2Na, Kai Song and essence more successively, restir becomes latex solution; Be cooled to room temperature, add ethanol then and stir, get washing composition; Through packing, after the check, the finished product warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010574177A CN102010798B (en) | 2010-11-27 | 2010-11-27 | Detergent for washing tableware or vegetables and fruits by hands |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010574177A CN102010798B (en) | 2010-11-27 | 2010-11-27 | Detergent for washing tableware or vegetables and fruits by hands |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102010798A true CN102010798A (en) | 2011-04-13 |
| CN102010798B CN102010798B (en) | 2012-09-05 |
Family
ID=43841131
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010574177A Expired - Fee Related CN102010798B (en) | 2010-11-27 | 2010-11-27 | Detergent for washing tableware or vegetables and fruits by hands |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102010798B (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102268334A (en) * | 2011-07-01 | 2011-12-07 | 湖南汉清生物技术有限公司 | Natural plant cleanser essence |
| CN102766542A (en) * | 2012-07-09 | 2012-11-07 | 陈文志 | Detergent containing tea saponin |
| CN103484265A (en) * | 2013-09-26 | 2014-01-01 | 陈理敬 | Green antibacterial efficient cleanser essence and preparation method thereof |
| CN103484264A (en) * | 2013-09-25 | 2014-01-01 | 周元材 | High concentrated paste-shaped detergent |
| CN103642602A (en) * | 2013-12-20 | 2014-03-19 | 黄山市徽山生物科技有限公司 | Liquid detergent |
| CN103725439A (en) * | 2013-12-20 | 2014-04-16 | 黄山市徽山生物科技有限公司 | Preparation method of liquid detergent |
| CN103937621A (en) * | 2014-04-10 | 2014-07-23 | 沈阳化工大学 | Tea saponin-containing pesticide removal detergent and preparation method thereof |
| CN104479916A (en) * | 2014-12-01 | 2015-04-01 | 邬石根 | Palm oil added pesticide scavenging agent and using method thereof |
| CN104531384A (en) * | 2015-01-09 | 2015-04-22 | 湖南新金浩茶油股份有限公司 | Tea saponin anti-bacterial detergent and preparing method thereof |
| CN105132201A (en) * | 2015-10-16 | 2015-12-09 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN105154247A (en) * | 2015-10-16 | 2015-12-16 | 青岛海之星生物科技有限公司 | Rich-foam toilet cleaning block |
| CN105154251A (en) * | 2015-10-16 | 2015-12-16 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN105199865A (en) * | 2015-10-16 | 2015-12-30 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN105861174A (en) * | 2016-04-28 | 2016-08-17 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Glass cleaning agent and preparation method thereof |
| CN106906064A (en) * | 2017-03-16 | 2017-06-30 | 长沙协浩吉生物工程有限公司 | A kind of compound method of ferment dish washing detergent |
| CN107502469A (en) * | 2017-09-13 | 2017-12-22 | 马书文 | A kind of environment protecting tableware fruits and vegetables detergent |
| CN108998291A (en) * | 2018-07-30 | 2018-12-14 | 合肥华盖生物科技有限公司 | A kind of special oily soil cleaning agent for kitchen use and preparation method thereof |
| CN111440673A (en) * | 2020-05-09 | 2020-07-24 | 佛山市南海区旭展洗涤用品厂 | Tea saponin detergent and preparation method thereof |
| CN112442424A (en) * | 2020-12-08 | 2021-03-05 | 苏州安科霖化工环保科技有限公司 | Preparation method of water-soluble cleaning agent |
| CN113621447A (en) * | 2020-10-23 | 2021-11-09 | 湖南汉清生物技术有限公司 | Pollution-free dish washer is with imitateing tea saponin detergent by force and processing equipment thereof |
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| CN1065880A (en) * | 1992-05-05 | 1992-11-04 | 库爱莲 | Safety non-toxic washing powder |
| CN1347975A (en) * | 2001-11-20 | 2002-05-08 | 黄宝生 | Natural detergent |
| CN1563313A (en) * | 2004-04-06 | 2005-01-12 | 中国计量学院 | Natural scavenging agent for removing residual pesticide on vegetable and fruitage |
-
2010
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065880A (en) * | 1992-05-05 | 1992-11-04 | 库爱莲 | Safety non-toxic washing powder |
| CN1347975A (en) * | 2001-11-20 | 2002-05-08 | 黄宝生 | Natural detergent |
| CN1563313A (en) * | 2004-04-06 | 2005-01-12 | 中国计量学院 | Natural scavenging agent for removing residual pesticide on vegetable and fruitage |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102268334A (en) * | 2011-07-01 | 2011-12-07 | 湖南汉清生物技术有限公司 | Natural plant cleanser essence |
| CN102268334B (en) * | 2011-07-01 | 2013-09-25 | 湖南汉清生物技术有限公司 | Natural plant cleanser essence |
| CN102766542A (en) * | 2012-07-09 | 2012-11-07 | 陈文志 | Detergent containing tea saponin |
| CN103484264A (en) * | 2013-09-25 | 2014-01-01 | 周元材 | High concentrated paste-shaped detergent |
| CN103484265A (en) * | 2013-09-26 | 2014-01-01 | 陈理敬 | Green antibacterial efficient cleanser essence and preparation method thereof |
| CN103642602B (en) * | 2013-12-20 | 2015-08-19 | 黄山市徽山生物科技有限公司 | A kind of liquid detergent |
| CN103725439A (en) * | 2013-12-20 | 2014-04-16 | 黄山市徽山生物科技有限公司 | Preparation method of liquid detergent |
| CN103642602A (en) * | 2013-12-20 | 2014-03-19 | 黄山市徽山生物科技有限公司 | Liquid detergent |
| CN103725439B (en) * | 2013-12-20 | 2015-08-19 | 黄山市徽山生物科技有限公司 | A kind of preparation method of liquid detergent |
| CN103937621A (en) * | 2014-04-10 | 2014-07-23 | 沈阳化工大学 | Tea saponin-containing pesticide removal detergent and preparation method thereof |
| CN104479916A (en) * | 2014-12-01 | 2015-04-01 | 邬石根 | Palm oil added pesticide scavenging agent and using method thereof |
| CN104531384A (en) * | 2015-01-09 | 2015-04-22 | 湖南新金浩茶油股份有限公司 | Tea saponin anti-bacterial detergent and preparing method thereof |
| CN105154251A (en) * | 2015-10-16 | 2015-12-16 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN105154247A (en) * | 2015-10-16 | 2015-12-16 | 青岛海之星生物科技有限公司 | Rich-foam toilet cleaning block |
| CN105132201A (en) * | 2015-10-16 | 2015-12-09 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN105199865A (en) * | 2015-10-16 | 2015-12-30 | 青岛海之星生物科技有限公司 | Foam cleaning composition |
| CN105861174A (en) * | 2016-04-28 | 2016-08-17 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Glass cleaning agent and preparation method thereof |
| CN106906064A (en) * | 2017-03-16 | 2017-06-30 | 长沙协浩吉生物工程有限公司 | A kind of compound method of ferment dish washing detergent |
| CN107502469A (en) * | 2017-09-13 | 2017-12-22 | 马书文 | A kind of environment protecting tableware fruits and vegetables detergent |
| CN108998291A (en) * | 2018-07-30 | 2018-12-14 | 合肥华盖生物科技有限公司 | A kind of special oily soil cleaning agent for kitchen use and preparation method thereof |
| CN111440673A (en) * | 2020-05-09 | 2020-07-24 | 佛山市南海区旭展洗涤用品厂 | Tea saponin detergent and preparation method thereof |
| CN113621447A (en) * | 2020-10-23 | 2021-11-09 | 湖南汉清生物技术有限公司 | Pollution-free dish washer is with imitateing tea saponin detergent by force and processing equipment thereof |
| CN112442424A (en) * | 2020-12-08 | 2021-03-05 | 苏州安科霖化工环保科技有限公司 | Preparation method of water-soluble cleaning agent |
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