CN109370793A - One kind removing pesticide residue washing salt and preparation method thereof - Google Patents
One kind removing pesticide residue washing salt and preparation method thereof Download PDFInfo
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- CN109370793A CN109370793A CN201811278674.2A CN201811278674A CN109370793A CN 109370793 A CN109370793 A CN 109370793A CN 201811278674 A CN201811278674 A CN 201811278674A CN 109370793 A CN109370793 A CN 109370793A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses one kind to remove pesticide residue washing salt and preparation method thereof, including following raw material by weight: 40~70 parts of sodium chloride, 5~10 parts of plant type surfactant, alkalization 5~10 parts of Loofah powder, 3~8 parts of water soluble chitosan, 3~8 parts of bio-extract, the bio-extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.The washing salt can effectively remove the pesticide residue on vegetables and fruits surface and not generate secondary pollution, non-hazardous to body using the raw material of plant type；It is environmentally friendly.
Description
Technical field
The present invention relates to a kind of washing salt technical fields more particularly to one kind to go to pesticide residue washing salt and its preparation side
Method belongs to household daily use chemicals detergent technical field.
Background technique
Pesticide is one of the means of production important in agricultural production, is often used a large amount of agricultures in the planting process of fruits and vegetables
Medicine improves its yield, and in terms of reducing the generation of insect-borne infectious disease and parasitic disease, improving yield, pesticide all plays very heavy
The effect wanted.But due to a large amount of uses of pesticide, China's fruit, vegetable pesticide residue excessive problem are increasingly severe.In the market
Some gourd, fruit and vegetables in planting process, due to pesticide it is excessive or plucking time is spaced too close together from spraying time,
There are the substances such as a large amount of pesticide and its metabolin, degradation product and poisonous impurities remaining in their remained on surface, some is even invaded
Enter inside fruits and vegetables, has been not easy to be washed off by clear water.It is soaking and water washing method and washing that family, which commonly removes pesticide residue method, at present
Agent ablution.Although soaking and water washing can dissolve removal water soluble pesticide, removal efficiency is not high, and this method is also not suitable for
In the fat-soluble pesticide for being attached to fruit and vegetable surfaces.Since most of detergent is all chemicals, during impregnating fruits and vegetables
It is possible that can penetrate into inside fruits and vegetables, while the detergent on pericarp is difficult to rinse out completely, residual detergent will cause pericarp
Secondary pollution, same harm health after eating.Saline solution can not only wash removal fruits and vegetables table because of osmotic pressure with higher
The pesticide residue in face can also accelerate to dissolve out the pesticide residue inside fruits and vegetables.Some researches show that fruits and vegetables are cleaned with saline solution, to agriculture
Medicine residue removal has preferable effect, cleans Chinese cabbage with 10% salt water, to chlopyrifos, DDT, cypermethrin and hundred bacterium
The removal rate of the several frequently seen organic agricultural chemicals such as clear up to 60%~70%, the removal rate 40% of common dish washing liquid aqueous solution~
60%, currently, existing much about the research of washing salt, such as Publication No. CN201710678559.3, disclose a kind of fruits and vegetables and wash
Salt and preparation method thereof is washed, the composition of raw materials of the fruits and vegetables washing salt includes 80%~90% salt, 4%~12% surface-active
Agent, 8%~15% builder, 0.1%~1.0% disinfectant, 0.5%~3% bio-extract.Preparation method includes: that will help
Lotion is placed in a mixing machine；Surfactant, disinfectant and lichens extract are added in the mixing machine, then mixed
Uniformly obtain primary mix；By the primary mix in 85 DEG C of dryings, then crushes and obtain sub-mixtures；By described time
Grade mixture is uniformly mixed to get fruits and vegetables washing salt with salt.The method of the present invention have simple production process, no three wastes generate,
The advantage of environmental protection.Although this kind of detergent washing effect gets a promotion, the ingredients such as disinfectant are the introduction of, as cleaning fruits and vegetables
Washing salt, it is unfavorable to human body.
Summary of the invention
Present invention seek to address that in the prior art washing salt there are the problem of, one kind is provided and removes pesticide residue washing salt, should
Washing salt can effectively remove the pesticide residue on vegetables and fruits surface and not generate secondary pollution, using the raw material of plant type, to body without
Harm；It is unfriendly to environment.
For achieving the above object, technical scheme is as follows:
One kind removing pesticide residue washing salt, including following raw material by weight: 40~70 parts of sodium chloride, plant type surface are living
Property 5~10 parts of agent, alkalization 5~10 parts of Loofah powder, 3~8 parts of water soluble chitosan, 3~8 parts of bio-extract, the biology
Extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.
The alkalization Loofah powder is prepared by following methods: luffa is sieved after crushing, by the weight ratio of 1:1:1
Example takes 75 mesh, 100 mesh, and the Loofah powder of 150 mesh impregnates after 24-28 is small in 5 ~ 8 % Na2CO3 solution, is filtered by vacuum, drying
Must alkalize Loofah powder.
The plant type surfactant is selected from spaonin powder or its extract, soapberry fruit peel powder or its extract, soap
Angle powder, Tea Saponin, tea seed powder soybean lecithin, sodium alginate.
The bio-extract is prepared as follows: first by agaric, tealeaves, Chinese prickly ash, cortex cinnamomi mixture at 40-60 DEG C
At a temperature of be dried to moisture content be 80-95%；Using ultramicro grinding, the crushing material after drying to partial size is lower than 25 microns；
By smashed material, add the ethanol solution of 10-20 times of quality, 72-78 DEG C of circumfluence distillation collects extracting solution；Extracting solution is dense
Contracting removes ethyl alcohol, and re-evaporation removes moisture to get bio-extract is arrived.
In Loofah powder soaking process, every 3-5 hours stirring is primary.
The sodium chloride is edible sodium chloride.
A kind of preparation method for removing pesticide residue washing salt, includes the following steps:
It is poly- to weigh 40~70 parts of sodium chloride, 5~10 parts of plant type surfactant, 5~10 parts of Loofah powder of alkalization, water soluble shells
Sugared 3~8 parts, 3~8 parts of bio-extract, it is spare；
(2) deionized water is added in the weighed raw material of step (1), stirs evenly, dries to go pesticide residue washing salt；
The bio-extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.
Beneficial effects of the present invention:
(1) raw material of the invention uses natural component and comestible composition, does not add chemical component, does not generate for fruits and vegetables washing
Secondary pollution is harmful to human health.
(2) present invention using plant type surfactant, alkalization Loofah powder, water soluble chitosan, bio-extract and
Bio-extract is the specific cooperation of mixture these types ingredient of agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract, can play sterilization
Effect is to wash the ingredients such as vegetables and fruits surface bacteria, while the ingredient of guaranteeing the quality as washing salt, washing salt can be prevented rotten or
Pollute harmful substance.
(3) in the present invention, the Loofah powder of alkalization can adsorb the heavy metal substance on fruits and vegetables, share with sodium chloride, effectively
Remove pesticide on fruits and vegetables.
Specific embodiment
The present invention is described in further detail below with reference to embodiment, embodiments of the present invention are not limited thereto.
One kind removing pesticide residue washing salt, including following raw material by weight: 40 parts of sodium chloride, plant type surface are living
Property 5 parts of agent, alkalization 5 parts of Loofah powder, 3 parts of water soluble chitosan, 3 parts of bio-extract, the bio-extract be agaric, tea
Leaf, Chinese prickly ash, cinnamomum cassia extract mixture.
Embodiment 2
One kind removing pesticide residue washing salt, including following raw material by weight: 70 parts of sodium chloride, plant type surfactant
10 parts, alkalization 10 parts of Loofah powder, 8 parts of water soluble chitosan, 8 parts of bio-extract, the bio-extract are agaric, tea
Leaf, Chinese prickly ash, cinnamomum cassia extract mixture.
Embodiment 3
One kind removing pesticide residue washing salt, including following raw material by weight: 50 parts of sodium chloride, plant type surfactant
7 parts, alkalization 7 parts of Loofah powder, 7 parts of water soluble chitosan, 7 parts of bio-extract, the bio-extract be agaric, tealeaves,
The mixture of Chinese prickly ash, cinnamomum cassia extract.
Embodiment 4
One kind removing pesticide residue washing salt, including following raw material by weight: 60 parts of sodium chloride, plant type surfactant
8 parts, alkalization 8 parts of Loofah powder, 88 parts of water soluble chitosan, 6 parts of bio-extract, the bio-extract be agaric, tealeaves,
The mixture of Chinese prickly ash, cinnamomum cassia extract.
Embodiment 5
One kind removing pesticide residue washing salt, including following raw material by weight: 60 parts of sodium chloride, plant type surfactant
8 parts, alkalization 8 parts of Loofah powder, 5 parts of water soluble chitosan, 5 parts of bio-extract, the bio-extract be agaric, tealeaves,
The mixture of Chinese prickly ash, cinnamomum cassia extract.
The alkalization Loofah powder is prepared by following methods: luffa is sieved after crushing, by the weight ratio of 1:1:1
Example takes 75 mesh, 100 mesh, and the Loofah powder of 150 mesh impregnates after 24-28 is small in 5 ~ 8 % Na2CO3 solution, is filtered by vacuum, drying
Must alkalize Loofah powder；In Loofah powder soaking process, every 3-5 hours stirring is primary.
The plant type surfactant is spaonin powder.
The bio-extract is prepared as follows: first by agaric, tealeaves, Chinese prickly ash, cortex cinnamomi mixture at 40-60 DEG C
At a temperature of be dried to moisture content be 95%；Using ultramicro grinding, the crushing material after drying to partial size is lower than 25 microns；It will
Smashed material, adds the ethanol solution of 20 times of quality, and 72-78 DEG C of circumfluence distillation collects extracting solution；Extracting solution concentration removes
Ethyl alcohol, re-evaporation remove moisture to get bio-extract is arrived.
The sodium chloride is edible sodium chloride.
Embodiment 6
A kind of preparation method for removing pesticide residue washing salt, includes the following steps:
(1) 40 parts of sodium chloride, 10 parts of plant type surfactant, 6 parts of Loofah powder of alkalization, 5 parts of water soluble chitosan, life are weighed
It is 5 parts of object extract, spare；
(2) deionized water is added in the weighed raw material of step (1), stirs evenly, dries to go pesticide residue washing salt；
The bio-extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.
Embodiment 7
One kind removing pesticide residue washing salt, including following raw material by weight: 60 parts of sodium chloride, plant type surfactant
8 parts, alkalization 8 parts of Loofah powder, 5 parts of water soluble chitosan, 5 parts of bio-extract, the bio-extract be agaric, tealeaves,
The mixture of Chinese prickly ash, cinnamomum cassia extract.
The alkalization Loofah powder is prepared by following methods: luffa is sieved after crushing, by the weight ratio of 1:1:1
Example takes 75 mesh, 100 mesh, the Loofah powder of 150 mesh impregnate in 5% Na2CO3 solution 28 it is small after, vacuum filtration dries to obtain alkalization silk
Melon network powder.
The plant type surfactant is the mixing of spaonin powder and Tea Saponin.
The bio-extract is prepared as follows: first by agaric, tealeaves, Chinese prickly ash, cortex cinnamomi mixture at 40-60 DEG C
At a temperature of be dried to moisture content be 80%；Using ultramicro grinding, the crushing material after drying to partial size is lower than 25 microns；It will
Smashed material, adds the ethanol solution of 20 times of quality, and 72-78 DEG C of circumfluence distillation collects extracting solution；Extracting solution concentration removes
Ethyl alcohol, re-evaporation remove moisture to get bio-extract is arrived.
Embodiment 8
A kind of preparation method for removing pesticide residue washing salt, includes the following steps:
Weigh 65 parts of sodium chloride, 5 parts of plant type surfactant, 10 parts of Loofah powder of alkalization, 8 parts of water soluble chitosan, biology
It is 5 parts of extract, spare；
(2) deionized water is added in the weighed raw material of step (1), stirs evenly, dries to go pesticide residue washing salt；
The bio-extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.
Embodiment 9
One kind removing pesticide residue washing salt, including following raw material by weight: 70 parts of sodium chloride, plant type surfactant
10 parts, alkalization 10 parts of Loofah powder, 8 parts of water soluble chitosan, 8 parts of bio-extract, the bio-extract are agaric, tea
Leaf, Chinese prickly ash, cinnamomum cassia extract mixture.
The alkalization Loofah powder is prepared by following methods: luffa is sieved after crushing, by the weight ratio of 1:1:1
Example takes 75 mesh, 100 mesh, and the Loofah powder of 150 mesh impregnates after 24-28 is small in 8 % Na2CO3 solution, and vacuum filtration dries to obtain alkali
Change Loofah powder.
The plant type surfactant is tea seed powder soybean lecithin and sodium alginate.
The bio-extract is prepared as follows: first by agaric, tealeaves, Chinese prickly ash, cortex cinnamomi mixture at 40-60 DEG C
At a temperature of be dried to moisture content be 90%；Using ultramicro grinding, the crushing material after drying to partial size is lower than 25 microns；It will
Smashed material, adds the ethanol solution of 15 times of quality, and 72-78 DEG C of circumfluence distillation collects extracting solution；Extracting solution concentration removes
Ethyl alcohol, re-evaporation remove moisture to get bio-extract is arrived.
The above is only presently preferred embodiments of the present invention, not does limitation in any form to the present invention, it is all according to
According to technical spirit any simple modification to the above embodiments of the invention, equivalent variations, protection of the invention is each fallen within
Within the scope of.
Claims (7)
1. one kind removes pesticide residue washing salt, it is characterised in that: including following raw material by weight: sodium chloride 40~70
Part, 5~10 parts of plant type surfactant, alkalization 5~10 parts of Loofah powder, 3~8 parts of water soluble chitosan, bio-extract 3
~8 parts, the bio-extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.
2. one kind according to claim 1 removes pesticide residue washing salt, it is characterised in that: the alkalization Loofah powder passes through
Following methods preparation: luffa is sieved after crushing, and takes 75 mesh, 100 mesh, the luffa of 150 mesh by the weight ratio of 1:1:1
After 24-28 is small in powder 5 ~ 8 % Na2CO3 solution of immersion, vacuum filtration dries to obtain alkalization Loofah powder.
3. one kind according to claim 1 removes pesticide residue washing salt, it is characterised in that: the plant type surfactant
Selected from spaonin powder or its extract, soapberry fruit peel powder or its extract, spaonin powder, Tea Saponin, tea seed powder soybean lecithin,
Sodium alginate.
4. one kind according to claim 1 removes pesticide residue washing salt, it is characterised in that: the bio-extract is by following
Method preparation: the mixture of agaric, tealeaves, Chinese prickly ash, cortex cinnamomi is first dried to moisture content at a temperature of 40-60 DEG C as 80-
95%；Using ultramicro grinding, the crushing material after drying to partial size is lower than 25 microns；By smashed material, add 10-20 times
The ethanol solution of quality, 72-78 DEG C of circumfluence distillation collect extracting solution；Extracting solution concentration removes ethyl alcohol, and re-evaporation removes water
Divide to get bio-extract is arrived.
5. one kind according to claim 1 removes pesticide residue washing salt, it is characterised in that: in Loofah powder soaking process,
Every 3-5 hours stirring is primary.
6. one kind according to claim 1 removes pesticide residue washing salt, it is characterised in that: the sodium chloride is edible chlorination
Sodium.
7. a kind of preparation method for removing pesticide residue washing salt, it is characterised in that: (1) weigh 40~70 parts of sodium chloride, plant type
5~10 parts of surfactant, alkalization 5~10 parts of Loofah powder, 3~8 parts of water soluble chitosan, 3~8 parts of bio-extract；
(2) deionized water is added in the weighed raw material of step (1), stirs evenly, dries to go pesticide residue washing salt；
The bio-extract be agaric, tealeaves, Chinese prickly ash, cinnamomum cassia extract mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811278674.2A CN109370793A (en) | 2018-10-30 | 2018-10-30 | One kind removing pesticide residue washing salt and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811278674.2A CN109370793A (en) | 2018-10-30 | 2018-10-30 | One kind removing pesticide residue washing salt and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109370793A true CN109370793A (en) | 2019-02-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811278674.2A Pending CN109370793A (en) | 2018-10-30 | 2018-10-30 | One kind removing pesticide residue washing salt and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093217A (en) * | 2019-06-10 | 2019-08-06 | 中原工学院 | A kind of high-activity bio-enzyme washes the dishes salt and preparation method thereof |
| CN110093216A (en) * | 2019-06-10 | 2019-08-06 | 中原工学院 | Low bubble environment friendly dishwashing salt of one kind and preparation method thereof |
| CN110157553A (en) * | 2019-06-10 | 2019-08-23 | 中原工学院 | A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof |
| CN110157552A (en) * | 2019-06-10 | 2019-08-23 | 中原工学院 | A kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267310A (en) * | 2017-06-16 | 2017-10-20 | 中原工学院 | A kind of green natural compounded efficient fruits and vegetables washing salt of plant type |
| CN107287050A (en) * | 2017-08-10 | 2017-10-24 | 合肥世雅达生物医药有限公司 | A kind of fruits and vegetables washing salt and preparation method thereof |
-
2018
- 2018-10-30 CN CN201811278674.2A patent/CN109370793A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107267310A (en) * | 2017-06-16 | 2017-10-20 | 中原工学院 | A kind of green natural compounded efficient fruits and vegetables washing salt of plant type |
| CN107287050A (en) * | 2017-08-10 | 2017-10-24 | 合肥世雅达生物医药有限公司 | A kind of fruits and vegetables washing salt and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110093217A (en) * | 2019-06-10 | 2019-08-06 | 中原工学院 | A kind of high-activity bio-enzyme washes the dishes salt and preparation method thereof |
| CN110093216A (en) * | 2019-06-10 | 2019-08-06 | 中原工学院 | Low bubble environment friendly dishwashing salt of one kind and preparation method thereof |
| CN110157553A (en) * | 2019-06-10 | 2019-08-23 | 中原工学院 | A kind of high-strength hard water adaptive type washes the dishes salt and preparation method thereof |
| CN110157552A (en) * | 2019-06-10 | 2019-08-23 | 中原工学院 | A kind of high-effective cleansing of natural green washes the dishes salt and preparation method thereof |
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Application publication date: 20190222 |
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