CN101970550A - 聚合物碳纳米管复合材料 - Google Patents
聚合物碳纳米管复合材料 Download PDFInfo
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- CN101970550A CN101970550A CN2008801231928A CN200880123192A CN101970550A CN 101970550 A CN101970550 A CN 101970550A CN 2008801231928 A CN2008801231928 A CN 2008801231928A CN 200880123192 A CN200880123192 A CN 200880123192A CN 101970550 A CN101970550 A CN 101970550A
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- Prior art keywords
- carbon nanotube
- solvent
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- cnt
- functionalized
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 253
- 229920000642 polymer Polymers 0.000 title claims abstract description 84
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 250
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 250
- 238000000034 method Methods 0.000 claims abstract description 171
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 139
- 239000000178 monomer Substances 0.000 claims abstract description 53
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229920001577 copolymer Polymers 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims description 101
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 94
- 239000000203 mixture Substances 0.000 claims description 44
- 239000000126 substance Substances 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 38
- 150000002148 esters Chemical class 0.000 claims description 37
- 239000007789 gas Substances 0.000 claims description 35
- 239000006185 dispersion Substances 0.000 claims description 32
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 30
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 25
- 239000012298 atmosphere Substances 0.000 claims description 23
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 22
- WURFKUQACINBSI-UHFFFAOYSA-M ozonide Chemical compound [O]O[O-] WURFKUQACINBSI-UHFFFAOYSA-M 0.000 claims description 20
- 239000011159 matrix material Substances 0.000 claims description 19
- 239000000010 aprotic solvent Substances 0.000 claims description 16
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical group ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 239000003999 initiator Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000012190 activator Substances 0.000 claims description 12
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical group [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 11
- 150000008065 acid anhydrides Chemical class 0.000 claims description 9
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- 239000002253 acid Substances 0.000 claims description 7
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 7
- 239000011790 ferrous sulphate Substances 0.000 claims description 7
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 7
- 230000003213 activating effect Effects 0.000 claims description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- 230000006315 carbonylation Effects 0.000 claims description 6
- 238000005810 carbonylation reaction Methods 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 5
- 239000003054 catalyst Substances 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 4
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical group [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
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- 239000002071 nanotube Substances 0.000 description 19
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- 125000000524 functional group Chemical group 0.000 description 12
- 239000012071 phase Substances 0.000 description 12
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- -1 carbon nano tube compound Chemical class 0.000 description 10
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 9
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- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 8
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- 238000010907 mechanical stirring Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
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- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 6
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229960001701 chloroform Drugs 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 150000002978 peroxides Chemical group 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
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- 230000000977 initiatory effect Effects 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 125000001340 2-chloroethyl group Chemical class [H]C([H])(Cl)C([H])([H])* 0.000 description 4
- ORTCGSWQDZPULK-UHFFFAOYSA-N 3-isocyanatopropyl prop-2-enoate Chemical compound C=CC(=O)OCCCN=C=O ORTCGSWQDZPULK-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 241001044369 Amphion Species 0.000 description 4
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- OANCNKPXGDDPQS-UHFFFAOYSA-N [C].C=CC1=CC=CC=C1 Chemical compound [C].C=CC1=CC=CC=C1 OANCNKPXGDDPQS-UHFFFAOYSA-N 0.000 description 4
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 4
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 230000000386 athletic effect Effects 0.000 description 3
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- 230000008859 change Effects 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
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- 238000010526 radical polymerization reaction Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
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- 238000001149 thermolysis Methods 0.000 description 3
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- ORMSTDJYMPIZAO-UHFFFAOYSA-N 1,1,2-trichloro-2-fluoroethane Chemical class FC(Cl)C(Cl)Cl ORMSTDJYMPIZAO-UHFFFAOYSA-N 0.000 description 2
- ZVEMLYIXBCTVOF-UHFFFAOYSA-N 1-(2-isocyanatopropan-2-yl)-3-prop-1-en-2-ylbenzene Chemical class CC(=C)C1=CC=CC(C(C)(C)N=C=O)=C1 ZVEMLYIXBCTVOF-UHFFFAOYSA-N 0.000 description 2
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
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- 238000001914 filtration Methods 0.000 description 2
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- MHAJPDPJQMAIIY-UHFFFAOYSA-M hydroperoxide group Chemical group [O-]O MHAJPDPJQMAIIY-UHFFFAOYSA-M 0.000 description 2
- 150000001261 hydroxy acids Chemical group 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
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- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
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- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 2
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- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
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- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
- C01B32/174—Derivatisation; Solubilisation; Dispersion in solvents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/28—Solid content in solvents
Abstract
Description
Claims (27)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07301580 | 2007-11-23 | ||
EP07301580A EP2062853A1 (en) | 2007-11-23 | 2007-11-23 | Polymer carbon nanotube composites |
PCT/CA2008/002052 WO2009065225A1 (en) | 2007-11-23 | 2008-11-21 | Polymer carbon nanotube composites |
Publications (2)
Publication Number | Publication Date |
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CN101970550A true CN101970550A (zh) | 2011-02-09 |
CN101970550B CN101970550B (zh) | 2012-12-26 |
Family
ID=39433841
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2008801231928A Expired - Fee Related CN101970550B (zh) | 2007-11-23 | 2008-11-21 | 聚合物碳纳米管复合材料 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8444950B2 (zh) |
EP (2) | EP2062853A1 (zh) |
JP (1) | JP5703026B2 (zh) |
CN (1) | CN101970550B (zh) |
CA (1) | CA2706390C (zh) |
WO (1) | WO2009065225A1 (zh) |
Cited By (3)
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CN108219539A (zh) * | 2016-12-12 | 2018-06-29 | Oci有限公司 | 炭黑制备装置及其制备方法 |
CN109193012A (zh) * | 2018-08-13 | 2019-01-11 | 浙江润涞科技服务有限公司 | 一种用于氢燃料电池的复合质子交换膜及其制备方法 |
CN113382958A (zh) * | 2018-11-14 | 2021-09-10 | 定向碳公司 | 用于碳纳米管纯化的方法 |
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GB0812320D0 (en) * | 2008-07-04 | 2008-08-13 | Imp Innovations Ltd | Activation |
JP5328043B2 (ja) * | 2009-12-21 | 2013-10-30 | 日機装株式会社 | ポリマーグラフトカーボンナノチューブ、及びその製造方法 |
JP5607407B2 (ja) * | 2010-03-31 | 2014-10-15 | 株式会社アドマテックス | 有機−無機複合粒子及び塗料組成物、並びにそれらの製造方法 |
TWI419920B (zh) * | 2010-07-09 | 2013-12-21 | Hon Hai Prec Ind Co Ltd | 奈米碳管複合結構之製備方法 |
TWI419919B (zh) * | 2010-07-09 | 2013-12-21 | Hon Hai Prec Ind Co Ltd | 奈米碳管複合結構之製備方法 |
ES2372856B1 (es) * | 2010-07-12 | 2012-12-05 | Consejo Superior De Investigaciones Científicas (Csic) | Procedimiento de obtencion de materiales nanocompuestos de polimeros clorados y nanoestructuras de carbono |
US8816007B2 (en) * | 2010-07-28 | 2014-08-26 | Fpinnovations | Phenol-formaldehyde polymer with carbon nanotubes, a method of producing same, and products derived therefrom |
JP6006623B2 (ja) * | 2012-11-20 | 2016-10-12 | 大陽日酸株式会社 | 酸化処理方法 |
SG11201506453QA (en) * | 2013-02-20 | 2015-09-29 | Tesla Nanocoatings Inc | Functionalized graphitic materials |
US9688538B2 (en) * | 2014-02-05 | 2017-06-27 | University Of Houston System | Graft polymerization initiated on graphitic nanomaterials and their nanocomposite formation |
KR101785172B1 (ko) | 2015-12-23 | 2017-10-17 | 고려대학교 산학협력단 | 이온성 블록 공중합체, 카본나노튜브 담지체, 카본나노튜브-그래핀산화물 복합체 및 금속 촉매 |
KR102178358B1 (ko) * | 2016-12-14 | 2020-11-12 | 주식회사 엘지화학 | 기능화된 그래핀의 제조 방법 |
CN109971004B (zh) * | 2017-12-27 | 2021-08-24 | 大连融科储能技术发展有限公司 | 一种全氟磺酸离子交换膜及其制备方法和应用 |
TW202035282A (zh) * | 2018-11-28 | 2020-10-01 | 日商昭和電工股份有限公司 | 含碳簇之組成物、及其製造方法 |
CN113668234B (zh) * | 2021-08-10 | 2023-02-10 | 瑞安市博安防刺穿材料科技有限公司 | 一种碳纳米管接枝聚氨酯改性芳纶防刺纤维合成方法及应用 |
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US5635581A (en) * | 1994-11-28 | 1997-06-03 | National Science Counsel | Fullerene polymers |
US6203814B1 (en) | 1994-12-08 | 2001-03-20 | Hyperion Catalysis International, Inc. | Method of making functionalized nanotubes |
CA2379667C (en) * | 1999-07-21 | 2008-12-09 | Hyperion Catalysis International, Inc. | Methods of oxidizing multiwalled carbon nanotubes |
US7250147B2 (en) | 2001-01-29 | 2007-07-31 | Tour James M | Process for derivatizing carbon nanotubes with diazonium species |
CA2465032A1 (en) | 2001-10-29 | 2003-05-08 | Hyperion Catalysis International, Inc. | Polymer containing functionalized carbon nanotubes |
KR100947702B1 (ko) | 2003-02-26 | 2010-03-16 | 삼성전자주식회사 | 경화성 작용기로 표면수식된 탄소나노튜브를 이용한패턴박막 형성방법 및 고분자 복합체의 제조방법 |
EP2368932B1 (en) | 2003-06-16 | 2014-01-15 | William Marsh Rice University | Fabrication of carbon nanotube reinforced polymer composites |
US7879940B2 (en) | 2003-06-20 | 2011-02-01 | William Marsh Rice University | Polymerization initated at sidewalls of carbon nanotubes |
US7122165B2 (en) * | 2003-11-03 | 2006-10-17 | The Research Foundation Of State University Of New York | Sidewall-functionalized carbon nanotubes, and methods for making the same |
US7247670B2 (en) * | 2004-08-24 | 2007-07-24 | General Electric Company | Nanotubes and methods of dispersing and separating nanotubes |
WO2006135439A2 (en) * | 2004-10-22 | 2006-12-21 | Hyperion Catalysis International, Inc. | Improved ozonolysis of carbon nanotubes |
WO2007050096A2 (en) * | 2004-11-23 | 2007-05-03 | William Marsh Rice University | Ozonation of carbon nanotubes in fluorocarbons |
KR100689866B1 (ko) * | 2005-10-12 | 2007-03-09 | 인하대학교 산학협력단 | 비닐계 고분자가 그래프팅된 탄소나노튜브의 제조방법 및그 전구체 |
FR2893947A1 (fr) * | 2005-11-30 | 2007-06-01 | Arkema Sa | Composition pulverulente de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres. |
FR2898139B1 (fr) * | 2006-03-06 | 2008-05-30 | Nanoledge Sa | Procede de fabrication de produits extrudes composites polymeres et nanotubes de carbone |
CN101531822A (zh) * | 2009-01-06 | 2009-09-16 | 华东理工大学 | 一种聚合物碳纳米管复合结构及其制备方法 |
-
2007
- 2007-11-23 EP EP07301580A patent/EP2062853A1/en not_active Withdrawn
-
2008
- 2008-11-21 CA CA2706390A patent/CA2706390C/en not_active Expired - Fee Related
- 2008-11-21 JP JP2010534330A patent/JP5703026B2/ja not_active Expired - Fee Related
- 2008-11-21 CN CN2008801231928A patent/CN101970550B/zh not_active Expired - Fee Related
- 2008-11-21 US US12/743,782 patent/US8444950B2/en not_active Expired - Fee Related
- 2008-11-21 EP EP08851390.8A patent/EP2227501A4/en not_active Withdrawn
- 2008-11-21 WO PCT/CA2008/002052 patent/WO2009065225A1/en active Application Filing
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108219539A (zh) * | 2016-12-12 | 2018-06-29 | Oci有限公司 | 炭黑制备装置及其制备方法 |
CN109193012A (zh) * | 2018-08-13 | 2019-01-11 | 浙江润涞科技服务有限公司 | 一种用于氢燃料电池的复合质子交换膜及其制备方法 |
CN113382958A (zh) * | 2018-11-14 | 2021-09-10 | 定向碳公司 | 用于碳纳米管纯化的方法 |
CN113382958B (zh) * | 2018-11-14 | 2024-04-09 | 定向碳公司 | 用于碳纳米管纯化的方法 |
Also Published As
Publication number | Publication date |
---|---|
EP2227501A4 (en) | 2016-06-08 |
CA2706390C (en) | 2013-05-07 |
US8444950B2 (en) | 2013-05-21 |
EP2062853A1 (en) | 2009-05-27 |
JP2011505313A (ja) | 2011-02-24 |
WO2009065225A1 (en) | 2009-05-28 |
JP5703026B2 (ja) | 2015-04-15 |
CN101970550B (zh) | 2012-12-26 |
CA2706390A1 (en) | 2009-05-28 |
US20110046316A1 (en) | 2011-02-24 |
EP2227501A1 (en) | 2010-09-15 |
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