CN101954274B - 降低卷烟烟气中苯酚类物质的含糖共聚物复合材料及制备 - Google Patents
降低卷烟烟气中苯酚类物质的含糖共聚物复合材料及制备 Download PDFInfo
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- CN101954274B CN101954274B CN2010102783417A CN201010278341A CN101954274B CN 101954274 B CN101954274 B CN 101954274B CN 2010102783417 A CN2010102783417 A CN 2010102783417A CN 201010278341 A CN201010278341 A CN 201010278341A CN 101954274 B CN101954274 B CN 101954274B
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IT1404015B1 (it) * | 2011-02-04 | 2013-11-08 | Hsd Holding Smart Device S R L | Uso di un polimero di destrano reticolato come filtro contro l'inalazione di sostanze nocive per la salute |
CN102090716A (zh) * | 2011-03-03 | 2011-06-15 | 中国海洋大学 | 新型脱镉过滤嘴 |
CN104720104B (zh) * | 2015-02-11 | 2018-01-30 | 浙江中烟工业有限责任公司 | 一种选择性降低卷烟烟气中巴豆醛的滤嘴添加剂及其制备方法和应用 |
CN104720105B (zh) * | 2015-02-11 | 2018-01-30 | 浙江中烟工业有限责任公司 | 一种选择性降低卷烟烟气中醛类物质的复合材料及其制备方法和应用 |
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CN113115980B (zh) * | 2021-04-01 | 2023-06-30 | 中国烟草总公司郑州烟草研究院 | 一种降低废气中苯酚含量的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3987802A (en) * | 1975-03-05 | 1976-10-26 | The University Of Delaware | Chitin as an extender and filter for tobacco |
US5664586A (en) * | 1993-01-19 | 1997-09-09 | Rothmans International Services Limited | Tobacco smoke filters and filter rods therefor |
CN2485971Y (zh) * | 2001-06-11 | 2002-04-17 | 邰增玉 | 三元复合过滤嘴 |
CN101171981A (zh) * | 2007-10-26 | 2008-05-07 | 梅建华 | 二元复合卷烟过滤嘴棒 |
-
2010
- 2010-09-10 CN CN2010102783417A patent/CN101954274B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3987802A (en) * | 1975-03-05 | 1976-10-26 | The University Of Delaware | Chitin as an extender and filter for tobacco |
US5664586A (en) * | 1993-01-19 | 1997-09-09 | Rothmans International Services Limited | Tobacco smoke filters and filter rods therefor |
CN2485971Y (zh) * | 2001-06-11 | 2002-04-17 | 邰增玉 | 三元复合过滤嘴 |
CN101171981A (zh) * | 2007-10-26 | 2008-05-07 | 梅建华 | 二元复合卷烟过滤嘴棒 |
Non-Patent Citations (2)
Title |
---|
谢山岭等.壳聚糖-分子筛复合物选择性吸附卷烟烟气中挥发性羰基化合物的应用研究.《化工技术与开发》.2009,第38卷(第11期),第15-18页. * |
邱晔等.烟用活性炭及其改性处理对卷烟主流烟气的影响.《昆明理工大学学报(理工版)》.2006,第31卷(第5期),第82-86页. * |
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