CN101765574A - 使卤化氢可逆性俘获与释放相结合的区域反应器 - Google Patents

使卤化氢可逆性俘获与释放相结合的区域反应器 Download PDF

Info

Publication number
CN101765574A
CN101765574A CN200880017028A CN200880017028A CN101765574A CN 101765574 A CN101765574 A CN 101765574A CN 200880017028 A CN200880017028 A CN 200880017028A CN 200880017028 A CN200880017028 A CN 200880017028A CN 101765574 A CN101765574 A CN 101765574A
Authority
CN
China
Prior art keywords
district
reactor
partially halogenated
carbon
coupling catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN200880017028A
Other languages
English (en)
Inventor
迈克尔·J.·韦斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GRT Inc
Original Assignee
GRT Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GRT Inc filed Critical GRT Inc
Publication of CN101765574A publication Critical patent/CN101765574A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C07C1/30—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms by splitting-off the elements of hydrogen halide from a single molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0438—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed next to each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0403—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal
    • B01J8/0423—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds
    • B01J8/0442—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the fluid flow within the beds being predominantly horizontal through two or more otherwise shaped beds the beds being placed in separate reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0492—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/12—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by gravity in a downward flow
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/093—Hydrogen bromide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/13—Iodine; Hydrogen iodide
    • C01B7/135—Hydrogen iodide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C01B7/191—Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
    • C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00761—Discharging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11

Abstract

提供使烃原料转化成较高级烃类的改进方法和区域反应器。该反应器中的第一区含有能够释放卤化氢(HX)的材料和碳-碳偶联催化剂；第二区最初是空的或含有卤化和/或卤氧化催化剂；而第三区含有碳-碳偶联催化剂和能够俘获HX的材料。将空气和氧引入第一区，将原料引入第二区，并且在第三区产生产物。在反应过程中所生产的HX在区1和区3进行可逆的俘获和释放。

Description

使卤化氢可逆性俘获与释放相结合的区域反应器
技术领域
本发明涉及将烃原料转化成较高级烃的一种方法和装置。
背景技术
美国专利号6,525,230披露了将烷类转化成醇类和/或醚类的一种方法，以及由一个空心的、非隔离而内部限定了第一区、第二区和第三区的区域反应器。在其第一实施方案中，空气或氧与金属溴化物在第一区中反应以提供溴；溴与一种或多种烷在第二区中反应以形成烷基溴化物；并且这些烷基溴化物与金属氧化物在第三区反应以形成相应的产物。来自第三区的金属溴化物通过容器输送到第一区，而来自第一区的金属氧化物再循环至第三区。其第二实施方案与该第一实施方案的区别在于金属氧化物通过容器从第一区输送到第三区，而金属溴化物从第三区再循环至第一区。其第三实施方案中，经过容器的气流被逆转以将金属氧化物转化回金属溴化物并且将金属溴化物转化回金属氧化物。
发明内容
本发明提供了将烃原料转化成一种或多种较高级烃类的改进的区域反应器和一种生产方法。在一个实施方案中，一个改进的区域反应器包括具有第一区、第二区、以及第三区的容器，其中该第一区含有能够释放卤化氢(HX)的材料和碳-碳偶联催化剂；该第二区最初是空的(但不是大气环境)或含有卤化和/或卤氧化催化剂；而该第三区含有碳-碳偶联催化剂和能够俘获HX的材料。气体可以分别流过第一区、第二区、和第三区。优选地，在第一区、第二区和第三区各自配置一个气体进口和/或出口，包括在第二区中用于引入气态烃原料的一个进口。
在本发明的另一个方面，一种将烃原料转化成较高级烃的改进方法包括，在空气或氧存在下，通过加热能够释放HX的材料以形成HX；根据需要，可将碳-碳偶联催化剂除焦；使烃原料与HX在空气或氧的存在下反应以形成烷基卤化物；使这些烷基卤化物在碳-碳偶联催化剂的存在下反应以形成较高级烃和HX(以及并不希望生成的焦炭)；并且通过使HX与能够俘获HX的材料反应以俘获HX。优选将该方法重复多次，其中HX可交替释放和俘获，而偶联催化剂的结焦和除焦也交替进行。在一个实施方案中，HX是通过将部分卤化的烯烃或聚烯烃脱卤化氢而释放，并且通过使烯烃或聚烯烃加卤化氢而将其俘获。
附图说明
当结合附图理解时，本发明以上这些方面和其他方面及其特征将变得更加清晰，其中：
图1是根据本发明的一个实施方案的区域反应器的示意图。
图2是根据本发明的另一个实施方案的改进区域反应器的第二区示意图。
具体实施方式
本发明提供将烃原料转化成一种或多种有用的产物，即“较高级的烃”的方法和改进的区域反应器。总体上，该方法包括通过在空气或氧中加热能够释放HX的材料，以形成卤化氢的第一气流或第一分量；通过使烃原料与该HX的第一气流在空气或氧中反应以形成烷基卤化物；通过使这些烷基卤化物在第二碳-碳偶联催化剂的存在下反应以形成较高级的烃和卤化物的第二气流或第二分量；并且通过使HX的第二气流与能够俘获HX的材料反应以俘获该HX的第二气流。
在图1A和1B中示意性地描述了改进的区域反应器的一个实施方案的操作模式和总体特征。以总体上空心的容器的形式存在的区域反应器10，包括第一区1，该第一区1进一步细分成两个亚区1A和1B；第二区2；以及第三区3，该第三区3进一步细分成亚区3A和亚区3B。
如以下所描述的，最初，区1A含有能够释放HX的材料。区1B含有碳-碳偶联催化剂，该催化剂催化碳-碳键形成以及较高级烃的生成。虽然并不受理论束缚，但是相信碳-碳键形成是经由烷基卤化物分子的分子间的、以及可能甚至是分子内的复分解反应而进行。如以下所描述的，在图中，在区1B中的催化剂已被焦炭覆盖和/或浸渍。但当反应器为它的初始运转进行装填时，并不存在焦炭。区2或者是空的或者含有一种卤化和/或卤氧化催化剂或催化反应剂。区3B也含有碳-碳偶联催化剂，而区3A含有能够俘获HX的材料。
在反应器的左端的第一开口或进口4使空气或氧进入容器。反应器中间的第二开口或进口5可以使气态的烃原料加入，而在容器的右端的第三开口或进口6使产品可以排出。此外，各个区和亚区在允许气流进入相邻的区的边界7处相遇。在一个实施方案中，容器内部无隔断，并且相连的区和亚区彼此没有物理分隔。在一个实施方案中，相连的区和亚区是通过筛网，或通过壁或其他分隔件而分离，该分隔件具有置于其中的至少一个敞口从而允许气体从一个区或亚区流到下一个区或亚区。各种加热器和/或冷却器(没有示出)直接地或间接地热偶连于容器，从而使得每个区和亚区的温度控制变得容易。
如图1A所示，最初，反应器从左到右运行，空气或氧通过气体进口4进入区1A，使得其中所含的原料释放气态的HX。加热的空气或氧以及来自区1A的HX进入区1B并且与碳-碳偶联催化剂接触。空气或氧与先前积存在催化剂之中或之上的任何焦炭反应并且将它转化成CO2。在过量的空气或氧的存在下，所形成的任何CO也将转化为CO2。
在区2中，气态的烃原料经过第二气体进口5进入容器，并且使其在空气或氧以及优选的一种卤化和/或卤氧化催化剂或催化反应剂的存在下与HX反应。这导致了一种或多种烷基卤化物(RX)和蒸气的形成，这些卤化物和蒸气连同存在的任何HX一起被带到了区3B。那里，这些烷基卤化物在碳-碳偶联催化剂的存在下反应而转化成较高级烃和HX。该反应还可能(实际一般都会)导致焦炭的形成，其中焦炭颗粒作为涂层沉积在碳-碳偶联催化剂上和/或沉积在催化剂的间隙中。所形成的HX然后与能够俘获它的材料在区3A中反应。气态烃产物、CO2、残留的空气(或它的贫氧成分)、以及可能的其他种类通过第三口6带出反应器容器，并且可以收集、分离并且纯化、进一步反应、和/或以一些其他的方式进行处理。
图1B表示准备用于从右到左的逆向运行的区域反应器。反应器10仍然含有区1-3和亚区1A、1B、3B和3A，但现在，当在空气或氧中加热时，区3A中的材料是能够释放HX的(即当反应器正向运行时它们已经被氢卤化)。相似地，区3B中的催化剂现在是被焦炭包覆和/或浸渍的，而区1B中的催化剂具有少许焦炭或无焦炭(理想状态)。区1A中的材料是准备与HX反应的，并且由此俘获而储存HX。空气或氧通过区3A中的第三入口6进入，并且使其中所含的材料释放HX，其中HX连同空气或氧一起流入区3B。空气或氧气氧化已经沉积在碳-碳偶联催化剂上的焦炭。使HX和空气或氧顺流到达区2，在那里，它们与烃原料反应以形成烷基卤化物和蒸气，烷基卤化物和蒸气进入区1B。这些烷基卤化物在碳-碳偶联催化剂的存在下在区1B中反应，并且形成烃产物、HX、以及焦炭，焦炭沉积在催化剂之上和/或之中。HX、CO2、空气或它们的成分、蒸气、以及可能的其他气体然后进入区1A，并且HX与其中所含的材料反应并且被它俘获。产品和残留的气体通过第一口4离开。反应器按正向再次准备运行。通过正向和逆向之间循环，反应器可以连续地运行。
在另一个实施方案中，气态反应物流一直保持在相同的方向，并且反应区是稳定的。然而，固体是连续再生的。由于耗尽了在区1A中所含的卤化物，固体从那个区以恒定的速率排出，并且输送到区3A。相似地，完全再生的固体不断地从区3A排出并且输送回区1A。在区1A与3A之间的固体输送通过重力、气动输送、和其他机械方式(例如传送机)、或这些方法的组合而变得便捷。以相似的方式，在区1B中再生的碳-碳偶联催化剂不断地排出并且输送到区3B，并且将焦化的碳-碳偶联催化剂从区3B输送到1B用于再生。偶联催化剂的输送通过重力、气动输送、其他机械方式、或这些方法的组合而变得容易。
如在这里和权利要求里所用的，关于一种化合物、催化剂或其他材料的单数或复数，并不旨在将该物质限制在具体的分子量数或质量数，也不旨在限制物质的具体的不同类型数，除非另外指出。例如，“较高级的烃”可以包括占优势的一种化合物，或确切存在的一种化合物(例如大量的异辛烷)，或者可以是两种或多种不同的化合物(例如，丁烷、苯、丙烯等)。相似地，“烯烃类”是指占大多数的单一烯烃，或者可以是两种或多种不同的烯烃；“沸石类”是指占大多数的一种沸石，或者可以是多种不同的沸石等。
很多烃原料都可考虑用于本发明的实践。非限制性实例包括一种或多种轻质烷类和/或烯烃类，例如，甲烷、乙烷、丙烷、丁烷、乙烯、丙烯、丁烯；天然气；以及烃类的其他混合物。在大多数实施方案中，原料将在性质上基本是脂肪类的。某些炼油厂加工生产的轻质烃流(称作“轻尾气”，典型地是C1-C3的烃混合物)，它们可以在添加或不添加甲烷的情况下使用。总之，原料是作为一种气体而加入反应器的。
区域反应器的产品-一种或多种“较高级烃”-将取决于原料、碳-碳偶联催化剂、以及反应器条件，例如气体流速(它影响反应器停留时间)、温度、和压力。在此所用的术语“较高级烃”是指具有较高碳数目(每个分子中有较多碳原子数)的烃，和/或与烃原料的一种或多种成分相比有较高键级的烃。例如，如果原料是纯甲烷(碳数目1，键级1)，最终生产的较高级烃可能是乙烷、丙烷、乙烯、丙烯、更高级的烷类和烯烃类、还可能是炔类、和/或芳香族化合物。如果原料是纯乙烷(碳数1；键级1)，所得的较高级烃可能是丙烷(碳数3；键级1)、乙烯(碳数2，键级2)等。如果原料是天然气-典型的轻质烃类，其中有占优势的甲烷、与较少量的乙烷、丙烷和丁烷，以及甚至少量的更长的烃，例如戊烷、己烷等的混合物，生成的较高级烃可能包括一种或多种C2或更高的烷类，例如乙烷、丙烷、丁烷、C5+烃类、以及其他轻质挥发油；烯烃类，例如乙烯、丙烯、丁烯等；和/或芳香族烃类。
某些类型的较高级烃类是特别期望的，包括“汽油范围”的烃类，例如C4-C12的烷类、更优选C5-C10的烷类，有或没有烯属的和/或芳香族的成分。具有高芳香族含量而苯含量较低的C5+烷类作为汽油或汽油掺合剂是特别可取的。其他所希望的产物包括芳香族化合物-苯、甲苯、二甲苯(尤其是对二甲苯)、均三甲苯等-以及尤其是苯含量低的芳香族化合物。在一个实施方案中，产物主要包括苯、或富苯的芳香族化合物。在另一个实施方案中，产物主要包括甲苯、或富甲苯的芳香族化合物。在一个实施方案中，产物的芳香族含量通过将非芳香的成分再循环至固体反应器而富集。在饱和的脂肪族化合物的情况下，这要求再溴化作用，接着在一种偶联催化剂的存在下进行碳-碳偶联，而在此处所描述的偶联催化剂的存在下烯属化合物可以直接偶联。
有代表性的卤化氢(HX)包括溴化氢(HBr)和氯化氢(HCl)。还考虑到可以使用氟化氢(HF)和碘化氢(HI)，但不一定有等效的结果。与使用氟相关联的一些问题可以通过使用HF的稀释流(例如用氦气、氮气或其他稀释剂携带HF气体)而可能得到解决。然而，可以预期，由于氟-碳键的强度大，烷基氟化物将需要更强的反应条件实现偶联并形成较高级烃。相似地，与HI相关联的问题(例如某些碘反应的吸热性质)可以通过在较高级温度和/或压力下进行卤化和/或偶联反应而可能得到解决。优选使用HBr或HCl，HBr是最优选的。
许多材料能够可逆地俘获和释放HX，并且特别是HCl和HBr。作为第一实例，这类材料包括中长链的烯烃类，即每个分子具有10-100、优选15-80、更优选20-50个碳原子的烯烃类。总体上，这类烯烃每个分子将具有一个以上的碳-碳双键。非限制性的特定的实例包括1-十二烯、1，12-十二碳二烯、以及1-二十烷。不饱和烯烃经过与HX的加成反应以形成部分卤化的烯烃或烷烃，并且由此“反应性地俘获”HX。当加热该材料时，它们会释放HX并且复原至烯烃。
作为第二实例，不饱和的有机聚合物可以俘获HX以形成部分卤化的有机聚合物，这些有机聚合物然后可以释放HX。非限制性实例包括聚乙炔、经部分脱氢的聚乙烯、经部分脱氢的聚丙烯、以及它们的混合物。聚乙烯和聚丙烯可以根据本领域的普通技术人员所熟知的方法，例如通过卤化反应接着再脱卤化氢而脱氢。聚丁二烯是可以用于俘获并且然后释放HX的不饱和有机聚合物的另一个实例。
烯烃和不饱和有机聚合物通过与HX反应来俘获HX以形成部分卤化的化合物。在空气或氧存在下，通过加热这些材料该反应可以逆向进行。以下反应式是该基本方案的非限制性实例：
Figure G2008800170289D00061
在一个实施方案中，不饱和材料携载于载体上，例如硅石、钛，或耐热的、无机的、总体上惰性的类似材料。作为一个实例，将硅石球粒与聚乙烯混合，将混合物加热到聚乙烯的玻璃化转变温度，这样聚乙烯便包覆在硅石粒料上，然后将卤素加到这些球粒中并且使该组合物暴露于紫外光下，由此该聚合物发生卤化反应。
在区2中，烷基卤化物是通过使烃原料与HX和O2反应(卤氧化反应)，和/或通过使烷基卤化物与X2反应(卤化反应)而形成的。UV光和/或热可以推进该反应。在一个优选的实施方案中，该反应是在一种卤化和/或卤氧化催化剂或催化反应剂的存在下发生的。非限制性实例包括金属氧化物类，例如氧化铜(CuO)，和金属卤化物类，例如CuCl2、CuBr2等。可以使用多种催化剂的混合物。催化的材料可以是加载的或不加载的。
在图1中，催化剂遍布整个区2。在图2所示的另一个实施方案中，卤化和/或卤氧化催化剂是限制在区2的下游和上游区域8的，留下一个空的中心区域9。
在区1B和区3B中，碳-碳偶联催化剂用于使烷基卤化物转化成较高级烃类变得容易。在此所用的术语“碳-碳偶联催化剂”是指能够催化碳-碳键形成的一种材料，可包括“真正的”催化剂，据推测这种催化剂是在机械学的水平上参与到反应中的，其在过程中不被消耗；也包括“催化反应剂”，所述催化反应剂在反应过程中会被化学转化，但它们可以经由再生反应回复到它们的原始形式。例如，在碳-碳偶联反应过程中，其催化反应剂中的氧原子便由卤原子代替了，但在随后的再生步骤中它又被再生(即卤素再被氧取代)，例如通过将空气或氧经过该已发生转化的催化反应剂材料而使其再生。碳-碳偶联催化剂还可以称作“低聚反应”催化剂，或简称为“偶联催化剂”。
偶联催化剂的非限制性实例包括非结晶的铝硅酸盐类(无定形的固体酸)、钨/氧化锆超酸、硫酸化的锆、磷酸铝类例如SAPO-34以及其骨架取代的类似物(例如用Ni或Mn取代)、沸石，例如ZSM-5和其离子交换的类似物，以及骨架取代的ZSM-5(用Ti、Fe、Ti+Fe、B或Ga取代)，以及其他微孔矿石。催化剂可以是天然的或合成的、掺杂的或未掺杂的、负载的或非负载的。
用于生产室温液态烃类的优选催化剂包括其所含SiO2/A12O3比例小于300∶1、优选小于100∶1、最优选为30∶1或更小的离子交换的ZSM-5。优选的交换离子的非限制性实例包括Ag、Ba、Bi、Ca、Fe、Li、Mg、Sr、K、Na、Rb、Mn、Co、Ni、Cu、Ru、Pb、Pd、Pt和Ce的离子。这些离子可以作为纯盐或作为盐的混合物而交换。掺杂的沸石的制备以及它们作为碳-碳偶联催化剂的用途，在专利公开号2005/0171393 A1中的4-5页描述过，该专利通过引用它的全文结合于本文中。
沸石可从各种来源获取，包括Zeolyst International(Valley Forge，PA)。具体实例包括掺杂的ZSM-5和掺杂的丝光沸石(其中，例如钙和/或镁是掺杂剂)。在本发明的一个实施方案中，使用其SiO2/Al2O3之比为30的Mn交换的ZSM-5作为偶联催化剂。在一定工艺条件下，用它可以生产选择性预先设定的液体烃产物。
产品分布可以通过改变沸石或其他催化剂的特性向有利于形成更多的芳香族含量、或较少的芳香族含量、汽油等级材料方面变换。可预期孔径大小和酸度对反应很重要。酸度可以用于控制产品的链长度和官能度，而孔径大小可以控制链长度和官能度。具有特定孔径的沸石可以选择性地生产苯、甲苯、对二甲苯、邻二甲苯、间二甲苯、混合的二甲苯、乙苯、苯乙烯、直链的烷基苯、和/或其他芳香族产物。也可以预期孔径大小会影响非芳香族产物的形成。
在本发明的不同的方面，空气和氧是用于完成所希望的结果，例如，除焦、卤氧化、HX释放、催化反应剂再生等。本文中的术语“空气或氧”，可理解为包括大量基于氧的或含氧的气流的任何一种。非限制性实例包括普通的空气、纯的氧气(O2)、含有较小量的其他气态成分的氧气、在载气(例如氦)中稀释的氧气流、富氧的空气等。
为了使HX俘获或释放、催化剂除焦、卤化和/或卤氧化、以及形成产物的不同步骤变得容易，反应器中的不同的区是在合适的压力和温度下运行的，同时考虑了原料、催化剂、气体流速、以及所希望的产物。在一个实施方案中，反应器是在(或稍微大于)大气压力下运行的。将区1A或3A加热到从0到500℃、优选100到400℃、更优选200到300℃的温度从而使HX释放变得容易。将区3A或区1A加热到稍微较低的温度，例如0到400℃、优选100到300℃、更优选150到250℃，从而使HX俘获变得容易。偶联催化剂的除焦是通过将区1B或3B加热到较高级温度，例如约500℃而变得容易。烃原料的卤化和/或卤氧化发生在区2，将该区加热到150到600℃、优选400到600℃、更优选450到515℃的温度。产物形成(碳-碳偶联)是通过将区3B或1B加热到150到600℃、优选275到425℃的温度而变得容易。有很多可替代的实施方案来实施本发明。例如，代替限定三个区的单一容器，区域反应器可以包括三个分离的容器，各自限定一个分离的区，1、2、或3。作为另一个实例，某些反应器的设计提供了改进热传递的可能性。因此，反应器可以配置为一系列的小管(内径小于6英寸，优从2到4英寸)。作为一个第三实例，代替串联构型，这些管可以并联安排，并且附在一个较大的容器内，合适的热传递流体在其中循环。此外，可以有空气或另一种惰性气体定向越过这些管束表面，从而使冷却和/或加热变得容易。
在一些应用中，其中从区2排除的物料必须在进入产品形成(复分解)区(区1B或3B)之前进行冷却，则可以使用预冷器。在一个实施方案中，预冷器包括空气冷却的管束或附在一个壳内的多个管子，该壳内有合适的热传递流体在这些管周围循环。使用预冷器可以减少复分解区中所需的反应器容量。在复分解过程中除热的要求可以很强地影响反应器的设计。
另一个替代方案是在反应器自身内部使用惰性的热载体。例如，可以加入过量的烷原料以分散热，由此使反应器形成填充床构型而不是管-壳布局。使用内部的热载体可以使反应器绝热地运行。也可以使用容易从反应产物流中分离出来的惰性流作为此构型中的热载体。绝热填充床方案预期可以显著地降低反应器成本。
在本发明的另一个实施方案中，区域反应器与用ZSM-5沸石或能使汽油范围的烃类生成变得容易的其他材料填充的后反应器床联合使用的。例如，区域反应器可以用于形成轻质烯烃，这些烯烃然后进料到沸石床，从而使轻质烯烃偶联成汽油范围内的烃类变得容易。
很多构建材料可以用于增加区域反应器的寿命。非限制性实例包括哈司特镍基合金、富铝和富铬的金属合金，钛、锆、钽和镍金属以及它们的合金，包覆的硅石、氧化铝、以及氧化锆的金属，以及传导热的陶瓷材料例如碳化硅。反应器容器还可以由绝缘的、抗腐蚀的材料构成，例如铝、硅石、和锆，或各自有抗腐蚀的内衬。但不一定用耐温的材料，例如聚四氟乙烯。在一些条件下，容器可以等温地运行，其中由热转移流体提供加热和/或冷却，而这些热转移流体，由以上列出的不同类型的热传导材料制成的管路来输送。此外，反应器也可以绝热地运行。
实施例
以下是本发明的非限制性实施例。
能够释放并俘获HBr的材料的制备
试剂A和B
高表面积(＞300m2/g)硅石粒料，通过混合粒料和聚乙烯并将其加热到高于聚乙烯的玻璃化转变温度的温度而使聚乙烯包覆粒料。将溴加入粒料并且将组合物暴露与UV光下，导致聚合物的溴化作用。将材料的一半进行分离并且加热到225℃，从而释放HBr，由此形成能够俘获HBr的材料，即试剂A。材料的另一半，即试剂B，用作能够释放HBr的材料。
试剂C和D
一种吸附剂的形成。高表面积(＞300m2/g)硅石粒料通过混合粒料和聚乙烯，并且将其加热到高于聚乙烯的玻璃化转变温度的温度而使聚乙烯包覆粒料。将氯加入粒料并且将组合物暴露于UV光下，导致聚合物的氯化作用。将材料的一半进行分离并且加热到225℃，从而释放HCl。材料的另一半不作处理，用作含HCl的吸附剂。
实施例1
如图1所示的区域反应器是用以下材料装填的：
区1A：试剂B。
区1B：ZSM-5偶联催化剂。
区2：氧化铜催化剂。
区3B：ZSM-5偶联催化剂。
区3A：试剂A。
在步骤1中，空气在225℃的温度下经过区1A，试剂B转化成试剂A，并且释放HBr。来自区1A的空气和HBr在500℃的温度下首先进入区1B(在随后的运行中，这将再生(除焦)偶联催化剂)，并且然后进入区2，天然气在这里在400℃被溴氧化。区2的产物在400℃经过区3B中的偶联催化剂，生产较高级烃和HBr。在区3A中，HBr是在150℃的温度下用试剂A俘获的(试剂A转化为试剂B)。
在步骤2中，空气在225℃的温度下经过区3A，试剂B转化成试剂A，并且释放HBr。来自区3A的空气和HBr在500℃的温度下进入3B，再生(除焦)偶联催化剂。在区2中，天然气在400℃被溴氧化。区2的产物在400℃经过区1B的偶联催化剂，生产较高级烃和HBr。在区A中，HBr是在150℃的温度下用试剂A俘获的(试剂A转化为试剂B)。
实施例2
实施例1的烃产物在350到450℃的温度经过ZSM-5催化剂，从而改变产物的平均分子量。
实施例3
按照实施例1的程序，但使用氧化钨和氧化锆的混合物(WZA)代替ZSM-5，作为碳-碳偶联催化剂。
实施例4
实施例3的烃产物在350到450℃的温度经过ZSM-5催化剂，从而改变产物的平均分子量。
实例5
如图1所示的区域反应器是用以下材料装填的：
区1A：试剂D。
区1B：ZSM-5偶联催化剂。
区2：氧化铜催化剂。
区3B：ZSM-5偶联催化剂。
区3A：试剂C。
在步骤1中，空气在225℃的温度下经过区1A，试剂D转化成试剂C，并且释放HCl。来自区A的空气和HCl在500℃的温度下进入区1B(在随后的运行中，这将再生(除焦)偶联催化剂)，并且然后进入区2，天然气在这里在400℃被氯氧化。区2的产物在400℃经过区3B中的偶联催化剂，生产较高级烃和HCl。在区3A中，HCl是在150℃的温度下用试剂C俘获的(试剂C转化为试剂D)。
在步骤2中，空气在225℃的温度下经过区3A，试剂D转化成试剂C，并且释放HCl。来自区3A的空气和HCl在500℃的温度下进入区3B，再生(除焦)偶联催化剂。在区2中，天然气在400℃被溴氧化。区2的产物在400℃经过区1B中的偶联催化剂，生产较高级烃和HCl。在区1A中，HCl是在150℃的温度下用试剂C俘获的(试剂C转化为试剂D)。
实例6
实例5的烃产物在350到450℃的温度下经过ZSM-5催化剂，从而改变产物的平均分子量。
实例7
按照实例5的程序，但使用氧化钨和氧化锆的混合物(WZA)代替ZSM-5，作为碳-碳偶联催化剂。
实例8
实例7的烃产物在350到450℃的温度下经过ZSM-5催化剂，从而改变产物的平均分子量。
本发明已经参考不同的实施方案、图、以及实例进行描述，但并非限制于此。本领域的普通技术人员将理解的是，本发明可以按多种方式进行更改而不脱离本发明，本发明仅由附属的权利要求书以及它的等效物来限定。

Claims (43)

1.一种用于将烃原料转化成一种或多种产物的反应器，它包括：
该反应器中有限定多个区的一个或多个空心的容器，其中，第一区含有能够释放卤化氢的材料和偶联催化剂；第二区与该第一区相连，而第三区与该第二区相连并且含有碳-碳偶联催化剂以及一种能够俘获卤化氢的材料。
2.如权利要求1所述的反应器，其中，该反应器包括一个单一的容器，并且第一区位于该容器的第一端，第二区位于该容器的中间，而第三区位于该容器的第二端，其中，气体可以从第一区流到第二区再从第二区流到第三区。
3.如权利要求1所述的反应器，其中，第一区位于第一容器中，第二区位于第二容器中，而第三区位于第三容器中，其中，气体可以从第一区流到第二区，再从第二区流到第三区。
4.如权利要求1所述的反应器，其中，能够释放卤化氢的材料位于第一区的第一亚区中；第一区中的碳-碳偶联催化剂位于第一区的第二亚区中；第三区中的偶联催化剂位于第三区的第一亚区中；而能够释放卤化氢的材料位于第三区的第二亚区中。
5.如权利要求1所述的反应器，其中，该能够释放卤化氢的材料包括部分卤化的烯烃类。
6.如权利要求5所述的反应器，其中，这些部分卤化的烯烃每个分子具有10-100个碳原子。
7.如权利要求5所述的反应器，其中，这些部分卤化的烯烃每个分子具有15-80个碳原子。
8.如权利要求5所述的反应器，其中，这些部分卤化的烯烃每个分子具有20-50个碳原子。
9.如权利要求5所述的反应器，其中，这些部分卤化的烯烃包括部分卤化的1-十二烯、1，12-十二碳二烯、和/或1-二十烷。
10.如权利要求5所述的反应器，其中，所述能够后释放卤化氢的材料包括部分卤化的有机聚合物类。
11.如权利要求10所述的反应器，其中，这些有机聚合物选自部分卤化的聚乙炔、经部分脱氢的和部分卤化的聚乙烯、经部分脱氢的和部分卤化的聚丙烯、以及它们的混合物。
12.如权利要求10所述的反应器，其中，所述部分卤化的有机聚合物包括部分卤化的聚丁二烯。
13.如权利要求1所述的反应器，其中，该能够俘获卤化氢的材料包括每个分子具有10-100个碳原子的烯烃类。
14.如权利要求13所述的反应器，其中，这些烯烃每个分子具有15-80个碳原子。
15.如权利要求13所述的反应器，其中，这些烯烃每个分子具有20-50个碳原子。
16.如权利要求1所述的反应器，其中，该能够俘获卤化氢的材料包括不饱和有机聚合物类。
17.如权利要求16所述的反应器，其中，这些不饱和有机聚合物选自聚乙炔、经部分脱氢的聚乙烯、经部分脱氢的聚丙烯、以及它们的混合物。
18.如权利要求16所述的反应器，其中，所述不饱和有机聚合物包括聚丁二烯。
19.如权利要求1所述的反应器，其中，该第二区含有卤化和/或卤氧化催化剂。
20.如权利要求1所述的反应器，其中，该卤化和/或卤氧化催化剂包括氧化铜。
21.如权利要求1所述的反应器，其中，该卤化和/或卤氧化催化剂包括卤化铜。
22.如权利要求1所述的反应器，其中，该卤化铜包括溴化铜或氯化铜。
23.如权利要求1所述的反应器，其中，该偶联催化剂包括微孔材料。
24.如权利要求23所述的反应器，其中，该微孔材料包括加载型或非加载型沸石类。
25.如权利要求24所述的反应器，其中，所述沸石包括掺杂型沸石类。
26.如权利要求24所述的反应器，其中，所述沸石包括ZSM-5型沸石类。
27.如权利要求1所述的反应器，其中，所有三个区都位于单一的空心容器内部，并且相邻的区通过其中具有至少一个开口的分隔件而分离。
28.如权利要求1所述的反应器，其中，该分隔件包括筛网。
29.一种用于将烃原料转化成较高级烃类的反应器，它包括：
具有第一区、第二区、和第三区的空心容器，其中，第一区含有部分卤化的烯烃和/或部分卤化的不饱和的有机聚合物以及ZSM-5沸石；第二区与第一区相连，并且含有金属氧化物；而第三区与第二区相连，并且含有微孔偶联催化剂和中-长链烯烃和/或不饱和有机聚合物。
30.如权利要求29所述的反应器，其中，所述金属氧化物包括氧化铜。
31.如权利要求29所述的反应器，其中，该微孔偶联催化剂包括ZSM-5沸石。
32.如权利要求29所述的反应器，其中，所述部分卤化的烯烃和/或部分卤化的不饱和有机聚合物位于第一区的第一亚区中；所述ZSM-5沸石位于第一区的第二亚区中；所述微孔偶联催化剂位于第三区的第一亚区中；并且所述中-长链烯烃和/或不饱和有机聚合物位于第三区的第二亚区中。
33.将烃原料转化成较高级烃类的方法，它包括：
加热在空气或氧中能够释放HX的材料形成卤化氢的第一气流；
使烃原料与该HX的第一气流在空气或氧中反应形成烷基卤化物；
使这些烷基卤化物在第二碳-碳偶联催化剂的存在下反应形成较高级烃类以及HX的第二气流；并且
使HX的第二气流与能够俘获HX的材料反应来俘获该HX的第二气流。
34.如权利要求33所述的方法，进一步包括使该第一偶联催化剂和该第二偶联催化剂除焦。
35.如权利要求33所述的方法，其中，该能够释放HX的材料包括部分卤化的烯烃类。
36.如权利要求33所述的方法，其中，所述烯烃每分子具有10-100个碳原子。
37.如权利要求33所述的方法，其中，该能够释放HX的材料包括部分卤化的有机聚合物。
38.如权利要求33所述的方法，其中，所述部分卤化的有机聚合物选自部分卤化的聚乙炔、聚丁二烯、经部分脱氢和部分卤化的聚乙烯、经部分脱氢和部分卤化的聚丙烯以及它们的混合物。
39.如权利要求33所述的方法，其中，该能够俘获HX的材料包括每分子具有10-100个碳原子的烯烃。
40.如权利要求33所述的方法，其中，该能够俘获HX的材料包括不饱和有机聚合物。
41.根据权利要求40所述的方法，其中，所述有机聚合物选自聚乙炔、聚丁二烯、经部分脱氢的聚乙烯、经部分脱氢的聚丙烯、以及它们的混合物。
42.将烃原料转化成较高级烃类的方法，它包括：
(a)在空气或氧中加热能够释放HX的材料形成卤化氢以及一种能够俘获HX的材料；
(b)使烃原料与步骤(a)中形成的HX在空气或氧中反应形成烷基卤化物；
(c)使所述烷基卤化物在偶联催化剂的存在下反应形成较高级烃类以及附加的HX；并且
(d)用能够俘获HX的材料反应性地俘获步骤(e)中形成的HX而形成能够释放HX的材料。
43.如权利要求42所述的方法，进一步包括该偶联催化剂的结焦和除焦步骤。
CN200880017028A 2007-05-24 2008-05-27 使卤化氢可逆性俘获与释放相结合的区域反应器 Pending CN101765574A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US93189107P 2007-05-24 2007-05-24
US60/931,891 2007-05-24
PCT/US2008/064922 WO2008148113A1 (en) 2007-05-24 2008-05-27 Zone reactor incorporating reversible hydrogen halide capture and release

Publications (1)

Publication Number Publication Date
CN101765574A true CN101765574A (zh) 2010-06-30

Family

ID=40075553

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200880017028A Pending CN101765574A (zh) 2007-05-24 2008-05-27 使卤化氢可逆性俘获与释放相结合的区域反应器

Country Status (17)

Country Link
US (2) US7998438B2 (zh)
EP (1) EP2148846A1 (zh)
JP (1) JP2010528054A (zh)
KR (1) KR20100027141A (zh)
CN (1) CN101765574A (zh)
AP (1) AP2010005097A0 (zh)
AU (1) AU2008256606A1 (zh)
CA (1) CA2687589A1 (zh)
CO (1) CO6251310A2 (zh)
EA (1) EA017699B1 (zh)
EC (1) ECSP099748A (zh)
MX (1) MX2009012581A (zh)
NO (1) NO20093359L (zh)
NZ (1) NZ581216A (zh)
TN (1) TN2009000485A1 (zh)
WO (1) WO2008148113A1 (zh)
ZA (1) ZA200908155B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113767064A (zh) * 2019-04-16 2021-12-07 霍尼韦尔国际公司 用于由氢气和碘制造碘化氢的整合方法和催化剂
US11884607B2 (en) 2018-08-24 2024-01-30 Honeywell International Inc. Processes for producing trifluoroiodomethane and trifluoroacetyl iodide

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
CA2532367C (en) 2003-07-15 2013-04-23 Grt, Inc. Hydrocarbon synthesis
US20060229228A1 (en) * 2005-04-11 2006-10-12 Zachary John Anthony Komon Method of making alkoxylates
EP2457887A1 (en) 2006-02-03 2012-05-30 GRT, Inc. Continuous process for converting natural gas to liquid hydrocarbons
KR20100027141A (ko) 2007-05-24 2010-03-10 지알티, 인코포레이티드 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기
AU2009270801B2 (en) 2008-07-18 2014-04-24 Reaction 35, Llc Continuous process for converting natural gas to liquid hydrocarbons
CN102516434B (zh) * 2011-12-14 2013-08-14 武汉理工大学 一种炔基化聚丁二烯的制备方法
CA2833822C (en) 2013-11-21 2020-08-04 Nova Chemicals Corporation Inherently safe odh operation
US10642957B1 (en) 2014-10-21 2020-05-05 Mckesson Corporation Systems and methods for determining, collecting, and configuring patient intervention screening information from a pharmacy
WO2017131862A1 (en) 2016-01-29 2017-08-03 Exxonmobil Chemical Patents Inc. Process for converting alkanes to para-xylene
US20190210875A1 (en) * 2016-05-12 2019-07-11 Covestro Deutschland Ag Photocatalytic oxidation of hydrogen chloride with oxygen
US11608449B2 (en) * 2018-02-22 2023-03-21 Texstars, Llc Water shedding finish
US11920089B1 (en) * 2023-05-11 2024-03-05 Chevron Phillips Chemical Company Lp Solid oxide and chemically-treated solid oxide catalysts for the pyrolysis of polyethylene

Family Cites Families (732)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172915A (en) * 1965-03-09 Preparation of oxygenated methane derivatives
GB156122A (en) 1919-12-08 1922-03-30 Otto Traun S Forschungslaborat Process for the manufacture of diolefines and derivatives thereof
GB294100A (en) 1927-07-16 1929-06-27 Curt Epner Improvements in and relating to the production of liquid polymerisation products from gases containing hydrocarbons
GB363009A (en) 1930-09-19 1931-12-17 John Philip Baxter Production of acetylene and vinyl chloride from ethylene dichloride
FR745544A (zh) 1931-11-11 1933-05-12
DE698778C (de) 1934-11-11 1941-07-10 I G Farbenindustrie Akt Ges Verfahren zur Herstellung von organischen Monochlor- oder Monobromverbindungen
GB474922A (en) 1936-05-14 1937-11-15 Ig Farbenindustrie Ag Process for chlorinating and brominating hydrocarbons
US2246082A (en) 1939-08-22 1941-06-17 Shell Dev Preparation of alkyl halides
GB536491A (en) 1939-09-28 1941-05-16 Bataafsche Petroleum A process for the production of aromatic hydrocarbons from unsaturated hydrocarbons
GB553950A (en) 1941-09-09 1943-06-11 Du Pont Improvements in or relating to the manufacture of halogenated hydrocarbons
GB586483A (en) 1944-07-05 1947-03-20 Standard Oil Dev Co Process for the conversion of normally gaseous olefins to liquid hydrocarbons
US2488083A (en) 1946-06-18 1949-11-15 Socony Vacuum Oil Co Inc Manufacture of liquid hydrocarbons
US2677598A (en) 1953-01-19 1954-05-04 Dow Chemical Co Oxidation of ferrous halides to form ferric halides
GB775590A (en) 1953-11-27 1957-05-29 Standard Oil Co Improvements in or relating to production of ethyl toluenes
US2941014A (en) 1954-08-06 1960-06-14 Hoechst Ag Manufacture of alkyl chlorination products
GB793214A (en) 1955-02-18 1958-04-09 Bataafsche Petroleum Process for the conversion of hydrocarbons containing acyclic carbon atoms
GB796085A (en) 1955-12-22 1958-06-04 Bataafsche Petroleum Hydrocarbon conversion process
GB796048A (en) 1956-02-06 1958-06-04 Bataafsche Petroleum Conversion of hydrocarbons
DE1037137B (de) * 1957-01-25 1958-08-21 Bayer Ag Verfahren zur Herstellung halogenhaltiger, aromatisch-aliphatischer Polyaether
GB883256A (en) 1958-05-02 1961-11-29 Columbia Southern Chem Corp Halogenation process
US3562321A (en) * 1961-10-10 1971-02-09 Sun Oil Co Preparation of oxygenated hydrocarbons
GB950976A (en) 1961-10-13 1964-03-04 British Hydrocarbon Chem Ltd Improvements in and relating to the production of olefines
BE623466A (zh) 1961-10-13
GB991303A (en) 1962-07-26 1965-05-05 British Hydrocarbon Chem Ltd The production of olefines by the dehydrochlorination of alkyl chlorides
US3294846A (en) 1962-10-10 1966-12-27 Dow Chemical Co Process for preparing metaaryloxy phenols
US3246043A (en) * 1962-12-12 1966-04-12 Universal Oil Prod Co Preparation of olefinic hydrocarbons
GB1015033A (en) 1963-01-31 1965-12-31 Shell Int Research Preparation of olefin oxides
US4011278A (en) * 1963-02-27 1977-03-08 Mobil Oil Corporation Conversion of polar compounds using a zsm-5 zeolite catalyst
NL125428C (zh) 1963-02-27
US3273964A (en) 1963-02-28 1966-09-20 Universal Oil Prod Co Process for producing bromine from a mixture of hydrogen bromide and olefinic hydrocarbon
GB1104294A (en) 1963-12-10 1968-02-21 Ralph William King Production of lower alkanols and lower alkyl bromides
US3310380A (en) * 1964-02-13 1967-03-21 Universal Oil Prod Co Bromine recovery
US3923913A (en) 1964-05-12 1975-12-02 Pechiney Saint Gobain Process for obtaining chlorinated derivatives of ethylene
US3353919A (en) 1964-07-23 1967-11-21 Air Preheater Apparatus for the elimination of odors from noxious gases
BE672377A (zh) 1964-11-24 1966-05-16
US3353916A (en) 1966-04-25 1967-11-21 Universal Oil Prod Co Quantitative recovery of bromine by two stage catalytic oxidation of hydrogen bromide
DE1618686B1 (de) 1966-04-28 1971-08-26 Marathon Oil Co Tieftemperatur-Verfahren für die Chlorierung oder Bromierung von Kohlenwasserstoffen
US3346340A (en) 1966-08-11 1967-10-10 Universal Oil Prod Co Production of bromine by oxidation of hydrogen bromide
DE1807780B2 (de) 1968-11-08 1976-11-04 Henkel & Cie GmbH, 4000 Düsseldorf Verfahren zur herstellung von aether- und polyaetheralkoholen
DE1618254B1 (de) 1967-06-29 1971-07-08 Kalk Chemische Fabrik Gmbh Verfahren zur Herstellung von Bromverbindungen aus Alkoholen aus Brom
US3496242A (en) * 1967-08-30 1970-02-17 Fmc Corp Oxychlorination of mixed hydrocarbons
US3598876A (en) 1967-11-13 1971-08-10 Universal Oil Prod Co Selective halogenation of hydrocarbons
US3879480A (en) * 1967-12-07 1975-04-22 Lummus Co Vinyl chloride process
US3679758A (en) 1968-02-05 1972-07-25 Sun Oil Co Dihalogenation of branched alkanes
GB1253618A (en) 1968-03-28 1971-11-17 Perstorp Ab Process for the production of dry semi-formals
CA920775A (en) 1968-05-13 1973-02-13 Vadekar Mohan Oxidation of hydrogen chloride using molecular sieve catalysts
US3673264A (en) 1968-05-21 1972-06-27 Dow Chemical Co Method of preparing optically active propylene chlorohydrins and propylene oxides
US3920764A (en) 1968-10-23 1975-11-18 Lummus Co Dehydrogenation process
US3657367A (en) * 1968-10-31 1972-04-18 Stauffer Chemical Co Oxychlorination of saturated and unsaturated hydrocarbons in the presence of a fluidized catalyst containing lanthanum and didymium
US3670037A (en) 1969-02-19 1972-06-13 Exxon Research Engineering Co Catalyst system
US3883651A (en) 1969-08-08 1975-05-13 Boehringer Sohn Ingelheim Pharmaceutical compositions containing a 2-(aminoalkylamino)-4-amino-thieno{8 3,2-d{9 pyrimidine and method of use
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3705196A (en) 1969-10-31 1972-12-05 Sun Oil Co Synthesis of aliphatic and alicyclic ethers
US3799997A (en) * 1971-11-08 1974-03-26 Universal Oil Prod Co Preparation of alkenynes
US3968200A (en) 1972-03-27 1976-07-06 The Lummus Company Reactor effluent quench system
US4172099A (en) 1972-05-30 1979-10-23 Stauffer Chemical Company Process for chlorination of ethylene
GB1395926A (en) 1972-07-27 1975-05-29 Bp Chem Int Ltd Process for the production of isoprene by the chlorination/ dehydrochlorination of 2-methylbutene-2
JPS5231022B2 (zh) 1972-10-06 1977-08-12
US3876715A (en) * 1972-12-01 1975-04-08 Gulf Research Development Co Process for preparing 2,3-dibromo-2-alkylalkanes
IT982662B (it) 1973-03-30 1974-10-21 Montedison Spa Procedimento di bromofluorurazio ne del metano
US4347391A (en) 1973-06-11 1982-08-31 Stauffer Chemical Company Process for preparing ethylene dichloride
US3865886A (en) * 1973-06-20 1975-02-11 Lummus Co Production of allyl chloride
US3894103A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization reactions
US3894107A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3894105A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Production of durene
US3879473A (en) * 1973-08-14 1975-04-22 Phillips Petroleum Co Preparation of ethers from alcohols and olefins catalyzed by iodine
US3987119A (en) 1973-10-23 1976-10-19 Allied Chemical Corporation Production of vinyl chloride from ethane
US3919336A (en) 1973-10-23 1975-11-11 Allied Chem Method of preparing vinyl chloride from liquid ethylene dichloride
US4092368A (en) 1974-03-13 1978-05-30 General Electric Company Vapor phase transesterification
US4046825A (en) 1974-05-15 1977-09-06 Mobil Oil Corporation Conversion of oxygenated compounds to gasoline
US4117251A (en) 1974-05-15 1978-09-26 Chemische Werke Huls Ag Method for preparing straight chain primary alcohols from 1-bromoalkanes
US4035285A (en) 1974-05-28 1977-07-12 Mobil Oil Corporation Hydrocarbon conversion process
US3965205A (en) 1974-06-10 1976-06-22 Mobil Oil Corporation Conversion of low octane hydrocarbons to high octane gasoline
US4169862A (en) 1974-07-22 1979-10-02 The B. F. Goodrich Company Low temperature catalytic combustion of chlorohydrocarbons
US4058576A (en) 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
US4138440A (en) * 1974-08-14 1979-02-06 Mobil Oil Corporation Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst
US4044061A (en) 1974-09-23 1977-08-23 Mobil Oil Corporation Preheating methanol effects steady state operation of conversion to gasoline
US3928483A (en) 1974-09-23 1975-12-23 Mobil Oil Corp Production of gasoline hydrocarbons
US3974062A (en) 1974-10-17 1976-08-10 Mobil Oil Corporation Conversion of full range crude oils with low molecular weight carbon-hydrogen fragment contributors over zeolite catalysts
US4071753A (en) 1975-03-31 1978-01-31 Gte Laboratories Incorporated Transducer for converting acoustic energy directly into optical energy
US4025576A (en) 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
US4025575A (en) 1975-04-08 1977-05-24 Mobil Oil Corporation Process for manufacturing olefins
US4049734A (en) 1975-04-08 1977-09-20 Mobil Oil Corporation Conversion of coal to high octane gasoline
US4133838A (en) * 1975-05-15 1979-01-09 Pearson Research Corp. Process for preparing hydrocarbons from methanol and phosphorus pentoxide
US4039600A (en) 1975-07-02 1977-08-02 Mobil Oil Corporation Conversion of synthesis gas to aromatic hydrocarbons
CA1099656A (en) 1975-07-02 1981-04-21 Clarence D. Chang Manufacture of gasoline
US4087475A (en) 1975-07-03 1978-05-02 Robert Kenneth Jordan Carbonyl fluorination process
US4052471A (en) 1975-08-06 1977-10-04 Pearsall Chemical Corporation Process for chlorinating C8 to C30 linear hydrocarbons
US3992466A (en) 1975-08-13 1976-11-16 Mobil Oil Corporation Hydrocarbon conversion
US4052472A (en) 1976-01-16 1977-10-04 Mobil Oil Corporation Mordenite conversion of alkanols to penta- and hexamethyl benzenes
US4049573A (en) 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
US4006169A (en) 1976-02-26 1977-02-01 Smithkline Corporation Epoxidation of α,β-ethylenic ketones
US4060568A (en) 1976-03-31 1977-11-29 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4072733A (en) * 1976-04-02 1978-02-07 Ethyl Corporation Conversion of methanol and dimethyl ether
US4110180A (en) 1976-04-28 1978-08-29 Diamond Shamrock Technologies S.A. Process for electrolysis of bromide containing electrolytes
IT1075503B (it) 1976-05-08 1985-04-22 Basf Ag Processo per la preparazione di glicolesteri
US4071756A (en) * 1976-05-10 1978-01-31 Continental Oil Company Determination of residual oil in a subterranean formation
US4025571A (en) 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
US4025572A (en) 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
GB1542112A (en) 1976-06-11 1979-03-14 Shell Int Research Process for the preparation of 2-phenylethanol or derivatives thereof
US4035430A (en) 1976-07-26 1977-07-12 Mobil Oil Corporation Conversion of methanol to gasoline product
US4194990A (en) * 1977-02-11 1980-03-25 Allied Chemical Corporation Catalyst and process for the production of chlorofluorinated hydrocarbons
US4380682A (en) * 1977-03-30 1983-04-19 Diamond Shamrock Corporation Balanced chlorination process
US4156698A (en) 1977-05-05 1979-05-29 Mobil Oil Corporation Conversion of alcohols or ethers using rare earth crystalline aluminosilicate in an alumina matrix
IT1077342B (it) * 1977-07-18 1985-05-04 Snam Progetti Processo per la produzione di oligomeri da alfaolefine lineari,successiva idrogenazione degli stessi e prodotti saturi cosi' ottenuti
NL7710901A (nl) * 1977-10-05 1979-04-09 Esmil B V Stationsstraat 48 Werkwijze voor het gelijktijdig verwerken van gebruikt metaal en/of metaalafval van gehaloge- neerde koolwaterstoffen.
US4300005A (en) 1977-12-02 1981-11-10 Monsanto Co. Preparation of vinyl chloride
US4133966A (en) * 1977-12-23 1979-01-09 Gulf Research & Development Company Selective formation of ethanol from methanol, hydrogen and carbon monoxide
US4282159A (en) 1978-06-19 1981-08-04 Wisconsin Alumni Research Foundation Preparation of alkylene oxides
DE2832532A1 (de) 1978-07-25 1980-02-07 Hoechst Ag Verfahren zur gewinnung von reinen 2-(perfluoralkyl)-aethanolen aus ihren gemischen mit 2-(perfluoralkyl)-aethylenen und gegebenenfalls 2-(perfluoralkyl)- aethylestern
US4187255A (en) * 1978-08-21 1980-02-05 Conoco, Inc. Process for methylating naphthalene
FR2434861A1 (fr) 1978-08-31 1980-03-28 Inst Francais Du Petrole Procede de production d'essence a haut indice d'octane et en particulier d'essence utilisable sans plomb
US4849573A (en) 1978-09-05 1989-07-18 Mobil Oil Corporation Process for manufacturing light olefins
US4300009A (en) 1978-12-28 1981-11-10 Mobil Oil Corporation Conversion of biological material to liquid fuels
US4311865A (en) * 1979-04-04 1982-01-19 Mobil Oil Corporation Manufacture of hydrocarbons from oxygenates
NL7902886A (nl) * 1979-04-12 1980-10-14 Shell Int Research Werkwijze voor de bereiding van een koolwaterstof- mengsel.
US4443620A (en) * 1979-05-03 1984-04-17 The Lummus Company Production of epoxy compounds from olefinic compounds
US4496752A (en) 1979-05-03 1985-01-29 The Lummus Company Production of epoxy compounds from olefinic compounds
US4410714A (en) 1979-05-03 1983-10-18 The Lummus Company Production of epoxy compounds from olefinic compounds
US4272338A (en) 1979-06-06 1981-06-09 Olin Corporation Process for the treatment of anolyte brine
EP0021497A1 (en) 1979-06-21 1981-01-07 THE PROCTER & GAMBLE COMPANY Synthesis of polyoxyalkylene glycol monoalkyl ethers
US4371716A (en) * 1979-09-04 1983-02-01 Shell Oil Company β-(Sec-alkoxy) ethanol process
US4462814A (en) 1979-11-14 1984-07-31 Koch Process Systems, Inc. Distillative separations of gas mixtures containing methane, carbon dioxide and other components
US4412086A (en) 1980-02-19 1983-10-25 Vulcan Materials Company Process for separating ferric iron from chlorinated hydrocarbons
US4307261A (en) 1980-02-19 1981-12-22 Vulcan Materials Company Process for separating ferric iron from chlorinated hydrocarbons
US4350511A (en) 1980-03-18 1982-09-21 Koch Process Systems, Inc. Distillative separation of carbon dioxide from light hydrocarbons
DE3164837D1 (en) * 1980-05-01 1984-08-23 Ici Plc Halogenation process using a halide carrier and process for regeneration of the halide carrier
US4302619A (en) 1980-06-04 1981-11-24 Mobil Oil Corporation Control of CO emissions in a process for producing gasoline from methanol
US4317934A (en) * 1980-08-15 1982-03-02 Ethyl Corporation Preparation of carbonyl compounds
US4320241A (en) * 1980-08-28 1982-03-16 Occidental Research Corporation Process for converting oxygenated hydrocarbons into hydrocarbons
US4308403A (en) 1980-09-12 1981-12-29 Texaco Inc. Process for preparing glycol ethers
US4317943A (en) * 1980-09-12 1982-03-02 Texaco Inc. Process for preparing glycol ethers
US4301253A (en) 1980-09-25 1981-11-17 Union Carbide Corporation Process for the selective production of ethanol and methanol directly from synthesis gas
US4333852A (en) 1980-09-25 1982-06-08 Union Carbide Corporation Catalyst for the selective production of ethanol and methanol directly from synthesis gas
US4431856A (en) * 1980-09-29 1984-02-14 Mobil Oil Corporation Fluid zeolite catalyst conversion of alcohols and oxygenated derivatives to hydrocarbons
DE3037093C1 (de) * 1980-10-01 1981-11-12 Chemische Werke Hüls AG, 4370 Marl Verfahren zur Herstellung von Cycloocten-4-ol-1 aus Cyclooctadien-1,5
US4543434A (en) 1981-01-28 1985-09-24 Mobil Oil Corporation Process for producing liquid hydrocarbon fuels
US4690903A (en) 1981-02-02 1987-09-01 Mobil Oil Corporation Process for preparing organic fuels and chemicals from biomass
GB2095245A (en) 1981-03-19 1982-09-29 Ici Plc Chlorination of alkanes
GB2095243A (en) 1981-03-19 1982-09-29 Ici Plc Production of methylene chloride
IN157669B (zh) 1981-03-23 1986-05-17 Pfizer
DE3117135A1 (de) * 1981-04-30 1982-11-18 Bayer Ag, 5090 Leverkusen Kristallines alumosilicat, verfahren zu dessen herstellung sowie dessen verwendung zur katalytischen umwandlung von methanol und/oder dimethylether in kohlenwasserstoffe
US4389391A (en) 1981-06-28 1983-06-21 Dunn Jr Wendell E Process for beneficiating titaniferous ores
US4373109A (en) 1981-08-05 1983-02-08 Olah George A Bifunctional acid-base catalyzed conversion of hetero-substituted methanes into olefins
DE3132692A1 (de) 1981-08-19 1983-03-17 Bayer Ag, 5090 Leverkusen Verfahren zur halogenierung von organischen verbindungen
EP0164798A1 (en) 1981-09-01 1985-12-18 George Andrew Olah Process for the preparation of methyl monohalides
US4467130A (en) 1981-09-01 1984-08-21 Olah George A Condensation of natural gas or methane into gasoline-range hydrocarbons
US4513164A (en) * 1981-09-01 1985-04-23 Olah George A Condensation of natural gas or methane into gasoline range hydrocarbons
US4433192A (en) * 1981-09-01 1984-02-21 Olah George A Condensation of natural gas or methane into gasoline range hydrocarbons
US4523040A (en) 1981-09-01 1985-06-11 Olah George A Methyl halides and methyl alcohol from methane
US4465893A (en) 1982-08-25 1984-08-14 Olah George A Oxidative condensation of natural gas or methane into gasoline range hydrocarbons
DE3137751A1 (de) 1981-09-23 1983-03-31 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum erzeugen von benzinkohlenwasserstoffen aus methanol
US4605803A (en) 1981-11-21 1986-08-12 Mobil Oil Corporation Acid-catalyzed organic compound conversion
CA1186345A (en) 1981-12-14 1985-04-30 Martin M.Y. Chang Hydrocarbon production
US4568660A (en) * 1982-01-25 1986-02-04 Hercules Incorporated Cycloolefin polymerization catalyst composition
US4489211A (en) 1982-02-04 1984-12-18 Onoda Cement Co., Ltd. Process for producing 2,2,2-trifluoroethanol
US4538014A (en) 1982-03-08 1985-08-27 Mobil Oil Corporation Catalysis over activated zeolites
US4538015A (en) 1982-03-08 1985-08-27 Mobil Oil Corporation Catalysis over activated zeolites
IT1150678B (it) 1982-03-12 1986-12-17 Anic Spa Procedimento per la produzione di eteri alchil terbutilici in presenza di butadiene
US4384159A (en) 1982-03-12 1983-05-17 The Dow Chemical Company Catalytic dehydrohalogenation process
US4433189A (en) * 1982-03-18 1984-02-21 Mobil Oil Corporation Catalytic conversion of methanol to light olefins
US4588835A (en) 1982-03-29 1986-05-13 Otsuka Kagaku Yakuhin Kabushiki Kaisha Process for preparing alkoxyphenols
US4499314A (en) * 1982-03-31 1985-02-12 Imperial Chemical Industries Plc Methanol conversion to hydrocarbons with zeolites and cocatalysts
DE3216722A1 (de) * 1982-05-05 1983-11-10 Hoechst Ag, 6230 Frankfurt 4-halomethylbenzoesaeure-alkylester-imine und verfahren zu deren herstellung
GB2120249B (en) 1982-05-15 1985-11-27 British Petroleum Co Plc Process for the production of methyl or ethyl mono-halide
US4467133A (en) 1982-06-21 1984-08-21 Mobil Oil Corporation Conversion of alcohols and ethers to distillate range hydrocarbons
FR2529883A1 (fr) * 1982-07-06 1984-01-13 Ugine Kuhlmann Procede de fabrication de chlorure de vinyle
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4509955A (en) * 1982-08-09 1985-04-09 The Lubrizol Corporation Combinations of carboxylic acylating agents substituted with olefin polymers of high and low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
US4465884A (en) 1982-08-17 1984-08-14 Mobil Oil Corporation Olefin processing
US4814527A (en) * 1982-10-18 1989-03-21 The Dow Chemical Company Catalytic process for ethylene dichloride
US4654449A (en) 1982-12-09 1987-03-31 Mobil Oil Corporation Formation of halogenated hydrocarbons from hydrocarbons
US4655893A (en) * 1983-02-07 1987-04-07 Battelle Development Corporation Cubic boron nitride preparation utilizing a boron and nitrogen bearing gas
US4788377A (en) 1983-04-22 1988-11-29 Mobil Oil Corporation Process for manufacturing olefins
US4720600A (en) * 1983-06-29 1988-01-19 Mobil Oil Corporation Production of middle distillate range hydrocarbons by light olefin upgrading
US4547612A (en) 1984-09-25 1985-10-15 Mobil Oil Corporation Production of lubricant and/or heavy distillate range hydrocarbons by light olefin upgrading
US4675410A (en) 1983-07-11 1987-06-23 Nepera Inc. Process for the production of pyridine or alkyl substituted pyridines
US4540826A (en) 1983-08-12 1985-09-10 Phillips Petroleum Company Process for preparing olefinic aldehydes
CA1202610A (en) 1983-08-15 1986-04-01 Ralph M. Dessau Activity enhancement of high silica zeolites
DE3470527D1 (en) * 1983-08-25 1988-05-26 Huels Chemische Werke Ag Process for the preparation of 3,3- or 2,3-dimethyl butene and 2,3- dimethyl butadiene or for the simultaneous preparation of these olefins and glycol or polyglycol-n-alkyl-3,3- or 2,3-dimethyl butyl ether from mono- and dichloro-dimethyl butane
US5175382A (en) 1983-09-22 1992-12-29 Werner Hebgen Preparation of 1,2-Dichloroethane
US4524227A (en) 1983-09-29 1985-06-18 Mobil Oil Corporation Coproduction of durene and gasoline from synthesis gas and alcohols and separation of durene-gasoline mixtures
US4524231A (en) 1983-09-29 1985-06-18 Mobil Oil Corporation Production of durene from alcohols and ethers
US4524228A (en) 1983-09-29 1985-06-18 Mobil Oil Corporation Production of durene and gasoline from synthesis gas
US4704493A (en) 1983-10-31 1987-11-03 Chevron Corporation Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst (II-A)
US4599474A (en) 1983-10-31 1986-07-08 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal-containing catalyst
US4709108A (en) 1983-10-31 1987-11-24 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst
US4704488A (en) 1983-10-31 1987-11-03 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal compound-containing catalyst (111-A)
GB8331982D0 (en) * 1983-11-30 1984-01-04 British Petroleum Co Plc Hydrocarbons from c1 to c4 alkyl monohalides
WO1985002608A1 (en) 1983-12-16 1985-06-20 The British Petroleum Company P.L.C. Process for the production of hydrocarbons from hetero-substituted alkanes
JPS60136525A (ja) 1983-12-26 1985-07-20 Agency Of Ind Science & Technol エタノ−ルの製造法
US4513092A (en) * 1984-01-04 1985-04-23 Mobil Oil Corporation Composite catalyst for halogenation and condensation of alkanes
US4621161A (en) 1984-01-23 1986-11-04 Mobil Oil Corporation Oxygenate conversion over activated zeolite catalyst
US4642404A (en) * 1984-01-23 1987-02-10 Mobil Oil Corporation Conversion of olefins and paraffins to higher hydrocarbons
US4550218A (en) 1984-03-05 1985-10-29 Mobil Oil Corporation Hydrocarbon synthesis with zeolite catalyst of improved hydrothermal stability
LU85285A1 (fr) 1984-04-03 1985-11-27 Labofina Sa Procede d'isomerisation d'olefines
US4634800A (en) * 1984-04-16 1987-01-06 Atlantic Richfield Company Methane conversion process
GB8410479D0 (en) * 1984-04-24 1984-05-31 British Petroleum Co Plc Conversion process
US4497967A (en) * 1984-06-15 1985-02-05 The Halcon Sd Group, Inc. Process for the preparation of ethanol from methanol, carbon monoxide _and hydrogen
US4590310A (en) 1984-08-02 1986-05-20 The Boc Group, Inc. Process for the preparation of 2,2,2-trifluoroethanol
US4550217A (en) 1984-08-29 1985-10-29 Mobil Oil Corporation Conversion of methanol to olefins using large size catalyst particles
GB8429007D0 (en) * 1984-11-16 1984-12-27 British Petroleum Co Plc Aromatics from ethane/ethylene
US4696985A (en) 1984-11-16 1987-09-29 Hercules Incorporated Catalyst composition for polymerization of cycloolefins
US4579977A (en) * 1984-12-20 1986-04-01 Phillips Petroleum Company Process for the oxidation of organic halides to organic aldehydes
US4764356A (en) * 1984-12-21 1988-08-16 Exxon Research & Engineering Co. Process for synthesizing a zeolite catalyst on a pH controlled basis to improve catalyst life
US4544781A (en) 1985-01-09 1985-10-01 Mobil Oil Corporation Control of temperature exotherms in the conversion of methanol to gasoline hydrocarbons
DE194931T1 (de) * 1985-03-14 1987-02-26 Societe Nationale Elf Aquitaine (Production), Courbevoie, Fr Verfahren und vorrichtung zur photochemischen sulfochlorinierung von gasfoermigen alkanen.
US4658077A (en) * 1985-06-07 1987-04-14 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
US5210357A (en) 1985-06-07 1993-05-11 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
JPS61242901A (ja) 1985-04-17 1986-10-29 Toyo Soda Mfg Co Ltd 臭素回収用吸着剤及び臭素回収方法
US5146027A (en) 1985-05-24 1992-09-08 Atlantic Richfield Co. Methane conversion process
US5093542A (en) 1985-05-24 1992-03-03 Atlantic Richfield Company Methane conversion process
US5959170A (en) 1985-05-24 1999-09-28 Atlantic Richfield Company Methane conversion process
US5105045A (en) 1985-06-07 1992-04-14 Phillips Petroleum Company Method of oxidative conversion
US4774216A (en) 1985-06-07 1988-09-27 Phillips Petroleum Company Composition of matter for oxidative conversion of organic compounds
WO1986007483A1 (en) * 1985-06-12 1986-12-18 Raychem Corporation Hydrocarbon sensor
US4724275A (en) * 1985-07-01 1988-02-09 National Distillers And Chemical Corporation Crystalline aluminosilicates and their use in the conversion of methanol to low molecular weight hydrocarbons
GB8518820D0 (en) 1985-07-25 1985-08-29 British Petroleum Co Plc Chemical process
GB8520977D0 (en) 1985-08-21 1985-09-25 British Petroleum Co Plc Production of aromatics
US4795843A (en) * 1985-08-26 1989-01-03 Uop Inc. Conversion of methane into larger organic hydrocarbons
US4665259A (en) 1985-08-28 1987-05-12 The Standard Oil Company Methane conversion process using phosphate-containing catalysts
US4633027A (en) 1985-09-23 1986-12-30 Mobil Oil Corporation Process for converting olefins to gasoline, distillate and alkylate liquid hydrocarbons
US4658073A (en) * 1985-09-23 1987-04-14 Mobil Oil Corporation Control system for multistage chemical upgrading
CA1322768C (en) 1988-12-29 1993-10-05 John E. Stauffer Process for the chlorination of ethane
US4788369A (en) 1985-12-31 1988-11-29 Mobil Oil Corporation Conversion of methanol to gasoline
LU86280A1 (fr) 1986-01-29 1987-09-03 Labofina Sa Procede de production d'essence
GB8613673D0 (en) 1986-06-05 1986-07-09 Bp Benzin Und Petroleum Ag Chemical process
ZA874948B (en) * 1986-07-07 1989-02-22 Mobil Oil Corp Aromatisation of aliphatics over gallium-containing zeolites
US4781733A (en) 1986-07-23 1988-11-01 Bend Research, Inc. Semipermeable thin-film membranes comprising siloxane, alkoxysilyl and aryloxysilyl oligomers and copolymers
US4814532A (en) * 1986-08-04 1989-03-21 Chemical Company, Ltd. Asahi Process for producing alkylcyclopentadiene derivatives
US4795848A (en) * 1986-08-28 1989-01-03 The Standard Oil Company Method for upgrading a low molecular weight alkane with a lead-zirconate catalyst
US5082816A (en) 1986-08-28 1992-01-21 The Standard Oil Company Lead-zirconate catalysts
US4720602A (en) * 1986-09-08 1988-01-19 Mobil Oil Corporation Process for converting C2 to C12 aliphatics to aromatics over a zinc-activated zeolite
US5120332A (en) 1986-11-06 1992-06-09 The Haser Company Limited Gas resonance device
US5118899A (en) 1986-12-22 1992-06-02 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
US5160502A (en) 1986-12-22 1992-11-03 Phillips Petroleum Company Composition of matter and method of oxidative conversion of organic compounds therewith
US5087787A (en) 1986-12-29 1992-02-11 Phillips Petroleum Company Method of oxidative conversion
DE3700132A1 (de) 1987-01-03 1988-07-14 Dow Chemical Gmbh Verfahren zum herstellen von ethylendichlorid
US4769504A (en) 1987-03-04 1988-09-06 The United States Of America As Represented By The United States Department Of Energy Process for converting light alkanes to higher hydrocarbons
US4795737A (en) * 1987-03-25 1989-01-03 Eastman Kodak Company Process for the iodination of aromatic compounds over solid catalysts
US4792642A (en) 1987-03-25 1988-12-20 Eastman Kodak Company Process for preparing iodinated aromatic compounds
US4886932A (en) 1987-03-30 1989-12-12 Atlantic Richfield Company Thin bed cofeed reaction system for methane conversion
CA1322769C (en) 1988-12-30 1993-10-05 John E. Stauffer Process for the chlorination of ethane
US4777321A (en) 1987-04-29 1988-10-11 Mobil Oil Corporation Feedstock preparation and conversion of oxygenates to olefins
US4775462A (en) 1987-06-22 1988-10-04 Uop Inc. Non-oxidative method of sweetening a sour hydrocarbon fraction
US4808763A (en) * 1987-08-05 1989-02-28 Amoco Corporation Process for upgrading light paraffins
US4804797A (en) * 1987-08-24 1989-02-14 Gas Research Institute Production of commodity chemicals from natural gas by methane chlorination
US4783566A (en) 1987-08-28 1988-11-08 Uop Inc. Hydrocarbon conversion process
GB8724373D0 (en) 1987-10-17 1987-11-18 British Petroleum Co Plc Chemical process
US4973786A (en) 1987-10-19 1990-11-27 Karra Sankaram B Process for the pyrolytic oxidation of methane to higher molecular weight hydrocarbons and synthesis gas
US5157189A (en) 1987-10-19 1992-10-20 Karra Sankaram B Conversion of light hydrocarbons to higher hydrocarbons
US4814536A (en) * 1987-12-15 1989-03-21 Mobil Oil Corporation Conversion of oxygenates to gasoline at variable space velocity
US4814535A (en) * 1987-12-15 1989-03-21 Mobil Oil Corporation Conversion of oxygenates to gasoline at variable inlet temperature
GB8802731D0 (en) 1988-02-06 1988-03-09 British Petroleum Co Plc Chemical process
US5059744A (en) 1988-03-03 1991-10-22 Mobil Oil Corporation Reactor and recovery system for upgrading lower olefins
GB8806675D0 (en) 1988-03-21 1988-04-20 Shell Int Research Process for preparing liquid hydrocarbons
US4851602A (en) 1988-04-11 1989-07-25 Mobil Oil Corporation Alkanes and alkenes conversion to high octane gasoline
US4851606A (en) 1988-04-25 1989-07-25 Mobil Oil Corporation Control of waste water chemical oxygen demand in an oxygenate to hydrocarbon conversion process
US4886925A (en) 1988-05-02 1989-12-12 Mobil Oil Corp Olefins interconversion and etherification process
JPH07106998B2 (ja) 1988-05-17 1995-11-15 ダイキン工業株式会社 １，１，１−トリフルオロ−２，２−ジクロロエタンの製造方法
US5013793A (en) 1990-07-26 1991-05-07 Exxon Chemical Patents Inc. Dynamically cured thermoplastic olefin polymers and process for producing the same
US4990711A (en) 1988-06-23 1991-02-05 Mobil Oil Corporation Synthetic polyolefin lubricant blends having high viscosity indices
US4950822A (en) 1988-06-27 1990-08-21 Ethyl Corporation Olefin oligomer synlube process
US4899002A (en) * 1988-07-25 1990-02-06 Mobil Oil Corp. Integrated staged conversion of methanol to gasoline and distillate
FR2635101B1 (fr) 1988-08-05 1990-09-28 Rhone Poulenc Chimie Procede de preparation du trifluoroethanol par hydrolyse, en phase gazeuse, du chlorotrifluoroethane
US4939311A (en) 1988-08-17 1990-07-03 Amoco Corporation Catalysts for the oxidative conversion of methane to higher hydrocarbons
US4956521A (en) 1988-10-06 1990-09-11 Uop Adsorption and isomerization of normal and mono-methyl paraffins
US5055634A (en) 1988-10-06 1991-10-08 Uop Adsorption and isomerization of normal and mono-methyl paraffins
US5055633A (en) 1988-10-06 1991-10-08 Uop Adsorption and isomerization of normal and mono-methyl paraffins
US5215648A (en) 1988-10-20 1993-06-01 Chevron Research And Technology Company Hydrocarbon conversion processes using SSZ-31
US4899001A (en) * 1988-11-21 1990-02-06 Uop Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds
US5194244A (en) 1988-11-23 1993-03-16 Shell Oil Company Basic alkali metal-zeolite compositions
US4929781A (en) 1988-11-30 1990-05-29 Uop Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds
US4895995A (en) * 1988-12-02 1990-01-23 Uop Process for the simultaneous hydroconversion of a first feedstock comprising unsaturated, halogenated organic compounds and a second feedstock comprising saturated, halogenated organic compounds
DE68927703T2 (de) 1988-12-07 1997-08-14 Sumitomo Chemical Co Verfahren zur Herstellung von 2,3-Dimethylbutenen
US5178748A (en) 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites
CA1304419C (en) 1988-12-22 1992-06-30 Raj N. Pandey Conversion of methane to gasoline-range hydrocarbons via isobutene
GB8829923D0 (en) 1988-12-22 1989-02-15 Ici Plc Zeolites
US4990696A (en) 1988-12-29 1991-02-05 Stauffer John E Methyl alcohol process
US4899000A (en) * 1989-01-27 1990-02-06 Stauffer John E Production of allyl chloride
US5436378A (en) 1989-02-16 1995-07-25 Atochem Drying of hydrocarbon/hydrochloric acid/water admixtures
US5107051A (en) 1989-03-14 1992-04-21 Exxon Chemical Patents Inc. Halogen resistant hydrotreating process and catalyst
US4945175A (en) 1989-05-26 1990-07-31 Uop Dehydrocyclodimerization process start-up procedure
US5202511A (en) 1989-08-16 1993-04-13 The Dow Chemical Company Catalyst diluent for oxychlorination process
US5071815A (en) 1989-09-01 1991-12-10 British Columbia Research Corporation Method for producing catalysts
ZA907446B (en) 1989-09-19 1991-07-31 Union Carbide Chem Plastic Silver-containing catalysts for oxidative coupling
US5073657A (en) 1989-09-19 1991-12-17 Union Carbide Chemicals And Plastics Company Inc. Vapor phase modifiers for oxidative coupling
EP0418975A1 (en) 1989-09-19 1991-03-27 Union Carbide Chemicals And Plastics Company, Inc. Low temperature catalysts for oxidative coupling processes
US5073656A (en) 1989-09-19 1991-12-17 Union Carbide Chemicals And Plastics Company, Inc. High ethylene to ethane processes for oxidative coupling
DE3933656A1 (de) 1989-10-09 1991-04-11 Basf Ag Verdunstungsarme polyesterharze
US5026944A (en) 1989-12-20 1991-06-25 Energy Mines And Resources Canada Synthesis of isobutene from methane and acetylene
US4982024A (en) 1989-12-26 1991-01-01 Ethyl Corporation Process for the selective dehydrohalogenation of an admixture of alkylhalides
US5004847A (en) 1989-12-27 1991-04-02 Ethyl Corporation Recovery of hexabromocyclododecane particles
US5026937A (en) 1989-12-29 1991-06-25 Uop Aromatization of methane using zeolite incorporated in a phosphorus-containing alumina
US4982041A (en) 1990-01-10 1991-01-01 Union Carbide Chemicals And Plastics Company Inc. Double perovskite catalysts for oxidative coupling
US5026934A (en) 1990-02-12 1991-06-25 Lyondell Petrochemical Company Method for converting light hydrocarbons to olefins, gasoline and methanol
US5043502A (en) 1990-03-16 1991-08-27 Uop Production of xylenes from light aliphatic hydrocarbons via dehydrocyclodimerization and methylation
US5228888A (en) 1990-03-23 1993-07-20 The Boc Group, Inc. Economical air separator
US5107061A (en) 1990-04-06 1992-04-21 Exxon Chemical Patents Inc. Removal of organochlorides from hydrocarbon feed streams
US5087786A (en) 1990-04-25 1992-02-11 Amoco Corporation Halogen-assisted conversion of lower alkanes
US5001293A (en) * 1990-04-25 1991-03-19 Amoco Corporation Halocarbon conversion
US5087779A (en) 1990-04-25 1992-02-11 Amoco Corporation Hydrocarbon halogenation
US5019652A (en) 1990-04-30 1991-05-28 The United States As Represented By The United States Department Of Energy Catalysts and method
US5139991A (en) 1990-04-30 1992-08-18 The United States Of American As Represented By The United States Department Of Energy Oxyhydrochlorination catalyst
US5051477A (en) 1990-05-04 1991-09-24 Advanced Elastomer Systems, L. P. Dynamically cured thermoplastic olefin polymers and process for producing the same
US5068478A (en) 1990-05-25 1991-11-26 Energia Andina, Ltd. Producing alkenes and alkynes from alkanes and alkenes
GB9013859D0 (en) 1990-06-21 1990-08-15 Ici Plc Zeolites
GB9013916D0 (en) 1990-06-22 1990-08-15 Ici Plc Zeolites
US4988660A (en) 1990-06-25 1991-01-29 Union Carbide Chemicals And Plastics Company Inc. Double perovskite catalysts for oxidative coupling
US5082473A (en) * 1990-07-23 1992-01-21 Keefer Bowie Extraction and concentration of a gas component
US5096469A (en) * 1990-07-23 1992-03-17 Keefer Bowie Adsorptive gas separator with inertial energy exchange
US5401890A (en) 1990-07-30 1995-03-28 Albemarle Corporation Process and apparatus for heat treating halogenated compounds
US5013424A (en) 1990-07-30 1991-05-07 Uop Process for the simultaneous hydrogenation of a first feedstock comprising hydrocarbonaceous compounds and having a non-distillable component and a second feedstock comprising halogenated organic compounds
US5138112A (en) 1990-08-31 1992-08-11 Uop Process for converting a C2 -C6 aliphatic hydrocarbon to high octane transportable fuel
DE4029875A1 (de) 1990-09-21 1992-03-26 Hoechst Ag Verfahren zur inhibierung und zerstoerung von peroxiden in dialkylethern
JP2970683B2 (ja) 1990-10-12 1999-11-02 日石三菱株式会社 水素化脱アルキル触媒を用いた水素化脱アルキル法
US5085674A (en) * 1990-10-25 1992-02-04 Union Carbide Industrial Gases Technology Corporation Duplex adsorption process
US5071449A (en) 1990-11-19 1991-12-10 Air Products And Chemicals, Inc. Gas separation by rapid pressure swing adsorption
US5107032A (en) 1990-11-20 1992-04-21 Noramco, Inc. Process for the preparation of o-phthalaldehydes
DE69120686T2 (de) * 1990-12-06 1996-10-31 Occidental Chem Co Verfahren zur herstellung von ethylen oder einer mischung von ethylen und vinylchlorid
US5055235A (en) 1990-12-12 1991-10-08 Ethyl Corporation Bromination process
US5105046A (en) 1990-12-12 1992-04-14 Amoco Corporation Oxidative conversion of lower alkanes to higher hydrocarbons via fluorine-containing materials
US5223471A (en) 1990-12-12 1993-06-29 Amoco Corporation Fluorine-containing materials
US5306855A (en) 1991-02-15 1994-04-26 Catalytica, Inc. Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons
US5233113A (en) 1991-02-15 1993-08-03 Catalytica, Inc. Process for converting lower alkanes to esters
GB9105167D0 (en) 1991-03-12 1991-04-24 Ici Plc Chemical process
US5188725A (en) 1991-03-15 1993-02-23 Mobil Oil Corporation Fluidized catalyst process for production and etherification of olefins
US5237115A (en) 1991-03-15 1993-08-17 Phillips Petroleum Company Integrated olefin processing
FR2674769B1 (fr) 1991-04-04 1994-04-29 Inst Francais Du Petrole Catalyseur du type galloaluminosilicate contenant du gallium, un metal noble de la famille du platine et au moins un metal additionnel, et son utilisation en aromatisation des hydrocarbures.
EP0510238A1 (en) 1991-04-26 1992-10-28 NOVAMONT S.p.A. Process for producing lower poliols and mixtures thereof
US5288677A (en) 1991-06-28 1994-02-22 Exxon Chemical Patents Inc. Immobilized Lewis acid catalysts
GB9116172D0 (en) 1991-07-26 1991-09-11 Thames Water Utilities A method of and apparatus for treating a fluid
US5399258A (en) 1991-08-15 1995-03-21 Mobil Oil Corporation Hydrocarbon upgrading process
MY108348A (en) 1991-08-16 1996-09-30 Exxon Chemical Patents Inc Ester free ethers.
US5264635A (en) 1991-10-03 1993-11-23 Mobil Oil Corporation Selective cracking and etherification of olefins
US5245109A (en) 1991-10-11 1993-09-14 Amoco Corporation Hydrocarbon conversion
JP3120292B2 (ja) 1991-10-18 2000-12-25 イハラケミカル工業株式会社 脂肪族カルボン酸ハロメチルエステル類の製造法
US5276240A (en) * 1991-10-18 1994-01-04 Board Of Regents, The University Of Texas System Catalytic hydrodehalogenation of polyhalogenated hydrocarbons
US5268518A (en) 1991-11-15 1993-12-07 The Dow Chemical Company Reactor feed pipe design
US5191142A (en) 1991-12-23 1993-03-02 Amoco Corporation Process for converting methanol to olefins or gasoline
JPH07503404A (ja) 1992-02-04 1995-04-13 カタリティカ，インコーポレイテッド ＣｅＢｒ↓３触媒，および臭素生成のプロセス
US6169218B1 (en) 1992-02-10 2001-01-02 Catalytic Distillation Technologies Selective hydrogenation of highly unsaturated compounds in hydrocarbon streams
US5354916A (en) 1992-03-10 1994-10-11 Exxon Research And Engineering Company Low temperature conversion of alkanes
CA2088939A1 (en) 1992-03-10 1993-09-11 Istvan T. Horvath Low temperature conversion of alkanes
US5202506A (en) 1992-04-02 1993-04-13 E. I. Du Pont De Nemours And Company Oxidative drown process for 2-perfluoroalkylethyl alcohols
US5185479A (en) 1992-04-21 1993-02-09 Stauffer John E Process for methyl alcohol
CA2097090A1 (en) 1992-06-02 1993-12-03 Quang N. Le Process for the production of tertiary alkyl ether rich fcc gasoline
US5395981A (en) 1992-06-22 1995-03-07 Uop Hydrocarbon conversion by catalytic distillation
US5254790A (en) 1992-07-01 1993-10-19 Phillips Petroleum Company Integrated process for producing motor fuels
US5284990A (en) 1992-07-16 1994-02-08 Stratco, Inc. Method for converting a hydrogen fluoride alkylation unit to a sulfuric acid alkylation unit
US5276242A (en) 1992-08-26 1994-01-04 Phillips Petroleum Company Alkylation process
US5243114A (en) 1992-09-08 1993-09-07 Mobil Oil Corporation Oligomerization of alpha-olefins over layered silicate compositions containing pillars of silica and group VIB metal oxide
US5453557A (en) 1992-10-01 1995-09-26 The Dow Chemical Company Processes for converting chlorinated byproducts and waste products to useful materials
US5430214A (en) 1992-10-01 1995-07-04 The Dow Chemical Company Hydrodehalogenation process and catalyst for use therein
IT1255710B (it) 1992-10-01 1995-11-10 Snam Progetti Procedimento integrato per produrre olefine da miscele gassose contenenti metano
US5276226A (en) 1992-10-05 1994-01-04 Exxon Research & Engineering Company Low temperature halogenation of alkanes
US5300126A (en) 1992-10-19 1994-04-05 Mobil Oil Corporation Process for improving olefin etherification catalyst life
US5243098A (en) 1992-11-04 1993-09-07 Energia Andina Ltd. Conversion of methane to methanol
US5744669A (en) 1992-11-25 1998-04-28 Uop Process for the conversion of a halogenated organic stream containing trace quantities of organic nitrates
US5817904A (en) 1992-12-11 1998-10-06 Repsol Petroleo S.A. Method for the conversion of methane into longer chain hydrocarbons
TW291486B (zh) 1992-12-17 1996-11-21 Exxon Chemical Patents Inc
US5470377A (en) 1993-03-08 1995-11-28 Whitlock; David R. Separation of solutes in gaseous solvents
US5354931A (en) 1993-03-10 1994-10-11 Uop Process for hydrotreating an organic feedstock containing oxygen compounds and a halogen component
US5994604A (en) 1993-03-17 1999-11-30 Lockheed Martin Idaho Technologies Company Method and apparatus for low temperature destruction of halogenated hydrocarbons
GB9407257D0 (en) 1993-04-22 1994-06-08 Ici Plc Vaporisation of liquids
US5382743A (en) 1993-04-26 1995-01-17 Mobil Oil Corporation Skeletal isomerization of n-pentenes using ZSM-35 in the presence of hydrogen
US5465699A (en) 1993-06-01 1995-11-14 Volkswagen Ag Intake pipe arrangement for an internal combustion engine having individual arc-shaped cylinder intake pipes
US5382704A (en) 1993-06-30 1995-01-17 E. I. Du Pont De Nemours And Company Fluorinated methyl ethers
US5382744A (en) 1993-07-12 1995-01-17 Phillips Petroleum Company Control of synthetic isopentane production during alkylation of amylenes
US5510525A (en) 1993-07-22 1996-04-23 Gas Research Institute Direct catalytic oxidative carbonylation of lower alkanes to acids
IT1265051B1 (it) 1993-08-06 1996-10-28 Eniricerche Spa Processo per l'alchilazione di idrocarburi alifatici con olefine
US5695890A (en) 1993-08-09 1997-12-09 The Trustees Of Princeton University Heterolamellar photoelectrochemical films and devices
US5906892A (en) 1993-08-09 1999-05-25 The Trustees Of Princeton University Electron acceptor compositions on polymer templates
US5500297A (en) 1993-08-09 1996-03-19 The Trustees Of Princeton University Electron acceptor compositions technical field
US5430210A (en) 1993-08-27 1995-07-04 Mobil Oil Corporation Selective hydrogen combustion processes
GB9318505D0 (en) 1993-09-07 1993-10-20 Evc Tech Ag By-product recycling in oxychlorination process
GB9318507D0 (en) 1993-09-07 1993-10-20 Evc Tech Ag Vinyl chloride production process
US5371313A (en) 1993-11-24 1994-12-06 Polysar Rubber Corporation Purification of hydrocarbon streams
US5600045A (en) 1993-12-02 1997-02-04 The Dow Chemical Company Process for conversion of crude hydrocarbon mixtures
US5414173A (en) 1993-12-22 1995-05-09 The Dow Chemical Company Process of preparing cyclopentadiene and substituted derivatives thereof
GB9400569D0 (en) 1994-01-13 1994-03-09 Rhone Poulenc Chemicals Process for the production of substituted aromatic hydrocarbons from corresponding anilines by dediazoniation
EP0746529B1 (en) 1994-02-18 2000-01-05 Chevron Chemical Company LLC Zeolite ssz-42
US5565092A (en) 1994-03-16 1996-10-15 Exxon Chemical Patents Inc. Halogen resistant hydrogenation process and catalyst
US5780703A (en) 1994-05-02 1998-07-14 Mobil Oil Corporation Process for producing low aromatic diesel fuel with high cetane index
US5565616A (en) 1994-05-09 1996-10-15 Board Of Regents, The University Of Texas System Controlled hydrothermal processing
US5444168A (en) 1994-05-16 1995-08-22 Mobil Oil Corporation Process for the production of symmetrical ethers from secondary alcohols
US5401894A (en) 1994-06-07 1995-03-28 Uop Process for the treatment of halogenated organic feedstocks
US5591421A (en) 1994-07-11 1997-01-07 Chevron U.S.A. Inc. Zeolite SSZ-41
US5523503A (en) 1994-07-13 1996-06-04 Uop Cocurrent simulated moving bed hydrocarbon alkylation process
GB9414972D0 (en) 1994-07-26 1994-09-14 Bnfl Fluorchem Ltd Halogenation reactions
US5661097A (en) 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
US6015867A (en) 1994-09-28 2000-01-18 Showa Denko K.K. 3-alkoxypropionic ester derivative, olefin polymerization catalyst, and process for preparation of polyolefin
US6117371A (en) 1994-10-05 2000-09-12 Great Lakes Chemical Corporation Continuous bromination process and products thereof
EP0784648B2 (en) 1994-10-05 2010-10-27 Great Lakes Chemical Corporation Continuous bromination process and products thereof
GB2294262B (en) 1994-10-20 1998-07-08 Evc Tech Ag Single stage fixed bed oxychlorination of ethylene
CA2203115C (en) 1994-10-20 2006-09-19 Pierluigi Fatutto Single stage fixed bed oxychlorination of ethylene
US5489727A (en) 1994-10-28 1996-02-06 Phillips Petroleum Company Isopentane disproportionation
US5693191A (en) 1994-11-23 1997-12-02 The Dow Chemical Company Process for recovery of anhydrous hydrogen chloride from mixtures with non-condensable gases
US5821394A (en) 1994-11-24 1998-10-13 Solvay Process for converting a chlorinated alkane into a less chlorinated alkene
US5486627A (en) 1994-12-02 1996-01-23 The Dow Chemical Company Method for producing epoxides
US5639930A (en) 1995-01-04 1997-06-17 Penick; Joe E. Process of producing alkylates
DK171707B1 (da) 1995-02-03 1997-04-01 Topsoe Haldor As Fremgangsmåde til fremstilling af dimetylæter i brændstofkvalitet
US5905169A (en) 1995-03-20 1999-05-18 E. I. Du Pont De Nemours And Company Process for producing polyfluoroacyl compositions
US5600043A (en) 1995-03-27 1997-02-04 The Geon Company Oxychlorination process
ATE204737T1 (de) 1995-04-21 2001-09-15 Procter & Gamble Shampoos mit konditionierungsmittel aus unlöslichen silikon, und kationischem polymer
FR2734172B1 (fr) 1995-05-19 1997-06-20 Air Liquide Dispositif et procede de separation de gaz par adsorption
DE19520612A1 (de) 1995-06-06 1996-12-12 Bayer Ag Verfahren zur Herstellung von Benzylalkohol
US5847224A (en) 1995-06-23 1998-12-08 Global Octanes Corporation Method for improving the color of MTBE, ETBE and TAME
US5977402A (en) 1995-07-20 1999-11-02 Sumitomo Chemical Company, Limited Processes for preparing 4-tert.-butylcyclohexanol and 4-tert.-butylcyclohexyl acetate
FR2736911A1 (fr) 1995-07-20 1997-01-24 Inst Francais Du Petrole Catalyseur liquide d'alkylation aliphatique
US5675052A (en) 1995-09-15 1997-10-07 The Boc Group, Inc. Hydrocarbon alkylation process
US5705712A (en) 1995-10-05 1998-01-06 Uop Integrated process for producing diisopropyl ether, an isopropyl tertiary alkyl ether and isopropyl alcohol
US5705729A (en) 1995-11-22 1998-01-06 Mobil Oil Corporation Isoparaffin-olefin alkylation process
FR2743079B1 (fr) 1995-12-27 1998-02-06 Inst Francais Du Petrole Procede et dispositif d'hydrogenation selective par distillation catalytique comportant une zone reactionnelle a co-courant ascendant liquide-gaz
DE19548876A1 (de) 1995-12-27 1997-07-03 Bayer Ag Verfahren zur kontinuierlichen Herstellung von Benzylalkohol
FR2743510B1 (fr) 1996-01-11 1998-04-03 Total Raffinage Distribution Nouveau catalyseur d'alkylation, son procede de preparation et son utilisation dans des procedes d'alkylation
US6090312A (en) 1996-01-31 2000-07-18 Ziaka; Zoe D. Reactor-membrane permeator process for hydrocarbon reforming and water gas-shift reactions
US6096933A (en) 1996-02-01 2000-08-01 Phillips Petroleum Company Hydrocarbon hydrogenation and catalyst therefor
AU692723B2 (en) 1996-02-01 1998-06-11 Phillips Petroleum Company Catalyst composition and process for selecting hydrogenation of diolefins
DE19603901A1 (de) 1996-02-03 1997-08-07 Krupp Uhde Gmbh Verfahren zur Gewinnung von Reinaromaten aus Reformatbenzin und Vorrichtung zur Durchführung des Verfahrens
SE517561C2 (sv) 1996-03-04 2002-06-18 Aga Ab Förfarande och anordning för framställning av en gas genom separation från en gasblandning
US5663474A (en) 1996-03-07 1997-09-02 Alliedsignal Inc. Alkylation process using hydrogen fluoride-containing alkylation catalysts
US5684213A (en) 1996-03-25 1997-11-04 Chemical Research & Licensing Company Method for the preparation of dialkyl ethers
US5675046A (en) 1996-04-10 1997-10-07 Showa Denko K.K. Process for producing perfluorocarbon
US5898086A (en) 1996-04-19 1999-04-27 Henkel Corporation Process for making alkyl ether glycerols
US6191324B1 (en) 1996-04-24 2001-02-20 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing unsaturated alcohols
USRE38493E1 (en) * 1996-04-24 2004-04-13 Questair Technologies Inc. Flow regulated pressure swing adsorption system
EP0914311B1 (en) 1996-05-29 2001-07-11 ExxonMobil Chemical Patents Inc. Process for producing aromatic compounds from aliphatic hydrocarbons
AU3232997A (en) 1996-06-07 1998-01-05 Chevron U.S.A. Inc. Zeolite me-utd-1
US5720858A (en) 1996-07-17 1998-02-24 The United States Of America As Represented By The United States Department Of Energy Method for the photocatalytic conversion of methane
US5708246A (en) 1996-08-28 1998-01-13 Battelle Memorial Institute Method of photocatalytic conversion of C-H organics
HU220573B1 (hu) 1996-11-18 2002-03-28 AGRO-CHEMIE Növényvédőszer Gyártó, Értékesítő és Forgalmazó Kft. Eljárás benzil-éterek előállítására
WO1998023560A1 (en) 1996-11-27 1998-06-04 Akzo Nobel N.V. Process for alkylating hydrocarbons
US5895831A (en) 1996-12-04 1999-04-20 Uop Llc Solid catalyst alkylation process
US7182871B2 (en) * 1996-12-17 2007-02-27 Global Biosciences, Inc. Wastewater treatment with alkanes
US6669846B2 (en) 1996-12-17 2003-12-30 Global Biosciences, Inc. Wastewater treatment with alkanes
US5952538A (en) 1996-12-31 1999-09-14 Exxon Chemical Patents Inc. Use of short contact time in oxygenate conversion
CA2283118A1 (en) 1997-03-07 1998-09-17 Basf Aktiengesellschaft Improved process for preparing cyclopropylacetylene
SG74047A1 (en) 1997-04-30 2000-07-18 Mitsubishi Chem Corp Process for producing alkylene glycol
US6018088A (en) 1997-05-07 2000-01-25 Olah; George A. Superacid catalyzed formylation-rearrangement of saturated hydrocarbons
DE19721301C1 (de) 1997-05-21 1998-10-01 Basf Ag Verfahren zur Hydrolyse von Alkylmonohalogeniden
US6056804A (en) 1997-06-30 2000-05-02 Questor Industries Inc. High frequency rotary pressure swing adsorption apparatus
AU8395898A (en) 1997-07-11 1999-02-08 University Of Southern California Charge generators in heterolamellar multilayer thin films
US5856584A (en) 1997-08-06 1999-01-05 The Nutrasweet Company Preparation of 3,3-dimethylbutyraldehyde by oxidation of 3, 3-dimethylbutanol
DK128697A (da) 1997-11-12 1999-05-13 Niels J Bjerrum Katalyseproces
DE19755636A1 (de) 1997-12-15 1999-06-17 Bayer Ag Verfahren zur elektrochemischen Aufarbeitung von HCl-Gas zu hochreinem Chlor
FR2773496B1 (fr) 1998-01-14 2000-03-03 Inst Francais Du Petrole Procede de separation par decantation dans plusieurs zones distinctes
US5968236A (en) 1998-02-20 1999-10-19 Bassine; Stuart Valve free oxygen concentrator
US6187983B1 (en) 1998-04-29 2001-02-13 Exxon Chemical Patents Inc Converting oxygenates to olefins in the presence of electromagnetic energy
US5998679A (en) 1998-05-20 1999-12-07 Jlm Technology, Ltd. Methods for converting lower alkanes and alkanes to alcohols and diols
US5983476A (en) 1998-06-09 1999-11-16 Uop Llc Conversion of an HF alkylation unit
US6096932A (en) 1999-07-27 2000-08-01 E. I. Du Pont De Nemours And Company Fluorocarbon manufacturing process
EP0976705A1 (en) 1998-07-30 2000-02-02 Ube Industries, Ltd. Method of producing a phenolalkylether compound
IT1302003B1 (it) 1998-08-05 2000-07-20 Enitecnologie Spa Procedimento per la trasformazione selettiva di idrocarburi.
US6087294A (en) 1998-08-12 2000-07-11 Kansas State University Research Foundation Dispersion and stabilization of reactive atoms on the surface of metal oxides
FR2782280B1 (fr) 1998-08-12 2000-09-22 Inst Francais Du Petrole Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques
US6921597B2 (en) 1998-09-14 2005-07-26 Questair Technologies Inc. Electrical current generation system
EP1034196B1 (en) 1998-10-05 2005-01-12 Promerus LLC Catalyst and methods for polymerizing cycloolefins
US6903171B2 (en) 1998-10-05 2005-06-07 Promerus, Llc Polymerized cycloolefins using transition metal catalyst and end products thereof
EP1121337B1 (en) 1998-10-12 2003-04-09 Great Lakes (Uk) Limited Preparation of cyclopropylethyne and intermediates for preparation of cyclopropylethyne
US6127588A (en) 1998-10-21 2000-10-03 Phillips Petroleum Company Hydrocarbon hydrogenation catalyst and process
US6002059A (en) 1998-10-28 1999-12-14 Mobil Oil Corporation Process for upgrading natural gas
DK0999182T3 (da) 1998-11-02 2003-07-14 Inst Francais Du Petrole Fremgangsmåde til fremstilling af en zeolit af strukturtypen EUO ved hjælp af kim af zeolitiske materialer og anvendelse heraf som katalysator til isomerisering af aromatiske forbindelser med otte carbonatomer
EP0999183B1 (fr) 1998-11-02 2003-06-18 Institut Francais Du Petrole Procédé de préparation d'une zéolithe de type structural EUO a l'aide de precurseurs du structurant et son utilisation comme catalyseur d'isomerisation des AC8
US6130260A (en) 1998-11-25 2000-10-10 The Texas A&M University Systems Method for converting natural gas to liquid hydrocarbons
US6782264B2 (en) * 1999-01-08 2004-08-24 Trueposition, Inc. Monitoring of call information in a wireless location system
US6936565B2 (en) 1999-01-12 2005-08-30 Hyperion Catalysis International, Inc. Modified carbide and oxycarbide containing catalysts and methods of making and using thereof
US6239057B1 (en) 1999-01-15 2001-05-29 Uop Llc Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst
US6114593A (en) 1999-01-27 2000-09-05 Phillips Petroleum Company Method for reducing organic fluoride levels in hydrocarbons
WO2000048971A1 (en) 1999-02-22 2000-08-24 Symyx Technologies, Inc. Compositions comprising nickel and their use as catalyst in oxidative dehydrogenation of alkanes
US6143939A (en) 1999-02-26 2000-11-07 The United States Of America As Represented By The United States Department Of Energy Method of dehalogenation using diamonds
US7220391B1 (en) 1999-03-25 2007-05-22 University Of Central Florida Research Foundation, Inc. UV photochemical option for closed cycle decomposition of hydrogen sulfide
US6248218B1 (en) 1999-03-25 2001-06-19 Clovis A. Linkous Closed cycle photocatalytic process for decomposition of hydrogen sulfide to its constituent elements
US7273957B2 (en) 1999-05-04 2007-09-25 Catalytic Distillation Technologies Process for the production of gasoline stocks
US6545192B2 (en) 1999-05-11 2003-04-08 Shell Oil Company Process for separating olefins from saturated hydrocarbons
FR2793706B1 (fr) 1999-05-18 2001-08-03 Total Raffinage Distribution Support catalytique a base d'oxyde d'un metal du groupe ivb de la classification periodique des elements, sa preparation et ses utilisations
US6225266B1 (en) * 1999-05-28 2001-05-01 Infineum Usa L.P. Zinc-free continuously variable transmission fluid
US6444223B1 (en) 1999-05-28 2002-09-03 Alkermes Controlled Therapeutics, Inc. Method of producing submicron particles of a labile agent and use thereof
US6727400B2 (en) 1999-06-08 2004-04-27 Triosyn Holdings, Inc. Deactivation of toxic chemical agents
US6406523B1 (en) 1999-06-09 2002-06-18 Questair Technologies, Inc. Rotary pressure swing adsorption apparatus
US6248931B1 (en) 1999-06-30 2001-06-19 Uop Llc Membrane process for the recovery of halides from hydrocarbon-containing streams
SE520971C2 (sv) 1999-08-20 2003-09-16 Perstorp Ab Förfarande för tillverkning av en eteralkohol
US6309453B1 (en) 1999-09-20 2001-10-30 Xerox Corporation Colorless compounds, solid inks, and printing methods
FR2798922B1 (fr) 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des germes de materiaux zeolithiques
FR2798923B1 (fr) 1999-09-29 2001-12-14 Inst Francais Du Petrole Procede de preparation d'une zeolithe de type structural mtt utilisant des precurseurs specifiques du structurant
US20020102672A1 (en) 1999-10-04 2002-08-01 Joseph Mizrahi Process for producing a purified lactic acid solution
DE19949211A1 (de) 1999-10-13 2001-05-31 Veba Oel Ag Verfahren zur Herstellung von n-Alkanen aus Mineralölfraktionen und Katalysator zur Durchführung des Verfahrens
US6372949B1 (en) 1999-10-15 2002-04-16 Mobil Oil Corporation Single stage process for converting oxygenates to gasoline and distillate in the presence of undimensional ten member ring zeolite
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6518474B1 (en) 1999-10-29 2003-02-11 Huntsman International Llc Process for producing isobutylene from tertiary butyl alcohol
US6909024B1 (en) 1999-11-22 2005-06-21 The Dow Chemical Company Process for the conversion of ethylene to vinyl chloride and novel catalyst compositions useful for such process
PL354730A1 (en) 1999-11-22 2004-02-23 The Dow Chemical Company A process for the conversion of ethylene to vinyl chloride, and novel catalyst compositions useful for such process
US6680415B1 (en) 1999-11-22 2004-01-20 Dow Global Technologies Inc. Oxyhalogenation process using catalyst having porous rare earth halide support
US6933417B1 (en) 1999-11-22 2005-08-23 Dow Global Technologies Inc. Process for vinyl chloride manufacture from ethane and ethylene with partial CHl recovery from reactor effluent
US6797845B1 (en) 1999-11-22 2004-09-28 Dow Global Technologies Inc. Process for vinyl chloride manufacture from ethane and ethylene with immediate HCl recovery from reactor effluent
US6514319B2 (en) 1999-12-09 2003-02-04 Questair Technologies Inc. Life support oxygen concentrator
AU2578201A (en) 1999-12-14 2001-06-25 Halocarbon Products Corporation Hydrothermal hydrolysis of halogenated compounds
EP1108701B1 (en) 1999-12-14 2003-04-23 Sumitomo Chemical Company Limited Process for preparing ketone, alcohol and hydroperoxide
US6376731B1 (en) 2000-01-14 2002-04-23 Arco Chemical Technology, L.P. Selective olefin oligomerization
DE60140425D1 (de) 2000-02-02 2009-12-24 Daikin Ind Ltd Produktionsverfahren von fluorkohlenwasserstoffen
IT1317757B1 (it) 2000-02-03 2003-07-15 Enitecnologie Spa Metodo per la preparazione di idrocarburi idrogenati.
FR2805255B1 (fr) 2000-02-21 2002-04-12 Inst Francais Du Petrole Zeolithe mtt comprenant des cristaux et des agregats de cristaux de granulometries specifiques et son utilisation comme catalyseur d'isomerisation des paraffines lineaires
US6566572B2 (en) 2000-03-06 2003-05-20 Wako Pure Chemical Industries, Ltd. Process for producing 9,10-diphenylanthracene
US6632416B2 (en) 2000-05-31 2003-10-14 Chevron U.S.A. Inc. Zeolite SSZ-53
US6475463B1 (en) 2000-03-07 2002-11-05 Chevron U.S.A. Inc. Zeolite SSZ-55
US6395945B1 (en) 2000-03-31 2002-05-28 Phillips Petroleum Company Integrated hydroisomerization alkylation process
US6710213B2 (en) 2000-03-31 2004-03-23 Showa Denko K.K. Production process and use for propargyl alcohol and its intermediate
CA2306311C (en) 2000-04-20 2007-04-10 Quest Air Gases Inc. Absorbent laminate structures
EP1151980A1 (en) 2000-05-03 2001-11-07 Solvias AG Catalytic halogenation of activated methylene and methine compound
FR2812301B1 (fr) 2000-07-26 2003-04-04 Inst Francais Du Petrole Procede flexible de production de bases huiles et de distillats moyens a partir de charge contenant des heteroatomes
IT1318682B1 (it) 2000-08-11 2003-08-27 Enichem Spa Procedimento integrato per la preparazione di ossidi olefinici.
IT1318680B1 (it) 2000-08-11 2003-08-27 Enichem Spa Processo per la produzione in continuo di ossidi olefinici.
US6495484B1 (en) 2000-08-28 2002-12-17 Univation Technologies, Llc Catalyst system and its use in a polymerization process
AU2001272904A1 (en) 2000-09-07 2002-03-22 Wisconsin Alumni Research Foundation Synthesis of 17f labeled fluoroalkanes
FR2813809B1 (fr) 2000-09-11 2003-07-25 Air Liquide Colonne a garnissage d'echange de chaleur et/ou de matiere
US6518476B1 (en) 2000-09-18 2003-02-11 Union Carbide Chemicals & Plastics Technology Corporation Methods for manufacturing olefins from lower alkans by oxidative dehydrogenation
ZA200108461B (en) 2000-10-27 2002-06-06 Celanese Chem Europe Gmbh Process of telomerizing conjugated dienes.
US6552241B1 (en) 2000-10-31 2003-04-22 Conocophillips Company Alkylation process
US20030004380A1 (en) 2000-11-29 2003-01-02 Helmut Grumann Method for producing 1,2-dichloroethane
AU2002215752A1 (en) 2000-12-08 2002-06-18 Denis Connor Methods and apparatuses for gas separation by pressure swing adsorption with partial gas product feed to fuel cell power source
CA2329475A1 (en) 2000-12-11 2002-06-11 Andrea Gibbs Fast cycle psa with adsorbents sensitive to atmospheric humidity
FR2818284B1 (fr) 2000-12-15 2006-08-04 Inst Francais Du Petrole Procede flexible ameliore de production de bases huiles et distillats moyens avec une conversion-hydroisomerisation suivie d'un deparaffinage catalytique
US6511526B2 (en) 2001-01-12 2003-01-28 Vbox, Incorporated Pressure swing adsorption gas separation method and apparatus
US6538162B2 (en) 2001-01-30 2003-03-25 Exxonmobil Chemical Patents Inc. Method for converting alkanes to oxygenates
US6509485B2 (en) 2001-02-22 2003-01-21 Sri International Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts
KR100519140B1 (ko) 2001-02-23 2005-10-04 쇼와 덴코 가부시키가이샤 퍼플루오로탄소의 제조방법 및 그 용도
US20030196680A1 (en) 2002-04-19 2003-10-23 Dielectric Systems, Inc Process modules for transport polymerization of low epsilon thin films
US6472572B1 (en) 2001-06-20 2002-10-29 Grt, Inc. Integrated process for synthesizing alcohols and ethers from alkanes
US7019182B2 (en) * 2001-04-18 2006-03-28 Grt, Inc. Method of hydrocarbon preservation and environmental protection
US6525230B2 (en) 2001-04-18 2003-02-25 Grt, Inc. Zone reactor
US7230150B2 (en) * 2001-04-18 2007-06-12 Grt, Inc. Zone reactor
US6452058B1 (en) 2001-05-21 2002-09-17 Dow Global Technologies Inc. Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons and integrated processes related thereto
EP1395537A1 (en) 2001-05-23 2004-03-10 Dow Global Technologies Inc. Process for vinyl chloride manufacture from ethane and ethylene with air feed and alternative hcl processing methods
CN1649808A (zh) 2001-05-23 2005-08-03 陶氏环球技术公司 从单碳原料的卤乙烯生产
MXPA03010693A (es) 2001-05-23 2004-07-01 Dow Global Technologies Inc Halogenacion oxidante y deshidreogenacion opcional de hidrocarburos de c3+.
EP1527035B1 (en) 2001-06-08 2015-03-04 Albemarle Netherlands B.V. Continuous process for the alkylation of hydrocarbons
US7001872B2 (en) 2001-06-11 2006-02-21 Halliburton Energy Services, Inc. Subterranean formation treating fluid and methods of fracturing subterranean formations
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US6486368B1 (en) 2001-06-20 2002-11-26 Grt, Inc. Integrated process for synthesizing alcohols, ethers, and olefins from alkanes
US7161050B2 (en) * 2001-06-20 2007-01-09 Grt, Inc. Method and apparatus for synthesizing olefins, alcohols, ethers, and aldehydes
US6465699B1 (en) 2001-06-20 2002-10-15 Gri, Inc. Integrated process for synthesizing alcohols, ethers, and olefins from alkanes
US20050192468A1 (en) 2001-06-20 2005-09-01 Sherman Jeffrey H. Hydrocarbon conversion process improvements
US20030069452A1 (en) 2001-06-20 2003-04-10 Sherman Jeffrey H. Method and apparatus for synthesizing from alcohols and ethers from alkanes, alkenes, and aromatics
US20030078456A1 (en) * 2001-06-20 2003-04-24 Aysen Yilmaz Integrated process for synthesizing alcohols, ethers, aldehydes, and olefins from alkanes
US6440894B1 (en) 2001-06-25 2002-08-27 Exxonmobil Chemical Patents, Inc. Methods of removing halogen from non-zeolitic molecular sieve catalysts
US6518471B1 (en) 2001-06-25 2003-02-11 Exxonmobil Chemical Patents Inc. Selective production of meta-diisopropylbenzene
DE02744727T1 (de) 2001-06-28 2005-02-10 Honeywell International Inc. Verfahren zur herstellung eines fluorierungskatalysators
US20030065239A1 (en) 2001-06-29 2003-04-03 Peter Zhu Non-hazardous basic neutralization of aldehydes
US6646102B2 (en) 2001-07-05 2003-11-11 Dow Global Technologies Inc. Process for manufacturing an alpha-dihydroxy derivative and epoxy resins prepared therefrom
US6540905B1 (en) 2001-07-13 2003-04-01 Chevron U.S.A. Inc. Hydrocarbon conversion using zeolite SSZ-58
US6616830B2 (en) 2001-07-13 2003-09-09 Chevron U.S.A. Inc. Hydrocarbon conversion using zeolite SSZ-57
US6547958B1 (en) 2001-07-13 2003-04-15 Chevron U.S.A. Inc. Hydrocarbon conversion using zeolite SSZ-59
US6867302B2 (en) 2001-07-13 2005-03-15 Board Of Trustees Of Michigan State University Process for the catalytic synthesis of biaryls and polymers from aryl compounds
US7094936B1 (en) 2001-07-20 2006-08-22 Great Lakes Chemical Corporation Process for preparing halogenated alkanes
FR2828193B1 (fr) 2001-08-03 2004-04-02 Atofina Nouveau procede de preparation du 1,1,1,-trifluoro-2,2-dichloroethane
WO2003018524A1 (en) 2001-08-03 2003-03-06 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
US6858770B2 (en) 2001-08-21 2005-02-22 Catalytic Distillation Technologies Paraffin alkylation
US6797851B2 (en) 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US6632971B2 (en) 2001-08-30 2003-10-14 Exxonmobil Chemical Patents Inc. Process for converting natural gas to higher value products using a methanol refinery remote from the natural gas source
US6552238B1 (en) 2001-08-31 2003-04-22 Vulcan Chemicals Separation of heavy ends from streams of halogenated alkanes
WO2003022827A1 (en) 2001-09-11 2003-03-20 Grt, Inc. Process for synthesizing olefin oxides
CN1286788C (zh) 2001-09-14 2006-11-29 东曹氟技术株式会社 2,2,2－三氟乙醇的制造方法
JP4014856B2 (ja) 2001-11-14 2007-11-28 株式会社トクヤマ ジハロゲン化アダマンタンの製造方法
WO2003043575A2 (en) 2001-11-19 2003-05-30 Merck & Co., Inc. Process for the synthesis of (r)-1-(3,5-bis(trifluoromethyl)-phenyl)ethan-1-ol and esters thereof by dynamic kinetic resolution
ZA200209011B (en) 2001-11-20 2003-05-26 Rohm & Haas Electroactive catalysis.
DE10159615A1 (de) 2001-12-05 2003-06-12 Basf Ag Verfahren zur Herstellung von 1,2-Dichlorethan
US6933404B2 (en) 2001-12-18 2005-08-23 Metabolix Inc. Methods of making intermediates from polyhydroxyalkanoates
US7199255B2 (en) 2001-12-18 2007-04-03 Univation Technologies, Llc Imino-amide catalysts for olefin polymerization
AU2002318266B2 (en) 2002-01-24 2009-06-04 Grt, Inc. Integrated process for synthesizing alcohols, ethers, and olefins from alkanes
JP4498744B2 (ja) 2002-01-25 2010-07-07 カウンシル・オブ・サイエンティフィック・アンド・インダストリアル・リサーチ 無害な臭素化試薬の製造
US7091270B2 (en) 2002-01-31 2006-08-15 Bromine Compounds Ltd. Pentabromobenzyl alkyl ethers and their use as fire retardants
US6770789B2 (en) 2002-03-13 2004-08-03 University Of Florida Research Foundation Process for trifluoromethylation of sulfates
EP1483035B1 (en) 2002-03-14 2011-09-14 QuestAir Technologies Inc. Gas separation by combined pressure swing and displacement purge
US20040152929A1 (en) 2002-05-08 2004-08-05 Clarke William D Process for vinyl chloride manufacture from ethane and ethylene with air feed and alternative hcl processing methods
NZ536672A (en) 2002-05-10 2007-01-26 Wisconsin Alumni Res Found Low-temperature hydrocarbon production from oxygenated hydrocarbons
US6545191B1 (en) 2002-06-13 2003-04-08 John E. Stauffer Process for preparing ethanol
US6946566B2 (en) 2002-07-31 2005-09-20 Daiso Co., Ltd. Process for preparation of optically active halogeno hydroxypropyl compound and glycidyl compound
EP1386664B1 (en) 2002-07-31 2016-05-11 Ineos Technologies (Vinyls) Limited A hollow parallelepiped pellet suitable as carrier of catalysts for selective exothermic reactions
US7238846B2 (en) 2002-08-14 2007-07-03 Exxonmobil Chemical Patents Inc. Conversion process
US6831032B2 (en) 2002-08-19 2004-12-14 Novolen Technology Holdings C.V. Ziegler-Natta catalyst and methods of making and using same
EP1539347B1 (en) 2002-08-22 2012-06-27 E.I. Du Pont De Nemours And Company Cobalt substituted chromium oxide compositions, their preparation and their use as catalysts and catalyst precursors
US6753390B2 (en) 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6740146B2 (en) 2002-09-12 2004-05-25 Edward L. Simonds Oxygen concentrator
DE10242223A1 (de) 2002-09-12 2004-03-25 Clariant Gmbh Verfahren zur Hydrodechlorierung von kernchlorierten ortho-Xylolen
FR2845077A1 (fr) 2002-09-26 2004-04-02 Atofina Procede d'abaissement de la teneur en matieres organiques et produits azotes contenus dans des effluents bromures
KR100531128B1 (ko) 2002-09-26 2005-11-28 한국화학연구원 분리막 반응기를 이용한 디메틸에테르의 제조방법
US6852896B2 (en) 2002-10-11 2005-02-08 John E. Stauffer Concerted process for the production of an alkenyl substituted aromatic compound
US6869903B2 (en) 2002-11-07 2005-03-22 Univation Technologies, Llc Synthesis of polymerization catalyst components
CN1203032C (zh) 2002-11-12 2005-05-25 石油大学(北京) 以复合离子液体为催化剂制备烷基化油剂的方法
US7060865B2 (en) 2002-11-12 2006-06-13 Exxonmobil Chemical Patents Inc. Recovery of C4 olefins from a product stream comprising C4 olefins, dimethyl ether and C5+ hydrocarbons
US7199083B2 (en) * 2002-12-06 2007-04-03 Self Generating Foam Incoporated Self-generating foamed drilling fluids
DE10257499A1 (de) * 2002-12-10 2004-07-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen
JP4441487B2 (ja) 2002-12-20 2010-03-31 エクソンモービル・ケミカル・パテンツ・インク 重合プロセス
JP4426527B2 (ja) 2002-12-20 2010-03-03 エクソンモービル・ケミカル・パテンツ・インク 重合プロセス
EP1440939A1 (en) 2003-01-07 2004-07-28 Humboldt-Universität zu Berlin Method for the preparation of amorphous metal fluorides
DE10303304A1 (de) 2003-01-28 2004-07-29 Ruhrgas Ag Verfahren zum Herstellen nichtaromatischer Kohlenwassersstoffe
US7265193B2 (en) 2003-01-31 2007-09-04 Exxonmobil Chemical Patents Inc. Polymerization process
US20040158108A1 (en) 2003-02-06 2004-08-12 Snoble Karel A.J. Purification of alcohol
KR100501922B1 (ko) 2003-02-19 2005-07-18 에스케이 주식회사 메탄올로부터 디메틸에테르의 제조방법
WO2004081147A2 (en) 2003-03-07 2004-09-23 Conocophillips Company Octane improvement of a hydrocarbon stream
US7091391B2 (en) 2003-03-19 2006-08-15 Stauffer John E Methane to olefins
FR2852866B1 (fr) 2003-03-25 2006-07-14 Bp Lavera Snc Compose metallique fixe sur un support, procede de preparation et utilisation du compose dans des reactions de metathese d'hydrocarbure
US20040187684A1 (en) 2003-03-26 2004-09-30 Saleh Elomari Using molecular sieve SSZ-65 for reduction of oxides of nitrogen in a gas stream
US7011811B2 (en) 2003-03-26 2006-03-14 Chevron U.S.A. Inc. Molecular sieve SSZ-65 composition of matter and synthesis thereof
US7083714B2 (en) 2003-03-26 2006-08-01 Chevron U.S.A. Inc. Hydrocarbon conversion using molecular sieve SSZ-65
US7301060B2 (en) 2003-03-28 2007-11-27 Ab-Cwt, Llc Process for conversion of organic, waste, or low-value materials into useful products
JP4111035B2 (ja) 2003-03-31 2008-07-02 日本ゼオン株式会社 重合トナーの製造方法
US6822123B2 (en) 2003-04-02 2004-11-23 John E. Stauffer Formaldehyde process
CN100400495C (zh) 2003-04-09 2008-07-09 国际壳牌研究有限公司 链烷二醇的制备方法
US7057081B2 (en) 2003-05-09 2006-06-06 Conocophillips Company Method for treating alkanes
US6953868B2 (en) 2003-06-05 2005-10-11 Dow Global Technologies Inc. Oxyfunctionalization of polyolefins
WO2005069751A2 (en) 2003-06-21 2005-08-04 Richards Alan K Anhydrous processing of methane into methane-sulfonic acid, methanol, and other compounds
US7193093B2 (en) * 2003-06-30 2007-03-20 Shell Oil Company Process for producing alkylene oxide
CA2532367C (en) 2003-07-15 2013-04-23 Grt, Inc. Hydrocarbon synthesis
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
UA84436C2 (ru) 2003-08-08 2008-10-27 Солвей (Сосьетэ Аноним) Способ регенерации катализатора гидрирования и способ получения мономера винилхлорида
DE10338581A1 (de) 2003-08-22 2005-03-17 Oxeno Olefinchemie Gmbh Verfahren zur Erzeugung von tert.-Butanol
US6958306B2 (en) 2003-08-28 2005-10-25 Univation Technologies, Llc Activated catalyst systems from substituted dialuminoxane complexes
US7045670B2 (en) 2003-09-03 2006-05-16 Synfuels International, Inc. Process for liquid phase hydrogenation
GB0320684D0 (en) 2003-09-03 2003-10-01 Bp Chem Int Ltd Process
US6825383B1 (en) 2003-09-22 2004-11-30 Council Of Scientific And Industrial Research Catalytic process for regiospecific chlorination of alkanes, alkenes and arenes
US7105710B2 (en) 2003-09-26 2006-09-12 Shell Oil Company Process of preparing an alkylene glycol
AU2004281985B2 (en) 2003-10-13 2010-09-16 Merck Serono Sa Method for preparing para-phenyl alkynyl benzaldehydes
US7335802B2 (en) 2003-10-15 2008-02-26 Shell Oil Company Methods of preparing branched aliphatic alcohols
WO2005035121A2 (en) 2003-10-16 2005-04-21 Universiteit Gent Schiff base metal complexes for use as catalysts in organic synthesis
US6838576B1 (en) 2003-10-23 2005-01-04 3M Innovative Properties Company Process for preparing functional group-containing olefinic compounds
US7196239B2 (en) * 2003-11-19 2007-03-27 Exxonmobil Chemical Patents Inc. Methanol and ethanol production for an oxygenate to olefin reaction system
RU2006122944A (ru) 2003-11-28 2008-01-10 Фирмениш Са (Ch) Мускусная ароматическая композиция
WO2005054120A2 (en) 2003-12-05 2005-06-16 Idaho Research Foundation, Inc. Polymer-supported metal nanoparticles and method for their manufacture and use
US7244795B2 (en) 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
WO2005056525A2 (en) 2003-12-09 2005-06-23 Bio-Technical Resources Deacetylation of n-acetylglucosamine
CN1894183B (zh) 2003-12-18 2010-09-08 埃克森美孚化学专利公司 氢化或相关方面的改进
US7064238B2 (en) 2004-01-02 2006-06-20 Marathon Oil Company Conversion of alkanes to oxygenates
FR2865731B1 (fr) 2004-01-30 2007-09-07 Solvay Procede de fabrication d'un hydrofluoroalcane
FR2866023B1 (fr) 2004-02-05 2007-10-12 Rhodia Chimie Sa Procede de preparation d'un compose fluoaromatique a partir d'un compose aminoaromatique
US7429621B2 (en) 2004-03-12 2008-09-30 University Of Utah Research Foundation Cyclone reactor and associated methods
WO2005095310A2 (en) 2004-03-23 2005-10-13 Shell Internationale Research Maatschappij B.V. The utilization of zirconium and zirconium based alloys for the containment of halogen containing environments used in the production of olefins, alcohols, ethers, ethoxylates glycols, and olefin oxides from alkanes
US7674941B2 (en) * 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
JP5027655B2 (ja) 2004-04-20 2012-09-19 ユーオーピー エルエルシー 結晶性アルミノシリケートゼオライト質組成物：ｕｚｍ−１５
US7462752B2 (en) 2004-04-21 2008-12-09 Shell Oil Company Process to convert linear alkanes into alpha olefins
US7091387B2 (en) 2004-04-21 2006-08-15 Shell Oil Company Process to convert alkanes into primary alcohols
JP4836939B2 (ja) 2004-04-23 2011-12-14 ユーオーピー エルエルシー 高シリカゼオライト：ｕｚｍ−５ｈｓ
WO2005110953A1 (en) 2004-04-30 2005-11-24 Shell Internationale Research Maatschappij B.V. Derivatives of alcohols and olefins
US7435760B2 (en) 2004-05-14 2008-10-14 Battelle Memorial Institute Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels
WO2006007093A1 (en) 2004-06-16 2006-01-19 Dow Global Technologies Inc. Apparatus and method for ziegler-natta research
CN1972886B (zh) 2004-06-23 2010-05-05 株式会社德山 多卤代金刚十四烷类及其衍生物的制造方法
DE102004030943B4 (de) 2004-06-26 2013-10-02 Evonik Oxeno Gmbh Verfahren zur Herstellung von tert.-Butanol aus Isobuten-haltigen Kohlenwasserstoffgemischen
EP1771403B1 (en) 2004-07-21 2010-01-06 Dow Global Technologies Inc. Conversion of a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin
US7429683B2 (en) 2004-07-27 2008-09-30 Eastman Kodak Company Process of maing naphthacene from propargyl alcohol
US7671248B2 (en) 2004-08-13 2010-03-02 Exxonmobil Chemical Patents Inc. Process for producing sec-butyl benzene
US7371916B1 (en) 2004-09-16 2008-05-13 Uop Llc Conversion of an alcoholic oxygenate to propylene using moving bed technology and an etherification step
US7271303B1 (en) 2004-09-22 2007-09-18 Uop Llc Multi-zone process for the production of diesel and aromatic compounds
AU2005292315A1 (en) 2004-09-30 2006-04-13 Chevron U.S.A. Inc. Molecular sieve SSZ-65
EP1808227B1 (en) 2004-10-15 2010-01-20 Toagosei Co., Ltd. Process for producing metal oxide catalyst
GB0423586D0 (en) 2004-10-22 2004-11-24 United States Borax Inc Selective oxidation of organic compounds
US9150494B2 (en) 2004-11-12 2015-10-06 Velocys, Inc. Process using microchannel technology for conducting alkylation or acylation reaction
TWI332418B (en) 2004-11-18 2010-11-01 Rohm & Haas Hybrid catalyst systems and hybrid process for converting alkanes to alkenes and to their corresponding oxygenated products
EP1824599B1 (en) 2004-12-21 2020-06-17 Albemarle Netherlands B.V. Attrition-resistant catalyst, a process for its preparation and its use
EP3456409B1 (en) 2004-12-22 2020-05-13 Chemtor, Lp Use of fiber film reactors to produce biodiesel
EP1843839A2 (en) 2004-12-22 2007-10-17 E.I. Dupont De Nemours And Company Copolymers of perfluoro (alkyl venyl ether) for photochemical reactor, process for increasing fluorine content and production of olefinic compound by photochlorination
US7537685B2 (en) 2004-12-23 2009-05-26 Chevron U.S.A. Inc. Hydrocarbon conversion using molecular sieve SSZ-71
BRPI0518657A2 (pt) 2004-12-23 2008-12-02 Solvay processos para a fabricaÇço de 1,2-dicloroetano e para a fabricaÇço de cloreto de vinila
CN101115679B (zh) 2004-12-23 2012-10-03 切夫里昂美国公司 分子筛ssz-70组合物及其合成
WO2006067190A1 (en) 2004-12-23 2006-06-29 Solvay (Société Anonyme) Process for the manufacture of 1,2-dichloroethane
WO2006067191A1 (en) 2004-12-23 2006-06-29 Solvay (Société Anonyme) Process for the manufacture of 1,2-dichloroethane
EA010364B1 (ru) 2004-12-23 2008-08-29 Солвей (Сосьете Аноним) Способ производства 1,2-дихлорэтана
EP1843975B1 (en) 2004-12-23 2014-06-11 Chevron U.S.A. Inc. Molecular sieve ssz-70 composition of matter and synthesis thereof
DE102005003109B4 (de) 2005-01-22 2015-02-12 Air Liquide Global E&C Solutions Germany Gmbh Verfahren zur Herstellung von synthetischen Kraftstoffen aus Oxigenaten
US7253328B2 (en) 2005-01-24 2007-08-07 John Stauffer Method for producing vinyl chloride monomer
WO2006104909A2 (en) 2005-03-28 2006-10-05 Shell Internationale Research Maatschappij B.V. Catalytic distillation process for primary haloalkanes
US20060229475A1 (en) 2005-04-11 2006-10-12 Weiss Michael J Synthesis of hydroxylated hydrocarbons
US20060229228A1 (en) * 2005-04-11 2006-10-12 Zachary John Anthony Komon Method of making alkoxylates
KR101347419B1 (ko) 2005-04-15 2014-02-06 이 아이 듀폰 디 네모아 앤드 캄파니 아릴-에틸렌 치환된 방향족 화합물 및 유기 반도체로서의 이의 용도
ITMI20050723A1 (it) 2005-04-21 2006-10-22 Consiglio Nazionale Ricerche Metodo di produzione del biodiesel
ZA200708923B (en) 2005-05-04 2009-02-25 Dow Global Technologies Inc Oxidative halogenation of C1 hydrocarbons to halogenated C1 hydrocarbons
TWI321129B (en) 2005-05-20 2010-03-01 Solvay Process for preparing a chlorohydrin
WO2007017900A2 (en) 2005-05-26 2007-02-15 Sisir Kumar Mandal Preparation of para dichlorobenzene from benzene or mono chlorobenzene
US20060270863A1 (en) 2005-05-27 2006-11-30 Amyris Biotechnologies Conversion of amorpha-4,11-diene to artemisinin and artemisinin precursors
CA2510093C (en) 2005-06-16 2009-09-29 Apotex Pharmachem Inc. Novel process for the preparation of.alpha.-chlorovinyl, .alpha.,.alpha.-dichloro, and acetylenes from ketones
US7442354B2 (en) 2005-06-23 2008-10-28 Chevron U.S.A. Inc. Treatment of engine exhaust using molecular sieve SSZ-56
EP1909947A4 (en) 2005-06-23 2012-09-26 Chevron Usa Inc MOLSIEB-SSZ-56-COMPOSITION AND SYNTHESIS THEREOF
US7226569B2 (en) 2005-06-23 2007-06-05 Chevron U.S.A. Inc. Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-56
US7226576B2 (en) 2005-06-23 2007-06-05 Chevron U.S.A. Inc. Molecular sieve SSZ-56 composition of matter and synthesis thereof
US7390395B2 (en) 2005-06-23 2008-06-24 Saleh Elomari Hydrocarbon conversion using molecular sieve SSZ-56
US7084308B1 (en) 2005-07-29 2006-08-01 Stauffer John E Manufacture of formaldehyde from methyl bromide
US8957259B2 (en) 2005-09-30 2015-02-17 Battelle Memorial Institute Dimethyl ether production from methanol and/or syngas
EP1940760B1 (en) 2005-10-07 2016-08-24 Badger Licensing LLC Bisphenol-a plant yield enhancement
US7683230B2 (en) 2005-10-27 2010-03-23 Stauffer John E Methyl bromide to olefins
WO2007050745A1 (en) 2005-10-28 2007-05-03 Shell Internationale Research Maatschappij B.V. Internal olefins process
US7888520B2 (en) 2005-12-21 2011-02-15 University Of Saskatchewan Process for the preparation of biodiesel
US20070197801A1 (en) 2005-12-22 2007-08-23 Bolk Jeroen W Method of installing an epoxidation catalyst in a reactor, a method of preparing an epoxidation catalyst, an epoxidation catalyst, a process for the preparation of an olefin oxide or a chemical derivable from an olefin oxide, and a reactor suitables for such a process
US20070213545A1 (en) 2005-12-22 2007-09-13 Bolk Jeroen W Method Of Installing An Epoxidation Catalyst In A Reactor, A Method Of Preparing An Epoxidation Catalyst, An Epoxidation Catalyst, A Process For The Preparation Of An Olefin Oxide Or A Chemical Derivable From An Olefin Oxide, And A Reactor Suitable For Such A Process
CA2635224C (en) 2005-12-28 2014-04-01 Chevron U.S.A. Inc. Molecular sieve ssz-74 composition of matter and synthesis thereof
US20070149778A1 (en) 2005-12-28 2007-06-28 Chevron U.S.A. Inc. Beckmann rearrangement using molecular sieve ssz-74
US7357904B2 (en) 2005-12-28 2008-04-15 Chevron Corporation Reduction of oxides of nitrogen in a gas stream using molecular sieve SSZ-74
US20080115666A1 (en) * 2005-12-28 2008-05-22 Chevron U.S.A. Inc. Gas separation using molecular sieve ssz-74
US7510697B2 (en) 2005-12-28 2009-03-31 Chevron U.S.A. Inc. Molecular sieve SSZ-74 composition of matter and synthesis thereof
US7432402B2 (en) 2005-12-28 2008-10-07 Chevron U.S.A. Partial oxidation using molecular sieve SSZ-74
US7422732B2 (en) 2005-12-28 2008-09-09 Chevron U.S.A. Inc Synthesis of amines using molecular sieve SSZ-74
US7473807B2 (en) 2005-12-28 2009-01-06 Chevron Usa, Inc. Acylation using molecular sieve SSZ-74
US7762059B2 (en) 2005-12-28 2010-07-27 Chevron U.S.A. Inc. Treatment of engine exhaust using molecular sieve SSZ-74
EP2457887A1 (en) 2006-02-03 2012-05-30 GRT, Inc. Continuous process for converting natural gas to liquid hydrocarbons
BRPI0707490A2 (pt) 2006-02-03 2011-05-03 Grt Inc separação de gases leves de halogênios
GB0602424D0 (en) 2006-02-07 2006-03-22 Sinclair Pharmaceuticals Ltd Compounds
EP2397457A3 (en) 2006-03-23 2013-11-20 Velocys Inc. Process for making styrene using microchannel process technology
EP1837320A1 (en) 2006-03-23 2007-09-26 ETH Zürich Production of saturated C2 to C5 hydrocarbons
JP2007269708A (ja) 2006-03-31 2007-10-18 Sumitomo Chemical Co Ltd 第３級オレフィンおよび脂肪族アルコールの製造方法
US20070238905A1 (en) 2006-04-05 2007-10-11 Victor Manuel Arredondo Processes for converting glycerol to glycerol ethers
BRPI0601460B1 (pt) 2006-04-26 2015-11-10 Petroleo Brasileiro Sa processo para hidroconversão de mistura de óleos orgânicos de diferentes origens
WO2007130054A1 (en) 2006-05-08 2007-11-15 Exxonmobil Chemical Patents Inc. Improved catalyst composition
US8222468B2 (en) 2006-05-08 2012-07-17 Exxonmobil Chemical Patents Inc. Organic compound conversion process
US7268263B1 (en) 2006-05-18 2007-09-11 Uop Llc Integrated process for aromatics production
US7304193B1 (en) 2006-05-18 2007-12-04 Uop Llc Integrated process for aromatics production
KR101385396B1 (ko) 2006-06-08 2014-04-14 셰브런 유.에스.에이.인크. 분자체 ｓｓｚ-75 조성물 및 이의 합성
WO2007141295A1 (en) 2006-06-08 2007-12-13 High Point Pharmaceuticals, Llc Process for preparing phenoxy acetic acid derivatives
US7906099B2 (en) 2006-06-09 2011-03-15 Exxonmobil Chemical Patents Inc. Intergrown molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins
AP2009004811A0 (en) 2006-09-21 2009-04-30 Albemarle Corp Methods for conversion of methane to useful hydrocarbons and catalysts for use therein
RU2009114847A (ru) 2006-09-21 2010-10-27 Альбермарл Корпорейшн (Us) Способы превращения метана в пригодные углеводороды, катализаторы для применения в таких способах и регенерация катализаторов
EP2125676A1 (en) 2007-02-28 2009-12-02 Albemarle Corporation Processes for producing higher hydrocarbons from methane and bromine
JP2010527358A (ja) 2007-05-14 2010-08-12 ジーアールティー インコーポレイテッド ハロゲンの電解回収とともに炭化水素原料を変換させるプロセス
KR20100027141A (ko) 2007-05-24 2010-03-10 지알티, 인코포레이티드 가역적으로 할로겐화수소를 흡수 및 방출할 수 있는 존 반응기
WO2008157047A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing hydrogen from hydrocarbon feed sources
WO2008157045A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from hydrocarbon feed sources
WO2008157046A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from methane
WO2008157044A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from methane
WO2008157043A1 (en) 2007-06-14 2008-12-24 Albemarle Corporation Processes for producing higher hydrocarbons from methane
AU2009270801B2 (en) 2008-07-18 2014-04-24 Reaction 35, Llc Continuous process for converting natural gas to liquid hydrocarbons
US7812201B2 (en) * 2008-10-01 2010-10-12 Targa Resources, Inc. Process and catalyst for converting alkanes

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11884607B2 (en) 2018-08-24 2024-01-30 Honeywell International Inc. Processes for producing trifluoroiodomethane and trifluoroacetyl iodide
CN113767064A (zh) * 2019-04-16 2021-12-07 霍尼韦尔国际公司 用于由氢气和碘制造碘化氢的整合方法和催化剂
CN113767064B (zh) * 2019-04-16 2024-03-22 霍尼韦尔国际公司 用于由氢气和碘制造碘化氢的整合方法和催化剂

Also Published As

Publication number Publication date
NZ581216A (en) 2011-06-30
AU2008256606A1 (en) 2008-12-04
JP2010528054A (ja) 2010-08-19
ZA200908155B (en) 2010-07-28
KR20100027141A (ko) 2010-03-10
US20090127163A1 (en) 2009-05-21
AP2010005097A0 (en) 2009-12-31
US7998438B2 (en) 2011-08-16
CO6251310A2 (es) 2011-02-21
EA200970992A1 (ru) 2010-06-30
TN2009000485A1 (en) 2011-03-31
NO20093359L (no) 2010-02-17
CA2687589A1 (en) 2008-12-04
US20110270003A1 (en) 2011-11-03
EP2148846A1 (en) 2010-02-03
EA017699B1 (ru) 2013-02-28
WO2008148113A1 (en) 2008-12-04
MX2009012581A (es) 2010-03-15
ECSP099748A (es) 2010-02-26

Similar Documents

Publication Publication Date Title
CN101765574A (zh) 使卤化氢可逆性俘获与释放相结合的区域反应器
CN101484406B (zh) 天然气转化为液体烃的连续方法
US8173851B2 (en) Processes for converting gaseous alkanes to liquid hydrocarbons
CN102099316B (zh) 天然气转化为液体烃的连续方法
US9206093B2 (en) Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7674941B2 (en) Processes for converting gaseous alkanes to liquid hydrocarbons
CN102482083A (zh) 将溴化氢转化成单质溴
CN102781881A (zh) 用于分阶段合成烷基溴的方法和***
CN103998397A (zh) 用于在循环催化剂反应器-再生器***中将烷基溴化物转化为较高分子量烃的方法和***
AU2012200808A1 (en) Continuous process for converting natural gas to liquid hydrocarbons

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1143573

Country of ref document: HK

C02 Deemed withdrawal of patent application after publication (patent law 2001)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20100630

REG Reference to a national code

Ref country code: HK

Ref legal event code: WD

Ref document number: 1143573

Country of ref document: HK