CN101545061B - Multivariate interalloy and smelting method thereof - Google Patents
Multivariate interalloy and smelting method thereof Download PDFInfo
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- CN101545061B CN101545061B CN200910061893XA CN200910061893A CN101545061B CN 101545061 B CN101545061 B CN 101545061B CN 200910061893X A CN200910061893X A CN 200910061893XA CN 200910061893 A CN200910061893 A CN 200910061893A CN 101545061 B CN101545061 B CN 101545061B
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Abstract
The invention relates to a multivariate interalloy and a smelting method thereof. AI is taken as a base, other metals comprising Mn, Si, Fe, Ni, Co, Nb and Ti are added in certain ratio, and the AI and the added two or more metals form a ternary interalloy, a quaternary interalloy and a quinary interalloy. The interalloy and the method have the advantages that: 1, a stokehold material has stable chemical composition, the first time quality can reach 98 percent; 2, the cost is reduced, flash melt is realized, the time for liquid copper in a smelting furnace is shortened, metal oxide is reducedand the casting yield is improved; 3, the production period is quickened and the interalloy can be continuously produced; 4, the interalloy has short melting time, and the quinary interalloy AI-Fe-Co-Ni-Si is taken as an example, only thirty-five minutes is needed to melt one furnace of the quinary interalloy AI-Fe-Co-Ni-Si (400kg), while at least one hour is needed to melt Cu-Co, Cu-Ni and the like; and 5, when the interalloy is used, the alloy types are few, so the management is easy.
Description
Technical field
The present invention relates to the alloy melting technical field, a kind of specifically polynary master alloy and melting method thereof.
Background technology
In producing special brass, as adopt the method for melting once (being that whole elements use simple substance to melt in smelting furnace) can be subjected to a lot of restrictions, material mark FA6100 as my company's production, contain the very high metallic element of fusing point: Co among the FA-5806, Ni, Fe, Ti etc., its fusing point: Co 1492, Ni 1455, Fe 1537, Ti 1660, and the flame temperature of brass is between 1100 ℃~1300 ℃, under this temperature be the simple substance that is difficult to surface element in the fusing, solving this type of problem only adds before the zinc in fusion process, with top simple substance fusing, this just needs fusing time long, and it is high that temperature is wanted, its consequence is splashed when adding zinc exactly, and (zinc surface has zinc oxide greatly, the easy moisture absorption, and copper liquid is met water and just is easy to generate and splashes, What is more can quick-fried stove), each simple substance melting loss of elements is big, chemical composition stability is poor, and the production cycle is long, and unsuitable continuous production.
Shortcoming based on top melting once, adopt the technology of secondary smelting just to arise at the historic moment, its process is exactly that element and the low-melting elementary composition master alloy that fusing point is high melts earlier, in actual production process master alloy is melted with Cu, Zn etc., the target that reaches our desired each element is formed content.
The master alloy of domestic production at present is generally binary alloy as Al-Fe, Cu-Co, Cu-Ni etc., in adopting these alloy processes a lot of inconvenience is arranged also, and one, batching is complicated, the alloy number is more to be mixed up easily; Two, procurement cycle longer, let funds lie idle easily; Three, increase cost, burn out rate increases; Four, the stokehold is transferred and is added the comparison difficulty, increases the production cycle; Five, be unfavorable for continuous production, the fusing point of some master alloy is higher, as Nb-Fe.
Summary of the invention
The objective of the invention is to develop a kind of burn-off rate fast, reduce burning, yield rate height, polynary master alloy and melting method thereof that temperature of fusion is low.
The polynary master alloy of the present invention, be to be base with Al, add a certain proportion of other metals to the centre, comprise Mn, Si, Fe, Ni, Co, Nb, Ti, form ternary master alloy, quaternary master alloy, five yuan of master alloys with the two or more metals that add wherein.
The weight percentages of components of ternary master alloy is:
Al 20~50
Mn 30~60
Si 10~25
Or
Al 30~50
Mn 20~40
Fe 18~35
The weight percentages of components of quaternary master alloy is:
Al 20~40
Mn 40~60
Ni 4~8
Si 10~18
Or
Al 25~50
Mn 25~45
Ni 3~22
Fe 12~25
The weight percentages of components of five yuan of master alloys is:
Al 30~45
Ni 20~40
Si 5~15
Co 2~13
Fe 3~14
Or
Al 30~45
Nb 1~6
Ni 18~35
Ti 5~16
Fe 6~16
A kind of melting method of ternary master alloy, its step is as follows:
1, elder generation puts into 4/5 Al ingot in smelting furnace, arranges along the furnace wall, the fusing that heats up, and furnace power is 150~250KW;
When 2, treating that Al is fused into solution, add whole Si in batches;
3, observe solution surface, when solution surface is turned white, in stove, add whole metal M n, power 180~250KW in batches;
4, after the metal M n fusing, add remaining metal A l, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1250 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
A kind of melting method of quaternary master alloy, its step is as follows:
1, elder generation puts into 4/5 Al ingot in smelting furnace, arranges along the furnace wall, and whole Ni are put in the middle of stove, the fusing that heats up, and furnace power is 150~250KW;
When 2, treating that Al is fused into solution, and color adds whole Si when dark red in batches, continues the fusing that heats up, power 150~250KW;
3, observe solution surface, when solution surface is turned white, in stove, add whole metal M n, the fusing that heats up, furnace power 180~250KW in batches;
4, after metal M n has melted, add remaining metal A l, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1200 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
A kind of melting method of five yuan of master alloys, its step is as follows:
1, put into earlier 2/3 Al ingot in smelting furnace, arrange along the furnace wall, whole Fe are put in the middle of stove, and lumpiness≤250mm of Fe is put 18%~36% Ni above, and is sturdy, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out; In stove, add whole metal Co, after Co adds, add 1/6 Al ingot;
3, blow-on adds whole Si and remaining metal Ni successively; The fusing that heats up, furnace power is 100~250KW;
4, after Si in the solution and the whole fusings of Ni, in stove, add remaining metal A l ingot, continue to heat up and melt; Furnace power is 200~300KW;
5, be warming up to about 1300 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
The advantage of polynary master alloy of the present invention and melting method thereof is: when adopting this master alloy, chemical composition stability, it is more convenient to prepare burden, particularly the alloy scaling loss is few, because master alloy is to be the alloy of base with Al, the fusing point of Al is low, after other element simple substance adds, the process that an alloying is arranged, as top master alloy when fusing Al and Fe a thermopositive reaction is arranged, utilize this thermopositive reaction can well be, so the burn out rate when having reduced its melting has been saved electric power with fusings such as Ni, Co.When secondary smelting afterwards, because this master alloy fusing point is lower, can be under lower temperature and copper liquid alloying, therefore have a lot of benefits when using multicomponent alloy: 1, the stokehold material chemical composition is more stable, once inspects qualification rate by ready samples and can reach 98%; 2, cost reduces, and adopts this master alloy to realize quick fusing, has shortened the time of copper liquid in smelting furnace, has reduced burning, and yield rate improves.Material burn out rate when not adopting master alloy according to statistics reaches 13%, and after adopting master alloy, burn out rate is generally about 8%; 3, accelerated the production cycle, but continuous production, adopt melting once when fusing second stove, copper liquid in the smelting furnace must be ladled out dried, so that input simple substance Cu, Al, Fe, Co, Ni, Si melt, the fusing back adds Zn, and this method fusing time is long, in stove amount 250Kg, melt a stove and got one and a half hours.And when adopting master alloy to melt second stove, can stay a spot of copper liquid in the smelting furnace, and shortened smelting time like this, equally in 250Kg, only need 45 minutes; 4, the master alloy fusing time is short, is example with five yuan of master alloy: Al-Fe-Co-Ni-Si equally, and melting this stove (400Kg) only needs 45 minutes, and Cu-Co, Cu-Ni etc. need one hour at least; When 5, using master alloy, alloy species is few, is easy to management.
Embodiment
Embodiment one
A kind of ternary master alloy, its weight percentages of components is:
Al 20
Mn 60
Si 20
A kind of melting method of ternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, in smelting furnace, put into 3 on Al ingot earlier, about 63Kg, the Al ingot is arranged along the furnace wall, the fusing that heats up, furnace power is 150~250KW;
When 2, treating that Al is fused into solution, add metal Si 80Kg (add 15Kg at every turn, added once in per three minutes) in batches, continue the fusing that heats up;
3, observe solution surface, when solution surface is turned white, in stove, add metal M n_240Kg (add 25Kg at every turn, added once in per two minutes), power 180~250KW in batches;
4, after the metal M n fusing, add remaining metal A l 17Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1250 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment two
A kind of ternary master alloy, its weight percentages of components is:
Al 50
Mn 35
Si 15
A kind of melting method of ternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, in smelting furnace, put into 5 on Al ingot earlier, about 105Kg, the Al ingot is arranged along the furnace wall, the fusing that heats up, furnace power is 150~250KW;
When 2, treating that Al is fused into solution, and color adds metal Si60Kg (add 15Kg at every turn, added once in per three minutes) when dark red in batches, continues the fusing that heats up;
3, observe solution surface, when solution surface is turned white, in stove, add metal M n140Kg (add 25Kg at every turn, added once in per two minutes), power 180~250KW in batches;
4, after metal M n has melted, add remaining metal A l95Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1200 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment three
A kind of ternary master alloy, its weight percentages of components is:
Al 35
Mn 47.5
Si 17.5
A kind of melting method of ternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, in smelting furnace, put into 4 on Al ingot earlier, about 84Kg, the Al ingot is arranged along the furnace wall, the fusing that heats up, furnace power is 150~250KW;
When 2, treating that Al is fused into solution, and color adds metal Si70Kg (add 15Kg at every turn, added once in per three minutes) when dark red in batches, continues the fusing that heats up;
3, observe solution surface, when solution surface is turned white, in stove, add metal M n190Kg (add 25Kg at every turn, added once in per two minutes), power 180~250KW in batches;
4, after metal M n has melted, add remaining metal A l 56Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1250 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment four
A kind of ternary master alloy, its weight percentages of components is:
Al 30
Mn 40
Fe 30
A kind of melting method of ternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe120Kg (all put into, the lumpiness of Fe≤250mm), in a down-to-earth manner, after the fusing that heats up, furnace power is 200~300KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out; Slagging-off;
3, blow-on adds metal M n 160Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 150~250KW in batches in stove;
4, after metal M n has melted, add remaining metal A l 36Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment five
A kind of ternary master alloy, its weight percentages of components is:
Al 50
Mn 25
Fe 25
A kind of melting method of ternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe100Kg (all put into, the lumpiness of Fe≤250mm), in a down-to-earth manner, after the fusing that heats up, furnace power is 200~300KW;
When 2, slight reaction sound being arranged in hearing stove, after the power of reduction smelting furnace: 50~100KW treats that total overall reaction is intact, blowing out, slagging-off;
3, blow-on adds metal M n 100Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 150~250KW in batches in stove;
4, after metal M n has melted, add remaining metal A l 116Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1300 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment six
A kind of ternary master alloy, its weight percentages of components is:
Al 40
Mn 33.5
Fe 26.5
A kind of melting method of ternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe106Kg (all put into, the lumpiness of Fe≤250mm), in a down-to-earth manner, after the fusing that heats up, furnace power is 200~300KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out, slagging-off;
3, in stove, add metal M n 134Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 150~250KW in batches;
4, after metal M n has melted, add remaining metal A l 76Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1300 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment seven
A kind of quaternary master alloy, its weight percentages of components is:
Al 20
Mn 60
Ni 4
Si 16
A kind of melting method of quaternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, in smelting furnace, put into 3 on Al ingot earlier, about 63Kg, the Al ingot is arranged along the furnace wall, and Ni16Kg is put in the middle of stove, and (all put into, the lumpiness of Ni≤200mm), intensification is melted, and furnace power is 150~250KW;
When 2, treating that Al is fused into solution, and color adds metal Si64Kg (add 15Kg at every turn, added once in per three minutes) when dark red in batches, continues the fusing that heats up, power 150~250KW;
3, observe solution surface, when solution surface is turned white, in stove, add metal M n240Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 180~250KW in batches;
4, after metal M n has melted, add remaining metal A l 17Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1200 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment eight
A kind of quaternary master alloy, its weight percentages of components is:
Al 40
Mn 40
Ni 8
Si 12
A kind of melting method of quaternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, in smelting furnace, put into 4 on Al ingot earlier, about 84Kg, the Al ingot is arranged along the furnace wall, and Ni32Kg is put in the middle of stove, and (all put into, the lumpiness of Ni≤200mm), intensification is melted, and furnace power is 150~250KW;
When 2, treating that Al is fused into solution, and color adds metal Si48Kg (add 15Kg at every turn, added once in per three minutes) when dark red in batches, continues the fusing that heats up, power 150~250KW;
3, observe solution surface, when solution surface is turned white, in stove, add metal M n160Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 180~250KW in batches;
4, after metal M n has melted, add remaining metal A l 76Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1250 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment nine
A kind of quaternary master alloy, its weight percentages of components is:
Al 30
Mn 50
Ni 6
Si 14
A kind of melting method of quaternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, in smelting furnace, put into 4 on Al ingot earlier, about 84Kg, the Al ingot is arranged along the furnace wall, and Ni 24Kg is put in the middle of stove, and (all put into, the lumpiness of Ni≤200mm), intensification is melted, and furnace power is 150~250KW;
When 2, treating that Al is fused into solution, and color adds metal Si56Kg (add 15Kg at every turn, added once in per three minutes) when dark red in batches, continues the fusing that heats up, power 150~250KW;
3, observe solution surface, when solution surface is turned white, in stove, add metal M n200Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 180~250KW in batches;
4, after metal M n has melted, add remaining metal A l 36Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1250 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment ten
A kind of quaternary master alloy, its weight percentages of components is:
Al 25
Mn 45
Ni 5
Fe 25
A kind of melting method of quaternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 3 on Al ingot, about 63Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe100Kg (all put into, the lumpiness of Fe≤250mm), put Ni 20Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out, slagging-off;
3, blow-on adds metal M n180Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power 150~300KW in batches in stove;
4, treat in the solution Mn all after the fusing, block-by-block adds remaining metal A l 37Kg in stove, continues the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 11
A kind of quaternary master alloy, its weight percentages of components is:
Al 50
Mn 25
Ni 13
Fe 12
A kind of melting method of quaternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe48Kg (all put into, the lumpiness of Fe≤250mm), put Ni52Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out, slagging-off;
3, blow-on adds metal M n100Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power: 150~300KW in batches in stove;
4, treat in the solution Mn all after the fusing, block-by-block adds remaining metal A l 116Kg in stove, continues the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1300 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 12
A kind of quaternary master alloy, its weight percentages of components is:
Al 37.5
Mn 35
Ni 9
Fe 18.5
A kind of melting method of quaternary master alloy, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe74Kg (all put into, the lumpiness of Fe≤250mm), put Ni36Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out, slagging-off;
3, blow-on adds metal M n140Kg (add 25Kg at every turn, added once in per two minutes), the fusing that heats up, furnace power: 150~300KW in batches in stove;
4, treat in the solution Mn all after the fusing, block-by-block adds remaining metal A l 66Kg in stove, continues the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1300 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 13
A kind of five yuan of master alloys, its weight percentages of components is:
Al 30
Ni 40
Si 5
Co 13
Fe 12
A kind of melting method of five yuan of master alloys, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe48Kg (all put into, the lumpiness of Fe≤250mm), put Ni 30Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out; In stove, add metal Co 52Kg (add 20Kg at every turn, added once in per five minutes) in batches, after Co adds, add 1 on Al ingot, about 21Kg;
3, blow-on adds metal Si20Kg and remaining metal Ni130Kg successively; The fusing that heats up, furnace power is 100~250KW;
4, after Si in the solution and the whole fusings of Ni, in stove, add remaining metal A l 15Kg, continue to heat up and melt; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 14
A kind of five yuan of master alloys, its weight percentages of components is:
Al 47
Ni 21
Si 16
Co 2
Fe 14
A kind of melting method of five yuan of master alloys, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe56Kg (all put into, the lumpiness of Fe≤250mm), put Ni30Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out; In stove, add metal Co 8Kg, after Co adds, add 2 on Al ingot, about 42Kg;
3, blow-on adds metal Si64Kg (add 15Kg at every turn, added once in per three minutes) and remaining metal Ni54Kg successively; The fusing that heats up, furnace power is 100~250KW;
4, after Si in the solution and the whole fusings of Ni, in stove, add remaining metal A l 62Kg, continue to heat up and melt; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 15
A kind of five yuan of master alloys, its weight percentages of components is:
Al 42
Ni 33
Si 12
Co 8
Fe 5
A kind of melting method of five yuan of master alloys, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 4 on Al ingot, about 84Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe20Kg (all put into, the lumpiness of Fe≤250mm), put Ni40Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out; In stove, add metal Co 32Kg (add 20Kg at every turn, added once in per five minutes), after Co adds, add 2 on Al ingot, about 42Kg;
3, blow-on adds metal Si48Kg (add 15Kg at every turn, added once in per three minutes) and remaining metal Ni92Kg successively; The fusing that heats up, furnace power is 100~250KW;
4, after Si in the solution and the whole fusings of Ni, in stove, add remaining metal A l 42Kg, continue to heat up and melt; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 16
A kind of five yuan of master alloys, its weight percentages of components is:
Al 45
Nb 6
Ni 18
Ti 16
Fe 15
A kind of melting method of five yuan of master alloys, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 5 on Al ingot, about 105Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe4Kg (all put into, the lumpiness of Fe≤250mm), put Ni72Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out; Slagging-off;
3, blow-on adds binary alloy Nb-Fe (content 51% of Nb) 47Kg in batches in stove, add 20Kg at every turn, added once in per five minutes); After Nb-Fe has melted, add solubility promoter, add binary alloy Ti-Fe (content 66% of Ti) 97Kg more in batches, add 15Kg at every turn, added once in per three minutes), the fusing that heats up, the power of electric furnace: 150~250KW;
4, after the Ti-Fe in the solution all melts, in stove, add remaining metal A l 75Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 17
A kind of five yuan of master alloys, its weight percentages of components is:
Al 60
Nb 1
Ni 18
Ti 5
Fe 16
A kind of melting method of five yuan of master alloys, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 5 on Al ingot, about 105Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe 50Kg (all put into, the lumpiness of Fe≤250mm), put Ni72Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out, slagging-off;
3, blow-on adds binary alloy Nb-Fe (content 51% of Nb) 7.8Kg in batches in stove; After Nb-Fe has melted, add solubility promoter, add binary alloy Ti-Fe (content 66% of Ti) 30Kg (add 15Kg at every turn, added once in per three minutes) again, the fusing that heats up, the power of electric furnace: 150~250KW in batches;
4, after the Ti-Fe in the solution all melts, in stove, add remaining metal A l 135Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Embodiment 18
A kind of five yuan of master alloys, its weight percentages of components is:
Al 54.6
Nb 2.4
Ni 22
Ti 10
Fe 11
A kind of melting method of five yuan of master alloys, its step is as follows: (in stove amount 400Kg, intermediate frequency furnace melting)
1, earlier in smelting furnace, put into 5 on Al ingot, about 105Kg, the Al ingot is arranged along the furnace wall, the middle of stove put Fe 14.2Kg (all put into, the lumpiness of Fe≤250mm), put Ni88Kg above, in a down-to-earth manner, after the fusing that heats up, furnace power is 150~250KW;
When 2, slight reaction sound being arranged in hearing stove, reduce the power of smelting furnace: 50~100KW, treat that total overall reaction is intact after, blowing out, slagging-off;
3, blow-on adds binary alloy Nb-Fe (content 51% of Nb) 18.8Kg in batches in stove; After Nb-Fe has melted, add solubility promoter, add binary alloy Ti-Fe (content 66% of Ti) 60.6Kg (add 15Kg at every turn, added once in per three minutes) again, the fusing that heats up, the power of electric furnace: 150~250KW in batches;
4, after the Ti-Fe in the solution all melts, in stove, add remaining metal A l 113.4Kg, continue the fusing that heats up; Furnace power is 200~300KW;
5, be warming up to about 1350 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6, prepare cast and cast spindle.
Claims (2)
1. polynary master alloy, it is characterized in that: be base with Al, add a certain proportion of Mn, Si, Fe, Ni, Co, Nb, Ti metal to the centre, form ternary master alloy, quaternary master alloy, five yuan of master alloys with two or three or four metals of adding wherein;
The weight percentages of components of described ternary master alloy is:
Al 20~50
Mn 30~60
Si 10~25
Or
Al 30~50
Mn 20~40
Fe 18~35;
The weight percentages of components of described quaternary master alloy is:
Al 20~40
Mn 40~60
Ni 4~8
Si 10~18
Or
Al 25~50
Mn 25~45
Ni 3~22
Fe 12~25;
The weight percentages of components of described five yuan of master alloys is:
Al 30~45
Ni 20~40
Si 5~15
Co 2~13
Fe 3~14
Or
Al 30~45
Nb 1~6
Ni 18~35
Ti 5~16
Fe 6~16。
2. polynary master alloy melting method according to claim 1 is characterized in that:
The melting method of described ternary master alloy, its step is as follows:
1. in smelting furnace, put into earlier 4/5 Al ingot, arrange along the furnace wall, the fusing that heats up, furnace power is 150~250KW;
When treating that 2. A1 is fused into solution, add whole Si in batches;
3. observe solution surface, when solution surface is turned white, in stove, add whole metal M n, power 180~250KW in batches;
4. after the metal M n fusing, add remaining metal A l, continue the fusing that heats up; Furnace power is 200~300KW;
5. be warming up to about 1250 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6. prepare cast and cast spindle;
Perhaps: the melting method of quaternary master alloy, its step is as follows:
1. put into earlier 4/5 Al ingot in smelting furnace, arrange along the furnace wall, whole Ni are put in the middle of stove, the fusing that heats up, and furnace power is 150~250KW;
When treating that 2. Al is fused into solution, and color adds whole Si when dark red in batches, continues the fusing that heats up, power 150~250KW;
3. observe solution surface, when solution surface is turned white, in stove, add whole metal M n, the fusing that heats up, furnace power 180~250KW in batches;
4. after metal M n has melted, add remaining metal A l, continue the fusing that heats up; Furnace power is 200~300KW;
5. be warming up to about 1200 ℃, be incubated 20~30 minutes, blowing out is stirred, slagging-off;
6. prepare cast and cast spindle;
Perhaps: the melting method of five yuan of master alloys, its step is as follows:
1. put into earlier 2/3 Al ingot in smelting furnace, arrange along the furnace wall, whole Fe are put in the middle of stove, and lumpiness≤250mm of Fe is put 18%~36% Ni above, and are sturdy, after the fusing that heats up, furnace power is 150~250KW;
When 2. slight reaction sound arranged, reduce the power of smelting furnace: 50~100KW in hearing stove, treat that total overall reaction is intact after, blowing out; In stove, add whole metal Co, after Co adds, add 1/6 Al ingot;
3. blow-on adds whole Si and remaining metal Ni successively; The fusing that heats up, furnace power is 100~250KW;
4. after Si in the solution and the whole fusings of Ni, in stove, add remaining metal A l ingot, continue to heat up and melt; Furnace power is 200~300KW;
5. be warming up to about 1300 ℃, be incubated 20~40 minutes, blowing out is stirred, slagging-off;
6. prepare cast and cast spindle.
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CN101928848B (en) * | 2010-09-01 | 2012-05-23 | 武汉泛洲中越合金有限公司 | Method for smelting copper alloy by Fe-containing intermediate alloy |
CN102618739B (en) * | 2012-04-18 | 2013-11-13 | 上海康臣特种金属材料有限公司 | Aluminum molybdenum vanadium chromium iron intermediate alloy and preparation method thereof |
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CN108179329B (en) * | 2017-12-04 | 2020-01-03 | 江苏大学 | Method for improving microalloying effect of rare earth elements in cast aluminum-silicon alloy |
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