CN101426867B - Paste composition for printing - Google Patents
Paste composition for printing Download PDFInfo
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- CN101426867B CN101426867B CN2007800140715A CN200780014071A CN101426867B CN 101426867 B CN101426867 B CN 101426867B CN 2007800140715 A CN2007800140715 A CN 2007800140715A CN 200780014071 A CN200780014071 A CN 200780014071A CN 101426867 B CN101426867 B CN 101426867B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/10—Intaglio printing ; Gravure printing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/003—Printing processes to produce particular kinds of printed work, e.g. patterns on optical devices, e.g. lens elements; for the production of optical devices
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J11/00—Gas-filled discharge tubes with alternating current induction of the discharge, e.g. alternating current plasma display panels [AC-PDP]; Gas-filled discharge tubes without any main electrode inside the vessel; Gas-filled discharge tubes with at least one main electrode outside the vessel
- H01J11/20—Constructional details
- H01J11/22—Electrodes, e.g. special shape, material or configuration
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J9/00—Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
- H01J9/02—Manufacture of electrodes or electrode systems
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/09—Use of materials for the conductive, e.g. metallic pattern
- H05K1/092—Dispersed materials, e.g. conductive pastes or inks
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2211/00—Plasma display panels with alternate current induction of the discharge, e.g. AC-PDPs
- H01J2211/20—Constructional details
- H01J2211/22—Electrodes
- H01J2211/225—Material of electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2211/00—Plasma display panels with alternate current induction of the discharge, e.g. AC-PDPs
- H01J2211/20—Constructional details
- H01J2211/34—Vessels, containers or parts thereof, e.g. substrates
- H01J2211/44—Optical arrangements or shielding arrangements, e.g. filters or lenses
- H01J2211/446—Electromagnetic shielding means; Antistatic means
Abstract
The present invention provides a paste composition for printing, characterized by comprising a)5 to 30% by weight of an acrylate polymer resin; b)5 to 35 wt% of a high boiling point solvent having a boiling point of at least 200 ℃; c)5 to 35 wt% of a low boiling point solvent having a boiling point of less than 200 ℃; and d)50 to 85% by weight of a metal powder. The paste composition for printing of the present invention is particularly suitable for gravure offset printing, which can substantially solve the problem of reprocessing of materials occurring when manufacturing an electrode of a mesh filter for shielding electromagnetic waves or an electrode pattern for a plasma display panel using the existing photolithography method, while satisfying a variety of properties required for the paste composition, each of which is required for a printing process, so that appropriate offset printing performance can be exerted.
Description
Technical field
The present invention relates to paste composition for printing, relate more specifically to be particularly suitable for the paste composition for printing of intaglio offset (gravure offset printing), described composition can solve and use existing photolithography manufacturing to be used for the electrode of mesh gauze filter of shielding electromagnetic wave or the handling problem again of the material that occurs when being used for the electrode pattern of Plasmia indicating panel, simultaneously can satisfy the required multiple character of paste composition, in the described character each all is that printing process is required, thereby can bring into play suitable offset properties.
Background technology
Recently along with growing demand to the large size in the display unit, high-density, high precision and high reliability, develop multiple pattern treatment technology, and the composition of the fine electrode (fine electrode) that is suitable for this multiple pattern treatment technology about being used to form of a large amount of kinds is being carried out positive research.
Because Plasmia indicating panel (PDP) has fast the speed of response and compare easy maximization with display panels, therefore they have been used for various fields at present.Usually, use the patterning method of the electrode materials of silk screen print method to be used on PDP, forming electrode.But, existing silk screen print method needs very high state of the art, paste can leave substrate because of its lower viscosity in the screen printing process, causes the precision on the silk screen to reduce, be difficult in thus obtain in the existing silk screen print method PDP required have a high-precision giant-screen pattern.And, in existing silk screen print method, short circuit (short) or opening might appear on the silk screen during printing.
Recently, the photolithography of having developed usability photopolymer resin composition is suitable for large-area high precision electrode circuits with formation.These methods are following carries out: form uniform thick film by the print process of using the photosensitive resin composition that is dispersed with conductive powders on it, the mask that has required configuration by use exposes then by using alkaline development solution to embody essential pattern to the thick film that forms thus.
But, when using above-mentioned photolithography to form pattern, need handle again to save manufacturing cost the material that is removed in the developing process, still underway about its a large amount of discussion.
Be to solve foregoing problems, carrying out now about on substrate, directly forming the research of required method of patterning, as in the Printing industry formerly shown in widely used gravure offset or the ink jet printing method.
Summary of the invention
Technical problem
For solving the problems referred to above of prior art, an object of the present invention is to provide a kind of paste composition for printing, said composition is particularly suitable for the intaglio offset mode, and the problem of pretreatment that can solve the material that occurs at developing process when using existing photolithography to be formed for the electrode pattern of mesh gauze filter Plasmia indicating panel or that be used for shielding electromagnetic wave to be saving manufacturing cost, and the method for the electrode of the mesh gauze filter that the method for using above-mentioned paste composition to form the plasma panel show electrode or preparation be used for shielding electromagnetic wave is provided.
In addition, another object of the present invention provides a kind of paste composition for printing, described composition can satisfy as the required multiple character of composition, in the described character each all is that printing process is required, thereby can bring into play suitable offset properties, and the method for the electrode of the method for the above-mentioned paste composition formation of use plasma panel show electrode or the mesh gauze filter that preparation is used for shielding electromagnetic wave is provided.
Technical scheme
For achieving the above object, the invention provides a kind of paste composition for printing, described composition comprises:
A) acrylate polymer resin of 5 weight %～30 weight %;
B) 5 weight %～boiling point of 35 weight % is at least 200 ℃ high boiling solvent;
C) 5 weight %～boiling point of 35 weight % is lower than 200 ℃ low boiling point solvent; With
D) metal-powder of 50 weight %～85 weight %.
In addition, the invention provides the method that forms the plasma panel show electrode, described method comprises that the gravure offset by using above-mentioned paste composition for printing forms pattern.
In addition, the invention provides the method for the electrode of the mesh gauze filter that is formed for shielding electromagnetic wave, described method comprises that the gravure offset by using above-mentioned paste composition for printing forms pattern.
Advantageous effects
Paste composition according to the present invention is suitable for directly forming the intaglio offset mode of fine pattern, and the method than existing photolithography class has excellent cost savings effect, simultaneously, these compositions can satisfy the required multiple character of composition (each in the described character all is that printing process is required), thereby can bring into play suitable offset properties.
Description of drawings
Fig. 1 is the photo that show to use according to minimum feature behind the intaglio offset of the paste composition for printing of embodiments of the invention and comparative example preparation.
Embodiment
Describe the present invention below.
The inventor finds, for preparing the intaglio offset paste composition that can satisfy as the required multiple character of composition (each in the described character all is that printing process is required), use has the acrylic ester polymer of suitable molecular weight to bring into play the required suitable elastic properties of OFF mode and to use suitable volatile solvent so that favourable calcining characteristic to be provided in the SET mode, the result can make the paste composition for printing that is suitable for gravure offset, and thereby finishes the present invention.
Paste composition for printing of the present invention comprises a) acrylate polymer resin of 5 weight %～30 weight %; B) 5 weight %～boiling point of 35 weight % is at least 200 ℃ high boiling solvent; C) 5 weight %～boiling point of 35 weight % is lower than 200 ℃ low boiling point solvent; And d) metal-powder of 50 weight %～85 weight %.
For a) acrylate polymer resin of using in the present invention, can use acrylate polymer resin commonly used, and preferably make by the undersaturated carboxylic acid monomer of polymerization, aromatic monomer and other monomers.
Described undersaturated carboxylic acid monomer's effect is to strengthen by the hydrogen bond in the polymkeric substance elasticity of polymkeric substance, particularly can use vinylformic acid, methacrylic acid, methylene-succinic acid, toxilic acid, fumaric acid, vinyl-acetic ester, its anhydride form or the like.
Preferably, amount with whole monomeric 20 weight %～50 weight % of being used to prepare acrylate polymer resin comprises described undersaturated carboxylic acid monomer, in the time of in content falls into above-mentioned scope, prevent when the elastic properties of polymkeric substance, polymerization that the control of the gelling and the polymerization degree all can be met.
The effect of described aromatic monomer is closely bonding of formation and substrate and stable pattern, particularly can use vinylbenzene, benzyl methacrylate, benzyl acrylate, phenyl acrylate, phenyl methacrylate, vinylformic acid 2-nitro phenyl ester, vinylformic acid 4-nitro phenyl ester, methacrylic acid 2-nitro phenyl ester, methacrylic acid 4-nitro phenyl ester, methacrylic acid 2-nitrobenzyl ester, methacrylic acid 4-nitrobenzyl ester, vinylformic acid 2-chlorobenzene ester, vinylformic acid 4-chlorobenzene ester, methacrylic acid 2-chlorobenzene ester, methacrylic acid 4-chlorobenzene ester etc.
Preferably, to be used to prepare the whole monomeric 10 weight %～30 weight % of acrylate polymer resin, more preferably the amount of 15 weight %～20 weight % comprises described aromatic monomer.In the time of in content falls into above-mentioned scope, closely bond with substrate, the bonding strength of pattern, the directivity of established pattern, the formation of stable pattern and the easy elimination in the calcination process all can be met.
Except described undersaturated carboxylic acid monomer and aromatic monomer, other monomeric effects that are used to prepare acrylate polymer resin are the second-order transition temperature and the polarity of the described polymkeric substance of control.
For described other monomers, can use (methyl) vinylformic acid 2-hydroxy methacrylate, (methyl) vinylformic acid 2-hydroxyl monooctyl ester, (methyl) methyl acrylate, (methyl) ethyl propenoate or n-butyl acrylate, consider thermotolerance and second-order transition temperature with the closely bonding of substrate, described polymkeric substance, preferably the amount with whole monomeric 20 weight %～60 weight % of being used to prepare acrylate polymer resin comprises described other monomers.
Described acrylate polymer resin can prepare at the above-mentioned monomer of polymerization in the presence of the solvent, thereby can prevent undersaturated carboxylic acid monomer in offset printing process, aromatic monomer and other monomeric gellings, and can control suitable volatilization character.
For described solvent, can use propylene glycol monomethyl ether, DPGME, propylene glycol monomethyl ether propionic ester, ethyl ether propionic ester, terpinol, propylene glycol monomethyl ether, dimethylamino formaldehyde, methyl ethyl ketone, diethylene glycol monobutyl ether, acetate of butyl carbitol, gamma-butyrolactone or ethyl lactate separately, perhaps use the mixture of above-mentioned substance.
The weight-average molecular weight that the acrylate polymer resin that obtains by the above-mentioned monomer of polymerization in the presence of solvent preferably has is 10,000～100,000, more preferably 20,000～50,000.In the time of in described weight-average molecular weight falls into above-mentioned scope, can solve following problem simultaneously: thus owing to cause the flow characteristics of polymkeric substance to strengthen in the OFF mode pattern being difficult to be transferred to the problem on the coverture (blanket) and because the composition that the over-drastic elastic properties of fluoropolymer resin causes is difficult to inject the problem of intaglio plate groove because of the second-order transition temperature of fluoropolymer resin is lower from the intaglio plate groove.
Preferably the amount with the 5 weight %～30 weight % of paste composition for printing of the present invention comprises described acrylate polymer resin.When this content during less than 5 weight % because the flexibility decrease of composition might go wrong in the OFF mode, and when its during above 30 weight %, the resistance of established pattern may increase.
In addition, the present invention comprises b) boiling point is at least 200 ℃ high boiling solvent.Described high boiling solvent is not limited to specific kind, as long as its boiling point more than 200 ℃, particularly, can use gamma-butyrolactone, acetate of butyl carbitol, Trivalin SF, methoxymethyl ether propionic ester, terpinol etc.
Preferably, the amount with the 5 weight %～35 weight % of paste composition for printing of the present invention comprises described high boiling solvent.When this content during less than 5 weight %, the mobile changing down of solvent becomes too fast, thereby the design transfer in the OFF pattern is difficult for carrying out in the printing process, and when it surpasses 35 weight %, the directivity of pattern reduces, this is because the flowing of the composition in the SET pattern when being difficult to the control offset printing, and the widening phenomenon and may worsen of pattern during printing.
In addition, the present invention comprises c) boiling point is lower than 200 ℃ low boiling point solvent.
Described low boiling point solvent is not limited to specific kind, as long as its boiling point is lower than 200 ℃, particularly can use propylene glycol monomethyl ether, DPGME, propylene glycol monomethyl ether propionic ester, ethyl ether propionic ester, propylene glycol monomethyl ether, methyl ethyl ketone, ethyl lactate etc.
Preferably, the amount with the 5 weight %～35 weight % of paste composition for printing of the present invention comprises described low boiling point solvent.When this content during less than 5 weight %, the directivity of pattern reduces, this is because the composition in the SET pattern flows when being difficult to the control offset printing, and the widening phenomenon and may worsen of when printing pattern, and when this content surpasses 35 weight %, mobile changing down becomes too fast, thereby the design transfer of OFF pattern is difficult for carrying out in the printing process.
Preferably, high boiling solvent b) and low boiling point solvent c) combined amount be below the 40 weight % of paste composition for printing of the present invention.When this content surpassed 40 weight %, the viscosity of paste reduced, thereby might make print performance.In addition, by the volatile solvent of suitable mixing high boiling solvent and low boiling point solvent, preferably with the viscosity controller of the final paste composition that is used for intaglio offset 5,000cp～20 are in the scope of 000cp.
Be used for metal-powder d of the present invention) be not limited to particular types, as long as its electrode that can be used for forming the PDP electrode or be used for the mesh gauze filter of shielding electromagnetic wave, particularly can use silver, copper, nickel or comprise the alloy etc. of these metals.
Preferably, the amount with the 50 weight %～85 weight % of paste composition for printing comprises described metal-powder.When this content is lower than 50 weight %, cause required performance of electrode and capability of electromagnetic shielding to worsen owing to the resistance of established pattern increases, and when it surpassed 85 weight %, the viscosity of composition increased, and became to be difficult to dispersion thereby print performance.
In addition, paste composition for printing of the present invention also can comprise in case of necessity be used for dispersive electrode with the dispersion agent of metal-powder, be used to control the black pigment of contrast gradient and when calcining, be used to increase glass powder with the bonding strength of glass, its content is preferably the 0.01 weight %～10 weight % of paste composition for printing of the present invention, more preferably 0.1 weight %～3 weight %.
In addition, the invention provides the method that forms the plasma panel show electrode, described method comprises that the gravure offset by using above-mentioned paste composition for printing forms pattern, it is characterized in that using offset printing of the present invention to replace being used to form traditional paste composition of the electrode of Plasmia indicating panel with paste composition, and the employing gravure offset, and any other known method may be used to form the plasma show electrode.
In addition, the invention provides the method for the electrode of the mesh gauze filter that is formed for shielding electromagnetic wave, described method comprises that the gravure offset by using above-mentioned paste composition for printing forms pattern, it is characterized in that using offset printing of the present invention to replace being used to form traditional paste composition of the electrode of the mesh gauze filter that is used for shielding electromagnetic wave with paste composition, and the employing gravure offset, and any other known method can be used for being formed for the electrode of the mesh gauze filter of shielding electromagnetic wave.
Use the electrode formation method of the Plasmia indicating panel of paste composition for printing of the present invention to provide excellent printing performance with the preparation method who is used for the mesh gauze filter of shielding electromagnetic wave, the pattern that forms has excellent directivity and stability, particularly when they take direct mode of printing, compare with the photolithography class methods and to have obvious improved cost savings effect.
For a better understanding of the present invention, below be preferred implementation.Following embodiment describes the present invention, is not to limit the scope of the invention.
Embodiment
Embodiment 1
(weight-average molecular weight is 25 with the fluoropolymer resin as acrylate polymer resin of 15 weight %, 000, methacrylic acid (MA) wherein: benzyl acrylate (BA): (methyl) vinylformic acid 2-hydroxy methacrylate (2-HEMA): (methyl) methyl acrylate (MMA) is with the weight ratio polymerization of 30:20:10:40), terpinol (α-terpinol of 15 weight % as high boiling solvent, β-terpinol, the mixture of γ-terpinol), the propylene glycol monomethyl ether propionic ester (PGMEP) of 10 weight % as low boiling point solvent, what the conduct of 63 weight % was used for the silver of metal-powder of electrode and 2 weight % comprises amino organic dispersing agent in mixed at room temperature and stir as dispersion agent, at last, use 3 roller mills to prepare required paste composition for printing at last.
Embodiment 2～3 and comparative example 1～2
Except following table 1 described composition is used for the embodiment 1, carry out the step identical with the preparation paste composition for printing with embodiment 1.
Used unit is weight % in the table 1.
Table 1
| Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | |
| Acrylate polymer resin | 10 | 10 | 15 | 15 |
| Terpinol | 10 | 8 | 17 | 3 |
| PGMEP | 8 | 10 | 3 | 17 |
| Silver | 70 | 70 | 63 | 63 |
| Dispersion agent | 2 | 2 | 2 | 2 |
The paste composition for printing that makes in use embodiment 1～3 and comparative example 1 or 2 carries out the intaglio offset evaluation about printing performance, minimum feature and pattern directionality, and the result is presented at down among Fig. 1 and the table 2.
Estimate printing performance by the composition levels that remains on the coverture of utilizing observation by light microscope in the SET mode, not to be transferred to substrate, wherein O represents not have printing composition to remain in situation on the coverture, X be illustrated in printing composition excess residual in the SET mode in coverture and pattern can not be transferred to the situation of substrate.For the evaluation of minimum feature, determine the minimum size of the pattern that can be shaped by intaglio offset, size is more little then makes an appointment.For pattern directionality, be formed on the directivity degree of the pattern on the substrate after the printing of use observation by light microscope, wherein, the good situation of pattern directionality represents that with zero normal circumstances represents that with △ relatively poor situation is represented with X.
Table 2
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | |
| Printing performance | ○ | ○ | ○ | ○ | × |
| Minimum feature | 15μm | 20μm | 20μm | 50μm | - |
| Pattern directionality | ○ | ○ | ○ | × | - |
By above table 2 and Fig. 1 as can be known, when comparing, have the embodiment 1～3 that uses the pattern that paste composition for printing of the present invention forms by gravure offset and demonstrate minimum feature and excellent pattern directivity below excellent printing performance, the narrower 20 μ m with comparative example 1 or 2.In addition, comparative example 2 can not print, and causes there is not pattern.
Industrial applicibility
Paste composition according to the present invention is applicable to the intaglio offset mode that can directly form fine pattern, and has excellent cost savings effect than existing photolithography class methods, simultaneously, these compositions can satisfy the required multiple character of composition (each in the described character all is that printing process is required), thereby can bring into play suitable offset properties.
Although by preferred embodiment having described the present invention in detail, what but it will be apparent to those skilled in the art that is to carry out various changes and modifications within the spirit and scope of the present invention, undoubtedly, these changes and improvements still fall in the scope of claims.
Claims (9)
1. paste composition for printing, described composition comprises:
A) acrylate polymer resin of 5 weight %～30 weight %;
B) 5 weight %～boiling point of 35 weight % is at least 200 ℃ high boiling solvent;
C) 5 weight %～boiling point of 35 weight % is lower than 200 ℃ low boiling point solvent; With
D) metal-powder of 50 weight %～85 weight %,
Wherein, a) described acrylate polymer resin is by polymerization i in the presence of solvent) the undersaturated carboxylic acid monomer of 20 weight %～50 weight %, the ii) aromatic monomer of 10 weight %～30 weight %, described aromatic monomer is selected from by vinylbenzene, benzyl methacrylate, benzyl acrylate, phenyl acrylate, phenyl methacrylate, vinylformic acid 2-nitro phenyl ester, vinylformic acid 4-nitro phenyl ester, methacrylic acid 2-nitro phenyl ester, methacrylic acid 4-nitro phenyl ester, methacrylic acid 2-nitrobenzyl ester, methacrylic acid 4-nitrobenzyl ester, vinylformic acid 2-chlorobenzene ester, vinylformic acid 4-chlorobenzene ester, methacrylic acid 2-chlorobenzene ester, methacrylic acid 4-chlorobenzene ester, the group that its mixture is formed and iii) 20 weight %～60 weight % be selected from hydroxy methacrylate by (methyl) vinylformic acid 2-, (methyl) vinylformic acid 2-hydroxyl monooctyl ester, (methyl) methyl acrylate, (methyl) ethyl propenoate, the monomer of the group that n-butyl acrylate and composition thereof is formed prepares.
2. paste composition for printing as claimed in claim 1, wherein, described undersaturated carboxylic acid is selected from the group of being made up of vinylformic acid, methacrylic acid, methylene-succinic acid, toxilic acid, fumaric acid, its anhydride form and composition thereof.
3. paste composition for printing as claimed in claim 1, wherein, the weight-average molecular weight that described acroleic acid polymerization resin has is 10,000～100,000.
4. paste composition for printing as claimed in claim 1, wherein, described high boiling solvent b) is selected from the group of being made up of gamma-butyrolactone, acetate of butyl carbitol, Trivalin SF, methoxymethyl ether propionic ester, terpinol and composition thereof.
5. paste composition for printing as claimed in claim 1, wherein, low boiling point solvent described c) is selected from the group of being made up of propylene glycol monomethyl ether, DPGME, propylene glycol monomethyl ether propionic ester, ethyl ether propionic ester, propylene glycol monomethyl ether, methyl ethyl ketone, ethyl lactate and composition thereof.
6. paste composition for printing as claimed in claim 1, wherein, described metal-powder d) is selected from the group of being made up of silver, copper, nickel, the alloy that comprises these metals, its mixture.
7. paste composition for printing as claimed in claim 1, described composition also comprise at least a additive that is selected from the group of being made up of dispersion agent, black pigment and glass powder.
8. method that forms the plasma panel show electrode, described method comprise by using as the gravure offset formation pattern of each described paste composition for printing in the claim 1～7.
9. the method for the electrode of a mesh gauze filter that is formed for shielding electromagnetic wave, described method comprise by using as the gravure offset formation pattern of each described paste composition for printing in the claim 1～7.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2006-0035141 | 2006-04-18 | ||
| KR1020060035141A KR100871075B1 (en) | 2006-04-18 | 2006-04-18 | Paste composition for printing |
| KR1020060035141 | 2006-04-18 | ||
| PCT/KR2007/001722 WO2007119955A1 (en) | 2006-04-18 | 2007-04-10 | Paste composition for printing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101426867A CN101426867A (en) | 2009-05-06 |
| CN101426867B true CN101426867B (en) | 2011-07-06 |
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ID=38609690
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800140715A Expired - Fee Related CN101426867B (en) | 2006-04-18 | 2007-04-10 | Paste composition for printing |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP5566686B2 (en) |
| KR (1) | KR100871075B1 (en) |
| CN (1) | CN101426867B (en) |
| TW (1) | TWI471339B (en) |
| WO (1) | WO2007119955A1 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100898518B1 (en) | 2006-04-25 | 2009-05-20 | 주식회사 동진쎄미켐 | Printing paste composition using in gravure off-set printing for making electro wave shielding mash filter |
| KR100978099B1 (en) * | 2008-02-18 | 2010-08-27 | 주식회사 에프피 | Conductive paste composite for gravure printing |
| JP5178279B2 (en) * | 2008-03-28 | 2013-04-10 | 積水化学工業株式会社 | Conductive paste for multilayer ceramic capacitors |
| KR20090108781A (en) * | 2008-04-14 | 2009-10-19 | 주식회사 동진쎄미켐 | Black paste composition having conductivity property, filter for shielding electromagnetic interference and display device comprising the same |
| KR20090125393A (en) * | 2008-06-02 | 2009-12-07 | 주식회사 동진쎄미켐 | Black paste composition having conductivity property, filter for shielding electromagnetic interference and display device comprising the same |
| JP5403717B2 (en) * | 2009-04-08 | 2014-01-29 | エルジー・ケム・リミテッド | Printing paste composition and electrode formed thereby |
| TWI510372B (en) * | 2010-12-30 | 2015-12-01 | Lg Chemical Ltd | Electrode, electronic device comprising the same and manufacturing method thereof |
| JP5756563B2 (en) * | 2011-04-05 | 2015-07-29 | エルジー・ケム・リミテッド | Printing composition and printing method using the same |
| JP6459261B2 (en) * | 2013-09-11 | 2019-01-30 | 株式会社リコー | Ink and method for forming conductive pattern |
| WO2015151941A1 (en) * | 2014-04-01 | 2015-10-08 | 株式会社ダイセル | Silver-nano-particle-containing ink for intaglio offset printing, and production method for silver-nano-particle-containing ink for intaglio offset printing |
| KR102056657B1 (en) * | 2015-06-05 | 2019-12-17 | 쇼와 덴코 가부시키가이샤 | Composition for forming insulating protective film by offset printing |
| WO2018150697A1 (en) * | 2017-02-14 | 2018-08-23 | バンドー化学株式会社 | Conductive paste for gravure offset printing, method for forming conductive pattern, and method for manufacturing conductive substrate |
| JP6348241B1 (en) * | 2017-02-14 | 2018-06-27 | バンドー化学株式会社 | Conductive paste for gravure offset printing, method for forming conductive pattern, and method for manufacturing conductive substrate |
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| US6214527B1 (en) * | 1997-12-27 | 2001-04-10 | Dai Nippon Printing Co., Ltd. | Photosensitive conductor paste |
| US20020125486A1 (en) * | 2001-01-09 | 2002-09-12 | Yasuhiko Kondo | Electrode substrate of plasma display panel and method for making the same |
| CN1423169A (en) * | 2001-11-22 | 2003-06-11 | 三井化学株式会社 | Photosensitive resin composition, dry type film and processing component using same |
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| JPS63227671A (en) * | 1987-03-17 | 1988-09-21 | Toyo Ink Mfg Co Ltd | Electron beam-curing type conductive paste |
| JP3343930B2 (en) * | 1992-02-20 | 2002-11-11 | 株式会社村田製作所 | Binder for conductive paste |
| TW301843B (en) * | 1994-11-15 | 1997-04-01 | Ibm | Electrically conductive paste and composite and their use as an electrically conductive connector |
| JP2878204B2 (en) * | 1996-09-27 | 1999-04-05 | 鹿児島日本電気株式会社 | Phosphor paste and fluorescent display tube using the same |
| TW353762B (en) * | 1996-10-21 | 1999-03-01 | Dainippon Printing Co Ltd | Transfer sheet, and pattern-forming method |
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| JPH11172169A (en) * | 1997-12-11 | 1999-06-29 | Dainippon Printing Co Ltd | Pattern-forming paste and pattern-formation |
| JP2000204130A (en) * | 1998-11-09 | 2000-07-25 | Toray Ind Inc | Photo-sensitive paste and production of display material using the same |
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| JP2002203428A (en) * | 2000-12-27 | 2002-07-19 | Jsr Corp | Conductive paste composition |
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| KR20050055276A (en) * | 2003-12-06 | 2005-06-13 | 이비텍(주) | Photosensitive electrode paste compositions, dry films and electrode-patterning method using them for plasma display panel |
| KR100996235B1 (en) * | 2004-06-01 | 2010-11-25 | 주식회사 동진쎄미켐 | Pb free Ag paste composition for PDP address electrode |
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2006
- 2006-04-18 KR KR1020060035141A patent/KR100871075B1/en not_active IP Right Cessation
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2007
- 2007-04-10 CN CN2007800140715A patent/CN101426867B/en not_active Expired - Fee Related
- 2007-04-10 WO PCT/KR2007/001722 patent/WO2007119955A1/en active Application Filing
- 2007-04-10 JP JP2009506404A patent/JP5566686B2/en not_active Expired - Fee Related
- 2007-04-16 TW TW96113328A patent/TWI471339B/en not_active IP Right Cessation
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| US6214527B1 (en) * | 1997-12-27 | 2001-04-10 | Dai Nippon Printing Co., Ltd. | Photosensitive conductor paste |
| US20020125486A1 (en) * | 2001-01-09 | 2002-09-12 | Yasuhiko Kondo | Electrode substrate of plasma display panel and method for making the same |
| CN1423169A (en) * | 2001-11-22 | 2003-06-11 | 三井化学株式会社 | Photosensitive resin composition, dry type film and processing component using same |
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| Title |
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| JP特开2004-66804A 2004.03.04 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007119955A1 (en) | 2007-10-25 |
| CN101426867A (en) | 2009-05-06 |
| JP5566686B2 (en) | 2014-08-06 |
| TWI471339B (en) | 2015-02-01 |
| TW200745176A (en) | 2007-12-16 |
| KR20070103262A (en) | 2007-10-23 |
| KR100871075B1 (en) | 2008-11-28 |
| JP2009534498A (en) | 2009-09-24 |
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