CN101338516A - Fibroin atomization strengthening method for fragile silk fabrics - Google Patents
Fibroin atomization strengthening method for fragile silk fabrics Download PDFInfo
- Publication number
- CN101338516A CN101338516A CNA2008100632557A CN200810063255A CN101338516A CN 101338516 A CN101338516 A CN 101338516A CN A2008100632557 A CNA2008100632557 A CN A2008100632557A CN 200810063255 A CN200810063255 A CN 200810063255A CN 101338516 A CN101338516 A CN 101338516A
- Authority
- CN
- China
- Prior art keywords
- silk
- solution
- fibroin
- silk fabric
- silk goods
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 108010022355 Fibroins Proteins 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 16
- 238000000889 atomisation Methods 0.000 title claims description 7
- 238000005728 strengthening Methods 0.000 title claims description 7
- 239000004744 fabric Substances 0.000 title abstract 10
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 10
- 239000000243 solution Substances 0.000 claims description 35
- 238000012545 processing Methods 0.000 claims description 7
- 238000012958 reprocessing Methods 0.000 claims description 6
- 108010013296 Sericins Proteins 0.000 claims description 5
- 239000012460 protein solution Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 abstract 2
- 238000005507 spraying Methods 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 108090000623 proteins and genes Proteins 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- -1 heat Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 241000589220 Acetobacter Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Peptides Or Proteins (AREA)
Abstract
The invention provides a fibroin atomizing and reinforcing method for decayed silk fabric, which adopts the following steps: (A) evenly spraying the fibroin solution with weight percentage concentration of 0.1-5% decayed silk fabric by an atomizer until the silk fabric is totally wetted by the solution, then naturally drying the silk fabric; (B) evenly spraying the glutaraldehyde solution with weight percentage concentration of 0. 001-0. 5% decayed silk fabric by the atomizer until the silk fabric is totally wetted by the solution, then naturally drying the silk fabric; (C) repeating step (A) n times and repeating step (B) m times, and arranging the repeated steps in the mode of AB, ABAB..., AABAAAB..., AAAABAAAB,....; wherein n is 0, 1, 2,..., 10 and m is 0, 1, 2,..., 5; acquiring reinforced silk fabric after the above treatment. The invention utilizes fibroin reinforcing method, greatly improves strength of decayed silk fabric, and can be used for silk cultural relics protection. The invention has advantages of simple method, easy operation, low cost, good effect, ability to greatly improve strength of silk cultural relics, benefit to cultural relics protection and so on.
Description
Technical field
What the present invention relates to is a kind of fibroin atomization strengthening method of poor rotten silk goods, belongs to the technical field of historical relic's protection.
Background technology
Silk is the symbol of Chinese mature culture.China all has a large amount of silk historical relics to be unearthed every year, these silk historical relics have been crossed over 6,000 years up and down, having very high history, archaeology and scientific value, is the important component part of China's historical relic, is research China successive dynasties politics, economy, art, the very important data in kind of scientific and technological aspects.Because silk protein is a kind of bioabsorbable polymer material, is easy to be subjected to multiple factor affecting and damaged.Different factors such as extraneous water, heat, oxygen, illumination, acid, alkali, microorganism all can cause the fracture of silk protein generation sex change and macromolecular chain, make silk fiber tender, fracture easily, and tool intensity obviously descends.Manyly seem intact harmless, bright in colour silk historical relic when unearthed; actual in various with the acting in conjunction of external factor under; serious aging, embrittlement; that is to say that serious sex change has taken place silk protein and with the fracture of a large amount of macromolecular chains; if processing can not effectively be protected, be easy to damage.Inquiring into the method for reinforcing and protecting of silk historical relic, is urgent, an important problem of departments in charge of cultural and historical relics.To poor rotten serious, one to touch be that broken unearthed silk goods carry out repairing and reinforcement, is a global problem of archaeology, historical relic's protection circle always.
The patent of invention of Hubei Provincial Museum (200410012737) discloses " the microorganism reinforcement means of no intensity silk ", and this invention is converted into cellulose with carbohydrate and organic acid with acetobacter, thereby reaches the purpose of reinforcing no intensity silk.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists; and provide a kind of method simple; cost is low; effective; the fibroin atomization strengthening method of poor rotten silk goods that helps the protection of historical relic; it utilizes the fibroin atomization strengthening method, increases substantially the intensity of poor rotten silk goods, is used for the protection of silk historical relic.
Utilization of the present invention and historical relic identical materials-fibroin are reinforced the silk historical relic, meet the principle of relevant " restoring the old as the old " in the historical relic's protection more, have durability simultaneously again.This method adopts following steps:
A) be that 0.1%～5% fibroin solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, wet through by solution, allow its air dry then up to silk goods;
B) be that 0.001%～0.5% glutaraldehyde solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, evenly drenched up to silk goods by glutaraldehyde solution, allow its air dry;
C) repeat A step n time; Repeat B step m time, and the step of repetition can be by AB, ABAB...., AABAAAB..., AAAABAAAB .... and mode carry out reprocessing; N=0 wherein, 1,2 ..., 10, m=0,1,2 ..., 5;
D) through after the above processing, obtain the silk goods of reinforcing.
Described fibroin solution adopts at least a in silk fibroin protein solution, the sericin solution.
The present invention compares with prior art, and have following outstanding advantage: 1) method is simple, and is easy to use; 2) cost is low, effective, can increase considerably the intensity of silk historical relic, helps the protection of historical relic; 3) do not influence outward appearance, color and the feel of silk historical relic; 4) utilize with the historical relic identical materials--fibroin is reinforced the silk historical relic, meet the principle of relevant " restoring the old as the old " in " Law For the Preservation of Antiques " more, have durability simultaneously again.
The specific embodiment
The present invention will be described in detail below in conjunction with specific embodiment: the fibroin reinforcement process of poor rotten silk goods of the present invention, and it adopts following steps:
A) be that 0.1%～5% fibroin solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, wet through by solution, allow its air dry then up to silk goods;
B) be that 0.001%～0.5% glutaraldehyde solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, evenly drenched up to silk goods by glutaraldehyde solution, allow its air dry;
C) repeat A step n time; Repeat B step m time, and the step of repetition can be by AB, ABAB...., AABAAAB..., AAAABAAAB .... and mode carry out reprocessing; N=01 wherein, 2 ..., 10, m=0,1,2 ..., 5;
D) through after the above processing, obtain the silk goods of reinforcing.
Described fibroin solution adopts at least a in silk fibroin protein solution, the sericin solution.
Embodiment 1, is that 0.1% fibroin solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration A), wet through by solution up to silk goods, allows its air dry then;
B) be that 0.001% glutaraldehyde solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, evenly drenched up to silk goods by glutaraldehyde solution, allow its air dry;
C) repeat A step 3 time; Repeat B step 2 time, and the step that repeats is carried out reprocessing by the mode of A, B, A, A, B;
D) through after the above processing, obtain the silk goods of reinforcing.
Above-described fibroin solution adopts silk fibroin protein solution.
Embodiment 2, are that 5% fibroin solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration A), wet through by solution up to silk goods, allow its air dry then;
B) be that 0.5% glutaraldehyde solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, evenly drenched up to silk goods by glutaraldehyde solution, allow its air dry;
C) repeat A step 10 time; Repeat B step 5 time, and the step that repeats can be carried out reprocessing by the mode of AABAABAABAABAAB;
D) through after the above processing, obtain the silk goods of reinforcing.
Described fibroin solution adopts the mixed liquor of silk fibroin protein solution and sericin solution.Embodiment 3, are that 2% fibroin solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration A), wet through by solution up to silk goods, allow its air dry then;
B) be that 0.1% glutaraldehyde solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, evenly drenched up to silk goods by glutaraldehyde solution, allow its air dry;
C) repeat A step 7 time; Repeat B step 2 time, and the step that repeats can be carried out reprocessing by the mode of AAAABAAAB;
D) through after the above processing, obtain the silk goods of reinforcing.
Described fibroin solution adopts sericin solution.
Claims (2)
1, a kind of fibroin atomization strengthening method of poor rotten silk goods is characterized in that this method adopts following steps:
A) be that 0.1%～5% fibroin solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, wet through by solution, allow its air dry then up to silk goods;
B) be that 0.001%～0.5% glutaraldehyde solution is sprayed onto on the poor rotten silk goods equably with sprayer unit with weight percent concentration, evenly drenched up to silk goods by glutaraldehyde solution, allow its air dry;
C) repeat A step n time; Repeat B step m time, and the step of repetition can be by AB, ABAB...., AABAAAB..., AAAABAAAB .... and mode carry out reprocessing; N=0 wherein, 1,2 ..., 10, m=0,1,2 ..., 5;
D) through after the above processing, obtain the silk goods of reinforcing.
2, the fibroin atomization strengthening method of poor rotten silk goods according to claim 1 is characterized in that fibroin solution adopts at least a in silk fibroin protein solution, the sericin solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100632557A CN101338516A (en) | 2008-07-28 | 2008-07-28 | Fibroin atomization strengthening method for fragile silk fabrics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008100632557A CN101338516A (en) | 2008-07-28 | 2008-07-28 | Fibroin atomization strengthening method for fragile silk fabrics |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101338516A true CN101338516A (en) | 2009-01-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100632557A Pending CN101338516A (en) | 2008-07-28 | 2008-07-28 | Fibroin atomization strengthening method for fragile silk fabrics |
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| CN (1) | CN101338516A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433739A (en) * | 2011-08-18 | 2012-05-02 | 浙江理工大学 | Amino acid composite reinforcement method for rotten silk cultural relics |
| CN102433740A (en) * | 2011-08-18 | 2012-05-02 | 中国丝绸博物馆 | Bionic reinforcement method for rotten silk cultural relics |
| CN102433738A (en) * | 2011-08-18 | 2012-05-02 | 浙江理工大学 | Cysteine reinforcement method for rotten silk cultural relics |
| CN102433737A (en) * | 2011-08-18 | 2012-05-02 | 浙江理工大学 | Histidine-lysine combination strengthening method of rotten silk fabrics |
| CN102797154A (en) * | 2012-09-04 | 2012-11-28 | 中国科学技术大学 | Reinforcing liquid and reinforcing method for protecting ancient silk fabric cultural relics |
| CN102965932A (en) * | 2012-11-19 | 2013-03-13 | 浙江理工大学 | Silk peptide-amino acid grafting and reinforcing method for decayed silk fabric cultural relic |
| CN104562669A (en) * | 2015-01-20 | 2015-04-29 | 中国科学技术大学 | Protective reinforcing liquid for ancient silk culture relics, preparation method and protective reinforcing method |
-
2008
- 2008-07-28 CN CNA2008100632557A patent/CN101338516A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433738B (en) * | 2011-08-18 | 2013-07-10 | 浙江理工大学 | Cysteine reinforcement method for rotten silk cultural relics |
| CN102433740A (en) * | 2011-08-18 | 2012-05-02 | 中国丝绸博物馆 | Bionic reinforcement method for rotten silk cultural relics |
| CN102433738A (en) * | 2011-08-18 | 2012-05-02 | 浙江理工大学 | Cysteine reinforcement method for rotten silk cultural relics |
| CN102433737A (en) * | 2011-08-18 | 2012-05-02 | 浙江理工大学 | Histidine-lysine combination strengthening method of rotten silk fabrics |
| CN102433739A (en) * | 2011-08-18 | 2012-05-02 | 浙江理工大学 | Amino acid composite reinforcement method for rotten silk cultural relics |
| CN102433737B (en) * | 2011-08-18 | 2013-07-10 | 浙江理工大学 | Histidine-lysine combination strengthening method of rotten silk fabrics |
| CN102433740B (en) * | 2011-08-18 | 2013-07-10 | 中国丝绸博物馆 | Bionic reinforcement method for rotten silk cultural relics |
| CN102433739B (en) * | 2011-08-18 | 2013-07-10 | 浙江理工大学 | Amino acid composite reinforcement method for rotten silk cultural relics |
| CN102797154A (en) * | 2012-09-04 | 2012-11-28 | 中国科学技术大学 | Reinforcing liquid and reinforcing method for protecting ancient silk fabric cultural relics |
| CN102965932A (en) * | 2012-11-19 | 2013-03-13 | 浙江理工大学 | Silk peptide-amino acid grafting and reinforcing method for decayed silk fabric cultural relic |
| CN102965932B (en) * | 2012-11-19 | 2014-12-03 | 浙江理工大学 | Silk peptide-amino acid grafting and reinforcing method for decayed silk fabric cultural relic |
| CN104562669A (en) * | 2015-01-20 | 2015-04-29 | 中国科学技术大学 | Protective reinforcing liquid for ancient silk culture relics, preparation method and protective reinforcing method |
| CN104562669B (en) * | 2015-01-20 | 2016-08-17 | 中国科学技术大学 | A kind of protection for silk weaving in ancient times historical relic adds solid-liquid, preparation method and protection reinforcement means |
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Open date: 20090107 |