CN104562669B - A kind of protection for silk weaving in ancient times historical relic adds solid-liquid, preparation method and protection reinforcement means - Google Patents
A kind of protection for silk weaving in ancient times historical relic adds solid-liquid, preparation method and protection reinforcement means Download PDFInfo
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Abstract
The invention discloses a kind of protection for silk weaving in ancient times historical relic and add solid-liquid, include the raw material of following quality proportioning: alcohol ether carboxylate: 0.05% 0.5%, dodecylbenzene sodium sulfonate 0.05% 0.5%, fatty alcohol-polyoxyethylene ether 0.08 0.12%, cyclodextrin 0.2% 0.3%, Air Bladder pseudosciaenae seu Acipenser 0.2% 0.3%, Bletilla glucomannan 0.1% 0.2%, remaining be deionized water.The invention also discloses this protection add the preparation method of solid-liquid and its in ancient times the application of silk weaving historical relic time protection reinforcement means.Before the reinforcement material of the present invention has a good effect reinforcing silk fabric cultural relics, and the silk fabric cultural relics that may be directly applied to be unearthed tears off work.After the complete infiltration solidification of reinforcement material of the present invention, can the fragility of Multi-stacking compaction be unearthed silk fabric cultural relics interlayer formed layer protecting film, make silk fabric cultural relics interlayer not stick together, do not change silk fabric cultural relics original state, nontoxic pollution-free.
Description
Technical field
The invention belongs to silk weaving category historical relic reinforcement protection technical field, relate to a kind of protection for Ancient Silk Textile historical relic and add solid-liquid preparation and method for reinforcing and protecting.
Background technology
Silk is Sinitic symbol, is the important component part of China's cultural heritage, is also the important burial articles in grave in ancient times.Silk fabric cultural relics is through burying for a long time, and great majority corrode the most completely totally, disappear, and what minority remained is substantially the rotten i.e. powder that can't bear, touch of grain.Silk fabric cultural relics be unearthed situation generally have that grain is rotten, damaged, harden, the problem such as more than one piece mixed strand, fold.So entirety tear off be silk cultural relics work the first step, be also a most important step.
Silk fabric cultural relics entirety tears off the technological difficulties of work and is: silk fabric cultural relics state of being unearthed is the most fragile, and historical relic can be caused bigger destruction by the most manual tearing off；And existing reinforcement technique is substantially and is coated with reinforcement material on silk surface, tear off after reinforcing and can make silk fabrics interlayer adhesion, and then historical relic is caused bigger destruction.Two kinds of contradictions cannot be in harmonious proportion always, not only hinders the enforcement of late protection work, also limit the development of resist technology, really belongs to silk cultural relics industry technical bottleneck for a long time.
Selectivity film forming reinforcement technique utilizes the effect in the uneven field of force (Van der Waals force) that silkworm silk surface molecular is subject to, when i.e. surfactant molecule is close to silkworm silk surface, attracted by silkworm silk surface molecular, and be tied to silkworm silk surface, the absorption of silkworm silk surface activating agent is occurred.Again because silkworm silk surface is with hydroxyl (OH) and amido (NH2), and surfactant is attracted each other by hydrogen bond between hydroxyl, amido or ether (-O-), and then the monolayer of formation one, complete a stable extensive chemical absorption.The second adsorption layer is formed by physical absorption more afterwards in this monolayer, in the silk interlayer selectivity film forming laminated after final solidification, while playing reinforcing silk fabric cultural relics effect, silk interlayer adhesion.
According to the feature of silk fabric cultural relics, select reinforcement protecting material particular/special requirement as follows:
(1) according to the principle of historical relic's protection, should follow and not change historical relic original appearance, reinforcement material is water white transparency, and after reinforcing, the character material such as silk fabric cultural relics color, sense of touch will not change；
(2) according to the phenomenon of the silk fabric cultural relics Multi-stacking compaction that is unearthed, the reinforced material of historical relic must can not occur interlayer adhesion after processing, destroys historical relic body.
(3) there are enough permeabilitys while reinforcement material has certain viscosity, it is possible to fully infiltrate into silkworm silk molecular surface；
(4) reinforcement material should be able to be effectively improved the intensity of silk fabric cultural relics, should have preferable bonding force and the compatibility with silk fabric cultural relics body；
(5) reinforcement material should have good film property, can eliminate the scattering phenomenon of incident illumination after process, and at silk surface no-reflection film, before and after use, value of chromatism (Δ E) should be less than equal to 5.
In sum, the reinforcement protecting material for the silk fabric cultural relics that is unearthed should possess good film property, can not change the outward appearance of silk after reinforcing, and reinforcement protecting material must take into account permeability and the ageing-resistant performance of excellence while having good reinforcement performance.The material being currently used for silk reinforcement protection is a lot, but still suffers from problems.Though traditional protection material cuts both ways, but the interlayer adhesion problems of silk cannot be solved all the time.In the present invention, this industry difficult problem is captured in the application of selectivity film technique.
Summary of the invention
Present invention aim at providing a kind of unearthed silk fabric cultural relics interlayer can selectivity film forming (soap-free emulsion polymeization between silk fiber), effectively reinforce silkworm silk body mechanical strength, do not change historical relic original state, the compatibility is good, permeability is strong, environment friendly and pollution-free silk fabric cultural relics tears off reinforcement protecting material.
A kind of protection for silk weaving in ancient times historical relic of the present invention adds solid-liquid, includes the raw material of following quality proportioning: alcohol ether carboxylate (AEC): 0.05%-0.5%, dodecylbenzene sodium sulfonate 0.05%-0.5%, fatty alcohol-polyoxyethylene ether (AE) 0-0.1%, cyclodextrin 0.2%-0.3%, Air Bladder pseudosciaenae seu Acipenser 0.2%-0.3%, Bletilla glucomannan 0.1%-0.2%, remaining be deionized water.
Preferably, above-mentioned raw materials quality proportioning is: alcohol ether carboxylate (AEC): 0.1%-0.2%, dodecylbenzene sodium sulfonate 0.1%-0.2%, fatty alcohol-polyoxyethylene ether (AE) 0.1%, cyclodextrin 0.2%-0.3%, Air Bladder pseudosciaenae seu Acipenser 0.2%-0.3%, Bletilla glucomannan 0.1%-0.2%, remaining be deionized water.
Raw material mass mixture ratio described above is most preferably: alcohol ether carboxylate (AEC) 0.2%, dodecylbenzene sodium sulfonate 0.2%, fatty alcohol-polyoxyethylene ether (AE) 0.1%, cyclodextrin 0.3%, Air Bladder pseudosciaenae seu Acipenser 0.3%, Bletilla glucomannan 0.2%, remaining is deionized water.
The described protection for silk weaving in ancient times historical relic adds the preparation method of solid-liquid; it is first to add alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) in 40 DEG C of-50 DEG C of warm water fully to dissolve; form combination solution; keep solution temperature; cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being sequentially added in combination solution, uniform stirring forms dispersion liquid again.
Add solid-liquid as the most unspent, when reusing, be heated to 40 DEG C, stir and can use.
Protection for silk weaving in ancient times historical relic adds the protection reinforcement means of solid-liquid, it is characterised in that be first placed in by silk fabric cultural relics equipped with in the historical relic rinse bath of draining；It is slow added into protection and adds solid-liquid until flooding silk fabric cultural relics completely, soak 10-30 hour, finally drain strengthening agent, put ventilation and treat that nature dries in the shade.
Alcohol ether carboxylate (AEC) in the present invention, dodecylbenzene sodium sulfonate are anion surfactant, are main film forming ingredients.Fatty alcohol-polyoxyethylene ether (AE) is nonionic surfactant, and spume inhibitory action.Cyclodextrin, Air Bladder pseudosciaenae seu Acipenser are for mainly to add solid content, and Bletilla glucomannan is permeation-promoter.Alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether, can make the critical micelle concentration of surfactant raise in the warm water of about 40 DEG C, reach optimum filming condition；Meanwhile cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan play consolidation effect between Surfactant Films and silkworm silk body, can't have bond effect at silk interlayer.
Cyclodextrin in the present invention, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan are dispersed in combination solution, effectively reach the effect of reinforcement material；Simultaneously, the present invention forms surfactant molecule film after utilizing alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) compounding, effectively prevent cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan in the effect of silk fabric cultural relics interlayer, make historical relic interlayer adhesion, enhance the mechanical strength of fragile silk fabric cultural relics.The experiment proved that the reinforcement material of the present invention has a good effect reinforcing silk fabric cultural relics, and before the silk fabric cultural relics that may be directly applied to be unearthed tears off work.This reinforcement protecting material is compounded gained by alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE), cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan; nontoxic, easily remove; after the complete infiltration solidification of reinforcement material; can the fragility of Multi-stacking compaction be unearthed silk fabric cultural relics interlayer formed layer protecting film; make silk fabric cultural relics interlayer not stick together, and do not change silk fabric cultural relics original state and nontoxic pollution-free.
Detailed description of the invention
Following embodiment is to further illustrate using as the explaination to the technology of the present invention content for present invention; but the flesh and blood of the present invention is not limited in described in following embodiment, those of ordinary skill in the art and can should know any simple change based on true spirit or replacement all should belong to protection domain of the presently claimed invention.
Due to the scarcity of silk fabric cultural relics and non-renewable, the present invention uses Nanling County, Anhui to shoot a retrievable arrow Jiang Zhentie and turns Song dynasty silk fabric cultural relics 2 unearthed for Song Mu as application example after removing simulation experiment maturation, remaining simulation experiment all uses the mode of heat ageing to prepare the simulation Ancient Silk Textile historical relic sample being largely used to repeat experiment: select the plain weave real silk fabric of 10cm × 10cm, for make simulation sample and Ancient Silk Textile historical relic closer to, simulation silk fabric cultural relics is placed in air dry oven, aging 60h at 240 DEG C.
Embodiment
1
First alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) are added in 40 DEG C of water and fully dissolve, form combination solution；Cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being added in combination solution, keep 40 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, dodecylbenzene sodium sulfonate mass concentration is 0.2%, fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and cyclodextrin mass concentration is 0.3%, Air Bladder pseudosciaenae seu Acipenser mass concentration is 0.3%, Bletilla glucomannan mass concentration is 0.2%.Simulation Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until complete flooding inundation simulation silk fabric cultural relics, soak 24 hours, treat that strengthening agent reacts complete with simulation silk fabric cultural relics；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.62 is recorded after being completely dried；Tensile strength is 1.96N；Overall assessment is excellent.
Embodiment
2
Only protection being added and form the temperature of combination solution in the preparation method of solid-liquid and be adjusted to 50 DEG C from 40 DEG C, other record value of chromatism Δ E=0.87 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is 1.73N；Overall assessment is excellent.
Embodiment
3
Only being adjusted to simulating silk fabric cultural relics soak time in adding solid-liquid in protection reinforcement means 12 hours from 24 hours, other record value of chromatism Δ E=0.75 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is 1.58
N；Overall assessment is excellent.
Embodiment
4
It was adjusted to 12 hours from 24 hours by protection reinforcement means simulates silk fabric cultural relics soak time in adding solid-liquid; protection is added simultaneously and the preparation method of solid-liquid is formed the temperature of combination solution be adjusted to 50 DEG C from 40 DEG C; other record value of chromatism Δ E=0.81 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is 1.44
N；Overall assessment is excellent.
Embodiment
5
The mass concentration that protection only adds the component alcohol ether carboxylate (AEC) forming combination solution in the preparation method of solid-liquid is adjusted to 0.1% from 0.2%, and other record value of chromatism Δ E=0.86 with embodiment 1, the simulation silk fabric cultural relics after process
；Tensile strength is 1.35 N；Overall assessment is excellent.
Embodiment
6
Only protection being added and form the temperature of combination solution in the preparation method of solid-liquid and be adjusted to 50 DEG C from 40 DEG C, other record value of chromatism Δ E=0.88 with embodiment 5, the simulation silk fabric cultural relics after process；Tensile strength is
1.17N；Overall assessment is excellent.
Embodiment
7
Only being adjusted to simulating silk fabric cultural relics soak time in adding solid-liquid in protection reinforcement means 12 hours from 24 hours, other record value of chromatism Δ E=0.63 with embodiment 5, the simulation silk fabric cultural relics after process；Tensile strength is 1.54
N；Overall assessment is excellent.
Embodiment
8
Protection is added the temperature forming combination solution in the preparation method of solid-liquid and is adjusted to 50 DEG C from 40 DEG C; it was adjusted to 12 hours by protection reinforcement means simulates silk fabric cultural relics soak time in adding solid-liquid from 24 hours simultaneously; other record value of chromatism Δ E=0.58 with embodiment 5, the simulation silk fabric cultural relics after process；Tensile strength is 1.40
N；Overall assessment is excellent.
Embodiment
9
The mass concentration that protection only adds the component dodecylbenzene sodium sulfonate forming combination solution in the preparation method of solid-liquid is adjusted to 0.1% from 0.2%, and other record value of chromatism Δ E=1.22 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is 1.68
N；Overall assessment is excellent.
Embodiment
10
Only protection being added and form the temperature of combination solution in the preparation method of solid-liquid and be adjusted to 50 DEG C from 40 DEG C, other record value of chromatism Δ E=0.98 with embodiment 9, the simulation silk fabric cultural relics after process；Tensile strength is 1.47
N；Overall assessment is excellent.
Embodiment
11
Only being adjusted to simulating silk fabric cultural relics soak time in adding solid-liquid in protection reinforcement means 12 hours from 24 hours, other record value of chromatism Δ E=0.78 with embodiment 9, the simulation silk fabric cultural relics after process；Tensile strength is 1.31
N；Overall assessment is excellent.
Embodiment
12
Protection is added the temperature forming combination solution in the preparation method of solid-liquid and is adjusted to 50 DEG C from 40 DEG C; it was adjusted to 12 hours by protection reinforcement means simulates silk fabric cultural relics soak time in adding solid-liquid from 24 hours simultaneously; other record value of chromatism Δ E=0.76 with embodiment 9, the simulation silk fabric cultural relics after process；Tensile strength is 1.49
N；Overall assessment is excellent.
Embodiment
13
First alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) are added in 50 DEG C of water and fully dissolve, form combination solution；Cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being added in combination solution, keep 50 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, dodecylbenzene sodium sulfonate mass concentration is 0.1%, and fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and cyclodextrin mass concentration is 0.2%, Air Bladder pseudosciaenae seu Acipenser mass concentration is 0.2%, and Bletilla glucomannan mass concentration is 0.1%.Simulation Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until complete flooding inundation simulation silk fabric cultural relics, soak 24 hours, treat that strengthening agent reacts complete with simulation silk fabric cultural relics；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.60 is recorded after being completely dried；Tensile strength is 1.62 N；Overall assessment is excellent.
Embodiment
14
Protection being added and form the component Air Bladder pseudosciaenae seu Acipenser mass concentration of combination solution in the preparation method of solid-liquid and be adjusted to 0.3% from 0.2%, other record value of chromatism Δ E=1.22 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is 1.54
N；Overall assessment is excellent.
Embodiment
15
Protection being added and form the component Bletilla glucomannan mass concentration of combination solution in the preparation method of solid-liquid and be adjusted to 0.2% from 0.1%, other record value of chromatism Δ E=0.92 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is
1.57N；Overall assessment is excellent.
Embodiment
16
Protection is added and the preparation method of solid-liquid is formed the component Air Bladder pseudosciaenae seu Acipenser mass concentration of combination solution is adjusted to 0.3% from 0.2%; Bletilla glucomannan mass concentration is adjusted to 0.2% from 0.1%; other record value of chromatism Δ E=0.86 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is
1.78N；Overall assessment is excellent.
Embodiment
17
Protection being added and form the component cyclodextrin mass concentration of combination solution in the preparation method of solid-liquid and be adjusted to 0.3% from 0.2%, other record value of chromatism Δ E=0.92 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is 1.66
N；Overall assessment is excellent.
Embodiment
18
Protection is added and the preparation method of solid-liquid is formed the component cyclodextrin mass concentration of combination solution is adjusted to 0.3% from 0.2%; Air Bladder pseudosciaenae seu Acipenser mass concentration is adjusted to 0.3% from 0.2%; other record value of chromatism Δ E=0.98 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is 1.69
N；Overall assessment is excellent.
Embodiment
19
Protection is added and the preparation method of solid-liquid is formed the component cyclodextrin mass concentration of combination solution is adjusted to 0.3% from 0.2%; Bletilla glucomannan mass concentration is adjusted to 0.2% from 0.1%; other record value of chromatism Δ E=0.75 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is 1.84
N；Overall assessment is excellent.
Embodiment
20
Protection is added and the preparation method of solid-liquid is formed the component cyclodextrin mass concentration of combination solution is adjusted to 0.3% from 0.2%; Air Bladder pseudosciaenae seu Acipenser mass concentration is adjusted to 0.3% from 0.2%; Bletilla glucomannan mass concentration is adjusted to 0.2% from 0.1%; other record value of chromatism Δ E=0.63 with embodiment 13, the simulation silk fabric cultural relics after process；Tensile strength is
2.48N；Overall assessment is excellent.
Comparative example
1
Only protection being added and form the temperature of combination solution in the preparation method of solid-liquid and be adjusted to 20 DEG C from 40 DEG C, other record value of chromatism Δ E=0.80 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is 1.07
N；Overall assessment is excellent.
Comparative example
2
Only being adjusted to simulating silk fabric cultural relics soak time in adding solid-liquid in protection reinforcement means 1 hour from 24 hours, other record value of chromatism Δ E=0.55 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is 0.88
N；Overall assessment is good.
Comparative example
3
Only protection being added and form component alcohol ether carboxylate (AEC) mass concentration of combination solution in the preparation method of solid-liquid and be adjusted to 0 from 0.2%, other record value of chromatism Δ E=0.84 with embodiment 1, the simulation silk fabric cultural relics after process
；Tensile strength is 1.12 N；Overall assessment is good.
Comparative example
4
Only protection being added and form the component dodecylbenzene sodium sulfonate mass concentration of combination solution in the preparation method of solid-liquid and be adjusted to 0 from 0.2%, other record value of chromatism Δ E=0.73 with embodiment 1, the simulation silk fabric cultural relics after process；Tensile strength is
1.32N；Overall assessment is good.
Comparative example
5
First alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) are added in 50 DEG C of water and fully dissolve, form combination solution；Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being added in combination solution, keep 50 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, and dodecylbenzene sodium sulfonate mass concentration is 0.1%, and fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and Air Bladder pseudosciaenae seu Acipenser mass concentration is 0.3%, and Bletilla glucomannan mass concentration is 0.2%.Simulation Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until complete flooding inundation simulation silk fabric cultural relics, soak 24 hours, treat that strengthening agent reacts complete with simulation silk fabric cultural relics；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.59 is recorded after being completely dried；Tensile strength is 1.13N；Overall assessment is excellent.
Comparative example
6
First alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) are added in 50 DEG C of water and fully dissolve, form combination solution；Cyclodextrin, Bletilla glucomannan being added in combination solution, keep 50 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, and dodecylbenzene sodium sulfonate mass concentration is 0.1%, and fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and cyclodextrin mass concentration is 0.3%, and Bletilla glucomannan mass concentration is 0.2%.Simulation Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until complete flooding inundation simulation silk fabric cultural relics, soak 24 hours, treat that strengthening agent reacts complete with simulation silk fabric cultural relics；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.88 is recorded after being completely dried；Tensile strength is 1.46 N；Overall assessment is excellent.
Comparative example
7
First alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) are added in 50 DEG C of water and fully dissolve, form combination solution；Cyclodextrin, Air Bladder pseudosciaenae seu Acipenser being added in combination solution, keep 50 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, and dodecylbenzene sodium sulfonate mass concentration is 0.1%, and fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and cyclodextrin mass concentration is 0.3%, and Air Bladder pseudosciaenae seu Acipenser mass concentration is 0.3%.Simulation Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until complete flooding inundation simulation silk fabric cultural relics, soak 24 hours, treat that strengthening agent reacts complete with simulation silk fabric cultural relics；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.75 is recorded after being completely dried；Tensile strength is 1.64 N；Overall assessment is excellent.
Song dynasty is unearthed textile example
1
Experience according to simulation experiment, select optimal case to apply the present invention to Anhui and be unearthed Song dynasty textile historical relic: first alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) added in 40 DEG C of water and fully dissolve, form combination solution；Cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being added in combination solution, keep 40 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, dodecylbenzene sodium sulfonate mass concentration is 0.2%, and fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and cyclodextrin mass concentration is 0.3%, Air Bladder pseudosciaenae seu Acipenser mass concentration is 0.3%, and Bletilla glucomannan mass concentration is 0.2%.Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until flooding silk fabric cultural relics completely, soak 24 hours, treat that strengthening agent and silk fabric cultural relics react complete；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.77 is recorded after being completely dried；Tensile strength is 3.63 N；Overall assessment is excellent.
Song dynasty is unearthed textile example
2
Experience according to simulation experiment, select optimal case to apply the present invention to Anhui and be unearthed Song dynasty textile historical relic: first alcohol ether carboxylate (AEC), dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether (AE) added in 40 DEG C of water and fully dissolve, form combination solution；Cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being added in combination solution, keep 40 DEG C of temperature conditionss stable, uniform stirring 1h forms dispersion liquid.Described alcohol ether carboxylate (AEC) mass concentration is 0.2%, dodecylbenzene sodium sulfonate mass concentration is 0.2%, and fatty alcohol-polyoxyethylene ether (AE) mass concentration is 0.1%, and cyclodextrin mass concentration is 0.3%, Air Bladder pseudosciaenae seu Acipenser mass concentration is 0.3%, and Bletilla glucomannan mass concentration is 0.2%.Ancient Silk Textile historical relic is placed in equipped with in the special historical relic rinse bath of draining；It is slow added into and adds solid-liquid until flooding silk fabric cultural relics completely, soak 24 hours, treat that strengthening agent and silk fabric cultural relics react complete；Finally drain strengthening agent, put ventilation and naturally dry in the shade.Value of chromatism Δ E=0.75 is recorded after being completely dried；Tensile strength is 3.66 N；Overall assessment is excellent.
In comparative example 1, owing to complex material fails to reach the maximum critical micelle concentration of surfactant under room temperature state, surfactant is sufficiently formed absorption on silkworm silk surface, causes consolidation effect part to decline.In comparative example 2, because the minimizing of soak time makes reaction insufficient, consolidation effect is also made to have certain decline.In comparative example 3, do not add alcohol ether carboxylate (AEC) and make surfactant, on silkworm silk surface, physical absorption only occur, lose chemisorbed, make consolidation effect have certain decline.In comparative example 4, do not add dodecylbenzene sodium sulfonate and make adsorption process not carry out second adsorption, selective double layer film could not be ultimately formed, cause consolidation effect to decline.In comparative example 5, not adding cyclodextrin, silk tensile strength is significantly improved, but fails to reach optimal consolidation effect.In comparative example 6, not adding Air Bladder pseudosciaenae seu Acipenser, silk tensile strength is significantly improved, but also fails to reach optimal consolidation effect.In comparative example 7, not adding Bletilla glucomannan, consolidation effect is pretty good, but strengthening agent mobility is poor.
Table 1 below, table 2 are the consolidation effect of Ancient Silk Textile historical relic sample after different technology conditions process, and aberration (aberration is the smaller the better), tensile strength (being the bigger the better) also fall slag overall assessment (excellent middle difference grading) test result with feel, vision, the crispest powder.
From table 1, table 2, the intensity of the simulation Ancient Silk Textile historical relic after the material reinforced process of the present invention is all improved, and aberration changes small, meets historical relic's protection principle, is preferable silk fabric cultural relics reinforcement protecting material.Shooting a retrievable arrow Jiang Zhentie to turn Song Mu be unearthed the actual application of Song dynasty silk fabric cultural relics through Nanling County, Anhui, stable performance of the present invention, effect are fine, solve the major issue in silk cultural relics.
Claims (4)
1. add a solid-liquid for the protection of silk weaving in ancient times historical relic, include the raw material of following quality proportioning: alcohol ether carboxylate: 0.05%-0.5%, dodecylbenzene sodium sulfonate 0.05%-0.5%, fatty alcohol-polyoxyethylene ether 0.08-0.12%, cyclodextrin 0.2%-0.3%, Air Bladder pseudosciaenae seu Acipenser 0.2%-0.3%, Bletilla glucomannan 0.1%-0.2%, remaining be deionized water.
2. the protection being used for silk weaving in ancient times historical relic as claimed in claim 1 adds solid-liquid; it is characterized in that, alcohol ether carboxylate: 0.1%-0.2%, dodecylbenzene sodium sulfonate 0.1%-0.2%, fatty alcohol-polyoxyethylene ether 0.1%, cyclodextrin 0.2%-0.3%, Air Bladder pseudosciaenae seu Acipenser 0.2%-0.3%, Bletilla glucomannan 0.1%-0.2%, remaining be deionized water.
3. the protection being used for silk weaving in ancient times historical relic described in claim 1 or 2 adds the preparation method of solid-liquid; it is first fully will to dissolve in alcohol ether carboxylate, dodecylbenzene sodium sulfonate, fatty alcohol-polyoxyethylene ether 40 DEG C of-50 DEG C of warm water of addition; form combination solution; keep solution temperature; cyclodextrin, Air Bladder pseudosciaenae seu Acipenser, Bletilla glucomannan being sequentially added in combination solution, uniform stirring forms dispersion liquid again.
4. use the protection being used for silk weaving in ancient times historical relic described in claim 1 or 2 to add the solid-liquid protection reinforcement means to silk weaving in ancient times historical relic, it is characterised in that to be first placed in by silk fabric cultural relics equipped with in the historical relic rinse bath of draining；It is slow added into protection and adds solid-liquid until flooding silk fabric cultural relics completely, soak 10-30 hour, finally drain strengthening agent, put ventilation and treat that nature dries in the shade.
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| CN107354748B (en) * | 2017-08-04 | 2019-12-24 | 浙江理工大学 | Reinforcing method for fragile silk fabric cultural relics |
| CN107386000A (en) * | 2017-08-14 | 2017-11-24 | 上海大学 | A kind of fragile organic matter historical relic extraction, reinforce and protect and use analog sample preparation method |
| CN109881535B (en) * | 2019-04-11 | 2021-08-20 | 山西博物院 | Reinforcing agent for protecting ancient paper cultural relics and using and preparation method thereof |
| CN112208258A (en) * | 2020-10-10 | 2021-01-12 | 湖北省博物馆 | Method for dewatering and reinforcing water-saturated paint woodware in semi-solid mode |
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| CN101338516A (en) * | 2008-07-28 | 2009-01-07 | 浙江理工大学 | Fibroin atomization strengthening method for fragile silk fabrics |
| CN102359020A (en) * | 2011-08-18 | 2012-02-22 | 浙江理工大学 | Method for unfolding ancient rotten silk |
| CN102797154A (en) * | 2012-09-04 | 2012-11-28 | 中国科学技术大学 | Reinforcing liquid and reinforcing method for protecting ancient silk fabric cultural relics |
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| CN101338516A (en) * | 2008-07-28 | 2009-01-07 | 浙江理工大学 | Fibroin atomization strengthening method for fragile silk fabrics |
| CN102359020A (en) * | 2011-08-18 | 2012-02-22 | 浙江理工大学 | Method for unfolding ancient rotten silk |
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