CN101177055A - 一种改性苯并噁嗪玻璃布层压板的制造方法 - Google Patents
一种改性苯并噁嗪玻璃布层压板的制造方法 Download PDFInfo
- Publication number
- CN101177055A CN101177055A CNA2007101902455A CN200710190245A CN101177055A CN 101177055 A CN101177055 A CN 101177055A CN A2007101902455 A CNA2007101902455 A CN A2007101902455A CN 200710190245 A CN200710190245 A CN 200710190245A CN 101177055 A CN101177055 A CN 101177055A
- Authority
- CN
- China
- Prior art keywords
- benzoxazine
- glass cloth
- veneer sheet
- manufacture method
- modified benzoxazine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000005130 benzoxazines Chemical class 0.000 title claims abstract description 32
- 239000004744 fabric Substances 0.000 title claims abstract description 30
- 239000011521 glass Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 29
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003292 glue Substances 0.000 claims abstract description 14
- -1 peroxide free radical Chemical class 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 18
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000005470 impregnation Methods 0.000 claims description 9
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Natural products CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 8
- 150000001451 organic peroxides Chemical class 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 6
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- KILURZWTCGSYRE-LNTINUHCSA-K (z)-4-bis[[(z)-4-oxopent-2-en-2-yl]oxy]alumanyloxypent-3-en-2-one Chemical group CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O KILURZWTCGSYRE-LNTINUHCSA-K 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- MFWFDRBPQDXFRC-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;vanadium Chemical compound [V].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MFWFDRBPQDXFRC-LNTINUHCSA-N 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 238000007731 hot pressing Methods 0.000 claims description 3
- GYUPBLLGIHQRGT-UHFFFAOYSA-N pentane-2,4-dione;titanium Chemical compound [Ti].CC(=O)CC(C)=O GYUPBLLGIHQRGT-UHFFFAOYSA-N 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- RIVJYLGQARVCBI-UHFFFAOYSA-N 2-tert-butylperoxy-2-methylpropane;cumene Chemical compound CC(C)C1=CC=CC=C1.CC(C)(C)OOC(C)(C)C RIVJYLGQARVCBI-UHFFFAOYSA-N 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 12
- 238000004132 cross linking Methods 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 230000009977 dual effect Effects 0.000 abstract description 2
- 238000003786 synthesis reaction Methods 0.000 abstract description 2
- 238000012719 thermal polymerization Methods 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000002250 absorbent Substances 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 238000007598 dipping method Methods 0.000 abstract 1
- 239000012774 insulation material Substances 0.000 abstract 1
- 230000001629 suppression Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 8
- 238000000465 moulding Methods 0.000 description 6
- 239000000853 adhesive Substances 0.000 description 5
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000010189 synthetic method Methods 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- 239000010754 BS 2869 Class F Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 235000021081 unsaturated fats Nutrition 0.000 description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007101902455A CN101177055B (zh) | 2007-11-23 | 2007-11-23 | 一种改性苯并噁嗪玻璃布层压板的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2007101902455A CN101177055B (zh) | 2007-11-23 | 2007-11-23 | 一种改性苯并噁嗪玻璃布层压板的制造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101177055A true CN101177055A (zh) | 2008-05-14 |
CN101177055B CN101177055B (zh) | 2010-06-16 |
Family
ID=39403551
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2007101902455A Expired - Fee Related CN101177055B (zh) | 2007-11-23 | 2007-11-23 | 一种改性苯并噁嗪玻璃布层压板的制造方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101177055B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102161762A (zh) * | 2011-01-19 | 2011-08-24 | 华东理工大学 | 一种改性苯并噁嗪树脂的方法 |
CN103012841A (zh) * | 2012-12-18 | 2013-04-03 | 四川大学 | 一种腰果酚-芳香二胺型苯并噁嗪增韧剂及其制备方法和用途 |
CN104903382B (zh) * | 2012-12-27 | 2017-06-16 | 3M创新有限公司 | 包含苯并噁嗪和成酸过氧化物催化剂的可聚合组合物、制品和方法 |
CN111205799A (zh) * | 2020-02-28 | 2020-05-29 | 杭摩新材料(嘉兴)有限公司 | 一种腰果酚改性酚醛树脂胶黏剂的生产工艺 |
CN111205797A (zh) * | 2020-02-28 | 2020-05-29 | 杭摩新材料(嘉兴)有限公司 | 酚醛树脂胶黏剂及其制备方法 |
CN111763151A (zh) * | 2020-06-29 | 2020-10-13 | 浙江万盛股份有限公司 | 一种高防腐性能腰果酚改性多元胺固化剂的制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1126769C (zh) * | 1999-01-06 | 2003-11-05 | 四川联合大学 | 植物油改性苯并噁嗪中间体及其制备方法和用途 |
CN1803887A (zh) * | 2005-12-31 | 2006-07-19 | 四川东材企业集团有限公司 | 一种含芳烷基结构的苯并噁嗪树脂及其制备方法和用途 |
-
2007
- 2007-11-23 CN CN2007101902455A patent/CN101177055B/zh not_active Expired - Fee Related
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102161762A (zh) * | 2011-01-19 | 2011-08-24 | 华东理工大学 | 一种改性苯并噁嗪树脂的方法 |
CN103012841A (zh) * | 2012-12-18 | 2013-04-03 | 四川大学 | 一种腰果酚-芳香二胺型苯并噁嗪增韧剂及其制备方法和用途 |
CN104903382B (zh) * | 2012-12-27 | 2017-06-16 | 3M创新有限公司 | 包含苯并噁嗪和成酸过氧化物催化剂的可聚合组合物、制品和方法 |
CN111205799A (zh) * | 2020-02-28 | 2020-05-29 | 杭摩新材料(嘉兴)有限公司 | 一种腰果酚改性酚醛树脂胶黏剂的生产工艺 |
CN111205797A (zh) * | 2020-02-28 | 2020-05-29 | 杭摩新材料(嘉兴)有限公司 | 酚醛树脂胶黏剂及其制备方法 |
CN111205799B (zh) * | 2020-02-28 | 2021-01-19 | 杭摩新材料(嘉兴)有限公司 | 一种腰果酚改性酚醛树脂胶黏剂的生产工艺 |
CN112940653A (zh) * | 2020-02-28 | 2021-06-11 | 杭摩新材料(嘉兴)有限公司 | 酚醛树脂胶黏剂及其制备方法 |
CN112940653B (zh) * | 2020-02-28 | 2022-08-30 | 杭摩新材料(嘉兴)有限公司 | 酚醛树脂胶黏剂及其制备方法 |
CN111763151A (zh) * | 2020-06-29 | 2020-10-13 | 浙江万盛股份有限公司 | 一种高防腐性能腰果酚改性多元胺固化剂的制备方法 |
CN111763151B (zh) * | 2020-06-29 | 2021-11-30 | 浙江万盛股份有限公司 | 一种高防腐性能腰果酚改性多元胺固化剂的制备方法 |
WO2022001515A1 (zh) * | 2020-06-29 | 2022-01-06 | 浙江万盛股份有限公司 | 一种高防腐性能腰果酚改性多元胺固化剂的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101177055B (zh) | 2010-06-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101177055B (zh) | 一种改性苯并噁嗪玻璃布层压板的制造方法 | |
US4954304A (en) | Process for producing prepreg and laminated sheet | |
JPH0156666B2 (zh) | ||
CN105928042A (zh) | 一种复合电热板及其制备方法 | |
CN101450493A (zh) | 改性木材、竹材胶合模板的制作方法 | |
CN107033328B (zh) | 一种改性环氧树脂及基于该树脂制备的玻璃纤维增强板材 | |
CN113277868B (zh) | 一种轻质碳纤维/碳复合热场材料及其制备方法 | |
CN106543391A (zh) | 一种双改性硼硅酚醛树脂的制备方法 | |
CN114800727A (zh) | 一种单板类人造板的制备方法 | |
CN107216608B (zh) | 一种高耐腐蚀的热固性树脂组合物及其应用 | |
CN115302885A (zh) | 一种高耐热高导热覆铜板及其制备方法 | |
CN110183824A (zh) | 一种导热绝缘环氧树脂层压复合材料及其制备方法和应用 | |
CN102212179A (zh) | 手糊玻璃钢用酚醛树脂的制备方法 | |
CN102069525B (zh) | 高频-接触联合加热制造纤维板厚板的工艺 | |
CN114851322B (zh) | 连续平压厚型人造板热压方法 | |
CN101961881B (zh) | 常温压制一种无机胶粘纤维板的制备方法及制备设备 | |
CN103172858B (zh) | 一种高频信号传输用电子材料的制备方法 | |
CN106928478B (zh) | 一种苯并噁嗪树脂层压板的制备方法 | |
CN103724931B (zh) | 一种改性酚醛树脂、透波复合材料及制备方法 | |
CN101735458B (zh) | 低熔体粘度氰酸酯/双马来酰亚胺树脂、制备方法及其应用 | |
CN102977337B (zh) | C级改性双马来酰亚胺玻璃纤维增强模塑料 | |
JPH037205B2 (zh) | ||
Hu et al. | Optimization of hot-press process and structural characterization of PF Camellia oleifera cake adhesive | |
CN106700462B (zh) | 一种用于制备特种变压器聚酯绝缘板的半固化片、特种变压器聚酯绝缘板及制备方法 | |
TWI381006B (zh) | An accelerated thermosetting thermosetting resin |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
PP01 | Preservation of patent right |
Effective date of registration: 20160226 Granted publication date: 20100616 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20160317 Granted publication date: 20100616 |
|
PP01 | Preservation of patent right |
Effective date of registration: 20160318 Granted publication date: 20100616 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20160918 Granted publication date: 20100616 |
|
PP01 | Preservation of patent right |
Effective date of registration: 20161020 Granted publication date: 20100616 |
|
RINS | Preservation of patent right or utility model and its discharge | ||
PD01 | Discharge of preservation of patent | ||
PD01 | Discharge of preservation of patent |
Date of cancellation: 20170420 Granted publication date: 20100616 |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100616 Termination date: 20191123 |