CN101155841B - 共聚物及其薄膜 - Google Patents
共聚物及其薄膜 Download PDFInfo
- Publication number
- CN101155841B CN101155841B CN2006800112462A CN200680011246A CN101155841B CN 101155841 B CN101155841 B CN 101155841B CN 2006800112462 A CN2006800112462 A CN 2006800112462A CN 200680011246 A CN200680011246 A CN 200680011246A CN 101155841 B CN101155841 B CN 101155841B
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- CN
- China
- Prior art keywords
- film
- multipolymer
- under
- alpha
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Laminated Bodies (AREA)
Abstract
Description
性质 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
密度(g/cm3) | 0.919 | 0.9194 | 0.9191 | 0.9181 | 0.9187 | 0.9184 |
熔体指数(g/10ml) | 1.3 | 1.2 | 1.1 | 0.95 | 1.28 | 1.17 |
流动活化能(kJ/mol) | 32 | 32 | ||||
分子量分布 | 3.8 | 3.8 | 3.9 | 3.8 | 3.9 | 3.7 |
熔体弹性模量G’(Pa) | 50 | 51 | 59 | 64 | 53 | 51 |
PS标准物 | 分子量 |
12345678910111213 | 752000042900002630000127000070600035500019000011400043700186001090065202950 |
性质 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
雾度(%) | 5.7 | 5.4 | 6.0 | 6.5 | 5.9 |
光泽度45°(%) | 69 | 72 | 76 | 71 | 70 |
落镖冲击强度(g) | 2250 | 2375 | 1323 | 1367 | 1980 |
Claims (16)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05250736.5 | 2005-02-09 | ||
EP05250736 | 2005-02-09 | ||
PCT/GB2006/000276 WO2006085051A1 (en) | 2005-02-09 | 2006-01-27 | Copolymers and films thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101155841A CN101155841A (zh) | 2008-04-02 |
CN101155841B true CN101155841B (zh) | 2011-06-08 |
Family
ID=34940444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006800112462A Active CN101155841B (zh) | 2005-02-09 | 2006-01-27 | 共聚物及其薄膜 |
Country Status (10)
Country | Link |
---|---|
US (1) | US7968659B2 (zh) |
EP (1) | EP1848750B1 (zh) |
JP (1) | JP5546730B2 (zh) |
CN (1) | CN101155841B (zh) |
AT (1) | ATE459665T1 (zh) |
DE (1) | DE602006012623D1 (zh) |
ES (1) | ES2340707T3 (zh) |
MY (1) | MY141927A (zh) |
TW (1) | TWI482783B (zh) |
WO (1) | WO2006085051A1 (zh) |
Families Citing this family (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1935909A1 (en) | 2006-12-21 | 2008-06-25 | Ineos Europe Limited | Copolymers and films thereof |
DE112008003204T5 (de) * | 2007-11-30 | 2010-10-14 | Sumitomo Chemical Company, Ltd. | Ethylen-a-Olefin-Copolymer und Formgegenstand |
EP2133367A1 (en) * | 2008-06-09 | 2009-12-16 | INEOS Manufacturing Belgium NV | Novel Copolymers |
JP2010150511A (ja) * | 2008-09-19 | 2010-07-08 | Sumitomo Chemical Co Ltd | エチレン系樹脂およびフィルム |
US8841391B2 (en) | 2008-10-03 | 2014-09-23 | Ineos Sales (Uk) Limited | Process for the introduction of a polymerisation catalyst into a gas-phase fluidised bed |
EP2172262A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Process |
EP2172490A1 (en) | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Controlled polymerisation process |
EP2177548A1 (en) * | 2008-10-14 | 2010-04-21 | Ineos Europe Limited | Copolymers and films thereof |
US8114946B2 (en) | 2008-12-18 | 2012-02-14 | Chevron Phillips Chemical Company Lp | Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches |
JP2010254963A (ja) * | 2009-03-31 | 2010-11-11 | Sumitomo Chemical Co Ltd | フードストレッチ用チューブ状フィルム |
EP2357035A1 (en) | 2010-01-13 | 2011-08-17 | Ineos Europe Limited | Polymer powder storage and/or transport and/or degassing vessels |
EP2348057A1 (en) | 2010-01-21 | 2011-07-27 | INEOS Manufacturing Belgium NV | Novel polymers |
EP2383301A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
EP2383298A1 (en) | 2010-04-30 | 2011-11-02 | Ineos Europe Limited | Polymerization process |
EP2410011A1 (en) | 2010-07-23 | 2012-01-25 | INEOS Manufacturing Belgium NV | Polyethylene composition |
CN103328518B (zh) | 2010-11-29 | 2016-07-06 | 英力士销售(英国)有限公司 | 聚合控制方法 |
US8383740B1 (en) | 2011-08-12 | 2013-02-26 | Ineos Usa Llc | Horizontal agitator |
EP2768870B1 (en) | 2011-10-17 | 2018-01-10 | Ineos Europe AG | Polymer degassing process control |
CN104080851B (zh) * | 2011-11-23 | 2016-10-26 | 陶氏环球技术有限责任公司 | 具有宽分子量分布和低可提取物的低密度的基于乙烯的聚合物 |
ES2610803T3 (es) * | 2011-11-23 | 2017-05-03 | Dow Global Technologies Llc | Polímeros basados en etileno de baja densidad con extractos de pesos moleculares más bajos |
EP2785786B1 (en) * | 2011-12-01 | 2018-05-30 | Ineos Europe AG | Polymer blends |
IN2014CN04332A (zh) | 2011-12-14 | 2015-09-04 | Ineos Europe Ag | |
CN104205245B (zh) | 2012-01-26 | 2020-06-23 | 英尼奥斯欧洲股份公司 | 用于电线和电缆应用的共聚物 |
US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
EP2864374B2 (en) * | 2012-06-26 | 2023-08-16 | Ineos Europe AG | Film composition |
US9096700B2 (en) | 2012-12-10 | 2015-08-04 | Exxonmobil Chemical Patents Inc. | Polymerization process for production of polymer |
JP6231579B2 (ja) | 2012-12-14 | 2017-11-15 | ノヴァ ケミカルズ(アンテルナショナル)ソシエテ アノニム | エチレンコポリマー組成物、フィルム及び重合プロセス |
CN104822716B (zh) * | 2012-12-21 | 2017-11-14 | 埃克森美孚化学专利公司 | 具有改进的加工性的支化聚乙烯及由其制成的高抗撕裂性膜 |
US9266977B2 (en) | 2012-12-21 | 2016-02-23 | Exxonmobil Chemical Patents Inc. | Bridged metallocene compounds, catalyst systems and processes for polymerization therewith |
CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
EP4321564A3 (en) | 2015-07-09 | 2024-04-24 | Ineos Europe AG | Copolymers and films thereof |
US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
US10442921B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations |
US10683376B2 (en) | 2017-11-07 | 2020-06-16 | Nova Chemicals (International) S.A. | Manufacturing ethylene interpolymer products at higher production rate |
US10995166B2 (en) | 2017-11-07 | 2021-05-04 | Nova Chemicals (International) S.A. | Ethylene interpolymer products and films |
US10882987B2 (en) | 2019-01-09 | 2021-01-05 | Nova Chemicals (International) S.A. | Ethylene interpolymer products having intermediate branching |
US11046843B2 (en) | 2019-07-29 | 2021-06-29 | Nova Chemicals (International) S.A. | Ethylene copolymers and films with excellent sealing properties |
CN114729080A (zh) | 2019-11-14 | 2022-07-08 | 埃克森美孚化学专利公司 | 气相聚乙烯共聚物 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6300437B1 (en) * | 1994-04-07 | 2001-10-09 | Bp Chemicals Limited | Polymerization process |
EP1443062A2 (en) * | 1998-01-07 | 2004-08-04 | BP Chemicals Limited | Homopolymers and copolymers of ethylene |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9122327D0 (en) | 1991-10-22 | 1991-12-04 | British Petroleum Co Plc | Polymer blends |
WO1994014855A1 (en) | 1992-12-28 | 1994-07-07 | Mobil Oil Corporation | Linear low density polyethylene film |
ES2125458T3 (es) | 1993-05-13 | 1999-03-01 | Exxon Chemical Patents Inc | Copolimeros de etileno que tienen una distribucion de la composicion estrecha, su produccion y uso. |
US6462161B1 (en) * | 1996-05-17 | 2002-10-08 | Bp Chemicals Limited | Polyolefin composition with molecular weight maximum occurring in that part of the composition that has the highest comonomer content |
US6204335B1 (en) | 1997-09-12 | 2001-03-20 | Eastman Chemical Company | Compositions of linear ultra low density polyethylene and propylene polymers and films therefrom |
CA2245375C (en) | 1998-08-19 | 2006-08-15 | Nova Chemicals Ltd. | Dual reactor polyethylene process using a phosphinimine catalyst |
EP1177225B1 (en) * | 1999-05-05 | 2009-01-14 | Ineos Europe Limited | Ethylene copolymers and films thereof |
US6339134B1 (en) * | 1999-05-06 | 2002-01-15 | Univation Technologies, Llc | Polymerization process for producing easier processing polymers |
BR0111310B1 (pt) * | 2000-06-01 | 2011-02-08 | novos filmes de polietileno. | |
US6884747B2 (en) * | 2000-10-06 | 2005-04-26 | Univation Technologies, Llc | Linear low density polyethylenes with high melt strength and high melt index ratio |
EP1312625A1 (en) * | 2001-11-20 | 2003-05-21 | BP Chemicals SNC | Gas phase polymerization process |
JP2004149760A (ja) * | 2002-03-28 | 2004-05-27 | Sumitomo Chem Co Ltd | 加工性に優れたエチレン重合体 |
JP2004149761A (ja) * | 2002-09-02 | 2004-05-27 | Sumitomo Chem Co Ltd | エチレン重合体 |
GB0319467D0 (en) | 2003-08-19 | 2003-09-17 | Bp Chem Int Ltd | Polymer blends |
-
2006
- 2006-01-27 AT AT06703268T patent/ATE459665T1/de not_active IP Right Cessation
- 2006-01-27 DE DE602006012623T patent/DE602006012623D1/de active Active
- 2006-01-27 JP JP2007554627A patent/JP5546730B2/ja active Active
- 2006-01-27 EP EP06703268A patent/EP1848750B1/en active Active
- 2006-01-27 CN CN2006800112462A patent/CN101155841B/zh active Active
- 2006-01-27 US US11/883,162 patent/US7968659B2/en active Active
- 2006-01-27 ES ES06703268T patent/ES2340707T3/es active Active
- 2006-01-27 WO PCT/GB2006/000276 patent/WO2006085051A1/en active Application Filing
- 2006-02-08 TW TW095104193A patent/TWI482783B/zh not_active IP Right Cessation
- 2006-02-08 MY MYPI20060544A patent/MY141927A/en unknown
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6300437B1 (en) * | 1994-04-07 | 2001-10-09 | Bp Chemicals Limited | Polymerization process |
EP1443062A2 (en) * | 1998-01-07 | 2004-08-04 | BP Chemicals Limited | Homopolymers and copolymers of ethylene |
Also Published As
Publication number | Publication date |
---|---|
JP5546730B2 (ja) | 2014-07-09 |
WO2006085051A1 (en) | 2006-08-17 |
MY141927A (en) | 2010-07-30 |
TWI482783B (zh) | 2015-05-01 |
DE602006012623D1 (de) | 2010-04-15 |
ES2340707T3 (es) | 2010-06-08 |
US7968659B2 (en) | 2011-06-28 |
JP2008530297A (ja) | 2008-08-07 |
EP1848750B1 (en) | 2010-03-03 |
CN101155841A (zh) | 2008-04-02 |
TW200634029A (en) | 2006-10-01 |
ATE459665T1 (de) | 2010-03-15 |
US20080249262A1 (en) | 2008-10-09 |
EP1848750A1 (en) | 2007-10-31 |
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C06 | Publication | ||
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C10 | Entry into substantive examination | ||
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: INEOS COMMERCIAL SERVICES UK LIMITED Free format text: FORMER OWNER: INNOVENE EUROP LTD. Effective date: 20111129 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20111129 Address after: England Hampshire Patentee after: Ineos Commercial Services UK Limited Address before: England Hampshire Patentee before: Innovene Europ Ltd. |
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ASS | Succession or assignment of patent right |
Owner name: INEOS SALES (UK) LIMITED Free format text: FORMER OWNER: INEOS COMMERCIAL SERVICES UK LIMITED Effective date: 20140722 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20140722 Address after: England Hampshire Patentee after: Neos Commercial Services UK Limited Address before: England Hampshire Patentee before: Ineos Commercial Services UK Limited |