CN101054435A - 一种耐水解、剥离强度高的湿式聚氨酯树脂及其制备方法 - Google Patents
一种耐水解、剥离强度高的湿式聚氨酯树脂及其制备方法 Download PDFInfo
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- CN101054435A CN101054435A CN 200710040024 CN200710040024A CN101054435A CN 101054435 A CN101054435 A CN 101054435A CN 200710040024 CN200710040024 CN 200710040024 CN 200710040024 A CN200710040024 A CN 200710040024A CN 101054435 A CN101054435 A CN 101054435A
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- polyurethane resin
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- 238000000034 method Methods 0.000 title claims abstract description 15
- 229920005989 resin Polymers 0.000 title description 4
- 239000011347 resin Substances 0.000 title description 4
- 229920000768 polyamine Polymers 0.000 title 1
- 229920005749 polyurethane resin Polymers 0.000 claims abstract description 21
- 230000007062 hydrolysis Effects 0.000 claims abstract description 20
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 20
- -1 alcohol compound Chemical class 0.000 claims abstract description 19
- 150000002009 diols Chemical class 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 29
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 15
- 229920005862 polyol Polymers 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 6
- 239000002649 leather substitute Substances 0.000 claims description 6
- 229920005906 polyester polyol Polymers 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 150000002148 esters Chemical class 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 229940051250 hexylene glycol Drugs 0.000 claims description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 claims 1
- 150000002334 glycols Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004606 Fillers/Extenders Substances 0.000 abstract 3
- 239000012948 isocyanate Substances 0.000 abstract 3
- 150000002513 isocyanates Chemical class 0.000 abstract 3
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 11
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 7
- BJZYYSAMLOBSDY-QMMMGPOBSA-N (2s)-2-butoxybutan-1-ol Chemical compound CCCCO[C@@H](CC)CO BJZYYSAMLOBSDY-QMMMGPOBSA-N 0.000 description 5
- 230000000655 anti-hydrolysis Effects 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 101000573147 Arabidopsis thaliana Pectinesterase 6 Proteins 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Polyurethanes Or Polyureas (AREA)
Abstract
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CN200710040024A CN101054435B (zh) | 2007-04-26 | 2007-04-26 | 一种耐水解、剥离强度高的湿式聚氨酯树脂及其制备方法 |
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CN200710040024A CN101054435B (zh) | 2007-04-26 | 2007-04-26 | 一种耐水解、剥离强度高的湿式聚氨酯树脂及其制备方法 |
Publications (2)
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CN101054435A true CN101054435A (zh) | 2007-10-17 |
CN101054435B CN101054435B (zh) | 2010-05-19 |
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CN200710040024A Expired - Fee Related CN101054435B (zh) | 2007-04-26 | 2007-04-26 | 一种耐水解、剥离强度高的湿式聚氨酯树脂及其制备方法 |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381448B (zh) * | 2008-10-14 | 2010-07-21 | 旭川化学(苏州)有限公司 | 一种防水透气服装革用聚氨酯树脂 |
CN101921381A (zh) * | 2010-09-07 | 2010-12-22 | 上海英诺威化学有限公司 | 水性聚氨酯乳液的制备方法及其作为真空吸塑胶用胶黏剂的应用 |
CN102010496A (zh) * | 2010-09-29 | 2011-04-13 | 上海汇得树脂有限公司 | 超软质湿法压花型聚氨酯树脂及其制备方法和应用 |
CN102010497A (zh) * | 2010-09-29 | 2011-04-13 | 上海汇得树脂有限公司 | 一种聚氨酯树脂及其制备方法和应用 |
CN102181034A (zh) * | 2010-10-20 | 2011-09-14 | 上海汇得化工有限公司 | 一种高密度鞋革用聚氨酯树脂及制备方法 |
CN102181031A (zh) * | 2010-10-20 | 2011-09-14 | 上海汇得化工有限公司 | 一种耐久性沙发革用聚氨酯树脂及制备方法 |
CN102181036A (zh) * | 2010-10-20 | 2011-09-14 | 上海汇得化工有限公司 | 一种鞋用透气吸水pu树脂 |
CN102733197A (zh) * | 2012-06-07 | 2012-10-17 | 温州瑞普三利高分子材料有限公司 | 一种湿法耐水解树脂的制备方法 |
CN102775577A (zh) * | 2012-08-02 | 2012-11-14 | 烟台万华超纤股份有限公司 | 耐水解粉末聚氨酯及其制备方法 |
CN102993398A (zh) * | 2012-10-16 | 2013-03-27 | 福建国邦树脂有限公司 | 湿法聚氨酯树脂及其生产工艺和使用方法 |
CN105153397A (zh) * | 2015-09-21 | 2015-12-16 | 合肥安利聚氨酯新材料有限公司 | 一种弹力革用干爽性、耐寒性面层聚氨酯树脂的制备方法 |
CN106008913A (zh) * | 2016-06-02 | 2016-10-12 | 台州禾欣高分子新材料有限公司 | 一种耐水解聚氨酯树脂及其在耐水解镜面革中的应用 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100471890C (zh) * | 2003-11-18 | 2009-03-25 | 三洋化成工业株式会社 | 合成皮革用聚氨酯树脂及多孔片状材料 |
-
2007
- 2007-04-26 CN CN200710040024A patent/CN101054435B/zh not_active Expired - Fee Related
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101381448B (zh) * | 2008-10-14 | 2010-07-21 | 旭川化学(苏州)有限公司 | 一种防水透气服装革用聚氨酯树脂 |
CN101921381A (zh) * | 2010-09-07 | 2010-12-22 | 上海英诺威化学有限公司 | 水性聚氨酯乳液的制备方法及其作为真空吸塑胶用胶黏剂的应用 |
CN101921381B (zh) * | 2010-09-07 | 2013-01-23 | 上海英诺威新材料科技有限公司 | 应用于水基真空吸塑胶用胶黏剂的聚氨酯乳液的制备方法 |
CN102010497B (zh) * | 2010-09-29 | 2012-08-22 | 上海汇得化工有限公司 | 一种聚氨酯树脂及其制备方法和应用 |
CN102010496A (zh) * | 2010-09-29 | 2011-04-13 | 上海汇得树脂有限公司 | 超软质湿法压花型聚氨酯树脂及其制备方法和应用 |
CN102010497A (zh) * | 2010-09-29 | 2011-04-13 | 上海汇得树脂有限公司 | 一种聚氨酯树脂及其制备方法和应用 |
CN102181031B (zh) * | 2010-10-20 | 2012-12-19 | 上海汇得化工有限公司 | 一种耐久性沙发革用聚氨酯树脂及制备方法 |
CN102181036A (zh) * | 2010-10-20 | 2011-09-14 | 上海汇得化工有限公司 | 一种鞋用透气吸水pu树脂 |
CN102181034B (zh) * | 2010-10-20 | 2012-12-19 | 上海汇得化工有限公司 | 一种高密度鞋革用聚氨酯树脂及制备方法 |
CN102181036B (zh) * | 2010-10-20 | 2012-12-19 | 上海汇得化工有限公司 | 一种鞋用透气吸水pu树脂 |
CN102181031A (zh) * | 2010-10-20 | 2011-09-14 | 上海汇得化工有限公司 | 一种耐久性沙发革用聚氨酯树脂及制备方法 |
CN102181034A (zh) * | 2010-10-20 | 2011-09-14 | 上海汇得化工有限公司 | 一种高密度鞋革用聚氨酯树脂及制备方法 |
CN102733197A (zh) * | 2012-06-07 | 2012-10-17 | 温州瑞普三利高分子材料有限公司 | 一种湿法耐水解树脂的制备方法 |
CN102775577A (zh) * | 2012-08-02 | 2012-11-14 | 烟台万华超纤股份有限公司 | 耐水解粉末聚氨酯及其制备方法 |
CN102993398A (zh) * | 2012-10-16 | 2013-03-27 | 福建国邦树脂有限公司 | 湿法聚氨酯树脂及其生产工艺和使用方法 |
CN105153397A (zh) * | 2015-09-21 | 2015-12-16 | 合肥安利聚氨酯新材料有限公司 | 一种弹力革用干爽性、耐寒性面层聚氨酯树脂的制备方法 |
CN106008913A (zh) * | 2016-06-02 | 2016-10-12 | 台州禾欣高分子新材料有限公司 | 一种耐水解聚氨酯树脂及其在耐水解镜面革中的应用 |
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CN101054435B (zh) | 2010-05-19 |
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EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shanghai Huide Chemical Co., Ltd. Assignor: Shanghai Huide Resin Co., Ltd. Contract record no.: 2010990000707 Denomination of invention: Wet-type polyamine resin with hydrolyzation resistance and high peeling strength and preparing method thereof Granted publication date: 20100519 License type: Exclusive License Open date: 20071017 Record date: 20100902 |
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Owner name: SHANGHAI HUIDE CHEMICAL CO., LTD. Free format text: FORMER OWNER: HUIDE RESINS CO., LTD., SHANGHAI Effective date: 20120312 |
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Free format text: CORRECT: ADDRESS; FROM: 201318 NANHUI, SHANGHAI TO: 201512 JINSHAN, SHANGHAI |
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Effective date of registration: 20120312 Address after: 201512 Shanghai City, Jinshan District Jinshanwei town Chunhua Road No. 180 Patentee after: Shanghai Huide Chemical Co., Ltd. Address before: 201318, No. 3736, Lane 8, Shanghai South Road, Zhou Town, Nanhui District, Shanghai Patentee before: Shanghai Huide Resin Co., Ltd. |
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C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 201512 Shanghai City, Jinshan District Jinshanwei town Chunhua Road No. 180 Patentee after: SHANGHAI HUIDE TECHNOLOGY CO., LTD. Address before: 201512 Shanghai City, Jinshan District Jinshanwei town Chunhua Road No. 180 Patentee before: Shanghai Huide Chemical Co., Ltd. |
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Granted publication date: 20100519 Termination date: 20190426 |