CA2877612C - Nanotubes de carbone et leur procede de production - Google Patents

Nanotubes de carbone et leur procede de production Download PDF

Info

Publication number
CA2877612C
CA2877612C CA2877612A CA2877612A CA2877612C CA 2877612 C CA2877612 C CA 2877612C CA 2877612 A CA2877612 A CA 2877612A CA 2877612 A CA2877612 A CA 2877612A CA 2877612 C CA2877612 C CA 2877612C
Authority
CA
Canada
Prior art keywords
catalyst
carbon nanotubes
carbon
catalyst particles
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2877612A
Other languages
English (en)
Other versions
CA2877612A1 (fr
Inventor
Suguru Noda
Zhongming Chen
Dong Young Kim
Shunsuke Ueda
Eisuke Haba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Tokyo NUC
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
University of Tokyo NUC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd, University of Tokyo NUC filed Critical Hitachi Chemical Co Ltd
Publication of CA2877612A1 publication Critical patent/CA2877612A1/fr
Application granted granted Critical
Publication of CA2877612C publication Critical patent/CA2877612C/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B01J35/50—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0238—Impregnation, coating or precipitation via the gaseous phase-sublimation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts

Abstract

La présente invention concerne un procédé de production de nanotubes de carbone capables de croître avec des nanotubes de carbone allongés de haute densité avec un petit diamètre et une bonne cristallinité. Ce procédé de production de nanotubes de carbone comporte une étape de formation de particules de catalyseur pour chauffer et réduire un matériau brut de catalyseur pour former des particules de catalyseur, et une étape de synthèse de nanotubes de carbone pour la circulation d'un matériau gazeux brut sur les particules de catalyseur dans un état chauffé pour synthétiser des nanotubes de carbone, où un composé de gaz contenant du carbone n'ayant pas de doubles liaisons insaturées est mis en circulation sur le matériau brut de catalyseur et/ou les particules de catalyseur dans l'étape de formation des particules de catalyseur et/ou l'étape de synthèse des nanotubes de carbone.
CA2877612A 2012-06-22 2013-06-20 Nanotubes de carbone et leur procede de production Expired - Fee Related CA2877612C (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2012-141428 2012-06-22
JP2012141428 2012-06-22
PCT/JP2013/066971 WO2013191253A1 (fr) 2012-06-22 2013-06-20 Nanotubes de carbone et leur procédé de production

Publications (2)

Publication Number Publication Date
CA2877612A1 CA2877612A1 (fr) 2013-12-27
CA2877612C true CA2877612C (fr) 2020-09-15

Family

ID=49768845

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2877612A Expired - Fee Related CA2877612C (fr) 2012-06-22 2013-06-20 Nanotubes de carbone et leur procede de production

Country Status (7)

Country Link
US (1) US9463981B2 (fr)
EP (1) EP2865644B1 (fr)
JP (1) JP6338219B2 (fr)
KR (1) KR102164225B1 (fr)
CN (2) CN110002430A (fr)
CA (1) CA2877612C (fr)
WO (1) WO2013191253A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7062365B2 (ja) * 2017-02-28 2022-05-06 株式会社名城ナノカーボン 電界放出装置
KR20210035201A (ko) 2018-07-31 2021-03-31 가부시키가이샤 오사카소다 탄소 나노 튜브의 제조 방법
CN115383119A (zh) * 2021-12-01 2022-11-25 昆明理工大学 一种CNTs@HEAp复合增强体及其制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6919064B2 (en) * 2000-06-02 2005-07-19 The Board Of Regents Of The University Of Oklahoma Process and apparatus for producing single-walled carbon nanotubes
WO2002095097A1 (fr) * 2001-05-21 2002-11-28 Trustees Of Boston College, The Nanotubes de carbone de morphologie diverse et procedes de fabrication
KR101275055B1 (ko) 2002-02-13 2013-06-14 도레이 카부시키가이샤 단층 카본 나노튜브 함유 조성물
TWI237064B (en) * 2002-03-25 2005-08-01 Ind Tech Res Inst Supported metal catalyst for synthesizing carbon nanotubes by low-temperature thermal chemical vapor deposition and method of synthesizing nanotubes using the same
KR100596676B1 (ko) * 2003-03-20 2006-07-04 이철진 기상합성법에 의한 단일벽 탄소 나노튜브의 대량 합성 방법
EP3181518A1 (fr) 2004-07-27 2017-06-21 National Institute of Advanced Industrial Science and Technology Structure massive de nanotube de carbone à paroi unique alignée, son procédé de production et utilisation
SG157390A1 (en) * 2004-11-10 2009-12-29 Nikon Corp Carbon nanotube assembly and manufacturing method thereof
CN1673073A (zh) 2005-03-11 2005-09-28 北京大学 一种合成单壁碳纳米管的方法
JP2006298684A (ja) * 2005-04-19 2006-11-02 Sony Corp 炭素系一次元材料およびその合成方法ならびに炭素系一次元材料合成用触媒およびその合成方法ならびに電子素子およびその製造方法
JP2007115854A (ja) * 2005-10-19 2007-05-10 Bussan Nanotech Research Institute Inc 電磁波吸収体
JP4847106B2 (ja) * 2005-11-18 2011-12-28 保土谷化学工業株式会社 炭素繊維構造体
KR101328294B1 (ko) * 2005-12-29 2013-11-14 도레이 카부시키가이샤 카본 나노 튜브의 제조 방법 및 카본 나노 튜브 제조용촉매
JP2009528254A (ja) 2006-03-03 2009-08-06 ザ ボード オブ トラスティーズ オブ ザ ユニヴァーシティー オブ イリノイ 空間的に配列したナノチューブ及びナノチューブアレイの作製方法
JP5570686B2 (ja) * 2007-05-07 2014-08-13 国立大学法人北海道大学 微細炭素繊維分散皮膜およびその製造方法
JP5301793B2 (ja) * 2007-05-07 2013-09-25 国立大学法人北海道大学 再分散用微細炭素繊維集合塊およびその製造方法
KR100962171B1 (ko) * 2007-12-26 2010-06-10 제일모직주식회사 탄소나노튜브 합성용 금속나노촉매 및 이를 이용한탄소나노튜브의 제조방법
US8591858B2 (en) * 2008-05-01 2013-11-26 Honda Motor Co., Ltd. Effect of hydrocarbon and transport gas feedstock on efficiency and quality of grown single-walled nanotubes
KR20110092274A (ko) * 2008-11-18 2011-08-17 유니버시티 세인즈 말레이시아 탄소 나노튜브 (ｃｎｔ)의 제조 방법
WO2010076885A1 (fr) * 2008-12-30 2010-07-08 独立行政法人産業技術総合研究所 Ensemble nanotubes de carbone à paroi simple aligne, ensemble nanotubes de carbone à paroi simple aligne en vrac, ensemble nanotubes de carbone à paroi simple aligne sous forme de poudre, et leur procede de production
WO2012057229A1 (fr) * 2010-10-26 2012-05-03 日立化成工業株式会社 Procédé pour la production de nanotubes de carbone

Also Published As

Publication number Publication date
CN104395233A (zh) 2015-03-04
CN110002430A (zh) 2019-07-12
EP2865644B1 (fr) 2018-01-31
EP2865644A4 (fr) 2016-02-24
US9463981B2 (en) 2016-10-11
KR20150035752A (ko) 2015-04-07
EP2865644A1 (fr) 2015-04-29
KR102164225B1 (ko) 2020-10-12
JPWO2013191253A1 (ja) 2016-05-26
US20150147263A1 (en) 2015-05-28
WO2013191253A1 (fr) 2013-12-27
JP6338219B2 (ja) 2018-06-06
CA2877612A1 (fr) 2013-12-27

Similar Documents

Publication Publication Date Title
Van Dommele et al. Tuning nitrogen functionalities in catalytically grown nitrogen-containing carbon nanotubes
Koós et al. Effect of the experimental parameters on the structure of nitrogen-doped carbon nanotubes produced by aerosol chemical vapour deposition
Henao et al. Selective synthesis of carbon nanotubes by catalytic decomposition of methane using Co-Cu/cellulose derived carbon catalysts: A comprehensive kinetic study
JP5106123B2 (ja) カーボンナノホーン担持体とカーボンナノチューブの合成方法
Gaikwad et al. Carbon nanotube/carbon nanofiber growth from industrial by-product gases on low-and high-alloy steels
Pasha et al. Hot filament CVD of Fe–Cr catalyst for thermal CVD carbon nanotube growth from liquid petroleum gas
CA2877612C (fr) Nanotubes de carbone et leur procede de production
Ezz et al. Synthesis and characterization of nanocarbon having different morphological structures by chemical vapor deposition over Fe-Ni-Co-Mo/MgO catalyst
Donato et al. Influence of carbon source and Fe-catalyst support on the growth of multi-walled carbon nanotubes
Mathur et al. A comparative study of the growth, microstructural and electrical properties of multiwall CNTs grown by thermal and microwave plasma enhanced CVD methods
Liu et al. Effects of argon flow rate and reaction temperature on synthesizing single-walled carbon nanotubes from ethanol
Yoshihara et al. Growth mechanism of carbon nanotubes over gold-supported catalysts
Shlyakhova et al. Catalytic synthesis of carbon nanotubes using Ni-and Co-doped calcium tartrates
KR101679693B1 (ko) 탄소나노튜브 제조방법 및 하이브리드 탄소나노튜브 복합체
US10357765B2 (en) Carbon-containing metal catalyst particles for carbon nanotube synthesis and method of producing the same, catalyst carrier support, and method of producing carbon nanotubes
Bertoni et al. Growth of multi-wall and single-wall carbon nanotubes with in situ high vacuum catalyst deposition
Rajesh et al. Lanthanum nickel alloy catalyzed growth of nitrogen-doped carbon nanotubes by chemical vapor deposition
Grimm et al. Catalytic decomposition of n-heptane for the growth of high quality single wall carbon nanotubes
Sengupta et al. Pre-heating effect on the catalytic growth of partially filled carbon nanotubes by chemical vapor deposition
Singh et al. Growth of multiwalled carbon nanotubes from acetylene over in situ formed Co nanoparticles on MgO support
Lee et al. Ultraviolet irradiated ozone treatment of a metal catalyst for the large-scale synthesis of single-walled carbon nanotubes with small, uniform diameters
Azam et al. Active Cobalt Catalyst for Carbon Powder Growth: Sol-gel Process and Alcohol Catalytic CVD Technique
Wang et al. Towards the single-walled B-and/or N-doped carbon nanotubes
Aghaei et al. Synthesis single-wall carbon nanotube by catalytic decomposition of methane over Fe–Mo/Al2O3

Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20180620

MKLA Lapsed

Effective date: 20210621