BR112019024660A2 - Composição oxidante, processo para oxidar um substrato e método para gerar um eletrófilo oxidante - Google Patents

Composição oxidante, processo para oxidar um substrato e método para gerar um eletrófilo oxidante Download PDF

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Publication number
BR112019024660A2
BR112019024660A2 BR112019024660-6A BR112019024660A BR112019024660A2 BR 112019024660 A2 BR112019024660 A2 BR 112019024660A2 BR 112019024660 A BR112019024660 A BR 112019024660A BR 112019024660 A2 BR112019024660 A2 BR 112019024660A2
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Brazil
Prior art keywords
oxidant
electrophile
deactivated
composition
substrate
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BR112019024660-6A
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English (en)
Inventor
A. Periana Roy
G. Hashiguchi Brian
M. Konnick Michael
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The Scripps Research Institute
Hyconix, Inc.
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Publication of BR112019024660A2 publication Critical patent/BR112019024660A2/pt

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
    • C07C27/16—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/18—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/202—Ethylene glycol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/18—Polyhydroxylic acyclic alcohols
    • C07C31/20—Dihydroxylic alcohols
    • C07C31/205—1,3-Propanediol; 1,2-Propanediol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62—Halogen-containing esters
    • C07C69/63—Halogen-containing esters of saturated acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Abstract

é fornecida uma composição oxidante, na qual um meio líquido é substancialmente inerte na presença de um eletrófilo oxidante contido no meio líquido. a composição compreende (a) um eletrófilo oxidante compreendendo um elemento do grupo principal na forma oxidada e pelo menos um ânion conjugado de um ácido oxigenado; (b) um líquido não oxidável selecionado a partir de um hidrocarboneto fluorado, uma sulfona, um areno desativado, um alifático desativado, um heteroareno desativado, um heteroalifático desativado e uma combinação dos mesmos; e (c) opcionalmente um ou mais aditivos de sal. além disso, é fornecido um método para usar a composição oxidante para oxidar um substrato e um método para gerar e/ ou regenerar um eletrófilo oxidante compreendendo um elemento do grupo principal.
BR112019024660-6A 2017-05-25 2018-05-25 Composição oxidante, processo para oxidar um substrato e método para gerar um eletrófilo oxidante BR112019024660A2 (pt)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201762511173P 2017-05-25 2017-05-25
US62/511,173 2017-05-25
US201862654119P 2018-04-06 2018-04-06
US201862654133P 2018-04-06 2018-04-06
US62/654,119 2018-04-06
US62/654,133 2018-04-06
PCT/US2018/034698 WO2018218171A1 (en) 2017-05-25 2018-05-25 Oxidizing liquid media for chemical transformations

Publications (1)

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BR112019024660A2 true BR112019024660A2 (pt) 2020-06-16

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BR112019024652A BR112019024652A2 (pt) 2017-05-25 2018-05-25 processo para converter um alcano em um alceno
BR112019024660-6A BR112019024660A2 (pt) 2017-05-25 2018-05-25 Composição oxidante, processo para oxidar um substrato e método para gerar um eletrófilo oxidante
BR112019024644A BR112019024644A2 (pt) 2017-05-25 2018-05-25 processo para oxidar um alceno

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BR112019024644A BR112019024644A2 (pt) 2017-05-25 2018-05-25 processo para oxidar um alceno

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US (3) US11078136B2 (pt)
EP (3) EP3634926A1 (pt)
CN (3) CN110831916A (pt)
AU (3) AU2018272065B2 (pt)
BR (3) BR112019024652A2 (pt)
CA (3) CA3064326A1 (pt)
RU (3) RU2733385C1 (pt)
WO (3) WO2018218171A1 (pt)

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TWI794742B (zh) 2020-02-18 2023-03-01 美商基利科學股份有限公司 抗病毒化合物
CN112675908A (zh) * 2020-12-23 2021-04-20 清华大学 一种醇类的有氧氧化方法
WO2022221514A1 (en) 2021-04-16 2022-10-20 Gilead Sciences, Inc. Methods of preparing carbanucleosides using amides

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Publication number Publication date
AU2018272055A1 (en) 2020-01-16
RU2732752C1 (ru) 2020-09-22
EP3634927A1 (en) 2020-04-15
CA3064335A1 (en) 2018-11-29
EP3634925A1 (en) 2020-04-15
CA3064326A1 (en) 2018-11-29
BR112019024644A2 (pt) 2020-06-09
RU2733385C1 (ru) 2020-10-01
US10858301B2 (en) 2020-12-08
AU2018273972B2 (en) 2020-10-29
WO2018218186A1 (en) 2018-11-29
CN110831916A (zh) 2020-02-21
AU2018272065A1 (en) 2020-01-16
US11078136B2 (en) 2021-08-03
EP3634926A1 (en) 2020-04-15
AU2018273972A1 (en) 2020-01-16
US20210163503A1 (en) 2021-06-03
CN110831917A (zh) 2020-02-21
AU2018272065B2 (en) 2020-08-13
US20200095179A1 (en) 2020-03-26
BR112019024652A2 (pt) 2020-06-09
CN110869338A (zh) 2020-03-06
AU2018272055B2 (en) 2020-10-22
WO2018218171A1 (en) 2018-11-29
CA3064336A1 (en) 2018-11-29
RU2733408C1 (ru) 2020-10-01
US11814348B2 (en) 2023-11-14
US20200095183A1 (en) 2020-03-26
WO2018218176A1 (en) 2018-11-29

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