BR112019024644A2 - processo para oxidar um alceno - Google Patents
processo para oxidar um alceno Download PDFInfo
- Publication number
- BR112019024644A2 BR112019024644A2 BR112019024644A BR112019024644A BR112019024644A2 BR 112019024644 A2 BR112019024644 A2 BR 112019024644A2 BR 112019024644 A BR112019024644 A BR 112019024644A BR 112019024644 A BR112019024644 A BR 112019024644A BR 112019024644 A2 BR112019024644 A2 BR 112019024644A2
- Authority
- BR
- Brazil
- Prior art keywords
- alkene
- oxidizing electrophile
- oxygenate
- oxidize
- reduced form
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 239000012039 electrophile Substances 0.000 abstract 4
- 230000001590 oxidative effect Effects 0.000 abstract 4
- 239000000654 additive Substances 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/50—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with an organic compound as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
- C07C27/10—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons
- C07C27/16—Processes involving the simultaneous production of more than one class of oxygen-containing compounds by oxidation of hydrocarbons with other oxidising agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/18—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
- C07C31/202—Ethylene glycol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
- C07C31/205—1,3-Propanediol; 1,2-Propanediol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/62—Halogen-containing esters
- C07C69/63—Halogen-containing esters of saturated acids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Abstract
é fornecido um processo para oxidar um alceno. o processo compreende o contato de um alceno e um eletrófilo oxidante compreendendo um elemento do grupo principal na forma oxidada ou um oxidante e uma forma reduzida do eletrófilo oxidante, em um meio líquido compreendendo um ácido oxigenado e, opcionalmente, um ou mais aditivos selecionados a partir de um líquido não oxidável, um aditivo de sal, um ácido de lewis e água, para fornecer um oxigenato e uma forma reduzida do eletrófilo oxidante. o processo opcionalmente compreende ainda a separação do oxigenato e a forma reduzida do eletrófilo oxidante. o oxigenato pode ser ainda mais hidrolisado para formar um álcool, diol ou poliol.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762511173P | 2017-05-25 | 2017-05-25 | |
US201862654119P | 2018-04-06 | 2018-04-06 | |
US201862654133P | 2018-04-06 | 2018-04-06 | |
PCT/US2018/034717 WO2018218186A1 (en) | 2017-05-25 | 2018-05-25 | Direct oxidation of olefins to oxygenated species |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112019024644A2 true BR112019024644A2 (pt) | 2020-06-09 |
Family
ID=62599756
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112019024652A BR112019024652A2 (pt) | 2017-05-25 | 2018-05-25 | processo para converter um alcano em um alceno |
BR112019024660-6A BR112019024660A2 (pt) | 2017-05-25 | 2018-05-25 | Composição oxidante, processo para oxidar um substrato e método para gerar um eletrófilo oxidante |
BR112019024644A BR112019024644A2 (pt) | 2017-05-25 | 2018-05-25 | processo para oxidar um alceno |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112019024652A BR112019024652A2 (pt) | 2017-05-25 | 2018-05-25 | processo para converter um alcano em um alceno |
BR112019024660-6A BR112019024660A2 (pt) | 2017-05-25 | 2018-05-25 | Composição oxidante, processo para oxidar um substrato e método para gerar um eletrófilo oxidante |
Country Status (8)
Country | Link |
---|---|
US (3) | US11078136B2 (pt) |
EP (3) | EP3634926A1 (pt) |
CN (3) | CN110831916A (pt) |
AU (3) | AU2018272065B2 (pt) |
BR (3) | BR112019024652A2 (pt) |
CA (3) | CA3064326A1 (pt) |
RU (3) | RU2733385C1 (pt) |
WO (3) | WO2018218171A1 (pt) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI794742B (zh) | 2020-02-18 | 2023-03-01 | 美商基利科學股份有限公司 | 抗病毒化合物 |
CN112675908A (zh) * | 2020-12-23 | 2021-04-20 | 清华大学 | 一种醇类的有氧氧化方法 |
WO2022221514A1 (en) | 2021-04-16 | 2022-10-20 | Gilead Sciences, Inc. | Methods of preparing carbanucleosides using amides |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE108969C (pt) | ||||
DD108969A1 (pt) * | 1973-06-28 | 1974-10-12 | ||
CA1079294A (en) | 1975-07-31 | 1980-06-10 | Takeshi Okano | Process for producing alkylene glycol esters |
SU722890A1 (ru) | 1978-07-31 | 1980-03-25 | Институт Теоретических Проблем Химической Технологии Ан Азербайджанской Сср | Способ получени аллена и метилацетилена |
US4508653A (en) | 1983-03-14 | 1985-04-02 | Ashland Oil, Inc. | Method for preparing acyloxy styrenes |
US5306855A (en) * | 1991-02-15 | 1994-04-26 | Catalytica, Inc. | Catalytic process for converting lower alkanes to esters, alcohols, and to hydrocarbons |
US5461179A (en) | 1993-07-07 | 1995-10-24 | Raytheon Engineers & Constructors, Inc. | Regeneration and stabilization of dehydrogenation catalysts |
IT1293497B1 (it) * | 1997-07-29 | 1999-03-01 | Snam Progetti | Procedimento per ottenere olefine leggere mediante deidrogenazione delle corrispondenti paraffine |
GB9806408D0 (en) * | 1998-03-25 | 1998-05-20 | Bp Chem Int Ltd | Olefin hydration process |
EP1077082A1 (en) * | 1999-08-17 | 2001-02-21 | Rohm And Haas Company | Heteropolyacid/polyoxometallate catalysts |
CN100354244C (zh) * | 2004-07-28 | 2007-12-12 | 华东理工大学 | C2~c3的二元醇的制备方法 |
CA2693965A1 (en) * | 2007-07-20 | 2009-01-29 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of alkylene glycols |
US7964765B2 (en) * | 2008-06-14 | 2011-06-21 | Lummus Technology Inc. | Styrene monomer process based on oxidative dehydrogenation of ethylbenzene using CO2 as a soft oxidant |
US8163825B2 (en) * | 2008-09-03 | 2012-04-24 | Exxonmobil Chemical Patents Inc. | Triglyceride plasticizers having low average levels of branching and process of making the same |
CN101597211B (zh) * | 2009-07-09 | 2012-03-28 | 华南理工大学 | 一种1,2-邻二醇化合物的制备方法 |
BR112013017429B1 (pt) | 2011-01-31 | 2019-02-12 | Shell Internationale Research Maatschappij B.V. | Processo para a produção de etileno glicol |
EP2771118A1 (en) * | 2011-10-24 | 2014-09-03 | Northwestern University | Alkane oxidation |
CN104114523A (zh) * | 2012-02-08 | 2014-10-22 | 神杰发展有限责任公司 | 生产醇的方法 |
EA030502B1 (ru) * | 2013-02-25 | 2018-08-31 | Дзе Скриппс Рисерч Инститьют | Окисление алканов до спиртов |
EP3030635B1 (en) * | 2013-08-06 | 2019-01-30 | The Scripps Research Institute | Conversion of alkanes to organoseleniums and organotelluriums |
WO2015176020A1 (en) * | 2014-05-16 | 2015-11-19 | Provivi, Inc. | Synthesis of olefinic alcohols via enzymatic terminal hydroxylation |
AU2015306741B2 (en) * | 2014-08-25 | 2020-03-05 | The Scripps Research Institute | Process for the functionalization of heteroalkanes and arenes |
-
2018
- 2018-05-25 CN CN201880034360.XA patent/CN110831916A/zh active Pending
- 2018-05-25 CA CA3064326A patent/CA3064326A1/en not_active Abandoned
- 2018-05-25 US US16/616,615 patent/US11078136B2/en active Active
- 2018-05-25 EP EP18733730.8A patent/EP3634926A1/en not_active Withdrawn
- 2018-05-25 AU AU2018272065A patent/AU2018272065B2/en not_active Ceased
- 2018-05-25 AU AU2018272055A patent/AU2018272055B2/en not_active Ceased
- 2018-05-25 BR BR112019024652A patent/BR112019024652A2/pt not_active Application Discontinuation
- 2018-05-25 WO PCT/US2018/034698 patent/WO2018218171A1/en active Application Filing
- 2018-05-25 RU RU2019143400A patent/RU2733385C1/ru active
- 2018-05-25 EP EP18733731.6A patent/EP3634927A1/en not_active Withdrawn
- 2018-05-25 WO PCT/US2018/034706 patent/WO2018218176A1/en active Application Filing
- 2018-05-25 RU RU2019143406A patent/RU2733408C1/ru active
- 2018-05-25 CN CN201880034329.6A patent/CN110869338A/zh active Pending
- 2018-05-25 EP EP18731316.8A patent/EP3634925A1/en not_active Withdrawn
- 2018-05-25 US US16/616,604 patent/US11814348B2/en active Active
- 2018-05-25 US US16/616,626 patent/US10858301B2/en active Active
- 2018-05-25 CA CA3064336A patent/CA3064336A1/en not_active Abandoned
- 2018-05-25 RU RU2019143401A patent/RU2732752C1/ru active
- 2018-05-25 BR BR112019024660-6A patent/BR112019024660A2/pt not_active Application Discontinuation
- 2018-05-25 CN CN201880034361.4A patent/CN110831917A/zh active Pending
- 2018-05-25 CA CA3064335A patent/CA3064335A1/en not_active Abandoned
- 2018-05-25 WO PCT/US2018/034717 patent/WO2018218186A1/en active Application Filing
- 2018-05-25 AU AU2018273972A patent/AU2018273972B2/en not_active Ceased
- 2018-05-25 BR BR112019024644A patent/BR112019024644A2/pt not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
AU2018272055A1 (en) | 2020-01-16 |
RU2732752C1 (ru) | 2020-09-22 |
EP3634927A1 (en) | 2020-04-15 |
CA3064335A1 (en) | 2018-11-29 |
EP3634925A1 (en) | 2020-04-15 |
CA3064326A1 (en) | 2018-11-29 |
RU2733385C1 (ru) | 2020-10-01 |
US10858301B2 (en) | 2020-12-08 |
AU2018273972B2 (en) | 2020-10-29 |
WO2018218186A1 (en) | 2018-11-29 |
CN110831916A (zh) | 2020-02-21 |
AU2018272065A1 (en) | 2020-01-16 |
US11078136B2 (en) | 2021-08-03 |
EP3634926A1 (en) | 2020-04-15 |
AU2018273972A1 (en) | 2020-01-16 |
US20210163503A1 (en) | 2021-06-03 |
CN110831917A (zh) | 2020-02-21 |
AU2018272065B2 (en) | 2020-08-13 |
US20200095179A1 (en) | 2020-03-26 |
BR112019024652A2 (pt) | 2020-06-09 |
CN110869338A (zh) | 2020-03-06 |
AU2018272055B2 (en) | 2020-10-22 |
WO2018218171A1 (en) | 2018-11-29 |
CA3064336A1 (en) | 2018-11-29 |
RU2733408C1 (ru) | 2020-10-01 |
US11814348B2 (en) | 2023-11-14 |
US20200095183A1 (en) | 2020-03-26 |
BR112019024660A2 (pt) | 2020-06-16 |
WO2018218176A1 (en) | 2018-11-29 |
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B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] | ||
B11B | Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements |